DE1767113C2 - Verfahren zur Herstellung von Hydroxylammoniumsulfat - Google Patents
Verfahren zur Herstellung von HydroxylammoniumsulfatInfo
- Publication number
- DE1767113C2 DE1767113C2 DE19681767113 DE1767113A DE1767113C2 DE 1767113 C2 DE1767113 C2 DE 1767113C2 DE 19681767113 DE19681767113 DE 19681767113 DE 1767113 A DE1767113 A DE 1767113A DE 1767113 C2 DE1767113 C2 DE 1767113C2
- Authority
- DE
- Germany
- Prior art keywords
- hydrogen
- nitrogen oxide
- gas
- reaction
- ratio
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 14
- VGYYSIDKAKXZEE-UHFFFAOYSA-L hydroxylammonium sulfate Chemical compound O[NH3+].O[NH3+].[O-]S([O-])(=O)=O VGYYSIDKAKXZEE-UHFFFAOYSA-L 0.000 title claims description 10
- 229910000378 hydroxylammonium sulfate Inorganic materials 0.000 title claims description 10
- 238000004519 manufacturing process Methods 0.000 title description 2
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 claims description 58
- 239000007789 gas Substances 0.000 claims description 37
- 229910052739 hydrogen Inorganic materials 0.000 claims description 25
- 239000001257 hydrogen Substances 0.000 claims description 25
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 21
- 239000003054 catalyst Substances 0.000 claims description 16
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 15
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 14
- 229910052697 platinum Inorganic materials 0.000 claims description 7
- 238000010924 continuous production Methods 0.000 claims description 3
- GQPLMRYTRLFLPF-UHFFFAOYSA-N Nitrous Oxide Chemical compound [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 35
- 239000000203 mixture Substances 0.000 description 21
- 239000002253 acid Substances 0.000 description 13
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 10
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 10
- 239000001272 nitrous oxide Substances 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 229910021529 ammonia Inorganic materials 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 4
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 3
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 3
- 235000011130 ammonium sulphate Nutrition 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 239000012295 chemical reaction liquid Substances 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- XHRCFGDFESIFRG-UHFFFAOYSA-N 2-chloro-n-ethyl-n-[(2-methylphenyl)methyl]ethanamine Chemical compound ClCCN(CC)CC1=CC=CC=C1C XHRCFGDFESIFRG-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- 101100330771 Neurospora crassa (strain ATCC 24698 / 74-OR23-1A / CBS 708.71 / DSM 1257 / FGSC 987) dbp-9 gene Proteins 0.000 description 1
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000003292 diminished effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 229910052711 selenium Inorganic materials 0.000 description 1
- 239000011669 selenium Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052714 tellurium Inorganic materials 0.000 description 1
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B21/00—Nitrogen; Compounds thereof
- C01B21/082—Compounds containing nitrogen and non-metals and optionally metals
- C01B21/14—Hydroxylamine; Salts thereof
- C01B21/1409—Preparation
- C01B21/1418—Preparation by catalytic reduction of nitrogen oxides or nitrates with hydrogen
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19681767113 DE1767113C2 (de) | 1968-04-03 | 1968-04-03 | Verfahren zur Herstellung von Hydroxylammoniumsulfat |
| FR6909669A FR2005436A1 (en)) | 1968-04-03 | 1969-03-31 | |
| CH486769A CH500133A (de) | 1968-04-03 | 1969-03-31 | Verfahren zur Herstellung von Hydroxylammoniumsulfat |
| BE730855D BE730855A (en)) | 1968-04-03 | 1969-04-01 | |
| GB1257363D GB1257363A (en)) | 1968-04-03 | 1969-04-02 | |
| NL6905162A NL164829B (nl) | 1968-04-03 | 1969-04-02 | Werkwijze voor het continu bereiden van hydroxyl- ammoniumsulfaat. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19681767113 DE1767113C2 (de) | 1968-04-03 | 1968-04-03 | Verfahren zur Herstellung von Hydroxylammoniumsulfat |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE1767113A1 DE1767113A1 (de) | 1971-08-12 |
| DE1767113C2 true DE1767113C2 (de) | 1981-10-15 |
Family
ID=5699231
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19681767113 Expired DE1767113C2 (de) | 1968-04-03 | 1968-04-03 | Verfahren zur Herstellung von Hydroxylammoniumsulfat |
Country Status (6)
| Country | Link |
|---|---|
| BE (1) | BE730855A (en)) |
| CH (1) | CH500133A (en)) |
| DE (1) | DE1767113C2 (en)) |
| FR (1) | FR2005436A1 (en)) |
| GB (1) | GB1257363A (en)) |
| NL (1) | NL164829B (en)) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4132800A1 (de) * | 1991-10-02 | 1993-04-08 | Basf Ag | Verfahren zur herstellung von hydroxylammoniumsulfat |
| KR20140024872A (ko) * | 2011-04-22 | 2014-03-03 | 디에스엠 아이피 어셋츠 비.브이. | 촉매를 사용하는 하이드록실아민의 제조 방법 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL74063C (en)) * | 1949-08-27 | |||
| NL123476C (en)) * | 1963-03-08 |
-
1968
- 1968-04-03 DE DE19681767113 patent/DE1767113C2/de not_active Expired
-
1969
- 1969-03-31 CH CH486769A patent/CH500133A/de not_active IP Right Cessation
- 1969-03-31 FR FR6909669A patent/FR2005436A1/fr not_active Withdrawn
- 1969-04-01 BE BE730855D patent/BE730855A/xx not_active IP Right Cessation
- 1969-04-02 NL NL6905162A patent/NL164829B/xx not_active Application Discontinuation
- 1969-04-02 GB GB1257363D patent/GB1257363A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| FR2005436A1 (en)) | 1969-12-12 |
| NL164829B (nl) | 1980-09-15 |
| DE1767113A1 (de) | 1971-08-12 |
| BE730855A (en)) | 1969-10-01 |
| CH500133A (de) | 1970-12-15 |
| NL6905162A (en)) | 1969-10-07 |
| GB1257363A (en)) | 1971-12-15 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| D2 | Grant after examination | ||
| 8330 | Complete disclaimer |