DE19728629A1 - Thermoplastische Formmassen mit geringer Eigenfarbe - Google Patents
Thermoplastische Formmassen mit geringer EigenfarbeInfo
- Publication number
- DE19728629A1 DE19728629A1 DE19728629A DE19728629A DE19728629A1 DE 19728629 A1 DE19728629 A1 DE 19728629A1 DE 19728629 A DE19728629 A DE 19728629A DE 19728629 A DE19728629 A DE 19728629A DE 19728629 A1 DE19728629 A1 DE 19728629A1
- Authority
- DE
- Germany
- Prior art keywords
- weight
- polymer
- graft
- molding compositions
- acrylonitrile
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000009757 thermoplastic moulding Methods 0.000 title claims abstract description 26
- 150000001875 compounds Chemical class 0.000 title description 26
- 239000000178 monomer Substances 0.000 claims abstract description 82
- 229920000642 polymer Polymers 0.000 claims abstract description 65
- 239000002245 particle Substances 0.000 claims abstract description 51
- 229920000578 graft copolymer Polymers 0.000 claims abstract description 47
- 238000002156 mixing Methods 0.000 claims abstract description 38
- 238000009826 distribution Methods 0.000 claims abstract description 24
- 238000001816 cooling Methods 0.000 claims abstract description 19
- 229920002959 polymer blend Polymers 0.000 claims abstract description 18
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 18
- 230000002902 bimodal effect Effects 0.000 claims abstract description 16
- 239000000654 additive Substances 0.000 claims abstract description 7
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 84
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 65
- 239000000203 mixture Substances 0.000 claims description 55
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 38
- 238000000034 method Methods 0.000 claims description 35
- 238000000465 moulding Methods 0.000 claims description 33
- 230000008569 process Effects 0.000 claims description 17
- 229920002554 vinyl polymer Polymers 0.000 claims description 16
- 238000004519 manufacturing process Methods 0.000 claims description 15
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 13
- 238000005054 agglomeration Methods 0.000 claims description 13
- 230000002776 aggregation Effects 0.000 claims description 13
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 12
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 12
- 239000007788 liquid Substances 0.000 claims description 11
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims description 10
- 150000003923 2,5-pyrrolediones Chemical class 0.000 claims description 8
- 238000007720 emulsion polymerization reaction Methods 0.000 claims description 8
- 238000002360 preparation method Methods 0.000 claims description 8
- 150000001993 dienes Chemical class 0.000 claims description 7
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 7
- 230000000379 polymerizing effect Effects 0.000 claims description 7
- 239000000463 material Substances 0.000 abstract description 2
- 239000000470 constituent Substances 0.000 abstract 2
- 238000010556 emulsion polymerization method Methods 0.000 abstract 1
- 239000012778 molding material Substances 0.000 abstract 1
- 239000002585 base Substances 0.000 description 27
- 239000006185 dispersion Substances 0.000 description 27
- 229920000126 latex Polymers 0.000 description 20
- 229920001971 elastomer Polymers 0.000 description 17
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 15
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- 238000006116 polymerization reaction Methods 0.000 description 14
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- -1 acrylic nitrile Chemical class 0.000 description 10
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- 238000006243 chemical reaction Methods 0.000 description 9
