DE1520493B2 - Verfahren zum herstellen von aethylencopolymerisaten - Google Patents
Verfahren zum herstellen von aethylencopolymerisatenInfo
- Publication number
- DE1520493B2 DE1520493B2 DE19621520493 DE1520493A DE1520493B2 DE 1520493 B2 DE1520493 B2 DE 1520493B2 DE 19621520493 DE19621520493 DE 19621520493 DE 1520493 A DE1520493 A DE 1520493A DE 1520493 B2 DE1520493 B2 DE 1520493B2
- Authority
- DE
- Germany
- Prior art keywords
- paper
- copolymer
- ethylene
- mixture
- methacrylic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims description 20
- 238000004519 manufacturing process Methods 0.000 title claims description 9
- 230000008569 process Effects 0.000 title claims description 6
- 229920001577 copolymer Polymers 0.000 claims description 57
- 239000000178 monomer Substances 0.000 claims description 27
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 22
- 238000000576 coating method Methods 0.000 claims description 18
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical group C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 15
- 239000005977 Ethylene Substances 0.000 claims description 15
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 9
- 230000001070 adhesive effect Effects 0.000 claims description 8
- 229920001038 ethylene copolymer Polymers 0.000 claims description 8
- 239000000853 adhesive Substances 0.000 claims description 7
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 7
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 5
- -1 alkyl methacrylate Chemical compound 0.000 claims description 5
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 claims description 5
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 claims description 4
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical group O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 4
- 229940044192 2-hydroxyethyl methacrylate Drugs 0.000 claims description 3
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 claims description 3
- 125000005250 alkyl acrylate group Chemical group 0.000 claims description 3
- 239000003054 catalyst Substances 0.000 claims description 3
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 3
- 150000003254 radicals Chemical class 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 230000000379 polymerizing effect Effects 0.000 claims description 2
- 150000003138 primary alcohols Chemical class 0.000 claims description 2
- 239000000123 paper Substances 0.000 description 76
- 239000000203 mixture Substances 0.000 description 32
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 20
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 20
- 229910052782 aluminium Inorganic materials 0.000 description 17
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 17
- 239000011248 coating agent Substances 0.000 description 16
- 239000012188 paraffin wax Substances 0.000 description 16
- 235000019809 paraffin wax Nutrition 0.000 description 15
- 235000019271 petrolatum Nutrition 0.000 description 15
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 12
- 239000011086 glassine Substances 0.000 description 11
- 239000000155 melt Substances 0.000 description 11
- 239000001993 wax Substances 0.000 description 11
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical class COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 230000035699 permeability Effects 0.000 description 8
- 239000012169 petroleum derived wax Substances 0.000 description 8
- 235000019381 petroleum wax Nutrition 0.000 description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 7
- 239000003999 initiator Substances 0.000 description 7
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical class CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 6
- 230000000903 blocking effect Effects 0.000 description 5
- 239000011888 foil Substances 0.000 description 5
- 238000002844 melting Methods 0.000 description 5
- 230000008018 melting Effects 0.000 description 5
- 229920003145 methacrylic acid copolymer Polymers 0.000 description 5
- 229940117841 methacrylic acid copolymer Drugs 0.000 description 5
- 230000004048 modification Effects 0.000 description 5
- 238000012986 modification Methods 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 239000004342 Benzoyl peroxide Substances 0.000 description 4
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 4
- 235000019400 benzoyl peroxide Nutrition 0.000 description 4
- 238000007789 sealing Methods 0.000 description 4
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 3
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 239000002657 fibrous material Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000004200 microcrystalline wax Substances 0.000 description 3
- 235000019808 microcrystalline wax Nutrition 0.000 description 3
- 239000004848 polyfunctional curative Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- 239000008096 xylene Substances 0.000 description 3
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 229920005680 ethylene-methyl methacrylate copolymer Polymers 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 229920006267 polyester film Polymers 0.000 description 2
- 229920002959 polymer blend Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- SWAXTRYEYUTSAP-UHFFFAOYSA-N tert-butyl ethaneperoxoate Chemical compound CC(=O)OOC(C)(C)C SWAXTRYEYUTSAP-UHFFFAOYSA-N 0.000 description 2
- LGJCFVYMIJLQJO-UHFFFAOYSA-N 1-dodecylperoxydodecane Chemical compound CCCCCCCCCCCCOOCCCCCCCCCCCC LGJCFVYMIJLQJO-UHFFFAOYSA-N 0.000 description 1
- QLZJUIZVJLSNDD-UHFFFAOYSA-N 2-(2-methylidenebutanoyloxy)ethyl 2-methylidenebutanoate Chemical compound CCC(=C)C(=O)OCCOC(=O)C(=C)CC QLZJUIZVJLSNDD-UHFFFAOYSA-N 0.000 description 1
- CYJRNFFLTBEQSQ-UHFFFAOYSA-N 8-(3-methyl-1-benzothiophen-5-yl)-N-(4-methylsulfonylpyridin-3-yl)quinoxalin-6-amine Chemical compound CS(=O)(=O)C1=C(C=NC=C1)NC=1C=C2N=CC=NC2=C(C=1)C=1C=CC2=C(C(=CS2)C)C=1 CYJRNFFLTBEQSQ-UHFFFAOYSA-N 0.000 description 1
