DE1592441C3 - - Google Patents
Info
- Publication number
- DE1592441C3 DE1592441C3 DE19511592441 DE1592441A DE1592441C3 DE 1592441 C3 DE1592441 C3 DE 1592441C3 DE 19511592441 DE19511592441 DE 19511592441 DE 1592441 A DE1592441 A DE 1592441A DE 1592441 C3 DE1592441 C3 DE 1592441C3
- Authority
- DE
- Germany
- Prior art keywords
- copper
- electrolyte solution
- hydroxide
- cathode
- sulfate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- JJLJMEJHUUYSSY-UHFFFAOYSA-L copper(II) hydroxide Inorganic materials [OH-].[OH-].[Cu+2] JJLJMEJHUUYSSY-UHFFFAOYSA-L 0.000 claims description 51
- 238000000034 method Methods 0.000 claims description 35
- 239000008151 electrolyte solution Substances 0.000 claims description 28
- 239000010949 copper Substances 0.000 claims description 21
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 19
- 229910052802 copper Inorganic materials 0.000 claims description 18
- AEJIMXVJZFYIHN-UHFFFAOYSA-N copper;dihydrate Chemical compound O.O.[Cu] AEJIMXVJZFYIHN-UHFFFAOYSA-N 0.000 claims description 18
- 239000011734 sodium Substances 0.000 claims description 13
- 239000000243 solution Substances 0.000 claims description 13
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 11
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 11
- 235000011152 sodium sulphate Nutrition 0.000 claims description 11
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 10
- 239000001488 sodium phosphate Substances 0.000 claims description 9
- 229910000406 trisodium phosphate Inorganic materials 0.000 claims description 9
- 235000019801 trisodium phosphate Nutrition 0.000 claims description 9
- 238000005868 electrolysis reaction Methods 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 239000002244 precipitate Substances 0.000 claims description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 36
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 13
- 235000011121 sodium hydroxide Nutrition 0.000 description 12
- 239000000047 product Substances 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 9
- 229910019142 PO4 Inorganic materials 0.000 description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 7
- 239000010452 phosphate Substances 0.000 description 7
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 238000001914 filtration Methods 0.000 description 5
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 4
- 229910000365 copper sulfate Inorganic materials 0.000 description 4
- 229910000366 copper(II) sulfate Inorganic materials 0.000 description 4
- 239000003792 electrolyte Substances 0.000 description 4
- 239000012065 filter cake Substances 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- MNPICTSLNPAQOZ-UHFFFAOYSA-K copper;sodium;phosphate Chemical compound [Na+].[Cu+2].[O-]P([O-])([O-])=O MNPICTSLNPAQOZ-UHFFFAOYSA-K 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 239000012295 chemical reaction liquid Substances 0.000 description 2
- 229960004643 cupric oxide Drugs 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000000855 fungicidal effect Effects 0.000 description 2
- 239000000417 fungicide Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000006228 supernatant Substances 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- SOBHUZYZLFQYFK-UHFFFAOYSA-K trisodium;hydroxy-[[phosphonatomethyl(phosphonomethyl)amino]methyl]phosphinate Chemical compound [Na+].[Na+].[Na+].OP(O)(=O)CN(CP(O)([O-])=O)CP([O-])([O-])=O SOBHUZYZLFQYFK-UHFFFAOYSA-K 0.000 description 2
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 239000004135 Bone phosphate Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- YZCKVEUIGOORGS-OUBTZVSYSA-N Deuterium Chemical compound [2H] YZCKVEUIGOORGS-OUBTZVSYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000005267 amalgamation Methods 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- AUNBHCWCUYFLLY-UHFFFAOYSA-K copper sodium phosphoric acid phosphate Chemical compound P(=O)([O-])([O-])[O-].[Na+].P(=O)(O)(O)O.[Cu+2] AUNBHCWCUYFLLY-UHFFFAOYSA-K 0.000 description 1
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 1
- OTNFTBTWTMXVRF-UHFFFAOYSA-N copper;hydrate Chemical compound O.[Cu+2] OTNFTBTWTMXVRF-UHFFFAOYSA-N 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 230000000254 damaging effect Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- RCJVRSBWZCNNQT-UHFFFAOYSA-N dichloridooxygen Chemical compound ClOCl RCJVRSBWZCNNQT-UHFFFAOYSA-N 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- -1 hydroxyl ions Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000010871 livestock manure Substances 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000011164 primary particle Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 229910000679 solder Inorganic materials 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G3/00—Compounds of copper