- 239000003995 emulsifying agent Substances 0.000 description 9
- 239000002826 coolant Substances 0.000 description 8
- 229920000638 styrene acrylonitrile Polymers 0.000 description 8
- 239000005062 Polybutadiene Substances 0.000 description 7
- 238000004040 coloring Methods 0.000 description 7
- 229920001577 copolymer Polymers 0.000 description 7
- 239000003999 initiator Substances 0.000 description 7
- 238000005259 measurement Methods 0.000 description 7
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- 239000000126 substance Substances 0.000 description 7
- 239000004793 Polystyrene Substances 0.000 description 6
- 238000001035 drying Methods 0.000 description 6
- 239000011521 glass Substances 0.000 description 6
- 239000003365 glass fiber Substances 0.000 description 6
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- 238000001746 injection moulding Methods 0.000 description 6
- 238000004898 kneading Methods 0.000 description 6
- 230000036961 partial effect Effects 0.000 description 6
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- 238000012545 processing Methods 0.000 description 6
- HIDBROSJWZYGSZ-UHFFFAOYSA-N 1-phenylpyrrole-2,5-dione Chemical group O=C1C=CC(=O)N1C1=CC=CC=C1 HIDBROSJWZYGSZ-UHFFFAOYSA-N 0.000 description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 5
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 5
- 229920006222 acrylic ester polymer Polymers 0.000 description 5
- 125000000217 alkyl group Chemical group 0.000 description 5
- 239000003963 antioxidant agent Substances 0.000 description 5
- 235000006708 antioxidants Nutrition 0.000 description 5
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 5
- 239000000975 dye Substances 0.000 description 5
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 238000004383 yellowing Methods 0.000 description 5
- YAJYJWXEWKRTPO-UHFFFAOYSA-N 2,3,3,4,4,5-hexamethylhexane-2-thiol Chemical compound CC(C)C(C)(C)C(C)(C)C(C)(C)S YAJYJWXEWKRTPO-UHFFFAOYSA-N 0.000 description 4
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 4
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 4
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 238000012662 bulk polymerization Methods 0.000 description 4
- 238000007872 degassing Methods 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- 239000011159 matrix material Substances 0.000 description 4
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 4
- 239000000049 pigment Substances 0.000 description 4
- 230000001737 promoting effect Effects 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- 239000000725 suspension Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 238000000149 argon plasma sintering Methods 0.000 description 3
- 239000000872 buffer Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000000112 cooling gas Substances 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 238000005453 pelletization Methods 0.000 description 3
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 description 3
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 3
- 238000012673 precipitation polymerization Methods 0.000 description 3
- 238000003825 pressing Methods 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- UIIMBOGNXHQVGW-UHFFFAOYSA-M sodium bicarbonate Substances [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 150000003440 styrenes Chemical class 0.000 description 3
- 239000004416 thermosoftening plastic Substances 0.000 description 3
- 150000005208 1,4-dihydroxybenzenes Chemical class 0.000 description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- 241000237858 Gastropoda Species 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
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- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
