DE2152366B2 - Glasklare thermoplastische Formmassen mit erhöhter Wärmeformbeständigkeit - Google Patents
Glasklare thermoplastische Formmassen mit erhöhter WärmeformbeständigkeitInfo
- Publication number
- DE2152366B2 DE2152366B2 DE19712152366 DE2152366A DE2152366B2 DE 2152366 B2 DE2152366 B2 DE 2152366B2 DE 19712152366 DE19712152366 DE 19712152366 DE 2152366 A DE2152366 A DE 2152366A DE 2152366 B2 DE2152366 B2 DE 2152366B2
- Authority
- DE
- Germany
- Prior art keywords
- weight
- percent
- acrylonitrile
- heat resistance
- thermoplastic molding
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 238000009757 thermoplastic moulding Methods 0.000 title claims description 7
- 150000001875 compounds Chemical class 0.000 title claims description 4
- 239000013078 crystal Substances 0.000 title claims 2
- 239000000203 mixture Substances 0.000 claims description 29
- 229920001577 copolymer Polymers 0.000 claims description 21
- 229920000642 polymer Polymers 0.000 claims description 18
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 17
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 16
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims description 8
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 22
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 10
- 239000004800 polyvinyl chloride Substances 0.000 description 10
- 229920000915 polyvinyl chloride Polymers 0.000 description 10
- 229920000578 graft copolymer Polymers 0.000 description 8
- 229920001971 elastomer Polymers 0.000 description 7
- 239000000178 monomer Substances 0.000 description 6
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 5
- 238000002156 mixing Methods 0.000 description 4
- 238000000465 moulding Methods 0.000 description 4
- 239000005060 rubber Substances 0.000 description 4
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 3
- 239000004801 Chlorinated PVC Substances 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- 239000000806 elastomer Substances 0.000 description 3
- 229920001519 homopolymer Polymers 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- 229920006222 acrylic ester polymer Polymers 0.000 description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 230000009477 glass transition Effects 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- -1 methyl- Chemical group 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- PRIUALOJYOZZOJ-UHFFFAOYSA-L 2-ethylhexyl 2-[dibutyl-[2-(2-ethylhexoxy)-2-oxoethyl]sulfanylstannyl]sulfanylacetate Chemical compound CCCCC(CC)COC(=O)CS[Sn](CCCC)(CCCC)SCC(=O)OCC(CC)CCCC PRIUALOJYOZZOJ-UHFFFAOYSA-L 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000005250 alkyl acrylate group Chemical group 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 241001233037 catfish Species 0.000 description 1
- 229920000457 chlorinated polyvinyl chloride Polymers 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
- 229920006352 transparent thermoplastic Polymers 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/16—Homopolymers or copolymers of alkyl-substituted styrenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19712152366 DE2152366B2 (de) | 1971-10-21 | 1971-10-21 | Glasklare thermoplastische Formmassen mit erhöhter Wärmeformbeständigkeit |
| NL7115851A NL7115851A (OSRAM) | 1971-10-21 | 1971-11-17 | |
| BE789404D BE789404A (fr) | 1971-10-21 | 1972-09-28 | Matieres a mouler thermoplastiques a stabilite dimensionnelle achaud amelioree |
| IT5344872A IT972380B (it) | 1971-10-21 | 1972-10-18 | Masse sagomabili termoplastiche con elevata termostabilita dimensionale |
| FR7237082A FR2156832B1 (OSRAM) | 1971-10-21 | 1972-10-19 | |
| GB4838372A GB1400848A (en) | 1971-10-21 | 1972-10-20 | Transparent thermoplastic moulding compositions having high heat distortion strength |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19712152366 DE2152366B2 (de) | 1971-10-21 | 1971-10-21 | Glasklare thermoplastische Formmassen mit erhöhter Wärmeformbeständigkeit |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2152366A1 DE2152366A1 (de) | 1973-05-03 |
| DE2152366B2 true DE2152366B2 (de) | 1974-09-05 |
Family
ID=5822939
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19712152366 Ceased DE2152366B2 (de) | 1971-10-21 | 1971-10-21 | Glasklare thermoplastische Formmassen mit erhöhter Wärmeformbeständigkeit |
Country Status (6)
| Country | Link |
|---|---|
| BE (1) | BE789404A (OSRAM) |
| DE (1) | DE2152366B2 (OSRAM) |
| FR (1) | FR2156832B1 (OSRAM) |
| GB (1) | GB1400848A (OSRAM) |
| IT (1) | IT972380B (OSRAM) |
| NL (1) | NL7115851A (OSRAM) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3022400A1 (de) * | 1980-06-14 | 1982-01-07 | Basf Ag, 6700 Ludwigshafen | Thermoplastische formmassen, verfahren zu deren herstellung sowie formteile aus diesen |
| JPS5839455B2 (ja) * | 1980-06-28 | 1983-08-30 | 鐘淵化学工業株式会社 | 熱可塑性樹脂組成物 |
| US4464514A (en) * | 1983-04-29 | 1984-08-07 | Mobil Oil Corporation | High clarity blends of polyvinyl chloride and para-methylstyrene-acrylonitrile copolymer |
| DE3912974A1 (de) * | 1989-04-20 | 1990-10-25 | Basf Ag | Thermoplastische formmassen auf basis von vinylchlorid |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3053800A (en) * | 1959-05-04 | 1962-09-11 | Borg Warner | Blends of (1) polyvinylchloride, (2) a copolymer of polybutadiene, styrene and acrylonitrile and (3) a copolymer of acrylonitrile, styrene and alpha methyl styrene |
| FR1410009A (fr) * | 1963-10-04 | 1965-09-03 | Dow Chemical Co | Composition de moulage contenant un polymère de chlorure de vinyle |
| FR1478490A (fr) * | 1966-03-04 | 1967-04-28 | Kulhmann Ets | Compositions thermoplastiques améliorées contenant du chlorure de polyvinyle |
-
1971
- 1971-10-21 DE DE19712152366 patent/DE2152366B2/de not_active Ceased
- 1971-11-17 NL NL7115851A patent/NL7115851A/xx unknown
-
1972
- 1972-09-28 BE BE789404D patent/BE789404A/xx unknown
- 1972-10-18 IT IT5344872A patent/IT972380B/it active
- 1972-10-19 FR FR7237082A patent/FR2156832B1/fr not_active Expired
- 1972-10-20 GB GB4838372A patent/GB1400848A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| GB1400848A (en) | 1975-07-16 |
| NL7115851A (OSRAM) | 1972-01-25 |
| IT972380B (it) | 1974-05-20 |
| FR2156832B1 (OSRAM) | 1977-01-14 |
| DE2152366A1 (de) | 1973-05-03 |
| BE789404A (fr) | 1973-01-15 |
| FR2156832A1 (OSRAM) | 1973-06-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| BHV | Refusal |