DE2034908C2 - Addukt aus einem Ruthenium(II)-carboxylat und einem stabilisierenden Donorliganden - Google Patents

Addukt aus einem Ruthenium(II)-carboxylat und einem stabilisierenden Donorliganden

Info

Publication number
DE2034908C2
DE2034908C2 DE2034908A DE2034908A DE2034908C2 DE 2034908 C2 DE2034908 C2 DE 2034908C2 DE 2034908 A DE2034908 A DE 2034908A DE 2034908 A DE2034908 A DE 2034908A DE 2034908 C2 DE2034908 C2 DE 2034908C2
Authority
DE
Germany
Prior art keywords
adduct
ruthenium
carboxylate
donor ligand
acetate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DE2034908A
Other languages
German (de)
English (en)
Other versions
DE2034908A1 (de
Inventor
Geoffrey Prof. London Wilkinson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Johnson Matthey PLC
Original Assignee
Johnson Matthey PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Johnson Matthey PLC filed Critical Johnson Matthey PLC
Publication of DE2034908A1 publication Critical patent/DE2034908A1/de
Application granted granted Critical
Publication of DE2034908C2 publication Critical patent/DE2034908C2/de
Expired legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0046—Ruthenium compounds
    • C07F15/0053—Ruthenium compounds without a metal-carbon linkage
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
    • B01J31/2239—Bridging ligands, e.g. OAc in Cr2(OAc)4, Pt4(OAc)8 or dicarboxylate ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/03—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of non-aromatic carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/03—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of non-aromatic carbon-to-carbon double bonds
    • C07C5/05—Partial hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/08—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of carbon-to-carbon triple bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/08—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of carbon-to-carbon triple bonds
    • C07C5/09—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of carbon-to-carbon triple bonds to carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/41—Preparation of salts of carboxylic acids
    • C07C51/412—Preparation of salts of carboxylic acids by conversion of the acids, their salts, esters or anhydrides with the same carboxylic acid part
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
    • C07C53/08—Acetic acid
    • C07C53/10—Salts thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
    • C07F1/005—Compounds containing elements of Groups 1 or 11 of the Periodic Table without C-Metal linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F11/00—Compounds containing elements of Groups 6 or 16 of the Periodic Table
    • C07F11/005—Compounds containing elements of Groups 6 or 16 of the Periodic Table compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0013—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/645—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0213—Complexes without C-metal linkages
    • B01J2531/0219—Bimetallic complexes, i.e. comprising one or more units of two metals, with metal-metal bonds but no all-metal (M)n rings, e.g. Cr2(OAc)4
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22—Organic complexes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/24—Phosphines
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S585/00—Chemistry of hydrocarbon compounds
    • Y10S585/8995—Catalyst and recycle considerations
    • Y10S585/906—Catalyst preservation or manufacture, e.g. activation before use

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • Molecular Biology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Pyridine Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
DE2034908A 1969-07-14 1970-07-14 Addukt aus einem Ruthenium(II)-carboxylat und einem stabilisierenden Donorliganden Expired DE2034908C2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB3524969 1969-07-14

Publications (2)

Publication Number Publication Date
DE2034908A1 DE2034908A1 (de) 1971-01-28
DE2034908C2 true DE2034908C2 (de) 1983-08-25

Family

ID=10375578

Family Applications (2)

Application Number Title Priority Date Filing Date
DE2034908A Expired DE2034908C2 (de) 1969-07-14 1970-07-14 Addukt aus einem Ruthenium(II)-carboxylat und einem stabilisierenden Donorliganden
DE2034909A Expired DE2034909C3 (de) 1969-07-14 1970-07-14 Ruthenium, Rhodium oder Molybdän enthaltender Katalysator sowie seine Verwendung als Hydrierungskatalysator

Family Applications After (1)

Application Number Title Priority Date Filing Date
DE2034909A Expired DE2034909C3 (de) 1969-07-14 1970-07-14 Ruthenium, Rhodium oder Molybdän enthaltender Katalysator sowie seine Verwendung als Hydrierungskatalysator

Country Status (6)