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- 229910052943 magnesium sulfate Inorganic materials 0.000 description 2
- 235000019341 magnesium sulphate Nutrition 0.000 description 2
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 2
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 2
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- 239000006082 mold release agent Substances 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical class CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
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- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 2
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- VNNBZUFJRRODHO-UHFFFAOYSA-N prop-2-enenitrile;prop-1-en-2-ylbenzene Chemical compound C=CC#N.CC(=C)C1=CC=CC=C1 VNNBZUFJRRODHO-UHFFFAOYSA-N 0.000 description 2
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- QHVBLSNVXDSMEB-UHFFFAOYSA-N 2-(diethylamino)ethyl prop-2-enoate Chemical compound CCN(CC)CCOC(=O)C=C QHVBLSNVXDSMEB-UHFFFAOYSA-N 0.000 description 1
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- 239000006096 absorbing agent Substances 0.000 description 1
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- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 229940037003 alum Drugs 0.000 description 1
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- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical class C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Chemical class 0.000 description 1
- 150000001565 benzotriazoles Chemical class 0.000 description 1
- AOJOEFVRHOZDFN-UHFFFAOYSA-N benzyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC1=CC=CC=C1 AOJOEFVRHOZDFN-UHFFFAOYSA-N 0.000 description 1
- GCTPMLUUWLLESL-UHFFFAOYSA-N benzyl prop-2-enoate Chemical compound C=CC(=O)OCC1=CC=CC=C1 GCTPMLUUWLLESL-UHFFFAOYSA-N 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 235000012241 calcium silicate Nutrition 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
- 239000000110 cooling liquid Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000013536 elastomeric material Substances 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000010433 feldspar Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 150000002432 hydroperoxides Chemical class 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 235000013980 iron oxide Nutrition 0.000 description 1
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 210000004072 lung Anatomy 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
- 239000012170 montan wax Substances 0.000 description 1
- DNTMQTKDNSEIFO-UHFFFAOYSA-N n-(hydroxymethyl)-2-methylprop-2-enamide Chemical compound CC(=C)C(=O)NCO DNTMQTKDNSEIFO-UHFFFAOYSA-N 0.000 description 1
- PZUGJLOCXUNFLM-UHFFFAOYSA-N n-ethenylaniline Chemical compound C=CNC1=CC=CC=C1 PZUGJLOCXUNFLM-UHFFFAOYSA-N 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- SEEYREPSKCQBBF-UHFFFAOYSA-N n-methylmaleimide Chemical group CN1C(=O)C=CC1=O SEEYREPSKCQBBF-UHFFFAOYSA-N 0.000 description 1
- KKFHAJHLJHVUDM-UHFFFAOYSA-N n-vinylcarbazole Chemical compound C1=CC=C2N(C=C)C3=CC=CC=C3C2=C1 KKFHAJHLJHVUDM-UHFFFAOYSA-N 0.000 description 1
- 230000006855 networking Effects 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910052756 noble gas Inorganic materials 0.000 description 1
- 150000002835 noble gases Chemical class 0.000 description 1
- QUWPKSVNVOPLKX-UHFFFAOYSA-N octan-3-yl 2-sulfanylacetate Chemical compound CCCCCC(CC)OC(=O)CS QUWPKSVNVOPLKX-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 239000002530 phenolic antioxidant Substances 0.000 description 1
- QIWKUEJZZCOPFV-UHFFFAOYSA-N phenyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1=CC=CC=C1 QIWKUEJZZCOPFV-UHFFFAOYSA-N 0.000 description 1
