DE2021069C3 - Verfahren zur Herstellung von Äthylen und Monochlortrifluoräthylen enthaltenden Mischpolymerisaten und Verwendung desselben - Google Patents
Verfahren zur Herstellung von Äthylen und Monochlortrifluoräthylen enthaltenden Mischpolymerisaten und Verwendung desselbenInfo
- Publication number
- DE2021069C3 DE2021069C3 DE2021069A DE2021069A DE2021069C3 DE 2021069 C3 DE2021069 C3 DE 2021069C3 DE 2021069 A DE2021069 A DE 2021069A DE 2021069 A DE2021069 A DE 2021069A DE 2021069 C3 DE2021069 C3 DE 2021069C3
- Authority
- DE
- Germany
- Prior art keywords
- ethylene
- copolymers
- copolymer
- monomers
- monochlorotrifluoroethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920001577 copolymer Polymers 0.000 title claims description 45
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title claims description 17
- 239000005977 Ethylene Substances 0.000 title claims description 17
- UUAGAQFQZIEFAH-UHFFFAOYSA-N chlorotrifluoroethylene Chemical group FC(F)=C(F)Cl UUAGAQFQZIEFAH-UHFFFAOYSA-N 0.000 title claims description 11
- 238000000034 method Methods 0.000 title claims description 5
- 238000002360 preparation method Methods 0.000 title claims description 3
- 239000000178 monomer Substances 0.000 claims description 41
- 125000000391 vinyl group Chemical class [H]C([*])=C([H])[H] 0.000 claims description 26
- 229920002554 vinyl polymer Polymers 0.000 claims description 24
- 238000002844 melting Methods 0.000 claims description 10
- 230000008018 melting Effects 0.000 claims description 10
- 239000000155 melt Substances 0.000 claims description 7
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- 125000003118 aryl group Chemical group 0.000 claims description 4
- 239000011248 coating agent Substances 0.000 claims description 3
- 230000000694 effects Effects 0.000 claims description 3
- XCKSMSLVYRMWOW-UHFFFAOYSA-N [F].[F].[F].ClC=C Chemical compound [F].[F].[F].ClC=C XCKSMSLVYRMWOW-UHFFFAOYSA-N 0.000 claims 1
- 229920000642 polymer Polymers 0.000 description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 229910052799 carbon Inorganic materials 0.000 description 5
- 239000003365 glass fiber Substances 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 229910052731 fluorine Inorganic materials 0.000 description 3
- 125000001153 fluoro group Chemical group F* 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 125000000962 organic group Chemical group 0.000 description 3
- -1 perfluoro Chemical group 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- AJDIZQLSFPQPEY-UHFFFAOYSA-N 1,1,2-Trichlorotrifluoroethane Chemical compound FC(F)(Cl)C(F)(Cl)Cl AJDIZQLSFPQPEY-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 125000000174 L-prolyl group Chemical group [H]N1C([H])([H])C([H])([H])C([H])([H])[C@@]1([H])C(*)=O 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- XJHCXCQVJFPJIK-UHFFFAOYSA-M caesium fluoride Chemical compound [F-].[Cs+] XJHCXCQVJFPJIK-UHFFFAOYSA-M 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000000748 compression moulding Methods 0.000 description 2
- 239000007822 coupling agent Substances 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 125000005010 perfluoroalkyl group Chemical group 0.000 description 2
