DE160482T1 - Katalytischer abgasfilter fuer teilchen eines dieselmotors. - Google Patents

Katalytischer abgasfilter fuer teilchen eines dieselmotors.

Info

Publication number
DE160482T1
DE160482T1 DE198585302799T DE85302799T DE160482T1 DE 160482 T1 DE160482 T1 DE 160482T1 DE 198585302799 T DE198585302799 T DE 198585302799T DE 85302799 T DE85302799 T DE 85302799T DE 160482 T1 DE160482 T1 DE 160482T1
Authority
DE
Germany
Prior art keywords
filter
particles
alkaline earth
earth metal
filter according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DE198585302799T
Other languages
English (en)
Inventor
Joseph C. Howell New Jersey Dettling
Robert Paterson New Jersey Skomoroski
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Catalysts LLC
Original Assignee
Engelhard Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Engelhard Corp filed Critical Engelhard Corp
Publication of DE160482T1 publication Critical patent/DE160482T1/de
Pending legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/24Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
    • F01N3/28Construction of catalytic reactors
    • F01N3/2882Catalytic reactors combined or associated with other devices, e.g. exhaust silencers or other exhaust purification devices
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/92Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/944Simultaneously removing carbon monoxide, hydrocarbons or carbon making use of oxidation catalysts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56Platinum group metals
    • B01J23/58Platinum group metals with alkali- or alkaline earth metals
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/02Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
    • F01N3/021Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
    • F01N3/022Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters characterised by specially adapted filtering structure, e.g. honeycomb, mesh or fibrous
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/02Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
    • F01N3/021Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
    • F01N3/022Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters characterised by specially adapted filtering structure, e.g. honeycomb, mesh or fibrous
    • F01N3/0222Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters characterised by specially adapted filtering structure, e.g. honeycomb, mesh or fibrous the structure being monolithic, e.g. honeycombs
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/02Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
    • F01N3/021Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
    • F01N3/033Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters in combination with other devices
    • F01N3/035Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters in combination with other devices with catalytic reactors, e.g. catalysed diesel particulate filters
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2250/00Combinations of different methods of purification
    • F01N2250/02Combinations of different methods of purification filtering and catalytic conversion
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2330/00Structure of catalyst support or particle filter
    • F01N2330/06Ceramic, e.g. monoliths
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02BINTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
    • F02B3/00Engines characterised by air compression and subsequent fuel addition
    • F02B3/06Engines characterised by air compression and subsequent fuel addition with compression ignition

Claims (9)

Patentansprüche
1. Dieselabgaspartikelfilter, enthaltend ein hoch temperaturfestes Filterelement mit porösen Wänden, die dazu geeignet sind, in den Abgasen von Dieselmaschinen enthaltene Partikel zu filtern und die Partikel aus den Gasen, die durch das Element geleitet werden, an den Oberflächen der porösen Wände zu sammeln, wobei die Oberflächen der Wände zunächst mit einem Katalysator versehen worden sind, der aus einer Mischung aus einem Metall der Platingruppe und einem Erdalkalimetalloxyd besteht, welche Katalysatormischung die Temperatur herabsetzt, bei der die gesammelten Partikel gezündet und deren Verbrennung eingeleitet wird, wodurch die Partikel kontinuierlich durch Verbrennung mit relativ hohem Wirkungsgrad und niedrigem Druckabfall beseitigt werden.
2. Filter nach Anspruch 1, bei dem das Filter aus einem keramischen Material besteht.
3. Filter nach Anspruch 2, bei dem das Filter aus einem geschäumten keramischen Material besteht.
4. Filter nach Anspruch 2, bei dem das Filter aus einem keramischen monolithischen Material besteht.
5. Filter nach einem der vorhergehenden Ansprüche, bei dem das Metall der Platingruppe Platin ist.
6. Filter nach einem der vorhergehenden Ansprüche, bei dem das Erdalkalimetalloxyd Magnesiumoxyd ist.
7. Filter nach Anspruch 5, bei dem das Platinmetall an der Oberfläche des Filters mit einer Konzentration von etwa 5 bis 150 g pro Kubikfuß der Filteroberfläche vorhanden ist.
8. Filter nach Anspruch 6 oder Anspruch 7, bei dem das Erdalkalimetalloxyd an der Oberfläche des Filters mit einer Konzentration von etwa 30 bis 1500 g pro Kubikfuß der FiI-teroberflache vorhanden ist.
9. Filter nach einem der vorhergehenden Ansprüche, bei dem das Atomverhältnis zwischen dem Metall der Platingruppe und dem Erdalkalimetall in der Katalysatormischung zwischen etwa 1:60 und etwa 1:6 liegt.
DE198585302799T 1984-04-23 1985-04-22 Katalytischer abgasfilter fuer teilchen eines dieselmotors. Pending DE160482T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US60278384A 1984-04-23 1984-04-23

