DE1618578C - - Google Patents

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Publication number

DE1618578C

DE1618578C DE1618578C DE 1618578 C DE1618578 C DE 1618578C DE 1618578 C DE1618578 C DE 1618578C

Authority

DE

Germany

Prior art keywords

peroxydicarbonates

tert

substituted

decomposition

peroxydicarbonate

Prior art date

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

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• -1 tert-amyl Chemical group 0.000 claims description 8
• 125000005634 peroxydicarbonate group Chemical group 0.000 claims description 7
• BLCKNMAZFRMCJJ-UHFFFAOYSA-N cyclohexyl cyclohexyloxycarbonyloxy carbonate Chemical class C1CCCCC1OC(=O)OOC(=O)OC1CCCCC1 BLCKNMAZFRMCJJ-UHFFFAOYSA-N 0.000 claims description 4
• MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 2
• 239000002253 acid Substances 0.000 claims description 2
• 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 2
• 150000002148 esters Chemical class 0.000 claims description 2
• 229910052739 hydrogen Inorganic materials 0.000 claims description 2
• 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 2
• 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 2
• 238000000354 decomposition reaction Methods 0.000 description 9
• 239000007858 starting material Substances 0.000 description 4
• BEQKKZICTDFVMG-UHFFFAOYSA-N 1,2,3,4,6-pentaoxepane-5,7-dione Chemical compound O=C1OOOOC(=O)O1 BEQKKZICTDFVMG-UHFFFAOYSA-N 0.000 description 3
• HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
• OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
• 239000003999 initiator Substances 0.000 description 2
• 150000002978 peroxides Chemical class 0.000 description 2
• 238000006116 polymerization reaction Methods 0.000 description 2
• 238000003756 stirring Methods 0.000 description 2
• BGVTUNYGVHSKMD-UHFFFAOYSA-N (4-cyclohexylcyclohexyl) (4-cyclohexylcyclohexyl)oxycarbonyloxy carbonate Chemical compound C(=O)(OC1CCC(CC1)C1CCCCC1)OOC(=O)OC1CCC(CC1)C1CCCCC1 BGVTUNYGVHSKMD-UHFFFAOYSA-N 0.000 description 1
• VNPCSRKMRZPBBO-UHFFFAOYSA-N (4-propan-2-ylcyclohexyl) (4-propan-2-ylcyclohexyl)oxycarbonyloxy carbonate Chemical compound C(=O)(OC1CCC(CC1)C(C)C)OOC(=O)OC1CCC(CC1)C(C)C VNPCSRKMRZPBBO-UHFFFAOYSA-N 0.000 description 1
• QWIQFVKKPYUHAT-UHFFFAOYSA-N (4-propan-2-ylcyclohexyl) carbonochloridate Chemical compound CC(C)C1CCC(OC(Cl)=O)CC1 QWIQFVKKPYUHAT-UHFFFAOYSA-N 0.000 description 1
• YXFSGPPQRCUVRL-UHFFFAOYSA-N (4-tert-butylcyclohexyl) carbonochloridate Chemical compound CC(C)(C)C1CCC(OC(Cl)=O)CC1 YXFSGPPQRCUVRL-UHFFFAOYSA-N 0.000 description 1
• ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 2,3-dimethylbutane Chemical group CC(C)C(C)C ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 0.000 description 1
• RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
• VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
• 239000005977 Ethylene Substances 0.000 description 1
• DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
• QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
• QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
• 239000007844 bleaching agent Substances 0.000 description 1
• 230000000052 comparative effect Effects 0.000 description 1
• 150000001875 compounds Chemical class 0.000 description 1
• 239000003995 emulsifying agent Substances 0.000 description 1
• 238000002474 experimental method Methods 0.000 description 1
• 235000013312 flour Nutrition 0.000 description 1
• 239000011521 glass Substances 0.000 description 1
• KIWBRXCOTCXSSZ-UHFFFAOYSA-N hexyl carbonochloridate Chemical compound CCCCCCOC(Cl)=O KIWBRXCOTCXSSZ-UHFFFAOYSA-N 0.000 description 1
• 239000000203 mixture Substances 0.000 description 1
• 239000000178 monomer Substances 0.000 description 1
• 239000003921 oil Substances 0.000 description 1
• 229910052760 oxygen Inorganic materials 0.000 description 1
• 239000001301 oxygen Substances 0.000 description 1
• 239000005297 pyrex Substances 0.000 description 1
• 239000011541 reaction mixture Substances 0.000 description 1
• 229910052708 sodium Inorganic materials 0.000 description 1
• 239000011734 sodium Substances 0.000 description 1
• 239000007787 solid Substances 0.000 description 1
• 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1