DE2161252C3 - Verfahren zur Ortho-Methylierung von Phenolen - Google Patents

Verfahren zur Ortho-Methylierung von Phenolen

Info

Publication number
DE2161252C3
DE2161252C3 DE2161252A DE2161252A DE2161252C3 DE 2161252 C3 DE2161252 C3 DE 2161252C3 DE 2161252 A DE2161252 A DE 2161252A DE 2161252 A DE2161252 A DE 2161252A DE 2161252 C3 DE2161252 C3 DE 2161252C3
Authority
DE
Germany
Prior art keywords
catalyst
phenol
reaction
iron
oxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DE2161252A
Other languages
German (de)
English (en)
Other versions
DE2161252B2 (de
DE2161252A1 (de
Inventor
Shinichi Izawa
Hitoshi Ageoshi Saitama Nakajiama
Fujio Nomura
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Asahi Kasei Corp
Original Assignee
Asahi Kasei Kogyo KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asahi Kasei Kogyo KK filed Critical Asahi Kasei Kogyo KK
Publication of DE2161252A1 publication Critical patent/DE2161252A1/de
Publication of DE2161252B2 publication Critical patent/DE2161252B2/de
Application granted granted Critical
Publication of DE2161252C3 publication Critical patent/DE2161252C3/de
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/847—Vanadium, niobium or tantalum or polonium
    • B01J23/8472—Vanadium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/11—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms
    • C07C37/16—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms by condensation involving hydroxy groups of phenols or alcohols or the ether or mineral ester group derived therefrom

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
DE2161252A 1970-12-11 1971-12-10 Verfahren zur Ortho-Methylierung von Phenolen Expired DE2161252C3 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP10938570 1970-12-11
JP11249170 1970-12-17
JP11249070 1970-12-17

Publications (3)

Publication Number Publication Date
DE2161252A1 DE2161252A1 (de) 1972-06-29
DE2161252B2 DE2161252B2 (de) 1974-02-21
DE2161252C3 true DE2161252C3 (de) 1974-10-03

Family

ID=27311459

Family Applications (1)

Application Number Title Priority Date Filing Date
DE2161252A Expired DE2161252C3 (de) 1970-12-11 1971-12-10 Verfahren zur Ortho-Methylierung von Phenolen

Country Status (5)

Country Link
US (1) US3855318A (enExample)
DE (1) DE2161252C3 (enExample)
FR (1) FR2117674A5 (enExample)
GB (2) GB1378179A (enExample)
IT (1) IT943869B (enExample)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3971832A (en) * 1970-07-17 1976-07-27 Mitsubishi Petrochemical Company Limited Process for producing ortho-methylphenols
DE2756461C2 (de) * 1977-12-17 1984-10-31 Rütgerswerke AG, 6000 Frankfurt Verfahren zur Herstellung von Mono-o-alkylphenolen
US4329517A (en) * 1979-05-16 1982-05-11 Mitsui Petrochemical Industries Ltd. Process for production of mono- or di-ortho-methyl-substituted phenols by catalytic methylation and catalyst therefor
JPS5663932A (en) * 1979-10-29 1981-05-30 Mitsui Toatsu Chem Inc Preparation of selectively ortho-alkylated phenol compound
DE3103665C2 (de) * 1981-02-04 1983-10-13 Union Rheinische Braunkohlen Kraftstoff AG, 5000 Köln Verfahren zur o-Methylierung von Phenolen und Katalysator zur Durchführung des Verfahrens
US4517389A (en) * 1982-08-10 1985-05-14 Asahi Kasei Kogyo Kabushiki Kaisha Process for methylating the ortho position of a phenol
KR960003790B1 (ko) * 1992-12-31 1996-03-22 한국과학기술원 신규한 변형 마그네슘 옥사이드 촉매 조성물 및 그의 제조방법
JP4294209B2 (ja) * 2000-09-18 2009-07-08 旭化成ケミカルズ株式会社 オルト位アルキル化ヒドロキシ芳香族化合物の製造方法
AU2003260344A1 (en) * 2002-08-02 2004-02-25 Vanetta S.P.A. Redox process particularly for the production of menadione and use of polyoxometalates
DE102011005228A1 (de) 2011-03-08 2012-09-13 Elantas Gmbh Verfahren zur Herstellung von alkylierten Hydroxyaromaten in Mikroreaktoren
CN118949985A (zh) * 2024-07-26 2024-11-15 天津大学 一种铁氧化物催化剂、酚和甲醇甲基化制备2,6-二甲酚联产邻甲酚催化剂的方法和应用

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2091483A (en) * 1934-11-02 1937-08-31 Sharples Solvents Corp Manufacture of secondary and tertiary alkyl phenols
US2435087A (en) * 1943-03-19 1948-01-27 Shell Dev Process for the separation of mixtures of alkyl phenols through selective alkylation
US2910515A (en) * 1958-10-24 1959-10-27 Universal Oil Prod Co Alkylation of aromatic compounds
NL264320A (enExample) * 1960-05-04
US3479410A (en) * 1967-05-18 1969-11-18 Gen Electric Selective vapor phase methylation of phenols
US3642912A (en) * 1967-12-11 1972-02-15 Coal Tar Research Ass The Alkylation of phenols

Also Published As

Publication number Publication date
US3855318A (en) 1974-12-17
DE2161252B2 (de) 1974-02-21
IT943869B (it) 1973-04-10
DE2161252A1 (de) 1972-06-29
FR2117674A5 (enExample) 1972-07-21
GB1378179A (en) 1974-12-27
GB1378180A (en) 1974-12-27

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Legal Events

Date Code Title Description
C3 Grant after two publication steps (3rd publication)
E77 Valid patent as to the heymanns-index 1977
8339 Ceased/non-payment of the annual fee