- WRAQQYDMVSCOTE-UHFFFAOYSA-N phenyl prop-2-enoate Chemical compound C=CC(=O)OC1=CC=CC=C1 WRAQQYDMVSCOTE-UHFFFAOYSA-N 0.000 description 1
- 230000010399 physical interaction Effects 0.000 description 1
- 229920006112 polar polymer Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Chemical class 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 230000000452 restraining effect Effects 0.000 description 1
- 150000003873 salicylate salts Chemical class 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- PVGBHEUCHKGFQP-UHFFFAOYSA-N sodium;n-[5-amino-2-(4-aminophenyl)sulfonylphenyl]sulfonylacetamide Chemical compound [Na+].CC(=O)NS(=O)(=O)C1=CC(N)=CC=C1S(=O)(=O)C1=CC=C(N)C=C1 PVGBHEUCHKGFQP-UHFFFAOYSA-N 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
- 229930003799 tocopherol Natural products 0.000 description 1
- 239000011732 tocopherol Substances 0.000 description 1
- 235000019149 tocopherols Nutrition 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- QUEDXNHFTDJVIY-UHFFFAOYSA-N γ-tocopherol Chemical class OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
- C08L25/12—Copolymers of styrene with unsaturated nitriles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
- C08F279/04—Vinyl aromatic monomers and nitriles as the only monomers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
- C08L25/14—Copolymers of styrene with unsaturated esters
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Graft Or Block Polymers (AREA)
Priority Applications (15)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19728629A DE19728629A1 (de) | 1997-07-04 | 1997-07-04 | Thermoplastische Formmassen mit geringer Eigenfarbe |
| ES98938632T ES2172908T3 (es) | 1997-07-04 | 1998-06-23 | Masas de moldeo termoplasticas con color propio reducido. |
| JP50626499A JP2002510349A (ja) | 1997-07-04 | 1998-06-23 | 固有色をほとんど有さない熱可塑性成形材料 |
| PCT/EP1998/003836 WO1999001489A1 (de) | 1997-07-04 | 1998-06-23 | Thermoplastische formmassen mit geringer eigenfarbe |
| CNB988088614A CN1140551C (zh) | 1997-07-04 | 1998-06-23 | 本体颜色很浅的热塑性模塑组合物 |
| KR1020007000027A KR100361001B1 (ko) | 1997-07-04 | 1998-06-23 | 고유 색이 거의 없는 열가소성 성형 재료 |
| AU87285/98A AU8728598A (en) | 1997-07-04 | 1998-06-23 | Low individual color thermoplastic molding material |
| US09/446,982 US6323279B1 (en) | 1997-07-04 | 1998-06-23 | Low individual color thermoplastic molding material |
| EP98938632A EP0993476B1 (de) | 1997-07-04 | 1998-06-23 | Thermoplastische formmassen mit geringer eigenfarbe |
| BR9810666-0A BR9810666A (pt) | 1997-07-04 | 1998-06-23 | Composição termoplástica de moldagem, processo e uso para preparação da mesma, e, moldado |
| DE59803025T DE59803025D1 (de) | 1997-07-04 | 1998-06-23 | Thermoplastische formmassen mit geringer eigenfarbe |
| CA002294918A CA2294918A1 (en) | 1997-07-04 | 1998-06-23 | Low individual color thermoplastic molding material |
| TW087110695A TW470755B (en) | 1997-07-04 | 1998-07-02 | Thermoplastic molding compositions having little intrinsic color |
| ZA9805868A ZA985868B (en) | 1997-07-04 | 1998-07-03 | Thermoplastic molding compositions having title intrinsic color. |
| ARP980103236A AR012259A1 (es) | 1997-07-04 | 1998-07-03 | Masas de moldeo termoplasticas, metodo de preparacion de las mismas, su uso y cuerpos de moldeo fabricados a partir de ellas. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19728629A DE19728629A1 (de) | 1997-07-04 | 1997-07-04 | Thermoplastische Formmassen mit geringer Eigenfarbe |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE19728629A1 true DE19728629A1 (de) | 1999-01-07 |
Family
ID=7834666
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19728629A Withdrawn DE19728629A1 (de) | 1997-07-04 | 1997-07-04 | Thermoplastische Formmassen mit geringer Eigenfarbe |
