DE2134116C3 - Verfahren zur Reduktion von Nickel- und CobaHoxyden - Google Patents
Verfahren zur Reduktion von Nickel- und CobaHoxydenInfo
- Publication number
- DE2134116C3 DE2134116C3 DE2134116A DE2134116A DE2134116C3 DE 2134116 C3 DE2134116 C3 DE 2134116C3 DE 2134116 A DE2134116 A DE 2134116A DE 2134116 A DE2134116 A DE 2134116A DE 2134116 C3 DE2134116 C3 DE 2134116C3
- Authority
- DE
- Germany
- Prior art keywords
- nickel
- cobalt
- briquettes
- oxide
- oxides
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title claims description 45
- 229910052759 nickel Inorganic materials 0.000 title claims description 20
- 238000000034 method Methods 0.000 title claims description 16
- 229910000480 nickel oxide Inorganic materials 0.000 claims description 25
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 claims description 24
- 230000001603 reducing effect Effects 0.000 claims description 19
- 239000000446 fuel Substances 0.000 claims description 14
- 239000007788 liquid Substances 0.000 claims description 13
- 229910017052 cobalt Inorganic materials 0.000 claims description 12
- 239000010941 cobalt Substances 0.000 claims description 12
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 12
- 238000010438 heat treatment Methods 0.000 claims description 11
- 239000008188 pellet Substances 0.000 claims description 11
- 229930195733 hydrocarbon Natural products 0.000 claims description 10
- 150000002430 hydrocarbons Chemical class 0.000 claims description 10
- 239000003638 chemical reducing agent Substances 0.000 claims description 8
- 229910000428 cobalt oxide Inorganic materials 0.000 claims description 8
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 claims description 8
- 230000001590 oxidative effect Effects 0.000 claims description 7
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 6
- 239000000428 dust Substances 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 5
- 230000015572 biosynthetic process Effects 0.000 claims description 5
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 4
- 238000002485 combustion reaction Methods 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- 230000005855 radiation Effects 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 150000002736 metal compounds Chemical class 0.000 claims description 3
- 239000004484 Briquette Substances 0.000 claims description 2
- 239000004215 Carbon black (E152) Substances 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 2
- -1 carbon halide Chemical class 0.000 claims description 2
- 238000002386 leaching Methods 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 238000005453 pelletization Methods 0.000 claims description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims 4
- 150000004679 hydroxides Chemical class 0.000 claims 3
- 229910044991 metal oxide Inorganic materials 0.000 claims 3
- 150000004706 metal oxides Chemical class 0.000 claims 3
- 238000001556 precipitation Methods 0.000 claims 2
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 claims 1
- 241000196324 Embryophyta Species 0.000 claims 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims 1
- 240000008042 Zea mays Species 0.000 claims 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 235000012501 ammonium carbonate Nutrition 0.000 claims 1
- 239000001099 ammonium carbonate Substances 0.000 claims 1
- 238000004140 cleaning Methods 0.000 claims 1
- 239000000567 combustion gas Substances 0.000 claims 1
- 235000005822 corn Nutrition 0.000 claims 1
- 238000002156 mixing Methods 0.000 claims 1
- 238000011946 reduction process Methods 0.000 claims 1
- 239000007789 gas Substances 0.000 description 17
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 239000011449 brick Substances 0.000 description 6