- 150000004756 silanes Chemical class 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- FXUHCQHWDACOKK-UHFFFAOYSA-N 1,1,1,2,3,3,3-heptafluoro-2-prop-2-enoxypropane Chemical compound FC(F)(F)C(F)(C(F)(F)F)OCC=C FXUHCQHWDACOKK-UHFFFAOYSA-N 0.000 description 1
- UJPMYEOUBPIPHQ-UHFFFAOYSA-N 1,1,1-trifluoroethane Chemical compound CC(F)(F)F UJPMYEOUBPIPHQ-UHFFFAOYSA-N 0.000 description 1
- RRZIJNVZMJUGTK-UHFFFAOYSA-N 1,1,2-trifluoro-2-(1,2,2-trifluoroethenoxy)ethene Chemical compound FC(F)=C(F)OC(F)=C(F)F RRZIJNVZMJUGTK-UHFFFAOYSA-N 0.000 description 1
- GZQZKLFXWPAMFW-UHFFFAOYSA-N 1,2,3,4,5-pentafluoro-6-(1,2,2-trifluoroethenyl)benzene Chemical compound FC(F)=C(F)C1=C(F)C(F)=C(F)C(F)=C1F GZQZKLFXWPAMFW-UHFFFAOYSA-N 0.000 description 1
- LVJZCPNIJXVIAT-UHFFFAOYSA-N 1-ethenyl-2,3,4,5,6-pentafluorobenzene Chemical compound FC1=C(F)C(F)=C(C=C)C(F)=C1F LVJZCPNIJXVIAT-UHFFFAOYSA-N 0.000 description 1
- DASQIKOOFDJYKA-UHFFFAOYSA-N CCIF Chemical compound CCIF DASQIKOOFDJYKA-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 239000004243 E-number Substances 0.000 description 1
- 235000019227 E-number Nutrition 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- 101000597193 Homo sapiens Telethonin Proteins 0.000 description 1
- HEFNNWSXXWATRW-UHFFFAOYSA-N Ibuprofen Chemical compound CC(C)CC1=CC=C(C(C)C(O)=O)C=C1 HEFNNWSXXWATRW-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 102100035155 Telethonin Human genes 0.000 description 1
- HXELGNKCCDGMMN-UHFFFAOYSA-N [F].[Cl] Chemical group [F].[Cl] HXELGNKCCDGMMN-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 125000002015 acyclic group Chemical group 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- BHELZAPQIKSEDF-UHFFFAOYSA-N allyl bromide Chemical compound BrCC=C BHELZAPQIKSEDF-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000012267 brine Substances 0.000 description 1
- 244000309464 bull Species 0.000 description 1
- 239000012986 chain transfer agent Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- TUFAENDKOLGWHG-UHFFFAOYSA-N chloroform;ethene Chemical compound C=C.ClC(Cl)Cl TUFAENDKOLGWHG-UHFFFAOYSA-N 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 235000019441 ethanol Nutrition 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000012065 filter cake Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- VBZWSGALLODQNC-UHFFFAOYSA-N hexafluoroacetone Chemical compound FC(F)(F)C(=O)C(F)(F)F VBZWSGALLODQNC-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical group 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 150000005673 monoalkenes Chemical class 0.000 description 1
- 150000001282 organosilanes Chemical class 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000002990 reinforced plastic Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/18—Monomers containing fluorine
- C08F214/24—Trifluorochloroethene
- C08F214/245—Trifluorochloroethene with non-fluorinated comonomers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Organic Insulating Materials (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US439470A | 1970-01-20 | 1970-01-20 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE2021069A1 DE2021069A1 (de) | 1971-11-25 |
| DE2021069B2 DE2021069B2 (de) | 1978-02-16 |