Publications (1)

Publication Number Publication Date
DE160482T1 true DE160482T1 (de) 1986-04-10

Family

ID=24412791

Family Applications (2)

Application Number Title Priority Date Filing Date
DE8585302799T Expired DE3567385D1 (en) 1984-04-23 1985-04-22 Catalyzed diesel exhaust particulate filter
DE198585302799T Pending DE160482T1 (de) 1984-04-23 1985-04-22 Katalytischer abgasfilter fuer teilchen eines dieselmotors.

Family Applications Before (1)

Application Number Title Priority Date Filing Date
DE8585302799T Expired DE3567385D1 (en) 1984-04-23 1985-04-22 Catalyzed diesel exhaust particulate filter

Country Status (5)

Country Link
EP (1) EP0160482B1 (de)
JP (1) JPH07106290B2 (de)
AT (1) ATE39853T1 (de)
CA (1) CA1242430A (de)
DE (2) DE3567385D1 (de)

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US6510686B2 (en) 2000-03-27 2003-01-28 Toyota Jidosha Kabushiki Kaisha Exhaust gas purifier for internal combustion engine and method for purifying exhaust gas
DE10114971B4 (de) * 2000-03-27 2011-08-11 Toyota Jidosha Kabushiki Kaisha, Aichi-ken Abgasreinigungsanlage für eine Verbrennungskraftmaschine
EP1138890B1 (de) * 2000-03-27 2005-05-18 Toyota Jidosha Kabushiki Kaisha Verfahren und Vorrichtung zum Reinigen von Abgasen einer Brennkraftmaschine
DE60110859T2 (de) * 2000-03-27 2006-01-19 Toyota Jidosha K.K., Toyota Vorrichtung zur Reinigung des Abgases einer Brennkraftmaschine
US6568178B2 (en) 2000-03-28 2003-05-27 Toyota Jidosha Kabushiki Kaisha Device for purifying the exhaust gas of an internal combustion engine
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JP3593305B2 (ja) 2000-07-03 2004-11-24 トヨタ自動車株式会社 内燃機関の排気装置
US20020007629A1 (en) 2000-07-21 2002-01-24 Toyota Jidosha Kabushiki Kaisha Device for purifying the exhaust gas of an internal combustion engine
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DE60106924T2 (de) 2000-07-24 2005-11-10 Toyota Jidosha K.K., Toyota Abgasreinigungsvorrichtung
JP4075292B2 (ja) 2000-07-24 2008-04-16 トヨタ自動車株式会社 パティキュレート浄化触媒
DE60115479T2 (de) 2000-09-20 2006-07-20 Toyota Jidosha K.K., Toyota Filter und verfahren zur kontrolle der abgasemissionen
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Also Published As

Publication number Publication date
DE3567385D1 (en) 1989-02-16
EP0160482A2 (de) 1985-11-06
JPS60235620A (ja) 1985-11-22
JPH07106290B2 (ja) 1995-11-15
EP0160482A3 (en) 1986-03-12
ATE39853T1 (de) 1989-01-15
CA1242430A (en) 1988-09-27
EP0160482B1 (de) 1989-01-11

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