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 238000006722 reduction reaction Methods 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000003921 oil Substances 0.000 description 5
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 4
- 229910002091 carbon monoxide Inorganic materials 0.000 description 4
- 230000007935 neutral effect Effects 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- 239000001569 carbon dioxide Substances 0.000 description 3
- 239000003345 natural gas Substances 0.000 description 3
- 229910000008 nickel(II) carbonate Inorganic materials 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 229910021446 cobalt carbonate Inorganic materials 0.000 description 2
- 150000001869 cobalt compounds Chemical class 0.000 description 2
- ZOTKGJBKKKVBJZ-UHFFFAOYSA-L cobalt(2+);carbonate Chemical compound [Co+2].[O-]C([O-])=O ZOTKGJBKKKVBJZ-UHFFFAOYSA-L 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- ZULUUIKRFGGGTL-UHFFFAOYSA-L nickel(ii) carbonate Chemical compound [Ni+2].[O-]C([O-])=O ZULUUIKRFGGGTL-UHFFFAOYSA-L 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate group Chemical group S(=O)(=O)([O-])[O-] QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 229910021503 Cobalt(II) hydroxide Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 1
- 229910001981 cobalt nitrate Inorganic materials 0.000 description 1
- OBWXQDHWLMJOOD-UHFFFAOYSA-H cobalt(2+);dicarbonate;dihydroxide;hydrate Chemical compound O.[OH-].[OH-].[Co+2].[Co+2].[Co+2].[O-]C([O-])=O.[O-]C([O-])=O OBWXQDHWLMJOOD-UHFFFAOYSA-H 0.000 description 1
- ASKVAEGIVYSGNY-UHFFFAOYSA-L cobalt(ii) hydroxide Chemical compound [OH-].[OH-].[Co+2] ASKVAEGIVYSGNY-UHFFFAOYSA-L 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- BFDHFSHZJLFAMC-UHFFFAOYSA-L nickel(ii) hydroxide Chemical compound [OH-].[OH-].[Ni+2] BFDHFSHZJLFAMC-UHFFFAOYSA-L 0.000 description 1
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 230000000284 resting effect Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/005—Preliminary treatment of ores, e.g. by roasting or by the Krupp-Renn process
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Geochemistry & Mineralogy (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA087696A CA921265A (en) | 1970-07-08 | 1970-07-08 | Reduction of nickel oxide in a rotary hearth furnace |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE2134116A1 DE2134116A1 (de) | 1972-01-27 |
| DE2134116B2 DE2134116B2 (OSRAM) | 1974-05-16 |
| DE2134116C3 true DE2134116C3 (de) | 1975-01-02 |
Family
ID=4087155
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2134116A Expired DE2134116C3 (de) | 1970-07-08 | 1971-07-08 | Verfahren zur Reduktion von Nickel- und CobaHoxyden |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US3793005A (OSRAM) |
| JP (1) | JPS53364B1 (OSRAM) |
| CA (1) | CA921265A (OSRAM) |
| DE (1) | DE2134116C3 (OSRAM) |
| FR (1) | FR2098257B1 (OSRAM) |
| GB (1) | GB1327340A (OSRAM) |
| NO (1) | NO129683B (OSRAM) |
| PH (1) | PH9789A (OSRAM) |
| ZA (1) | ZA714232B (OSRAM) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1011955A (en) * | 1973-11-05 | 1977-06-14 | Inco Limited | Process for treatment of lateritic ores |
| AT370138B (de) * | 1981-03-05 | 1983-03-10 | Voest Alpine Ag | Verfahren zur rueckgewinnung von schwermetallen |
| US4597564A (en) * | 1985-05-23 | 1986-07-01 | The International Metals Reclamation Company, Inc. | Rotary hearth |
| RU2132400C1 (ru) * | 1998-09-03 | 1999-06-27 | Открытое акционерное общество "Серовский металлургический завод" | Способ переработки окисленных никелевых руд |
