DE19634700A1 - Verfahren zur Herstellung von Polyurethanhartschaumstoffen - Google Patents
Verfahren zur Herstellung von PolyurethanhartschaumstoffenInfo
- Publication number
- DE19634700A1 DE19634700A1 DE19634700A DE19634700A DE19634700A1 DE 19634700 A1 DE19634700 A1 DE 19634700A1 DE 19634700 A DE19634700 A DE 19634700A DE 19634700 A DE19634700 A DE 19634700A DE 19634700 A1 DE19634700 A1 DE 19634700A1
- Authority
- DE
- Germany
- Prior art keywords
- weight
- polyamines
- blowing agent
- rigid polyurethane
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 229920005830 Polyurethane Foam Polymers 0.000 title claims description 15
- 238000000034 method Methods 0.000 title claims description 15
- 239000011496 polyurethane foam Substances 0.000 title claims description 15
- 238000004519 manufacturing process Methods 0.000 title claims description 12
- 239000006260 foam Substances 0.000 claims description 19
- 229920005862 polyol Polymers 0.000 claims description 17
- 150000003077 polyols Chemical class 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 16
- 239000004359 castor oil Substances 0.000 claims description 13
- 235000019438 castor oil Nutrition 0.000 claims description 13
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 13
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 claims description 11
- 229920001228 polyisocyanate Polymers 0.000 claims description 11
- 239000005056 polyisocyanate Substances 0.000 claims description 11
- 239000004604 Blowing Agent Substances 0.000 claims description 8
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 8
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 125000002947 alkylene group Chemical group 0.000 claims description 7
- 229920000768 polyamine Polymers 0.000 claims description 7
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 6
- 239000012948 isocyanate Substances 0.000 claims description 6
- 229920000570 polyether Polymers 0.000 claims description 6
- 239000000047 product Substances 0.000 claims description 6
- DGRGLKZMKWPMOH-UHFFFAOYSA-N 4-methylbenzene-1,2-diamine Chemical compound CC1=CC=C(N)C(N)=C1 DGRGLKZMKWPMOH-UHFFFAOYSA-N 0.000 claims description 5
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 5
- 239000000654 additive Substances 0.000 claims description 5
- 150000002513 isocyanates Chemical class 0.000 claims description 5
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 5
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 claims description 5
- 239000003054 catalyst Substances 0.000 claims description 4
- 239000007795 chemical reaction product Substances 0.000 claims description 4
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 claims description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
- 125000003118 aryl group Chemical group 0.000 claims description 3
- 238000010276 construction Methods 0.000 claims description 3
- 229920005906 polyester polyol Polymers 0.000 claims description 3
- 239000003063 flame retardant Substances 0.000 claims description 2
- 238000009413 insulation Methods 0.000 claims description 2
- 239000004744 fabric Substances 0.000 claims 1
- 238000005187 foaming Methods 0.000 description 9
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 6
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 5
- -1 isocyanates compounds Chemical class 0.000 description 5
- 239000011541 reaction mixture Substances 0.000 description 5
- 239000003381 stabilizer Substances 0.000 description 5
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 229920002635 polyurethane Polymers 0.000 description 4
- 239000004814 polyurethane Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- FZQMJOOSLXFQSU-UHFFFAOYSA-N 3-[3,5-bis[3-(dimethylamino)propyl]-1,3,5-triazinan-1-yl]-n,n-dimethylpropan-1-amine Chemical compound CN(C)CCCN1CN(CCCN(C)C)CN(CCCN(C)C)C1 FZQMJOOSLXFQSU-UHFFFAOYSA-N 0.000 description 3
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 239000012190 activator Substances 0.000 description 3