| DE2021069C3 true DE2021069C3 (de) | 1978-10-19 |
Family
ID=21710587
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2021069A Expired DE2021069C3 (de) | 1970-01-20 | 1970-04-29 | Verfahren zur Herstellung von Äthylen und Monochlortrifluoräthylen enthaltenden Mischpolymerisaten und Verwendung desselben |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US3624250A (enExample) |
| JP (1) | JPS4919709B1 (enExample) |
| BE (1) | BE748155A (enExample) |
| DE (1) | DE2021069C3 (enExample) |
| FR (1) | FR2074835A5 (enExample) |
| GB (1) | GB1307564A (enExample) |
| NL (1) | NL147155B (enExample) |
Families Citing this family (82)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5219959Y2 (enExample) * | 1972-03-17 | 1977-05-09 | ||
| US3847881A (en) * | 1973-04-30 | 1974-11-12 | Allied Chem | Stress-crack resistant ethylene-perhaloethylene copolymers |
| US4033939A (en) * | 1975-04-02 | 1977-07-05 | Allied Chemical Corporation | Stress-crack resistant ethylene-perhaloethylene terpolymers |
| US4098756A (en) * | 1976-07-12 | 1978-07-04 | Allied Chemical Corporation | Fluoropolymer primer compositions |
| US4170686A (en) * | 1976-07-12 | 1979-10-09 | Allied Chemical Corporation | Substrates and articles of manufacture incorporating a fluoropolymer primer coating |
| GB1550874A (en) * | 1976-10-28 | 1979-08-22 | Asahi Glass Co Ltd | Process for producing fluorinated copolymer having ion-exchange groups |
| JPS5950163B2 (ja) * | 1977-08-19 | 1984-12-06 | 旭硝子株式会社 | エチレン−四弗化エチレン系共重合体及びその製法 |
| JPS58164609A (ja) * | 1982-03-25 | 1983-09-29 | Daikin Ind Ltd | 光学繊維用鞘材 |
| US4510300A (en) * | 1982-04-08 | 1985-04-09 | E. I. Du Pont De Nemours And Company | Perfluorocarbon copolymer films |
| JPS58219025A (ja) * | 1982-06-01 | 1983-12-20 | イ−・アイ・デユポン・デ・ニモアス・アンド・カンパニ− | フルオルカーボン共重合体フイルム及びその製造方法 |
| US4510301A (en) * | 1982-06-01 | 1985-04-09 | E. I. Du Pont De Nemours And Company | Fluorocarbon copolymer films |
| US4426501A (en) | 1983-01-17 | 1984-01-17 | E. I. Du Pont De Nemours And Company | Emulsion copolymerization process using comonomer solubility affecting additives |
| US4521575A (en) * | 1983-02-12 | 1985-06-04 | Daikin Kogyo Co., Ltd. | Tetrafluoroethylene-ethylene type copolymer |
| JPS59197411A (ja) * | 1983-04-25 | 1984-11-09 | Daikin Ind Ltd | エチレン−テトラフルオロエチレンまたはクロロトリフルオロエチレン系共重合体 |
| JPS6056532A (ja) * | 1983-09-09 | 1985-04-02 | Unitika Ltd | フツ素系延伸フイルムの製造方法 |
| US4544721A (en) * | 1983-10-06 | 1985-10-01 | E. I. Du Pont De Nemours And Company | Chlorotriflouroethylene polymer oriented films |
| US4736006A (en) * | 1984-12-19 | 1988-04-05 | Ausimont, U.S.A., Inc. | Terpolymers of chlorotrifluoroethylene, or tetrafluoroethylene, ethylene and perfluoroisoalkoxy perfluoroalkyl ethylenes |
| CN85100468B (zh) * | 1985-04-01 | 1985-09-10 | 中国科学院上海有机化学研究所 | 四氟乙烯、乙烯三元共聚物的生产方法 |
| US5137999A (en) * | 1987-11-20 | 1992-08-11 | Allied-Signal Inc. | Copolymerization of vinyl acetate and a fluoromonomer in an aqueous medium |
| US5151477A (en) * | 1987-11-20 | 1992-09-29 | Allied-Signal Inc. | Copolymerization of vinyl acetate and a fluoromonomer in an aqueous medium |
| US4963609A (en) * | 1989-11-01 | 1990-10-16 | E. I. Du Pont De Nemours And Company | Low smoke and flame-resistant composition |