| RU2166555C1 (ru) * | 2000-08-22 | 2001-05-10 | Открытое акционерное общество "Кольская горно-металлургическая компания" | Способ переработки огарка обжига никелевого концентрата от флотационного разделения медно-никелевого файнштейна |
| RU2234546C1 (ru) * | 2003-01-17 | 2004-08-20 | Открытое акционерное общество "Уфалейникель" | Способ подготовки шихты к плавке для производства штейна из окисленных никелевых руд |
| DE10308269B4 (de) * | 2003-02-26 | 2015-06-11 | Thyssenkrupp Industrial Solutions Ag | Verfahren zur Gewinnung von Nickel |
| RU2359049C2 (ru) * | 2007-06-18 | 2009-06-20 | Открытое акционерное общество "Кольская горно-металлургическая компания" | Способ получения активного никелевого порошка |
| US10537885B2 (en) | 2014-07-02 | 2020-01-21 | Invista North America S.A.R.L. | Nickel metal particle production |
| EP3445488A1 (en) | 2016-04-22 | 2019-02-27 | INVISTA Textiles (U.K.) Limited | Heterogeneous catalyst process and nickel catalyst |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1871848A (en) * | 1930-03-06 | 1932-08-16 | Gustafsson Emil Gustaf Torvald | Process for producing metal sponge |
| US1983604A (en) * | 1934-01-13 | 1934-12-11 | John W Flannery | Production of refined metal |
| US2473795A (en) * | 1944-05-10 | 1949-06-21 | Nicaro Nickel Company | Reduction of ores containing nickel |
| US2850376A (en) * | 1954-12-28 | 1958-09-02 | Int Nickel Co | Treatment of nickel-containing laterite ores |
| US3030201A (en) * | 1960-09-02 | 1962-04-17 | Int Nickel Co | Method of producing ferro-nickel from nickel-containing silicate ores |
| US3188196A (en) * | 1963-06-19 | 1965-06-08 | Pullman Inc | Method for desiccating and reducing ore |
| DE1458771B2 (de) * | 1965-06-23 | 1973-01-04 | Metallgesellschaft Ag, 6000 Frankfurt | Verfahren zum Reduzieren von Eisenerzen im Drehrohrofen |
| DE1542305A1 (de) * | 1965-06-23 | 1970-04-30 | Metallgesellschaft Ag | Verfahren zur Durchfuehrung endothermer Reaktionen im Drehrohrofen |
| US3443931A (en) * | 1965-09-10 | 1969-05-13 | Midland Ross Corp | Process for making metallized pellets from iron oxide containing material |
| US3503735A (en) * | 1966-05-19 | 1970-03-31 | Hanna Mining Co | Process of recovering metallic nickel from nickeliferous lateritic ores |
| CA896902A (en) * | 1969-03-28 | 1972-04-04 | Curlook Walter | Rotary kiln reduction of limonitic ores |
| US3535105A (en) * | 1969-07-14 | 1970-10-20 | Falconbridge Nickel Mines Ltd | Recovery of ferronickel from oxidized ores |
| US3656935A (en) * | 1970-04-24 | 1972-04-18 | Univ Minnesota | Process for recovering nickel from nickel ores |
-
1970
- 1970-07-08 CA CA087696A patent/CA921265A/en not_active Expired
-
1971
- 1971-06-28 ZA ZA714232A patent/ZA714232B/xx unknown
- 1971-06-30 NO NO02486/71A patent/NO129683B/no unknown
- 1971-07-02 US US00159289A patent/US3793005A/en not_active Expired - Lifetime
- 1971-07-02 PH PH12596A patent/PH9789A/en unknown
- 1971-07-06 GB GB3172771A patent/GB1327340A/en not_active Expired
- 1971-07-08 FR FR7125110A patent/FR2098257B1/fr not_active Expired
- 1971-07-08 DE DE2134116A patent/DE2134116C3/de not_active Expired
- 1971-07-08 JP JP5065571A patent/JPS53364B1/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| FR2098257B1 (OSRAM) | 1974-10-31 |
| FR2098257A1 (OSRAM) | 1972-03-10 |
| DE2134116A1 (de) | 1972-01-27 |
| GB1327340A (en) | 1973-08-22 |
| US3793005A (en) | 1974-02-19 |
| CA921265A (en) | 1973-02-20 |
| JPS53364B1 (OSRAM) | 1978-01-07 |
| NO129683B (OSRAM) | 1974-05-13 |
| DE2134116B2 (OSRAM) | 1974-05-16 |
| PH9789A (en) | 1976-03-17 |
| ZA714232B (en) | 1972-04-26 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C3 | Grant after two publication steps (3rd publication) | ||
| E77 | Valid patent as to the heymanns-index 1977 | ||
| EHJ | Ceased/non-payment of the annual fee |