| DE59803025T Expired - Lifetime DE59803025D1 (de) | 1997-07-04 | 1998-06-23 | Thermoplastische formmassen mit geringer eigenfarbe |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE59803025T Expired - Lifetime DE59803025D1 (de) | 1997-07-04 | 1998-06-23 | Thermoplastische formmassen mit geringer eigenfarbe |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US6323279B1 (https=) |
| EP (1) | EP0993476B1 (https=) |
| JP (1) | JP2002510349A (https=) |
| KR (1) | KR100361001B1 (https=) |
| CN (1) | CN1140551C (https=) |
| AR (1) | AR012259A1 (https=) |
| AU (1) | AU8728598A (https=) |
| BR (1) | BR9810666A (https=) |
| CA (1) | CA2294918A1 (https=) |
| DE (2) | DE19728629A1 (https=) |
| ES (1) | ES2172908T3 (https=) |
| TW (1) | TW470755B (https=) |
| WO (1) | WO1999001489A1 (https=) |
| ZA (1) | ZA985868B (https=) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| DE10021565A1 (de) * | 2000-05-03 | 2001-11-22 | Basf Ag | Thermoplastische Formmassen mit verbesserter Schlagzähigkeit |
| US6617047B1 (en) | 1998-12-30 | 2003-09-09 | Basf Aktiengesellschaft | Method for coating apparatuses and parts of apparatuses used in chemical manufacturing |
| EP2025498A2 (de) | 2007-08-16 | 2009-02-18 | Evonik Degussa GmbH | Verfahren zur Dekorierung von Oberflächen |
| WO2012007269A1 (de) | 2010-07-12 | 2012-01-19 | Basf Se | Stabilisierte acrylnitril/styrol/butadien formmassen |
| WO2012019982A1 (en) * | 2010-08-09 | 2012-02-16 | Basf Se | Thermoplastic moulding compositions with improved adhesion of electroplated metal layer |
| WO2012080407A1 (en) * | 2010-12-16 | 2012-06-21 | Basf Se | Thermoplastic moulding compositions for metal plated articles with improved resistance against repeated impact |
| DE102011103882A1 (de) | 2011-03-25 | 2012-09-27 | Eckart Gmbh | Kupferhaltige Metallpigmente mit Metalloxidschicht und Kunststoffschicht, Verfahren zu deren Herstellung, Beschichtungsmittel und beschichteter Gegenstand |
| US8318262B2 (en) | 2006-12-22 | 2012-11-27 | Eckart Gmbh | Use of spherical metal particles as laser-marking or laser-weldability agents, and laser-markable and/or laser-weldable plastic |
| DE102011052119A1 (de) | 2011-07-25 | 2013-01-31 | Eckart Gmbh | Verfahren zur Substratbeschichtung und Verwendung additivversehener, pulverförmiger Beschichtungsmaterialien in derartigen Verfahren |
| WO2013014211A2 (de) | 2011-07-25 | 2013-01-31 | Eckart Gmbh | Verwendung speziell belegter, pulverförmiger beschichtungsmaterialien und beschichtungsverfahren unter einsatz derartiger beschichtungsmaterialien |
| WO2013014213A2 (de) | 2011-07-25 | 2013-01-31 | Eckart Gmbh | Verfahren zur substratbeschichtung und verwendung additivversehener, pulverförmiger beschichtungsmaterialien in derartigen verfahren |
| WO2013053649A1 (de) | 2011-10-13 | 2013-04-18 | Styrolution GmbH | Stabilisierte polyamid-abs formmassen |
| WO2013104527A1 (de) | 2012-01-13 | 2013-07-18 | Styrolution GmbH | Terpolymer-formmassen mit geringem gelbwert, verfahren zu deren herstellung sowie deren verwendung |
| US8877332B2 (en) | 2007-11-30 | 2014-11-04 | Eckart Gmbh | Use of a mixture comprising spherical metal particles and metal flakes as laser-marking or laser-weldability agents and laser markable and/or laser weldable plastic |
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| WO2017194380A1 (de) * | 2016-05-10 | 2017-11-16 | Ineos Styrolution Group Gmbh | Verfahren zur herstellung einer thermoplastischen formmasse |
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| DE19960855A1 (de) * | 1999-12-16 | 2001-06-28 | Basf Ag | Verfahren zur Herstellung von thermoplastischen Formmassen |
| DE10060411A1 (de) * | 2000-12-05 | 2002-06-06 | Bayer Ag | Thermoplastische Formmassen |
| US6637213B2 (en) * | 2001-01-19 | 2003-10-28 | Crane Plastics Company Llc | Cooling of extruded and compression molded materials |