- 150000001335 aliphatic alkanes Chemical class 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920001296 polysiloxane Polymers 0.000 description 3
- VOZKAJLKRJDJLL-UHFFFAOYSA-N 2,4-diaminotoluene Chemical compound CC1=CC=C(N)C=C1N VOZKAJLKRJDJLL-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 239000000022 bacteriostatic agent Substances 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical group NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 230000001413 cellular effect Effects 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 230000001408 fungistatic effect Effects 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 2
- XFNJVJPLKCPIBV-UHFFFAOYSA-N trimethylenediamine Chemical compound NCCCN XFNJVJPLKCPIBV-UHFFFAOYSA-N 0.000 description 2
- CXIGIYYQHHRBJC-UHFFFAOYSA-N 1,1,1,4,4,4-hexafluorobutane Chemical compound FC(F)(F)CCC(F)(F)F CXIGIYYQHHRBJC-UHFFFAOYSA-N 0.000 description 1
- FRCHKSNAZZFGCA-UHFFFAOYSA-N 1,1-dichloro-1-fluoroethane Chemical compound CC(F)(Cl)Cl FRCHKSNAZZFGCA-UHFFFAOYSA-N 0.000 description 1
- CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical compound CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 description 1
- LFSYUSUFCBOHGU-UHFFFAOYSA-N 1-isocyanato-2-[(4-isocyanatophenyl)methyl]benzene Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=CC=C1N=C=O LFSYUSUFCBOHGU-UHFFFAOYSA-N 0.000 description 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- OHKOAJUTRVTYSW-UHFFFAOYSA-N 2-[(2-aminophenyl)methyl]aniline Chemical compound NC1=CC=CC=C1CC1=CC=CC=C1N OHKOAJUTRVTYSW-UHFFFAOYSA-N 0.000 description 1
- OBCSAIDCZQSFQH-UHFFFAOYSA-N 2-methyl-1,4-phenylenediamine Chemical compound CC1=CC(N)=CC=C1N OBCSAIDCZQSFQH-UHFFFAOYSA-N 0.000 description 1
- AXNUJYHFQHQZBE-UHFFFAOYSA-N 3-methylbenzene-1,2-diamine Chemical compound CC1=CC=CC(N)=C1N AXNUJYHFQHQZBE-UHFFFAOYSA-N 0.000 description 1
- YBRVSVVVWCFQMG-UHFFFAOYSA-N 4,4'-diaminodiphenylmethane Chemical compound C1=CC(N)=CC=C1CC1=CC=C(N)C=C1 YBRVSVVVWCFQMG-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 238000005684 Liebig rearrangement reaction Methods 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- AWMVMTVKBNGEAK-UHFFFAOYSA-N Styrene oxide Chemical compound C1OC1C1=CC=CC=C1 AWMVMTVKBNGEAK-UHFFFAOYSA-N 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 150000004982 aromatic amines Chemical class 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- VPKDCDLSJZCGKE-UHFFFAOYSA-N carbodiimide group Chemical group N=C=N VPKDCDLSJZCGKE-UHFFFAOYSA-N 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 210000000038 chest Anatomy 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000000779 depleting effect Effects 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- MGHPNCMVUAKAIE-UHFFFAOYSA-N diphenylmethanamine Chemical compound C=1C=CC=CC=1C(N)C1=CC=CC=C1 MGHPNCMVUAKAIE-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 239000004872 foam stabilizing agent Substances 0.000 description 1
- DYDNPESBYVVLBO-UHFFFAOYSA-N formanilide Chemical compound O=CNC1=CC=CC=C1 DYDNPESBYVVLBO-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical group OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- LSHROXHEILXKHM-UHFFFAOYSA-N n'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine Chemical compound NCCNCCNCCNCCNCCN LSHROXHEILXKHM-UHFFFAOYSA-N 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical class CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- MSSNHSVIGIHOJA-UHFFFAOYSA-N pentafluoropropane Chemical compound FC(F)CC(F)(F)F MSSNHSVIGIHOJA-UHFFFAOYSA-N 0.000 description 1
- 150000004986 phenylenediamines Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920006149 polyester-amide block copolymer Polymers 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- KIDHWZJUCRJVML-UHFFFAOYSA-N putrescine Chemical compound NCCCCN KIDHWZJUCRJVML-UHFFFAOYSA-N 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
- 150000004998 toluenediamines Chemical class 0.000 description 1
