DE2037043B2 - Suspensionspolymerisation von Vinyl chlond - Google Patents
Suspensionspolymerisation von Vinyl chlondInfo
- Publication number
- DE2037043B2 DE2037043B2 DE19702037043 DE2037043A DE2037043B2 DE 2037043 B2 DE2037043 B2 DE 2037043B2 DE 19702037043 DE19702037043 DE 19702037043 DE 2037043 A DE2037043 A DE 2037043A DE 2037043 B2 DE2037043 B2 DE 2037043B2
- Authority
- DE
- Germany
- Prior art keywords
- vinyl chloride
- polymerization
- percent
- weight
- chloride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title claims description 47
- 239000000725 suspension Substances 0.000 title claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 31
- 238000006116 polymerization reaction Methods 0.000 claims description 22
- 239000000178 monomer Substances 0.000 claims description 11
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 10
- 239000004800 polyvinyl chloride Substances 0.000 claims description 10
- 230000001681 protective effect Effects 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 239000000084 colloidal system Substances 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 6
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 6
- 229920002554 vinyl polymer Polymers 0.000 claims description 6
- 239000003999 initiator Substances 0.000 claims description 5
- 229920000642 polymer Polymers 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- 238000010557 suspension polymerization reaction Methods 0.000 claims description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 3
- 229920001519 homopolymer Polymers 0.000 claims description 3
- 239000007900 aqueous suspension Substances 0.000 claims description 2
- 230000002411 adverse Effects 0.000 claims 1
- 238000013459 approach Methods 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 238000002474 experimental method Methods 0.000 description 6
- 238000012545 processing Methods 0.000 description 6
- 239000004014 plasticizer Substances 0.000 description 5
- 229920002689 polyvinyl acetate Polymers 0.000 description 4
- 101100117236 Drosophila melanogaster speck gene Proteins 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 229920003086 cellulose ether Polymers 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000011118 polyvinyl acetate Substances 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- OPQYOFWUFGEMRZ-UHFFFAOYSA-N tert-butyl 2,2-dimethylpropaneperoxoate Chemical compound CC(C)(C)OOC(=O)C(C)(C)C OPQYOFWUFGEMRZ-UHFFFAOYSA-N 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- HGCIXCUEYOPUTN-UHFFFAOYSA-N cyclohexene Chemical compound C1CCC=CC1 HGCIXCUEYOPUTN-UHFFFAOYSA-N 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical group CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 1
- 229920012485 Plasticized Polyvinyl chloride Polymers 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- 239000000337 buffer salt Substances 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- BSVQJWUUZCXSOL-UHFFFAOYSA-N cyclohexylsulfonyl ethaneperoxoate Chemical compound CC(=O)OOS(=O)(=O)C1CCCCC1 BSVQJWUUZCXSOL-UHFFFAOYSA-N 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000000546 pharmaceutical excipient Substances 0.000 description 1
- BWJUFXUULUEGMA-UHFFFAOYSA-N propan-2-yl propan-2-yloxycarbonyloxy carbonate Chemical compound CC(C)OC(=O)OOC(=O)OC(C)C BWJUFXUULUEGMA-UHFFFAOYSA-N 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 238000005029 sieve analysis Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/02—Monomers containing chlorine
- C08F14/04—Monomers containing two carbon atoms
- C08F14/06—Vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F259/00—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00
- C08F259/02—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00 on to polymers containing chlorine
- C08F259/04—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00 on to polymers containing chlorine on to polymers of vinyl chloride
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19702037043 DE2037043B2 (de) | 1970-07-25 | 1970-07-25 | Suspensionspolymerisation von Vinyl chlond |
| FR7124886A FR2100369A5 (enExample) | 1970-07-25 | 1971-07-07 | |
| BE769950A BE769950A (fr) | 1970-07-25 | 1971-07-13 | Polymerisation en suspension du chlorure de vinyle |
| GB3459671A GB1348426A (en) | 1970-07-25 | 1971-07-23 | Suspension polymerisation of vinyl chloride |
| NL7110204A NL153888B (nl) | 1970-07-25 | 1971-07-23 | Werkwijze voor de bereiding van vinylchloride-homopolymeren, alsmede voorwerpen geheel of gedeeltelijk vervaardigd van het aldus verkregen polyvinylchloride. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19702037043 DE2037043B2 (de) | 1970-07-25 | 1970-07-25 | Suspensionspolymerisation von Vinyl chlond |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2037043A1 DE2037043A1 (de) | 1972-02-10 |
| DE2037043B2 true DE2037043B2 (de) | 1973-10-31 |
Family
ID=5777922
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19702037043 Ceased DE2037043B2 (de) | 1970-07-25 | 1970-07-25 | Suspensionspolymerisation von Vinyl chlond |
Country Status (5)
| Country | Link |
|---|---|
| BE (1) | BE769950A (enExample) |
| DE (1) | DE2037043B2 (enExample) |
| FR (1) | FR2100369A5 (enExample) |
| GB (1) | GB1348426A (enExample) |
| NL (1) | NL153888B (enExample) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1489866A (en) * | 1973-12-26 | 1977-10-26 | Bp Chem Int Ltd | Polymerisation process |
| JPS56807A (en) * | 1979-06-15 | 1981-01-07 | Mitsubishi Monsanto Chem Co | Preparation of vinyl polymer |
-
1970
- 1970-07-25 DE DE19702037043 patent/DE2037043B2/de not_active Ceased
-
1971
- 1971-07-07 FR FR7124886A patent/FR2100369A5/fr not_active Expired
- 1971-07-13 BE BE769950A patent/BE769950A/xx unknown
- 1971-07-23 GB GB3459671A patent/GB1348426A/en not_active Expired
- 1971-07-23 NL NL7110204A patent/NL153888B/xx not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| NL7110204A (enExample) | 1972-01-27 |
| FR2100369A5 (enExample) | 1972-03-17 |
| GB1348426A (en) | 1974-03-20 |
| DE2037043A1 (de) | 1972-02-10 |
| BE769950A (fr) | 1972-01-13 |
| NL153888B (nl) | 1977-07-15 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| BHV | Refusal |