| US6578368B1 (en) * | 2001-01-19 | 2003-06-17 | Crane Plastics Company Llc | Cryogenic cooling of extruded and compression molded materials |
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| GB0206880D0 (en) | 2002-03-23 | 2002-05-01 | Rolls Royce Plc | A vane for a rotor arrangement for a gas turbine engine |
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| FR2895085B1 (fr) | 2005-12-21 | 2008-07-04 | Breuil Sa Engineering Const Et | Dispositf de mirage d'oeufs. |
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| DE102008015124A1 (de) | 2007-05-16 | 2008-11-20 | Bayer Materialscience Ag | Schlagzähmodifizierte Polycarbonat-Zusammensetzungen |
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| DE3505749A1 (de) | 1985-02-20 | 1986-08-21 | Bayer Ag, 5090 Leverkusen | Formmassen mit einheitlicher korngroesse und verbesserter thermostabilitaet ii |
| US5817266A (en) | 1994-01-27 | 1998-10-06 | Basf Aktiengesellschaft | Dewatering of water-moist graft rubber |
| DE4402394B4 (de) | 1994-01-27 | 2005-02-10 | Basf Ag | Verfahren zur Entwässerung von wasserfeuchtem Pfropfkautschuk |
| AU1836095A (en) * | 1994-02-22 | 1995-09-04 | Dow Chemical Company, The | Process for the preparation of multimodal abs polymers |
| DE4414124A1 (de) | 1994-04-22 | 1995-10-26 | Bayer Ag | ABS-Formmassen mit verbesserter Zähigkeit |
| EP0712895B1 (en) | 1994-11-21 | 1999-04-28 | General Electric Company | Impact modified alpha alkyl substituted vinyl aromatic-vinyl cyanide thermoplastic compositions |
| DE19520286A1 (de) | 1995-06-02 | 1996-12-05 | Bayer Ag | ABS-Formmassen mit verbesserten Eigenschaften |
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- 1998-06-23 WO PCT/EP1998/003836 patent/WO1999001489A1/de not_active Ceased
- 1998-06-23 JP JP50626499A patent/JP2002510349A/ja active Pending
- 1998-06-23 BR BR9810666-0A patent/BR9810666A/pt not_active Application Discontinuation
- 1998-06-23 CA CA002294918A patent/CA2294918A1/en not_active Abandoned
- 1998-06-23 AU AU87285/98A patent/AU8728598A/en not_active Abandoned
- 1998-06-23 US US09/446,982 patent/US6323279B1/en not_active Expired - Lifetime
- 1998-06-23 KR KR1020007000027A patent/KR100361001B1/ko not_active Expired - Lifetime
- 1998-06-23 EP EP98938632A patent/EP0993476B1/de not_active Expired - Lifetime
- 1998-06-23 ES ES98938632T patent/ES2172908T3/es not_active Expired - Lifetime
- 1998-06-23 DE DE59803025T patent/DE59803025D1/de not_active Expired - Lifetime
- 1998-07-02 TW TW087110695A patent/TW470755B/zh not_active IP Right Cessation
- 1998-07-03 ZA ZA9805868A patent/ZA985868B/xx unknown
- 1998-07-03 AR ARP980103236A patent/AR012259A1/es unknown
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| US6617047B1 (en) | 1998-12-30 | 2003-09-09 | Basf Aktiengesellschaft | Method for coating apparatuses and parts of apparatuses used in chemical manufacturing |
| US6835775B2 (en) | 2000-05-03 | 2004-12-28 | Basf Aktiengesellschaft | Thermoplastic molding compounds with improved impact resistance |
| DE10021565A1 (de) * | 2000-05-03 | 2001-11-22 | Basf Ag | Thermoplastische Formmassen mit verbesserter Schlagzähigkeit |
| DE102005022635B4 (de) * | 2005-05-11 | 2018-05-30 | Ineos Styrolution Europe Gmbh | Thermoplastische Formmassen mit verbesserter Anfärbbarkeit |
| US8318262B2 (en) | 2006-12-22 | 2012-11-27 | Eckart Gmbh | Use of spherical metal particles as laser-marking or laser-weldability agents, and laser-markable and/or laser-weldable plastic |
| EP2025498A2 (de) | 2007-08-16 | 2009-02-18 | Evonik Degussa GmbH | Verfahren zur Dekorierung von Oberflächen |
| DE102007038578A1 (de) | 2007-08-16 | 2009-02-19 | Evonik Degussa Gmbh | Verfahren zur Dekorierung von Oberflächen |