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
- AVWRKZWQTYIKIY-UHFFFAOYSA-N urea-1-carboxylic acid Chemical group NC(=O)NC(O)=O AVWRKZWQTYIKIY-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4804—Two or more polyethers of different physical or chemical nature
- C08G18/482—Mixtures of polyethers containing at least one polyether containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3271—Hydroxyamines
- C08G18/329—Hydroxyamines containing aromatic groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4891—Polyethers modified with higher fatty oils or their acids or by resin acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/50—Polyethers having heteroatoms other than oxygen
- C08G18/5021—Polyethers having heteroatoms other than oxygen having nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/50—Polyethers having heteroatoms other than oxygen
- C08G18/5021—Polyethers having heteroatoms other than oxygen having nitrogen
- C08G18/5033—Polyethers having heteroatoms other than oxygen having nitrogen containing carbocyclic groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6666—Compounds of group C08G18/48 or C08G18/52
- C08G18/6696—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/36 or hydroxylated esters of higher fatty acids of C08G18/38
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0025—Foam properties rigid
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Polyurethanes Or Polyureas (AREA)
Priority Applications (10)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19634700A DE19634700A1 (de) | 1996-08-28 | 1996-08-28 | Verfahren zur Herstellung von Polyurethanhartschaumstoffen |
| US08/904,894 US5886062A (en) | 1996-08-28 | 1997-08-01 | Process for the production of rigid polyurethane foams |
| MX9706240A MX9706240A (es) | 1996-08-28 | 1997-08-15 | Procedimiento para la produccion de espumas duras en poliuretano. |
| EP00106008A EP1028134A1 (de) | 1996-08-28 | 1997-08-18 | Verfahren zur Herstellung von Polyurethanhartschaumstoffen |
| ES97114241T ES2210432T3 (es) | 1996-08-28 | 1997-08-18 | Procedimiento para la fabricacion de espumas rigidas de poliuretano. |
| EP97114241A EP0826708B1 (de) | 1996-08-28 | 1997-08-18 | Verfahren zur Herstellung von Polyurethanhartschaumstoffen |
| DE59710943T DE59710943D1 (de) | 1996-08-28 | 1997-08-18 | Verfahren zur Herstellung von Polyurethanhartschaumstoffen |
| CA002213925A CA2213925C (en) | 1996-08-28 | 1997-08-25 | Process for the production of rigid polyurethane foams |
| JP9241710A JPH10101763A (ja) | 1996-08-28 | 1997-08-25 | 硬質ポリウレタンフォームの製造方法 |
| BR9704523A BR9704523A (pt) | 1996-08-28 | 1997-08-27 | Processo para a produção de espumas de poliuretano rígidas |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19634700A DE19634700A1 (de) | 1996-08-28 | 1996-08-28 | Verfahren zur Herstellung von Polyurethanhartschaumstoffen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE19634700A1 true DE19634700A1 (de) | 1998-03-05 |
Family
ID=7803879
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19634700A Withdrawn DE19634700A1 (de) | 1996-08-28 | 1996-08-28 | Verfahren zur Herstellung von Polyurethanhartschaumstoffen |
| DE59710943T Expired - Lifetime DE59710943D1 (de) | 1996-08-28 | 1997-08-18 | Verfahren zur Herstellung von Polyurethanhartschaumstoffen |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE59710943T Expired - Lifetime DE59710943D1 (de) | 1996-08-28 | 1997-08-18 | Verfahren zur Herstellung von Polyurethanhartschaumstoffen |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US5886062A (cg-RX-API-DMAC7.html) |
| EP (2) | EP0826708B1 (cg-RX-API-DMAC7.html) |
| JP (1) | JPH10101763A (cg-RX-API-DMAC7.html) |
| BR (1) | BR9704523A (cg-RX-API-DMAC7.html) |
| CA (1) | CA2213925C (cg-RX-API-DMAC7.html) |
| DE (2) | DE19634700A1 (cg-RX-API-DMAC7.html) |
| ES (1) | ES2210432T3 (cg-RX-API-DMAC7.html) |
