DE1546331B - - Google Patents
Info
- Publication number
- DE1546331B DE1546331B DE1546331B DE 1546331 B DE1546331 B DE 1546331B DE 1546331 B DE1546331 B DE 1546331B
- Authority
- DE
- Germany
- Prior art keywords
- pulp
- tap water
- tissue paper
- bacteriostatic
- dodecylguanidine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- -1 guanidine compound Chemical class 0.000 claims description 17
- 230000003385 bacteriostatic effect Effects 0.000 claims description 15
- 150000003839 salts Chemical group 0.000 claims description 11
- ZRALSGWEFCBTJO-UHFFFAOYSA-N anhydrous guanidine Natural products NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 claims description 7
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 claims description 6
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 claims description 6
- 239000000123 paper Substances 0.000 description 39
- 239000008399 tap water Substances 0.000 description 32
- 235000020679 tap water Nutrition 0.000 description 32
- CGMKPKRNUNDACU-UHFFFAOYSA-N carbamimidoyl(dodecyl)azanium;chloride Chemical compound Cl.CCCCCCCCCCCCN=C(N)N CGMKPKRNUNDACU-UHFFFAOYSA-N 0.000 description 21
- 150000002357 guanidines Chemical class 0.000 description 11
- 230000000844 anti-bacterial effect Effects 0.000 description 9
- 239000000835 fiber Substances 0.000 description 9
- 229920002678 cellulose Polymers 0.000 description 8
- 239000001913 cellulose Substances 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 7
- 239000004744 fabric Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 239000011347 resin Substances 0.000 description 6
- 229920005989 resin Polymers 0.000 description 6
- 241000894006 Bacteria Species 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 5
- 229960004198 guanidine Drugs 0.000 description 5
- 230000005764 inhibitory process Effects 0.000 description 5
- YIKWKLYQRFRGPM-UHFFFAOYSA-N 1-dodecylguanidine acetate Chemical compound CC(O)=O.CCCCCCCCCCCCN=C(N)N YIKWKLYQRFRGPM-UHFFFAOYSA-N 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 4
- 241000191967 Staphylococcus aureus Species 0.000 description 4
- 239000003899 bactericide agent Substances 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 229920000297 Rayon Polymers 0.000 description 3
- JLEUKPBYQZJCMD-UHFFFAOYSA-N S(=O)(=O)(O)O.C(CCCCCCCCCCC)NC(=N)N Chemical compound S(=O)(=O)(O)O.C(CCCCCCCCCCC)NC(=N)N JLEUKPBYQZJCMD-UHFFFAOYSA-N 0.000 description 3
- 229940037003 alum Drugs 0.000 description 3
- 239000000022 bacteriostatic agent Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000002964 rayon Substances 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 3
- 229910021653 sulphate ion Inorganic materials 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 2
- LCJXWPNOZQDXKW-UHFFFAOYSA-N 2-hexadecylguanidine sulfuric acid Chemical compound S(=O)(=O)(O)O.C(CCCCCCCCCCCCCCC)NC(=N)N LCJXWPNOZQDXKW-UHFFFAOYSA-N 0.000 description 2
- VAFNFGUOIFCIFZ-UHFFFAOYSA-N 2-octadecylguanidine phosphoric acid Chemical compound P(=O)(O)(O)O.C(CCCCCCCCCCCCCCCCC)NC(=N)N VAFNFGUOIFCIFZ-UHFFFAOYSA-N 0.000 description 2
- 229920001817 Agar Polymers 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- ALPJPNDYWBZKJJ-UHFFFAOYSA-N acetic acid 2-tetradecylguanidine Chemical compound C(C)(=O)O.C(CCCCCCCCCCCCC)NC(=N)N ALPJPNDYWBZKJJ-UHFFFAOYSA-N 0.000 description 2
- WTRKLIQALZYMCH-UHFFFAOYSA-N acetic acid;2-octylguanidine Chemical compound CC([O-])=O.CCCCCCCC[NH2+]C(N)=N WTRKLIQALZYMCH-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000008272 agar Substances 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 239000002518 antifoaming agent Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000001580 bacterial effect Effects 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 239000013065 commercial product Substances 0.000 description 2
- 239000013068 control sample Substances 0.000 description 2
- 229940109275 cyclamate Drugs 0.000 description 2
- HCAJEUSONLESMK-UHFFFAOYSA-N cyclohexylsulfamic acid Chemical compound OS(=O)(=O)NC1CCCCC1 HCAJEUSONLESMK-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- PJJJBBJSCAKJQF-UHFFFAOYSA-N guanidinium chloride Chemical compound [Cl-].NC(N)=[NH2+] PJJJBBJSCAKJQF-UHFFFAOYSA-N 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 230000000622 irritating effect Effects 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 235000019645 odor Nutrition 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 210000002700 urine Anatomy 0.000 description 2