Country Link
US (2) US3725305A (OSRAM)
JP (2) JPS518927B1 (OSRAM)
DE (2) DE2034908C2 (OSRAM)
FR (2) FR2055059A5 (OSRAM)
GB (1) GB1326012A (OSRAM)
NL (2) NL172303C (OSRAM)

Families Citing this family (38)

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Publication number Priority date Publication date Assignee Title
US3939219A (en) * 1969-07-14 1976-02-17 Johnson, Matthey & Co., Limited Hyrogenation of unsaturated compounds
US3948999A (en) * 1973-08-13 1976-04-06 Universal Oil Products Company Hydroformylation of an unsaturated compound
US3974196A (en) * 1973-11-28 1976-08-10 Japan Synthetic Rubber Co., Ltd. Method for disproportionating ethylenically unsaturated compounds having functional ester groups
US3962131A (en) * 1975-01-28 1976-06-08 Pfizer Inc. Rhodium containing catalyst and use thereof in preparation of 6-deoxy-5-oxytetracycline
US4039585A (en) * 1975-09-08 1977-08-02 Uop Inc. Hydroformylation process
US4102920A (en) * 1977-01-13 1978-07-25 Air Products & Chemicals, Inc. Production of carboxylic acids and esters
US4313893A (en) * 1978-12-26 1982-02-02 Standard Oil Company Carbonylation of olefinically unsaturated compounds
US4246177A (en) * 1979-06-21 1981-01-20 Phillips Petroleum Company Preparation of dihydropyrans
US4266085A (en) * 1979-08-13 1981-05-05 Shell Oil Company Olefin disproportionation process
US4273936A (en) * 1979-09-28 1981-06-16 Union Carbide Corporation Rhodium-catalyzed oxidation process for producing carboxylic acids
US4652677A (en) * 1980-03-10 1987-03-24 The Standard Oil Company Selective hydrocarboxylation of propylene to isobutyric acid
US4417077A (en) * 1980-10-01 1983-11-22 University Of Illinois Foundation Heterogeneous anionic transition metal catalysts
NL8204883A (nl) * 1982-12-17 1984-07-16 Shell Int Research Werkwijze voor de bereiding van carbonzuuranhydriden.
US4863892A (en) * 1983-08-16 1989-09-05 Phillips Petroleum Company Antifoulants comprising tin, antimony and aluminum for thermal cracking processes
US4544789A (en) * 1983-09-06 1985-10-01 University of Illinois Board of Trustees Stereoselective synthesis of internal olefins
US4806678A (en) * 1983-10-13 1989-02-21 Texaco Inc. Process for the hydroformylation of allylic esters using a cobalt catalyst
JPS62265293A (ja) * 1986-05-13 1987-11-18 Takasago Corp ルテニウム−ホスフイン錯体
US4704377A (en) * 1986-05-19 1987-11-03 Ethyl Corporation Metathesis of acetylenes
JPS63145291A (ja) * 1986-12-09 1988-06-17 Takasago Corp ルテニウム−ホスフイン錯体
US5155253A (en) * 1988-06-30 1992-10-13 Union Carbide Chemicals & Plastics Technology Corporation Transvinylation process for the preparation of thermally labile vinyl compounds and for vinyl compounds prepared from thermally labile acids
US4981973A (en) * 1988-06-30 1991-01-01 Union Carbide Chemicals And Plastics Company, Inc. Transvinylation reaction
DE3921263A1 (de) * 1989-06-29 1991-01-24 Bayer Ag Verfahren zur selektiven hydrierung nitrilgruppenhaltiger olefine
US5149854A (en) * 1990-12-10 1992-09-22 Mooney Chemicals, Inc. Preparation of platinum group metal and rhenium carboxylates
US5210207A (en) * 1991-01-31 1993-05-11 Union Carbide Chemicals & Plastics Technology Corporation Transvinylation process by reactive distillation
US5187136A (en) * 1991-06-17 1993-02-16 Ethyl Corporation Asymmetric hydrogenation of aromatic-substituted olefins using organorhenium catalyst
US5177231A (en) * 1991-06-17 1993-01-05 Ethyl Corporation Asymmetric hydrogenation of aromatic-substituted olefins using cationic ruthenium(III) complexes
US5191095A (en) * 1991-06-17 1993-03-02 Ethyl Corporation Asymmetric hydrogenation of olefinic amides using organoruthenium catalyst
US5187281A (en) * 1991-06-17 1993-02-16 Ethyl Corporation Asymmetric hydrogenation of aromatic-substituted olefins using organoiridium catalyst
US5190905A (en) * 1991-06-17 1993-03-02 Ethyl Corporation Asymmetric hydrogenation of aromatic-substituted olefins using metal or metal alloy catalysts
US5202472A (en) * 1991-06-17 1993-04-13 Ethyl Corporation Asymmetric hydrogenation of aromatic-substituted olefins using organonickel catalyst
US5198576A (en) * 1991-08-26 1993-03-30 Ethyl Corporation Bicyclooctyl phosphines and catalysts thereof
FR2730229B1 (fr) * 1995-02-02 1997-04-11 Rhone Poulenc Chimie Procede de preparation de carboxylates d'iridium et leur utilisation comme catalyseurs
US6812184B1 (en) 1996-06-17 2004-11-02 Exxonmobil Chemical Patents Inc. Supported late transition metal catalyst systems
GB0427821D0 (en) * 2004-12-17 2005-01-19 Bp Chem Int Ltd Catalyst and process
JP5343483B2 (ja) * 2008-09-24 2013-11-13 Ｊｓｒ株式会社 化学気相成長材料および化学気相成長方法
JP5343482B2 (ja) * 2008-09-24 2013-11-13 Ｊｓｒ株式会社 化学気相成長方法
US8957235B2 (en) * 2011-12-12 2015-02-17 Chevron Phillips Chemical Company Lp Preparation of transition metal carboxylates
US9956548B2 (en) 2011-12-12 2018-05-01 Chevron Phillips Chemical Company Lp Preparation of an olefin oligomerization catalyst