| MX (1) | MX9706240A (cg-RX-API-DMAC7.html) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000047648A1 (de) * | 1999-02-11 | 2000-08-17 | Bayer Aktiengesellschaft | Verfahren zur herstellung von polyurethan-hartschaumstoffen mit verbesserter formstandzeit |
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|---|---|---|---|---|
| US7204848B1 (en) | 1995-03-01 | 2007-04-17 | Boston Scientific Scimed, Inc. | Longitudinally flexible expandable stent |
| US6288133B1 (en) * | 1997-09-10 | 2001-09-11 | H. B. Fuller Licensing & Financing Inc. | Foaming urethane composition and methods of using such compositions |
| US6455605B1 (en) | 1997-09-10 | 2002-09-24 | H. B. Fuller Licensing & Financing Inc. | Foamable composition exhibiting instant thixotropic gelling |
| JP4146572B2 (ja) * | 1999-04-08 | 2008-09-10 | 住化バイエルウレタン株式会社 | 硬質ポリウレタンフォームの製造方法及び硬質ポリウレタンフォーム用組成物 |
| DE19916647B4 (de) * | 1999-04-14 | 2006-06-08 | Bayer Materialscience Ag | Polyolgemisch für die Herstellung von Polyurethan-Hartschäumen |
| US6420443B1 (en) | 1999-09-09 | 2002-07-16 | Crompton Corporation | Additives for enhanced hydrocarbon compatibility in rigid polyurethane foam systems |
| US8070792B2 (en) | 2000-09-22 | 2011-12-06 | Boston Scientific Scimed, Inc. | Stent |
| US20030083394A1 (en) | 2001-06-07 | 2003-05-01 | Clatty Jan L. | Polyurethane foams having improved heat sag and a process for their production |
| DE10162344A1 (de) * | 2001-12-18 | 2003-07-10 | Henkel Kgaa | Schwerbrennbare Polyurethanklebstoffe |
| KR100850995B1 (ko) * | 2002-01-04 | 2008-08-12 | 주식회사 엘지이아이 | 경질 폴리우레탄 발포체 제조용 조성물 및 그로부터제조된 경질 폴리우레탄 발포체 |
| US7300961B2 (en) * | 2002-06-24 | 2007-11-27 | Bayer Materialscience Llc | Polyol compositions useful for preparing dimensionally stable, low density water-blown rigid foams and the processes related thereto |
| US7682381B2 (en) * | 2004-04-23 | 2010-03-23 | Boston Scientific Scimed, Inc. | Composite medical textile material and implantable devices made therefrom |
| US20080161441A1 (en) * | 2006-12-27 | 2008-07-03 | Lance Wang | Rigid polyurethane/polyisocyanurate castor oil based foams |
| KR20100103691A (ko) * | 2008-01-17 | 2010-09-27 | 다우 글로벌 테크놀로지스 인크. | 열적 단열성 이소시아네이트-계 발포체 |
| US20090270522A1 (en) * | 2008-04-25 | 2009-10-29 | Honeywell International Inc. | Blowing agents for polymeric foams |
| US9834638B2 (en) * | 2008-06-04 | 2017-12-05 | Covestro Llc | Process for preparing rigid polyisocyanurate foams using natural-oil polyols |
| RU2525240C2 (ru) * | 2009-03-18 | 2014-08-10 | Басф Се | Способ получения жестких пенополиуретанов |
| US20110034580A1 (en) * | 2009-08-07 | 2011-02-10 | ATI Industries, Inc. | Carbon-Negative Bio-Plastic Furniture |
| JP5627333B2 (ja) * | 2010-08-12 | 2014-11-19 | 住化バイエルウレタン株式会社 | インテグラルスキンフォーム用ポリウレタン組成物 |
| MA35041B1 (fr) | 2011-04-15 | 2014-04-03 | Basf Se | Procédé de fabrication de mousses de polyuréthane dures |
| PT2697296T (pt) | 2011-04-15 | 2017-05-30 | Basf Se | Processo para preparação de espumas rígidas de poliuretano |
| US9334383B2 (en) * | 2011-04-15 | 2016-05-10 | Basf Se | Process for producing rigid polyurethane foams |
| US20120264842A1 (en) * | 2011-04-15 | 2012-10-18 | Basf Se | Process for producing rigid polyurethane foams |
| US20130030073A1 (en) * | 2011-07-26 | 2013-01-31 | Bayer Materialscience Llc | Amine-initiated polyols from renewable resources and processes for their production and use |
| EP2634201A1 (de) | 2012-03-01 | 2013-09-04 | Basf Se | Polyurethan-Hartschaumstoffe |
| US9353234B2 (en) | 2012-03-01 | 2016-05-31 | Basf Se | Rigid polyurethane foams |
| JP2015532315A (ja) | 2012-09-27 | 2015-11-09 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 脂肪酸変性ポリエーテルポリオールを主原料とする硬質ポリウレタン及びポリイソシアヌレート |
| EP3033369B1 (de) * | 2013-08-13 | 2018-07-18 | Covestro Deutschland AG | Polyurethanschaumstoffe und ihre verwendung |
| CN109219627A (zh) * | 2016-06-07 | 2019-01-15 | 科思创德国股份有限公司 | 多层结构及其制造和用途 |
