DE2151793A1 - Verfahren zur Entfernung von Schwefelverbindungen in der Form von Schwefeloxyden aus Gasen oder Gasgemischen,die eine oder mehrere gasfoermige Schwefelverbindungen enthalten,sowie eine zu diesem Zweck geeignete Vorrichtung - Google Patents
Verfahren zur Entfernung von Schwefelverbindungen in der Form von Schwefeloxyden aus Gasen oder Gasgemischen,die eine oder mehrere gasfoermige Schwefelverbindungen enthalten,sowie eine zu diesem Zweck geeignete VorrichtungInfo
- Publication number
- DE2151793A1 DE2151793A1 DE19712151793 DE2151793A DE2151793A1 DE 2151793 A1 DE2151793 A1 DE 2151793A1 DE 19712151793 DE19712151793 DE 19712151793 DE 2151793 A DE2151793 A DE 2151793A DE 2151793 A1 DE2151793 A1 DE 2151793A1
- Authority
- DE
- Germany
- Prior art keywords
- gas
- gases
- layer
- contact
- acceptor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000007789 gas Substances 0.000 title claims description 229
- 238000000034 method Methods 0.000 title claims description 55
- 150000003464 sulfur compounds Chemical class 0.000 title claims description 26
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 title claims description 26
- 229910052815 sulfur oxide Inorganic materials 0.000 title claims description 26
- 239000000203 mixture Substances 0.000 title claims description 17
- 230000001590 oxidative effect Effects 0.000 claims description 38
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 claims description 32
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 29
- 239000001301 oxygen Substances 0.000 claims description 29
- 229910052760 oxygen Inorganic materials 0.000 claims description 29
- 238000011068 loading method Methods 0.000 claims description 18
- 230000008929 regeneration Effects 0.000 claims description 18
- 238000011069 regeneration method Methods 0.000 claims description 18
- 239000011261 inert gas Substances 0.000 claims description 16
- 229910052751 metal Inorganic materials 0.000 claims description 12
- 239000002184 metal Substances 0.000 claims description 12
- 239000007787 solid Substances 0.000 claims description 10
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 8
- 229910000037 hydrogen sulfide Inorganic materials 0.000 claims description 8
- 150000002736 metal compounds Chemical class 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 6
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 4
- 238000004891 communication Methods 0.000 claims description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 2
- 239000001569 carbon dioxide Substances 0.000 claims description 2
- 230000006698 induction Effects 0.000 claims 1
- 239000000575 pesticide Substances 0.000 claims 1
- 108090000623 proteins and genes Proteins 0.000 claims 1
- 239000000370 acceptor Substances 0.000 description 71
- 239000000567 combustion gas Substances 0.000 description 11
- 239000000126 substance Substances 0.000 description 10
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 8
- 230000003647 oxidation Effects 0.000 description 8
- 238000007254 oxidation reaction Methods 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000010949 copper Substances 0.000 description 5
- 239000011521 glass Substances 0.000 description 5
- 238000005192 partition Methods 0.000 description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 4
- 229910052802 copper Inorganic materials 0.000 description 4
- 238000007789 sealing Methods 0.000 description 4
- 230000003197 catalytic effect Effects 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 229910052976 metal sulfide Inorganic materials 0.000 description 2
- 239000003345 natural gas Substances 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 239000005751 Copper oxide Substances 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- YAIQCYZCSGLAAN-UHFFFAOYSA-N [Si+4].[O-2].[Al+3] Chemical compound [Si+4].[O-2].[Al+3] YAIQCYZCSGLAAN-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229910001570 bauxite Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229910000431 copper oxide Inorganic materials 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000012717 electrostatic precipitator Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000010881 fly ash Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- -1 hydrogen sulfide Chemical class 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- ZADYMNAVLSWLEQ-UHFFFAOYSA-N magnesium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[Mg+2].[Si+4] ZADYMNAVLSWLEQ-UHFFFAOYSA-N 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000006187 pill Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/48—Sulfur dioxide; Sulfurous acid
- C01B17/50—Preparation of sulfur dioxide