| IT1263955B (it) * | 1993-02-23 | 1996-09-05 | Ausimont Spa | Processo di (co) polimerizzazione radicalica di monomeri olefinici fluorurati |
| IT1271136B (it) * | 1993-03-23 | 1997-05-27 | Ausimont Spa | Processo di (co)polimerizzazione in emulsione acquosa di monomeri olefinici fluorurati |
| IT1265068B1 (it) * | 1993-05-18 | 1996-10-30 | Ausimont Spa | Processo di (co)polimerizzazione radicalica di monomeri olefinici fluorurati in emulsione acquosa |
| IT1266647B1 (it) * | 1993-10-29 | 1997-01-09 | Ausimont Spa | Processo di (co)polimerizzazione di monomeri olefinici fluorurati in emulsione acquosa |
| US5409997A (en) * | 1993-11-01 | 1995-04-25 | E. I. Du Pont De Nemours And Company | Thermally-stable melt processible fluoropolymer compositions and process |
| IT1271621B (it) * | 1994-03-21 | 1997-06-04 | Ausimont Spa | Processo per la preparazione di fluoropolimeri termoplastici contenenti idrogeno |
| IT1271622B (it) * | 1994-03-21 | 1997-06-04 | Ausimont Spa | Processo di (co) polimerizzazione in sospensione per la preparazione ddi fluoropolimeri termoplastici contenenti idrogeno |
| DE4424466A1 (de) | 1994-07-12 | 1996-01-18 | Hoechst Ag | Copolymeres vom Typ Tetrafluorethylen-Ethylen mit einer Kern-Hülle-Teilchenstruktur |
| IT1274711B (it) * | 1994-08-04 | 1997-07-24 | Ausimont Spa | Processo per la preparazione di fluoropolimeri contenenti idrogeno tramite (co)polimerizzazione in sospensione |
| IT1270703B (it) | 1994-11-17 | 1997-05-07 | Ausimont Spa | Microemulsioni di fluoropoliossialchileni in miscela con idrocarburi, e loro uso in processi di (co)polimerizzazione di monomeri fluorurati |
| IT1272861B (it) * | 1995-01-04 | 1997-07-01 | Ausimont Spa | Copolimeri dell'etilene con tetrafluoroetilene e/o clorotrifluoroetilene,aventi migliorate proprieta' meccaniche alle alte temperature |
| IT1276072B1 (it) * | 1995-10-31 | 1997-10-24 | Ausimont Spa | Processo di (co)polimerizzazione di monomeri fluorurati per ottenere polimeri contenenti idrogeno |
| US6136911A (en) * | 1996-01-11 | 2000-10-24 | E.I. Du Pont De Nemours And Company | Fibers flash-spun from partially fluorinated polymers |
| IT1284112B1 (it) * | 1996-07-05 | 1998-05-08 | Ausimont Spa | Copolimeri fluorurati dell'etilene |
| IT1286028B1 (it) * | 1996-07-09 | 1998-07-07 | Ausimont Spa | Processo di polimerizzazione in sospensione di monomeri fluorurati |
| IT1290426B1 (it) * | 1997-03-21 | 1998-12-03 | Ausimont Spa | Polimeri fluorurati termoprocessabili |
| IT1298091B1 (it) * | 1998-01-09 | 1999-12-20 | Ausimont Spa | Processo per la preparazione degli alogenuri di diclorofluoroacetile |
| US6197904B1 (en) | 1998-02-26 | 2001-03-06 | E. I. Du Pont De Nemours And Company | Low-melting tetrafluoroethylene copolymer |
| JP3951277B2 (ja) * | 1998-03-20 | 2007-08-01 | 旭硝子株式会社 | エチレン／テトラフルオロエチレン系共重合体粉末及びその成形方法 |
| US6764762B2 (en) | 2002-09-10 | 2004-07-20 | E. I. Du Pont De Nemours And Company | Lubricated fluoropolymer yarn |
| US20040236083A1 (en) * | 2003-05-14 | 2004-11-25 | Libert Sharon Ann | Protein separation column |
| US20040242855A1 (en) * | 2003-05-14 | 2004-12-02 | Libert Sharon Ann | Protein treatment process |