| US8877332B2 (en) | 2007-11-30 | 2014-11-04 | Eckart Gmbh | Use of a mixture comprising spherical metal particles and metal flakes as laser-marking or laser-weldability agents and laser markable and/or laser weldable plastic |
| WO2012007269A1 (de) | 2010-07-12 | 2012-01-19 | Basf Se | Stabilisierte acrylnitril/styrol/butadien formmassen |
| WO2012019982A1 (en) * | 2010-08-09 | 2012-02-16 | Basf Se | Thermoplastic moulding compositions with improved adhesion of electroplated metal layer |
| WO2012080407A1 (en) * | 2010-12-16 | 2012-06-21 | Basf Se | Thermoplastic moulding compositions for metal plated articles with improved resistance against repeated impact |
| US9650506B2 (en) | 2010-12-16 | 2017-05-16 | Ineos Styrolution Europe Gmbh | Thermoplastic moulding compositions for metal plated articles with improved resistance against repeated impact |
| WO2012130680A1 (de) | 2011-03-25 | 2012-10-04 | Eckart Gmbh | Kupferhaltige metallpigmente mit metalloxidschicht und kunststoffschicht, verfahren zu deren herstellung, beschichtungsmittel und beschichteter gegenstand |
| DE102011103882A1 (de) | 2011-03-25 | 2012-09-27 | Eckart Gmbh | Kupferhaltige Metallpigmente mit Metalloxidschicht und Kunststoffschicht, Verfahren zu deren Herstellung, Beschichtungsmittel und beschichteter Gegenstand |
| US9777160B2 (en) | 2011-03-25 | 2017-10-03 | Eckart Gmbh | Copper-containing metal pigments with a metal oxide layer and a plastic layer, method for the production thereof, coating agent and coated object |
| WO2013014211A2 (de) | 2011-07-25 | 2013-01-31 | Eckart Gmbh | Verwendung speziell belegter, pulverförmiger beschichtungsmaterialien und beschichtungsverfahren unter einsatz derartiger beschichtungsmaterialien |
| DE102011052120A1 (de) | 2011-07-25 | 2013-01-31 | Eckart Gmbh | Verwendung speziell belegter, pulverförmiger Beschichtungsmaterialien und Beschichtungsverfahren unter Einsatz derartiger Beschichtungsmaterialien |
| WO2013014213A2 (de) | 2011-07-25 | 2013-01-31 | Eckart Gmbh | Verfahren zur substratbeschichtung und verwendung additivversehener, pulverförmiger beschichtungsmaterialien in derartigen verfahren |
| DE102011052119A1 (de) | 2011-07-25 | 2013-01-31 | Eckart Gmbh | Verfahren zur Substratbeschichtung und Verwendung additivversehener, pulverförmiger Beschichtungsmaterialien in derartigen Verfahren |
| WO2013053649A1 (de) | 2011-10-13 | 2013-04-18 | Styrolution GmbH | Stabilisierte polyamid-abs formmassen |
| WO2013104527A1 (de) | 2012-01-13 | 2013-07-18 | Styrolution GmbH | Terpolymer-formmassen mit geringem gelbwert, verfahren zu deren herstellung sowie deren verwendung |
| US9249290B2 (en) | 2012-01-13 | 2016-02-02 | Styrolution Europe Gmbh | Terpolymer molding compounds with a low yellow index, method for producing same, and use thereof |
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| WO2017194380A1 (de) * | 2016-05-10 | 2017-11-16 | Ineos Styrolution Group Gmbh | Verfahren zur herstellung einer thermoplastischen formmasse |
| US10710274B2 (en) | 2016-05-10 | 2020-07-14 | Ineos Styrolution Group Gmbh | Method for producing a thermoplastic moulding compound |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1269808A (zh) | 2000-10-11 |
| DE59803025D1 (de) | 2002-03-21 |
| AU8728598A (en) | 1999-01-25 |
| TW470755B (en) | 2002-01-01 |
| ZA985868B (en) | 2000-01-10 |
| EP0993476B1 (de) | 2002-02-06 |
| ES2172908T3 (es) | 2002-10-01 |
| BR9810666A (pt) | 2000-09-26 |
| CN1140551C (zh) | 2004-03-03 |
| EP0993476A1 (de) | 2000-04-19 |
| JP2002510349A (ja) | 2002-04-02 |
| CA2294918A1 (en) | 1999-01-14 |
| WO1999001489A1 (de) | 1999-01-14 |
| KR100361001B1 (ko) | 2002-11-22 |
| US6323279B1 (en) | 2001-11-27 |
| AR012259A1 (es) | 2000-09-27 |
| KR20010021502A (ko) | 2001-03-15 |
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