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GB1121642A (en) * 1965-02-18 1968-07-31 Ici Ltd New organic rhodium complexes and uses thereof
BE598298A (OSRAM) * 1959-10-06 1900-01-01
US3366646A (en) * 1965-06-23 1968-01-30 Shell Oil Co Hydrogenation process
GB1197723A (en) * 1966-07-12 1970-07-08 Johnson Matthey Co Ltd Improvements in and relating to Catalysts.
FR1537041A (fr) * 1967-06-29 1968-08-23 Rhone Poulenc Sa Nouveaux complexes du ruthénium et procédés pour leur obtention
US3562181A (en) * 1967-07-19 1971-02-09 Du Pont Supported catalysts for dimerization of acrylonitriles and process of using the same
US3511885A (en) * 1967-12-11 1970-05-12 Phillips Petroleum Co Olefin conversion and catalyst therefor
GB1258045A (OSRAM) * 1967-12-22 1971-12-22
US3558517A (en) * 1969-03-24 1971-01-26 Phillips Petroleum Co Complexes of fe,ru,os,rh or ir with organoaluminums as olefin reaction catalysts
US3542751A (en) * 1969-04-09 1970-11-24 Goodyear Tire & Rubber Production of cis-1,4-polydienes by means of a ternary catalyst system

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
NICHTS-ERMITTELT

Also Published As

Publication number Publication date
JPS5023393B1 (OSRAM) 1975-08-07
NL172303B (nl) 1983-03-16
US3725305A (en) 1973-04-03
DE2034908A1 (de) 1971-01-28
NL172303C (nl) 1983-08-16
US3748332A (en) 1973-07-24
NL7010375A (OSRAM) 1971-01-18
NL170924B (nl) 1982-08-16
DE2034909B2 (de) 1979-06-21
FR2055060A5 (OSRAM) 1971-05-07
JPS518927B1 (OSRAM) 1976-03-22
DE2034909A1 (de) 1971-01-28
NL170924C (nl) 1983-01-17
DE2034909C3 (de) 1980-04-03
FR2055059A5 (OSRAM) 1971-05-07
NL7010315A (OSRAM) 1971-01-18
GB1326012A (en) 1973-08-08

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