| DE202004016119U1 (de) * | 2004-10-18 | 2006-02-23 | Fischerwerke Artur Fischer Gmbh & Co. Kg | Montageschraube zur Befestigung von Beschlagteilen, insbesondere von Bandteilen an Hohlkammerprofilen |
| EP1757443A1 (en) * | 2005-08-25 | 2007-02-28 | Solvay Advanced Polymers, L.L.C. | Improved multilayer polymer structure |
| US20060246546A1 (en) * | 2005-04-29 | 2006-11-02 | Jenkins Lauri L | Manufacture of biologic cellular products |
| US20060246537A1 (en) * | 2005-04-29 | 2006-11-02 | Jenkins Lauri L | Multi-step process for the manufacture of therapeutic protein |
| US20060243666A1 (en) * | 2005-04-29 | 2006-11-02 | Jenkins Lauri L | Process for the preparation of protein separation solution |
| US20060246008A1 (en) * | 2005-04-29 | 2006-11-02 | Jenkins Lauri L | Process for the formulation of therapeutic protein |
| US20060246244A1 (en) * | 2005-04-29 | 2006-11-02 | Jenkins Lauri L | Disposable vessel for the containment of biological materials and corrosive reagents |
| EP1743920A1 (en) | 2005-07-13 | 2007-01-17 | Solvay Solexis S.p.A. | Thermoplastic fluoropolymer composition |
| EP1743921A1 (en) | 2005-07-13 | 2007-01-17 | Solvay Solexis S.p.A. | Thermoplastic halopolymer composition |
| BRPI0614862A2 (pt) * | 2005-08-19 | 2012-12-04 | Solvay | processo para fabricar uma estrutura celular à base de plástico, e, dispositivo para implementar o processo |
| EP1795565B1 (en) * | 2005-12-06 | 2016-05-18 | Solvay Specialty Polymers Italy S.p.A. | Water-based fluoropolymer composition |
| US20070276080A1 (en) * | 2006-05-25 | 2007-11-29 | Jacob Lahijani | Melt fabrication of fiber-filled fluoropolymer |
| ITMI20062308A1 (it) * | 2006-11-30 | 2008-06-01 | Solvay Solexis Spa | Additivi per alo-polimeri |
| RU2440372C2 (ru) * | 2006-12-08 | 2012-01-20 | Асахи Гласс Компани, Лимитед | Этилен/тетрафторэтиленовый сополимер и способ его получения |
| EP2380923B1 (en) * | 2007-08-03 | 2013-07-24 | Cable Components Group LLC | Perfluoropolymer foamable composition |
| US20090227749A1 (en) * | 2008-03-05 | 2009-09-10 | Asahi Glass Company, Limited | Process for producing perfluorocarbon polymer |
| US8247486B2 (en) * | 2008-07-01 | 2012-08-21 | E.I. Du Pont De Nemours And Company | Creep resistant fluoropolymer |
| US20110092614A1 (en) * | 2008-07-10 | 2011-04-21 | E. I. Dupont Denemours And Company | Applications of ethylene/terafluoroethylene copolymer |
| JP2011527717A (ja) * | 2008-07-10 | 2011-11-04 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | エチレン／テトラフルオロエチレンコポリマーの水分散液重合方法 |
| US9006565B2 (en) * | 2008-10-16 | 2015-04-14 | Solvay Specialty Polymers Italy S.P.A. | Opaque fluoropolymer composition comprising white pigments for photovoltaic elements of solar cells |
| WO2010123002A1 (ja) * | 2009-04-21 | 2010-10-28 | ダイキン工業株式会社 | エチレン／テトラフルオロエチレン共重合体、電線及び回転成形用フッ素樹脂粉末 |
| US8409379B2 (en) | 2010-07-30 | 2013-04-02 | E I Du Pont De Nemours And Company | Multilayer structures containing a fluorinated copolymer resin layer and an ethylene terpolymer layer |
| CN103052505A (zh) | 2010-07-30 | 2013-04-17 | 纳幕尔杜邦公司 | 包含氟化共聚物树脂层和包封层的多层膜 |
| EP2627510B1 (en) * | 2010-10-15 | 2015-01-28 | Solvay Specialty Polymers Italy S.p.A. | Multilayer assembly |
| CN102432725B (zh) * | 2011-08-29 | 2014-04-09 | 费植煌 | 一种含氟树脂的制备方法及其应用 |
