DE2204066A1 - Polymere Zinn(II)-glycoloxide und Verfahren zu ihrer Herstellung - Google Patents
Polymere Zinn(II)-glycoloxide und Verfahren zu ihrer HerstellungInfo
- Publication number
- DE2204066A1 DE2204066A1 DE19722204066 DE2204066A DE2204066A1 DE 2204066 A1 DE2204066 A1 DE 2204066A1 DE 19722204066 DE19722204066 DE 19722204066 DE 2204066 A DE2204066 A DE 2204066A DE 2204066 A1 DE2204066 A1 DE 2204066A1
- Authority
- DE
- Germany
- Prior art keywords
- tin
- glycol
- oxide
- polymeric
- radical
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 title claims description 69
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 title claims description 29
- IUTCEZPPWBHGIX-UHFFFAOYSA-N tin(2+) Chemical compound [Sn+2] IUTCEZPPWBHGIX-UHFFFAOYSA-N 0.000 title claims description 14
- 238000000034 method Methods 0.000 title claims description 11
- 238000002360 preparation method Methods 0.000 title description 3
- QHGNHLZPVBIIPX-UHFFFAOYSA-N tin(ii) oxide Chemical compound [Sn]=O QHGNHLZPVBIIPX-UHFFFAOYSA-N 0.000 claims description 21
- 238000006243 chemical reaction Methods 0.000 claims description 13
- 239000011541 reaction mixture Substances 0.000 claims description 9
- 238000010992 reflux Methods 0.000 claims description 7
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 229920000642 polymer Polymers 0.000 claims description 6
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical group [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 5
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 3
- 239000004215 Carbon black (E152) Substances 0.000 claims description 2
- 229930195733 hydrocarbon Natural products 0.000 claims description 2
- -1 hydrocarbon radical Chemical class 0.000 claims description 2
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical group C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 1
- 150000001721 carbon Chemical group 0.000 claims 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims 1
- 150000003254 radicals Chemical class 0.000 claims 1
- 229910052718 tin Inorganic materials 0.000 claims 1
- 239000003054 catalyst Substances 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000000203 mixture Substances 0.000 description 5
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- 239000003085 diluting agent Substances 0.000 description 4
- 150000002334 glycols Chemical class 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- QPKOBORKPHRBPS-UHFFFAOYSA-N bis(2-hydroxyethyl) terephthalate Chemical compound OCCOC(=O)C1=CC=C(C(=O)OCCO)C=C1 QPKOBORKPHRBPS-UHFFFAOYSA-N 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 2
- 238000002845 discoloration Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 238000006068 polycondensation reaction Methods 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000011343 solid material Substances 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- RRQYJINTUHWNHW-UHFFFAOYSA-N 1-ethoxy-2-(2-ethoxyethoxy)ethane Chemical compound CCOCCOCCOCC RRQYJINTUHWNHW-UHFFFAOYSA-N 0.000 description 1
- FPZWZCWUIYYYBU-UHFFFAOYSA-N 2-(2-ethoxyethoxy)ethyl acetate Chemical compound CCOCCOCCOC(C)=O FPZWZCWUIYYYBU-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N carbon dioxide Natural products O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 229920006037 cross link polymer Polymers 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000008034 disappearance Effects 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002430 hydrocarbons Chemical group 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000003701 inert diluent Substances 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000012768 molten material Substances 0.000 description 1
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 1
- 239000012454 non-polar solvent Substances 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 235000013772 propylene glycol Nutrition 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G79/00—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule
- C08G79/12—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule a linkage containing tin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyesters Or Polycarbonates (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11204571A | 1971-02-02 | 1971-02-02 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2204066A1 true DE2204066A1 (de) | 1972-09-14 |
Family
ID=22341845
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19722204066 Withdrawn DE2204066A1 (de) | 1971-02-02 | 1972-01-28 | Polymere Zinn(II)-glycoloxide und Verfahren zu ihrer Herstellung |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US3706774A (enExample) |
| BR (1) | BR7200515D0 (enExample) |
| CA (1) | CA978689A (enExample) |
| DE (1) | DE2204066A1 (enExample) |
| ES (1) | ES399378A1 (enExample) |
| FR (1) | FR2124371B1 (enExample) |
| GB (1) | GB1314807A (enExample) |
| IT (1) | IT955126B (enExample) |
| LU (1) | LU64700A1 (enExample) |
| NL (1) | NL167708C (enExample) |
| ZA (1) | ZA72237B (enExample) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8405049D0 (en) * | 1984-02-27 | 1984-04-04 | Raychem Ltd | Organic polymers |
| GB8514330D0 (en) * | 1985-06-06 | 1985-07-10 | Bp Chem Int Ltd | Polymer composition |
| US5442092A (en) * | 1994-04-04 | 1995-08-15 | Jame Fine Chemicals, Inc. | Preparation of esters of 3,5,6-trichlorosalicyclic acid |
| EP3950768A4 (en) * | 2019-04-05 | 2023-01-11 | Hyosung Tnc Corporation | POLYESTER POLYMERIZATION CATALYST AND PROCESS FOR MAKING POLYESTER WITH IT |
| KR102225086B1 (ko) * | 2019-04-05 | 2021-03-10 | 효성티앤씨 주식회사 | 폴리에스터 중합 촉매 및 이를 이용한 폴리에스터의 제조방법 |
| KR102621249B1 (ko) * | 2020-08-19 | 2024-01-08 | 효성티앤씨 주식회사 | 폴리에스터 원사 및 그의 제조방법 |
| US20230295841A1 (en) * | 2020-08-19 | 2023-09-21 | Hyosung TNC Corporation | Polyester yarn and method for manufacturing same |
-
1971
- 1971-02-02 US US112045A patent/US3706774A/en not_active Expired - Lifetime
-
1972
- 1972-01-13 ZA ZA720237A patent/ZA72237B/xx unknown
- 1972-01-26 NL NL7201073A patent/NL167708C/xx not_active IP Right Cessation
- 1972-01-28 DE DE19722204066 patent/DE2204066A1/de not_active Withdrawn
- 1972-01-31 BR BR515/72A patent/BR7200515D0/pt unknown
- 1972-01-31 IT IT9332/72A patent/IT955126B/it active
- 1972-02-01 ES ES399378A patent/ES399378A1/es not_active Expired
- 1972-02-01 LU LU64700D patent/LU64700A1/xx unknown
- 1972-02-01 CA CA133,643A patent/CA978689A/en not_active Expired
- 1972-02-02 GB GB491172A patent/GB1314807A/en not_active Expired
- 1972-02-02 FR FR7203420A patent/FR2124371B1/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| IT955126B (it) | 1973-09-29 |
| ES399378A1 (es) | 1974-12-01 |
| US3706774A (en) | 1972-12-19 |
| BR7200515D0 (pt) | 1973-09-25 |
| FR2124371A1 (enExample) | 1972-09-22 |
| FR2124371B1 (enExample) | 1977-09-02 |
| CA978689A (en) | 1975-11-25 |
| NL7201073A (enExample) | 1972-08-04 |
| NL167708B (nl) | 1981-08-17 |
| NL167708C (nl) | 1982-01-18 |
| LU64700A1 (enExample) | 1972-06-29 |
| ZA72237B (en) | 1972-10-25 |
| GB1314807A (en) | 1973-04-26 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OGA | New person/name/address of the applicant | ||
| OD | Request for examination | ||
| 8139 | Disposal/non-payment of the annual fee |