DE2152097A1 - Verfahren zur kontinuierlichen Behandlung von Koksofengas - Google Patents
Verfahren zur kontinuierlichen Behandlung von KoksofengasInfo
- Publication number
- DE2152097A1 DE2152097A1 DE19712152097 DE2152097A DE2152097A1 DE 2152097 A1 DE2152097 A1 DE 2152097A1 DE 19712152097 DE19712152097 DE 19712152097 DE 2152097 A DE2152097 A DE 2152097A DE 2152097 A1 DE2152097 A1 DE 2152097A1
- Authority
- DE
- Germany
- Prior art keywords
- ozone
- coke oven
- oven gas
- gas
- nitrogen oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims description 27
- 239000000571 coke Substances 0.000 title claims description 20
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 claims description 125
- 239000007789 gas Substances 0.000 claims description 45
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims description 44
- 239000001301 oxygen Substances 0.000 claims description 11
- 229910052760 oxygen Inorganic materials 0.000 claims description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 9
- 150000001875 compounds Chemical class 0.000 claims description 9
- 239000001257 hydrogen Substances 0.000 claims description 5
- 229910052739 hydrogen Inorganic materials 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
- 239000000306 component Substances 0.000 claims 1
- 238000002347 injection Methods 0.000 description 10
- 239000007924 injection Substances 0.000 description 10
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- 238000001816 cooling Methods 0.000 description 7
- 230000009467 reduction Effects 0.000 description 7
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- 238000009826 distribution Methods 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- 229910021529 ammonia Inorganic materials 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000003245 coal Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 238000010924 continuous production Methods 0.000 description 2
- HGCIXCUEYOPUTN-UHFFFAOYSA-N cyclohexene Chemical compound C1CCC=CC1 HGCIXCUEYOPUTN-UHFFFAOYSA-N 0.000 description 2
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004155 Chlorine dioxide Substances 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- ODUCDPQEXGNKDN-UHFFFAOYSA-N Nitrogen oxide(NO) Natural products O=N ODUCDPQEXGNKDN-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000002730 additional effect Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 239000012159 carrier gas Substances 0.000 description 1
- 235000019398 chlorine dioxide Nutrition 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- -1 ethylene, propylene, Butadiene Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 231100000817 safety factor Toxicity 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/54—Nitrogen compounds
- B01D53/56—Nitrogen oxides
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- Industrial Gases (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Treating Waste Gases (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US8194570A | 1970-10-19 | 1970-10-19 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2152097A1 true DE2152097A1 (de) | 1972-04-27 |
Family
ID=22167410
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19712152097 Pending DE2152097A1 (de) | 1970-10-19 | 1971-10-19 | Verfahren zur kontinuierlichen Behandlung von Koksofengas |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US3773897A (enExample) |
| CA (1) | CA965222A (enExample) |
| DE (1) | DE2152097A1 (enExample) |
| FR (1) | FR2111247A5 (enExample) |
| GB (1) | GB1356147A (enExample) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS49126566A (enExample) * | 1973-04-10 | 1974-12-04 | ||
| US4055624A (en) * | 1973-10-03 | 1977-10-25 | Hodogaya Chemical Co., Ltd. | Process for removing nitrogen oxides from gaseous mixtures |
| US3961018A (en) * | 1973-12-06 | 1976-06-01 | United Air Specialists, Inc. | Method for purification of gas streams by removal of acidic gases |
| JPS5643771B2 (enExample) * | 1973-12-18 | 1981-10-15 | ||
| JPS5217824B2 (enExample) * | 1974-04-19 | 1977-05-18 | ||
| GB1505169A (en) * | 1974-11-02 | 1978-03-30 | Fuji Kasui Eng Co Ltd | Process for removing nitrogen oxides from waste gas |
| US4247321A (en) * | 1979-05-21 | 1981-01-27 | Persinger James G | Method and apparatus for obtaining fertilizing solution from fossil fueled stationary engines |
| US8449288B2 (en) * | 2003-03-19 | 2013-05-28 | Nalco Mobotec, Inc. | Urea-based mixing process for increasing combustion efficiency and reduction of nitrogen oxides (NOx) |
| US7670569B2 (en) * | 2003-06-13 | 2010-03-02 | Mobotec Usa, Inc. | Combustion furnace humidification devices, systems & methods |
| US8353698B2 (en) * | 2003-06-13 | 2013-01-15 | Nalco Mobotec, Inc. | Co-axial injection system |
| US7537743B2 (en) * | 2004-02-14 | 2009-05-26 | Mobotec Usa, Inc. | Method for in-furnace regulation of SO3 in catalytic NOx reducing systems |
| US20050178303A1 (en) * | 2004-02-14 | 2005-08-18 | Higgins Brian S. | Method for in-furnace reduction and control of sulfur trioxide |
| US8251694B2 (en) * | 2004-02-14 | 2012-08-28 | Nalco Mobotec, Inc. | Method for in-furnace reduction flue gas acidity |
| US7410356B2 (en) | 2005-11-17 | 2008-08-12 | Mobotec Usa, Inc. | Circulating fluidized bed boiler having improved reactant utilization |
| US8069824B2 (en) * | 2008-06-19 | 2011-12-06 | Nalco Mobotec, Inc. | Circulating fluidized bed boiler and method of operation |
| CN109569232A (zh) * | 2018-12-18 | 2019-04-05 | 中国科学院过程工程研究所 | 一种气动式臭氧分布器及烟道 |
-
1970
- 1970-10-19 US US00081945A patent/US3773897A/en not_active Expired - Lifetime
-
1971
- 1971-10-04 GB GB4613171A patent/GB1356147A/en not_active Expired
- 1971-10-05 CA CA124,492A patent/CA965222A/en not_active Expired
- 1971-10-12 FR FR7136564A patent/FR2111247A5/fr not_active Expired
- 1971-10-19 DE DE19712152097 patent/DE2152097A1/de active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| FR2111247A5 (enExample) | 1972-06-02 |
| US3773897A (en) | 1973-11-20 |
| GB1356147A (en) | 1974-06-12 |
| CA965222A (en) | 1975-04-01 |
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