- C01B17/60—Isolation of sulfur dioxide from gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/0407—Constructional details of adsorbing systems
- B01D53/0423—Beds in columns
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/0407—Constructional details of adsorbing systems
- B01D53/0446—Means for feeding or distributing gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/28—Moving reactors, e.g. rotary drums
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/30—Sulfur compounds
- B01D2257/302—Sulfur oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40003—Methods relating to valve switching
- B01D2259/40005—Methods relating to valve switching using rotary valves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/403—Further details for adsorption processes and devices using three beds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00121—Controlling the temperature by direct heating or cooling
- B01J2219/00123—Controlling the temperature by direct heating or cooling adding a temperature modifying medium to the reactants
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inorganic Chemistry (AREA)
- Treating Waste Gases (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL7015312A NL7015312A (https=) | 1970-10-19 | 1970-10-19 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2151793A1 true DE2151793A1 (de) | 1972-04-20 |
Family
ID=19811332
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19712151793 Pending DE2151793A1 (de) | 1970-10-19 | 1971-10-18 | Verfahren zur Entfernung von Schwefelverbindungen in der Form von Schwefeloxyden aus Gasen oder Gasgemischen,die eine oder mehrere gasfoermige Schwefelverbindungen enthalten,sowie eine zu diesem Zweck geeignete Vorrichtung |
Country Status (6)
| Country | Link |
|---|---|
| BE (1) | BE773741A (https=) |
| CA (1) | CA957830A (https=) |
| DE (1) | DE2151793A1 (https=) |
| FR (1) | FR2111485A5 (https=) |
| GB (1) | GB1367941A (https=) |
| NL (1) | NL7015312A (https=) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102010049487B3 (de) * | 2010-10-27 | 2012-01-26 | Mann + Hummel Protec Gmbh | Vorrichtung zum Trocknen von Fluid und Verfahren zum Betreiben derselben |
| CN108585141A (zh) * | 2018-04-02 | 2018-09-28 | 宁波帝杨电子科技有限公司 | 一种上下罐体分离的利用定量明矾进行污水处理的装置 |
| CN108658187A (zh) * | 2018-04-02 | 2018-10-16 | 宁波帝杨电子科技有限公司 | 一种上下罐体分离的利用明矾进行污水处理的装置 |
| CN108675414A (zh) * | 2018-04-02 | 2018-10-19 | 宁波帝杨电子科技有限公司 | 一种通过分离上罐体和下罐体进行污水处理的装置 |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3713844C2 (de) * | 1986-04-24 | 1997-04-17 | Mitsubishi Heavy Ind Ltd | Verfahren zum Reinigen eines Hochtemperatur-Reduktionsgases |
| US5248325A (en) * | 1991-05-09 | 1993-09-28 | Mitsubishi Jukogyo Kabushiki Kaisha | Gas separating system and gas recovery system |
| NL1003504C2 (nl) * | 1996-07-04 | 1998-01-07 | Univ Delft Tech | Roterende reactor en toepassing daarvan. |
| DE69902695T2 (de) | 1998-12-29 | 2003-07-31 | Shell Internationale Research Maatschappij B.V., Den Haag | Katalytischer reaktor |
| US7491380B2 (en) | 2001-06-21 | 2009-02-17 | Shell Oil Company | Catalytic reactor |
| CN107051200A (zh) * | 2016-12-28 | 2017-08-18 | 华电电力科学研究院 | 一种应用于scr脱硝系统的旋转式喷氨格栅 |
| CN110694429A (zh) * | 2019-10-11 | 2020-01-17 | 海口海关热带植物隔离检疫中心 | 一种熏蒸剂溴甲烷活性炭纤维吸附回收设备 |
| CN112516750A (zh) * | 2020-12-16 | 2021-03-19 | 吴廷贵 | 一种用于烟气净化的环保装置 |
-
1970
- 1970-10-19 NL NL7015312A patent/NL7015312A/xx unknown
-
1971
- 1971-10-11 BE BE773741A patent/BE773741A/nl unknown
- 1971-10-18 FR FR7137312A patent/FR2111485A5/fr not_active Expired
- 1971-10-18 CA CA125,406A patent/CA957830A/en not_active Expired
- 1971-10-18 GB GB4825171A patent/GB1367941A/en not_active Expired
- 1971-10-18 DE DE19712151793 patent/DE2151793A1/de active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102010049487B3 (de) * | 2010-10-27 | 2012-01-26 | Mann + Hummel Protec Gmbh | Vorrichtung zum Trocknen von Fluid und Verfahren zum Betreiben derselben |
| CN108585141A (zh) * | 2018-04-02 | 2018-09-28 | 宁波帝杨电子科技有限公司 | 一种上下罐体分离的利用定量明矾进行污水处理的装置 |
| CN108658187A (zh) * | 2018-04-02 | 2018-10-16 | 宁波帝杨电子科技有限公司 | 一种上下罐体分离的利用明矾进行污水处理的装置 |
| CN108675414A (zh) * | 2018-04-02 | 2018-10-19 | 宁波帝杨电子科技有限公司 | 一种通过分离上罐体和下罐体进行污水处理的装置 |
| CN108585141B (zh) * | 2018-04-02 | 2021-03-09 | 张倩瑜 | 一种上下罐体分离的利用定量明矾进行污水处理的装置 |
| CN108658187B (zh) * | 2018-04-02 | 2021-03-12 | 王玉涛 | 一种上下罐体分离的利用明矾进行污水处理的装置 |
| CN108675414B (zh) * | 2018-04-02 | 2021-09-21 | 宁波帝杨电子科技有限公司 | 一种通过分离上罐体和下罐体进行污水处理的装置 |
Also Published As
| Publication number | Publication date |
|---|---|
| GB1367941A (en) | 1974-09-25 |
| BE773741A (nl) | 1972-04-11 |
| FR2111485A5 (https=) | 1972-06-02 |
| CA957830A (en) | 1974-11-19 |
| NL7015312A (https=) | 1972-04-21 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OD | Request for examination | ||
| OHN | Withdrawal |