- C01G3/02—Oxides; Hydroxides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/10—Particle morphology extending in one dimension, e.g. needle-like
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/50—Agglomerated particles
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Electrolytic Production Of Metals (AREA)
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19511592441 DE1592441A1 (de) | 1951-01-28 | 1951-01-28 | Elektrolytisches Verfahren zur Gewinnung von Kupferhydroxid |
| FR24361A FR1441900A (fr) | 1951-01-28 | 1965-07-12 | Procédé électrolytique de fabrication d'hydroxyde cuprique |
| GB2948065A GB1059745A (en) | 1951-01-28 | 1965-07-12 | Electrolytic method of making cupric hydroxide |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19511592441 DE1592441A1 (de) | 1951-01-28 | 1951-01-28 | Elektrolytisches Verfahren zur Gewinnung von Kupferhydroxid |
| DEK0056593 | 1965-07-12 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE1592441A1 DE1592441A1 (de) | 1970-12-17 |
| DE1592441B2 DE1592441B2 (enrdf_load_html_response) | 1974-04-18 |
| DE1592441C3 true DE1592441C3 (enrdf_load_html_response) | 1974-12-05 |
Family
ID=25753372
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19511592441 Granted DE1592441A1 (de) | 1951-01-28 | 1951-01-28 | Elektrolytisches Verfahren zur Gewinnung von Kupferhydroxid |
Country Status (2)
| Country | Link |
|---|---|
| DE (1) | DE1592441A1 (enrdf_load_html_response) |
| GB (1) | GB1059745A (enrdf_load_html_response) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4342620C1 (de) * | 1993-12-14 | 1995-07-06 | Starck H C Gmbh Co Kg | Verfahren zur Herstellung von Metallhydroxiden |
| US6596246B2 (en) * | 2001-03-20 | 2003-07-22 | Dermet Sa De Cv | Process for producing stable cupric hydroxide and basic cupric salts |
| CN114684847B (zh) * | 2020-12-25 | 2023-11-10 | 广州科城环保科技有限公司 | 氢氧化铜及其制备方法、应用和杀菌剂 |
-
1951
- 1951-01-28 DE DE19511592441 patent/DE1592441A1/de active Granted
-
1965
- 1965-07-12 GB GB2948065A patent/GB1059745A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| DE1592441A1 (de) | 1970-12-17 |
| GB1059745A (en) | 1967-02-22 |
| DE1592441B2 (enrdf_load_html_response) | 1974-04-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE69620198T2 (de) | Intensives, jedoch energieeffizientes verfahren zur elektrogewinnung von zink in mobilen teilchenbetten | |
| DE10030093C1 (de) | Verfahren und Vorrichtung zur Herstellung von Metallhydroxiden oder basischen Metallcarbonaten | |
| DE2164799A1 (de) | Verfahren zum Herstellen synthetischen Mangandioxids | |
| EP0599136B1 (de) | Verfahren zur Herstellung von reinem Nickelhydroxid sowie dessen Verwendung | |
| DE2548620C2 (de) | Verfahren zur Gewinnung vonretoem Elektrolytkupfer durch Reduktionselektrolyse | |
| EP0279174A1 (de) | Verfahren zur Herstellung von Elektrolytmangandioxid | |
| EP1190114B1 (de) | Verfahren zur herstellung von nickelhydroxiden | |
| DE3046913C2 (enrdf_load_html_response) | ||
| DE19519328C1 (de) | Verfahren zur Herstellung basischer Kobalt(II)carbonate, die nach dem Verfahren hergestellten Kobalt(II)carbonate sowie deren Verwendung | |
| DE2908592C3 (de) | Verfahren zur Abtrennung und Gewinnung eines chalcophilen Elements aus einer wäßrigen Lösung | |
| DE1301587B (de) | Verfahren und Vorrichtung zur elektrolytischen Abscheidung von Kupferpulver | |
| DE1592441C3 (enrdf_load_html_response) | ||
| DE10143076B4 (de) | Verfahren zur Herstellung eines Kupfergalvanisierungsmaterials und nach dem Verfahren erhältliches Kupfergalvanisierungsmaterial | |
| DE2713236B2 (de) | Verfahren zur Herstellung basischer Aluminiumchloride | |
| DE2539618C3 (enrdf_load_html_response) | ||
| US3194749A (en) | Electrolytic method of making cupric hydroxide | |
| DE69710870T2 (de) | Elektrolytische Gewinnung von Reinzink aus einer Mangan enthaltenden Laugungslösung durch vorhergehender Entmanganisierung der Lösung mittels kalter Elektrolyse | |
| DE1592453A1 (de) | Verfahren zum Herstellen eines alkalischen Zinnoxyd-Sols | |
| DE2419857A1 (de) | Verfahren zur elektrolyse von alkalimetallchloriden | |
| DE2304063A1 (de) | Verfahren zur reinigung von quecksilber | |
| DE1592217C3 (de) | Verfahren zur Herstellung von pharmazeutischem Bismuthylnitrat | |
| DE845038C (de) | Verfahren zur Elektrolyse von Alkalimetallchloridloesungen in Quecksilberzellen mit Graphitanoden | |
| DE707394C (de) | Verfahren zur Aufarbeitung von metallischen Stoffen | |
| DE3104578A1 (de) | Verfahren zum entfernen von metallen aus metallsalzloesungen | |
| DE812611C (de) | Verfahren zur elektrolytischen Reinigung von Nickel |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C3 | Grant after two publication steps (3rd publication) | ||
| E77 | Valid patent as to the heymanns-index 1977 | ||
| EGA | New person/name/address of the applicant | ||
| 8339 | Ceased/non-payment of the annual fee |