| EP2631260A1 (en) | 2012-02-27 | 2013-08-28 | Solvay Sa | Process for Producing Graphene-Polymer Nanocomposites |
| US20140255703A1 (en) | 2013-03-05 | 2014-09-11 | E I Du Pont De Nemours And Company | Adhesion of Fluoropolymer to Metal |
| CN105431464B (zh) * | 2013-07-30 | 2017-12-26 | 索尔维特殊聚合物意大利有限公司 | 含氟热塑性弹性体组合物 |
| CN104892811B (zh) * | 2014-03-07 | 2017-12-01 | 浙江省化工研究院有限公司 | 一种乙烯‑三氟氯乙烯共聚物、其制备方法及应用 |
| CN104945549B (zh) * | 2014-03-26 | 2017-06-06 | 浙江省化工研究院有限公司 | 具有稳定端基结构的乙烯‑三氟氯乙烯共聚物、其制备方法及应用 |
| US10032542B2 (en) | 2014-11-07 | 2018-07-24 | Cable Components Group, Llc | Compositions for compounding, extrusion and melt processing of foamable and cellular halogen-free polymers |
| US10031301B2 (en) | 2014-11-07 | 2018-07-24 | Cable Components Group, Llc | Compositions for compounding, extrusion, and melt processing of foamable and cellular polymers |
| JP6691539B2 (ja) | 2014-11-13 | 2020-04-28 | ソルベイ スペシャルティ ポリマーズ イタリー エス．ピー．エー． | コーティング組成物 |
| JP6885337B2 (ja) * | 2015-10-20 | 2021-06-16 | Ａｇｃ株式会社 | フッ素樹脂の製造方法 |
| WO2020127654A1 (en) | 2018-12-20 | 2020-06-25 | Solvay Specialty Polymers Italy S.P.A. | Process for the preparation of perhaloacyl peroxides |
| US20230272135A1 (en) * | 2020-09-01 | 2023-08-31 | Solvay Specialty Polymers Italy S.P.A. | Fluoropolymer composition |
| WO2024257869A1 (ja) * | 2023-06-16 | 2024-12-19 | Ａｇｃ株式会社 | 共重合体、組成物および成形体 |
| WO2024257868A1 (ja) * | 2023-06-16 | 2024-12-19 | Ａｇｃ株式会社 | 共重合体、組成物および成形体 |
| WO2024257865A1 (ja) * | 2023-06-16 | 2024-12-19 | Ａｇｃ株式会社 | 共重合体、組成物および成形体 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2392378A (en) * | 1943-10-25 | 1946-01-08 | Du Pont | Copolymers of chlorotrifluoroethylene and olefin hydrocarbons |
| US2468664A (en) * | 1945-08-28 | 1949-04-26 | Du Pont | Tetrafluoroethylene copolymers |
| US3235537A (en) * | 1961-06-23 | 1966-02-15 | Du Pont | Fluorine containing terpolymer of a perfluorovinyl ether, vinylidene fluoride and a monomer of the structure cfx=cfy |
| US3303154A (en) * | 1962-10-18 | 1967-02-07 | Nitto Chemical Industry Co Ltd | Coating compositions |
| US3444148A (en) * | 1964-10-05 | 1969-05-13 | Du Pont | Copolymers of selected polyfluoroper-haloketone adducts with other selected ethylenic compounds |
| US3445434A (en) * | 1964-10-30 | 1969-05-20 | Du Pont | Copolymers of tetrafluoroethylene,ethylene and an olefinic acid |
-
1970
- 1970-01-20 US US4394A patent/US3624250A/en not_active Expired - Lifetime
- 1970-03-27 BE BE748155D patent/BE748155A/xx not_active IP Right Cessation
- 1970-04-15 JP JP45031681A patent/JPS4919709B1/ja active Pending
- 1970-04-29 FR FR7015780A patent/FR2074835A5/fr not_active Expired
- 1970-04-29 DE DE2021069A patent/DE2021069C3/de not_active Expired
- 1970-04-29 NL NL707006364A patent/NL147155B/xx not_active IP Right Cessation
- 1970-05-08 GB GB2249170A patent/GB1307564A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| JPS4919709B1 (enExample) | 1974-05-20 |
| US3624250A (en) | 1971-11-30 |
| GB1307564A (en) | 1973-02-21 |
| DE2021069B2 (de) | 1978-02-16 |
| NL147155B (nl) | 1975-09-15 |
| FR2074835A5 (enExample) | 1971-10-08 |
| BE748155A (fr) | 1970-08-31 |
| NL7006364A (enExample) | 1971-07-22 |
| DE2021069A1 (de) | 1971-11-25 |
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