| BR112019010988A2 (pt) * | 2016-11-29 | 2019-10-15 | Covestro Deutschland Ag | espuma rígida de poliuretano, método para produzir a mesma e uso da mesma |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2955091A (en) * | 1957-08-27 | 1960-10-04 | Du Pont | Compositions comprising reaction product of a polyalkyleneether glycol, a fatty acid triglyceride, and an arylene diisocyanate and foam prepared therefrom |
| GB893746A (en) * | 1959-01-21 | 1962-04-11 | Ici Ltd | Improvements in cellular polyurethanes |
| IT649594A (cg-RX-API-DMAC7.html) * | 1960-04-12 | |||
| GB1311095A (en) * | 1969-04-09 | 1973-03-21 | Ici Ltd | Alkylene oxide orthotolylene diamine compositions |
| DE2704196A1 (de) * | 1977-02-02 | 1978-08-10 | Basf Ag | Verfahren zur herstellung von polyurethanhartschaumstoffen |
| US4225678A (en) * | 1979-07-19 | 1980-09-30 | George F. Thagard, Jr. | Foamed polyurethane materials with a bitumen and a hydroxy fatty oil |
| DE3629390A1 (de) * | 1986-07-04 | 1988-02-18 | Bayer Ag | Polyolkomposition und ihre verwendung zur herstellung von flammwidrigen polyurethanschaumstoffen |
| DE3740634A1 (de) * | 1987-12-01 | 1989-06-15 | Bayer Ag | Polyetherpolyole auf basis o-toluylendiamin, verfahren zu ihrer herstellung und verwendung fuer polyurethan- und polyisocyanurat-kunststoffe |
| US5112876A (en) * | 1988-10-28 | 1992-05-12 | Takeda Chemical Industries, Ltd. | Polyether polyol and rigid polyurethane foam |
| DE3910100C1 (cg-RX-API-DMAC7.html) * | 1989-03-29 | 1990-01-04 | Bayer Ag, 5090 Leverkusen, De | |
| US5258418A (en) * | 1992-12-04 | 1993-11-02 | Basf Corporation | Low density, water-blown, rigid polyurethane foams having good physical properties and improved initial surface friability |
| US5260347A (en) * | 1992-12-04 | 1993-11-09 | Basf Corporation | Low density, water-blown, rigid polyurethane foams having good physical properties and improved initial surface friability |
| US5547608A (en) * | 1994-09-09 | 1996-08-20 | Basf Corporation | Polyurethane SRIM compositions having internal mold release properties |
| US5451615A (en) * | 1994-10-20 | 1995-09-19 | The Dow Chemical Company | Process for preparing polyurethane foam in the presence of a hydrocarbon blowing agent |
| DE19502578A1 (de) * | 1995-01-27 | 1996-08-01 | Bayer Ag | Neue Polyetherpolyole, Polyformulierung enthaltend diese Polyetherpolyole und deren Verwendnung zur Herstellung von harten Polyurethanschaumstoffen |
| DE19502969A1 (de) * | 1995-01-31 | 1996-08-01 | Elastogran Gmbh | Verfahren zur Herstellung von Polyurethan-Hartschaumstoffen |
| DE19521058A1 (de) * | 1995-06-09 | 1996-12-12 | Basf Ag | Verfahren zur Herstellung von Aromaten enthaltenden Polyetherpolyolen |
-
1996
- 1996-08-28 DE DE19634700A patent/DE19634700A1/de not_active Withdrawn
-
1997
- 1997-08-01 US US08/904,894 patent/US5886062A/en not_active Expired - Lifetime
- 1997-08-15 MX MX9706240A patent/MX9706240A/es unknown
- 1997-08-18 EP EP97114241A patent/EP0826708B1/de not_active Expired - Lifetime
- 1997-08-18 ES ES97114241T patent/ES2210432T3/es not_active Expired - Lifetime
- 1997-08-18 EP EP00106008A patent/EP1028134A1/de not_active Withdrawn
- 1997-08-18 DE DE59710943T patent/DE59710943D1/de not_active Expired - Lifetime
- 1997-08-25 JP JP9241710A patent/JPH10101763A/ja active Pending
- 1997-08-25 CA CA002213925A patent/CA2213925C/en not_active Expired - Fee Related
- 1997-08-27 BR BR9704523A patent/BR9704523A/pt not_active IP Right Cessation
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000047648A1 (de) * | 1999-02-11 | 2000-08-17 | Bayer Aktiengesellschaft | Verfahren zur herstellung von polyurethan-hartschaumstoffen mit verbesserter formstandzeit |
Also Published As
| Publication number | Publication date |
|---|---|
| DE59710943D1 (de) | 2003-12-11 |
| CA2213925C (en) | 2007-08-07 |
| US5886062A (en) | 1999-03-23 |
| MX9706240A (es) | 1998-02-28 |
| ES2210432T3 (es) | 2004-07-01 |
| EP1028134A1 (de) | 2000-08-16 |
| EP0826708B1 (de) | 2003-11-05 |
| CA2213925A1 (en) | 1998-02-28 |
| JPH10101763A (ja) | 1998-04-21 |
| BR9704523A (pt) | 1998-12-22 |
| EP0826708A1 (de) | 1998-03-04 |
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