- BZWMYDJJDBFAPE-UHFFFAOYSA-N 2-chloro-4-phenylphenol Chemical compound C1=C(Cl)C(O)=CC=C1C1=CC=CC=C1 BZWMYDJJDBFAPE-UHFFFAOYSA-N 0.000 description 1
- WPHJBWLXZODCNA-UHFFFAOYSA-N 2-decylguanidine;2-hydroxypropanoic acid Chemical compound CC(O)C(O)=O.CCCCCCCCCCN=C(N)N WPHJBWLXZODCNA-UHFFFAOYSA-N 0.000 description 1
- WEFVVVNZWWXTSA-UHFFFAOYSA-N 2-decylguanidine;hydrochloride Chemical compound Cl.CCCCCCCCCCN=C(N)N WEFVVVNZWWXTSA-UHFFFAOYSA-N 0.000 description 1
- GMEJIJCFEDISEL-UHFFFAOYSA-N 2-dodecylguanidine;phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O.CCCCCCCCCCCCN=C(N)N GMEJIJCFEDISEL-UHFFFAOYSA-N 0.000 description 1
- FZRWLIOCKSFGRG-UHFFFAOYSA-N 2-hexadecylguanidine Chemical compound CCCCCCCCCCCCCCCCN=C(N)N FZRWLIOCKSFGRG-UHFFFAOYSA-N 0.000 description 1
- GLKRSFJCYTXIOF-UHFFFAOYSA-N 2-octadecylguanidine Chemical compound CCCCCCCCCCCCCCCCCCN=C(N)N GLKRSFJCYTXIOF-UHFFFAOYSA-N 0.000 description 1
- CZLXOPXIUDVOME-UHFFFAOYSA-N 2-octadecylguanidine;sulfuric acid Chemical compound OS(O)(=O)=O.CCCCCCCCCCCCCCCCCCN=C(N)N CZLXOPXIUDVOME-UHFFFAOYSA-N 0.000 description 1
- RDVHHVOTQIQHQO-UHFFFAOYSA-N 2-tetradecylguanidine;hydrochloride Chemical compound [Cl-].CCCCCCCCCCCCCCN=C(N)[NH3+] RDVHHVOTQIQHQO-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- PFWSEYMNCOMKDX-UHFFFAOYSA-O CSC(C)=[SH+] Chemical compound CSC(C)=[SH+] PFWSEYMNCOMKDX-UHFFFAOYSA-O 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- YZBSTPDCHICUMO-UHFFFAOYSA-N [Cl-].C[NH+](C)C.C[NH+](C)C.CC1=C(C(=C(C=C1)C)C)CCCCCCCCCCCC.[Cl-] Chemical compound [Cl-].C[NH+](C)C.C[NH+](C)C.CC1=C(C(=C(C=C1)C)C)CCCCCCCCCCCC.[Cl-] YZBSTPDCHICUMO-UHFFFAOYSA-N 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- ODNUZAZTUMVHMC-UHFFFAOYSA-N acetic acid;2-decylguanidine Chemical compound CC(O)=O.CCCCCCCCCCN=C(N)N ODNUZAZTUMVHMC-UHFFFAOYSA-N 0.000 description 1
- LWTJHAPMZKZYMQ-UHFFFAOYSA-N acetic acid;2-octadecylguanidine Chemical compound CC(O)=O.CCCCCCCCCCCCCCCCCCNC(N)=N LWTJHAPMZKZYMQ-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- FHJYNYPTQRHJFQ-UHFFFAOYSA-N carbamimidoyl(octadecyl)azanium;2-hydroxypropanoate Chemical compound CC(O)C([O-])=O.CCCCCCCCCCCCCCCCCC[NH2+]C(N)=N FHJYNYPTQRHJFQ-UHFFFAOYSA-N 0.000 description 1
- DZONCCFWXXJBEF-UHFFFAOYSA-N carbamimidoyl(octyl)azanium;chloride Chemical compound Cl.CCCCCCCCN=C(N)N DZONCCFWXXJBEF-UHFFFAOYSA-N 0.000 description 1
- DESITMMYBWQMOG-UHFFFAOYSA-N carbonic acid;2-dodecylguanidine Chemical compound OC(O)=O.CCCCCCCCCCCCN=C(N)N DESITMMYBWQMOG-UHFFFAOYSA-N 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 150000003841 chloride salts Chemical class 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000012765 fibrous filler Substances 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 239000007850 fluorescent dye Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- PGBHMTALBVVCIT-VCIWKGPPSA-N framycetin Chemical compound N[C@@H]1[C@@H](O)[C@H](O)[C@H](CN)O[C@@H]1O[C@H]1[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](N)C[C@@H](N)[C@@H]2O)O[C@@H]2[C@@H]([C@@H](O)[C@H](O)[C@@H](CN)O2)N)O[C@@H]1CO PGBHMTALBVVCIT-VCIWKGPPSA-N 0.000 description 1
- 230000002070 germicidal effect Effects 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 229960000789 guanidine hydrochloride Drugs 0.000 description 1
- 150000003840 hydrochlorides Chemical class 0.000 description 1
- 238000011534 incubation Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 238000009533 lab test Methods 0.000 description 1
- 150000004701 malic acid derivatives Chemical class 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 229940053050 neomycin sulfate Drugs 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 230000003389 potentiating effect Effects 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000008237 rinsing water Substances 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 239000011550 stock solution Substances 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- YFYABWXIJBTAAM-UHFFFAOYSA-M trimethyl(2-phenyltetradecan-2-yl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCC(C)([N+](C)(C)C)C1=CC=CC=C1 YFYABWXIJBTAAM-UHFFFAOYSA-M 0.000 description 1
- 229960005486 vaccine Drugs 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
Family
ID=
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