- 229920002126 Acrylic acid copolymer Polymers 0.000 description 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical class O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 1
- 239000004831 Hot glue Substances 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- UEKQGZQLUMSLNW-UHFFFAOYSA-N Propyl isome Chemical compound C1=C2C(C(=O)OCCC)C(C(=O)OCCC)C(C)CC2=CC2=C1OCO2 UEKQGZQLUMSLNW-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 241000276425 Xiphophorus maculatus Species 0.000 description 1
- 150000001253 acrylic acids Chemical class 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- BNMJSBUIDQYHIN-UHFFFAOYSA-N butyl dihydrogen phosphate Chemical compound CCCCOP(O)(O)=O BNMJSBUIDQYHIN-UHFFFAOYSA-N 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 239000011111 cardboard Substances 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 229920006244 ethylene-ethyl acrylate Polymers 0.000 description 1
- 239000005042 ethylene-ethyl acrylate Substances 0.000 description 1
- 229920006225 ethylene-methyl acrylate Polymers 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical class O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 description 1
- 238000004508 fractional distillation Methods 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- LNMQRPPRQDGUDR-UHFFFAOYSA-N hexyl prop-2-enoate Chemical compound CCCCCCOC(=O)C=C LNMQRPPRQDGUDR-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 150000002924 oxiranes Chemical class 0.000 description 1
- ULDDEWDFUNBUCM-UHFFFAOYSA-N pentyl prop-2-enoate Chemical group CCCCCOC(=O)C=C ULDDEWDFUNBUCM-UHFFFAOYSA-N 0.000 description 1
- 238000004525 petroleum distillation Methods 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 229920002620 polyvinyl fluoride Polymers 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000005031 sulfite paper Substances 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 229950011008 tetrachloroethylene Drugs 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/20—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/22—Polyalkenes, e.g. polystyrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
- C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J123/04—Homopolymers or copolymers of ethene
- C09J123/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/10—Materials in mouldable or extrudable form for sealing or packing joints or covers
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
- D04H1/587—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives characterised by the bonding agents used
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
- D04H1/64—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/20—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2200/00—Chemical nature of materials in mouldable or extrudable form for sealing or packing joints or covers
- C09K2200/06—Macromolecular organic compounds, e.g. prepolymers
- C09K2200/0642—Copolymers containing at least three different monomers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/935—Hot melt adhesive
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Dispersion Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Paints Or Removers (AREA)
- Laminated Bodies (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US118521A US3201374A (en) | 1961-06-21 | 1961-06-21 | Terpolymers containing at least 65% ethylene |
Publications (2)
Publication Number | Publication Date |
---|---|
DE1520493A1 DE1520493A1 (de) | 1969-07-24 |
DE1520493B2 true DE1520493B2 (de) | 1972-05-18 |
Family
ID=22379125
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE19621520493 Pending DE1520493B2 (de) | 1961-06-21 | 1962-05-24 | Verfahren zum herstellen von aethylencopolymerisaten |
Country Status (11)
Country | Link |
---|---|
US (1) | US3201374A (en, 2012) |
AT (1) | AT260520B (en, 2012) |
BE (1) | BE618157A (en, 2012) |
BR (1) | BR6240214D0 (en, 2012) |
CH (1) | CH447610A (en, 2012) |
DE (1) | DE1520493B2 (en, 2012) |
DK (1) | DK108199C (en, 2012) |
GB (1) | GB991568A (en, 2012) |
LU (1) | LU41788A1 (en, 2012) |
NL (2) | NL278859A (en, 2012) |
SE (1) | SE318718B (en, 2012) |
Families Citing this family (53)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE633686A (en, 2012) * | 1962-06-19 | 1900-01-01 | ||
NL294247A (en, 2012) * | 1962-06-19 | 1900-01-01 | ||
US3249570A (en) * | 1962-11-15 | 1966-05-03 | Union Carbide Corp | Terpolymer of ethylene, alkyl acrylate and acrylic acid |
US3317631A (en) * | 1963-09-09 | 1967-05-02 | Du Pont | Thermosetting resins of aliphatic olefin, unsaturated acid copolymers and melamine-formaldehyde resins |
US3488405A (en) * | 1964-06-19 | 1970-01-06 | Monsanto Co | Blends of styrene-acrylonitrile resins with graft copolymers of diene rubber substrate and hydroxylic polymer superstrate |
NL147977B (nl) * | 1965-01-29 | 1975-12-15 | Montedison Spa | Werkwijze om gevormde voorwerpen te vervaardigen van gevulcaniseerde polymeren. |
US3365519A (en) * | 1965-02-05 | 1968-01-23 | Dow Chemical Co | Olefin polymers containing graft copolymers of aziridines onto polyolefin substrates |
DK112345B (da) * | 1966-04-23 | 1968-12-02 | Hoechst Ag | Laminat af metalplader med svingningsdæmpende mellemlag. |
US3516897A (en) * | 1966-10-27 | 1970-06-23 | Rohm & Haas | Adhesive for bonding a reinforcing element to a rubbery composition |
GB1112788A (en) * | 1967-04-14 | 1968-05-08 | Shell Int Research | Lubricant compositions |
US3655504A (en) * | 1968-05-24 | 1972-04-11 | Basf Ag | Laminated metal plates |
US3952136A (en) * | 1970-12-28 | 1976-04-20 | Sumitomo Chemical Company, Limited | Multi-layer product of metal and resin, and its production |
US3909280A (en) * | 1971-07-09 | 1975-09-30 | Allied Chem | Ethylene-acrylic acid-vinyl acetate terpolymer telomer waxes |
US3952135A (en) * | 1972-01-18 | 1976-04-20 | Imperial Chemical Industries Limited | Laminated glass windows for vehicles |
US3869416A (en) * | 1973-03-22 | 1975-03-04 | Du Pont | Reinforced wax compositions having universal adhesion |
GB1446586A (en) * | 1973-07-30 | 1976-08-18 | Ici Ltd | Thermoplastic polyurethanes mixed with ehtylene copolymers |
DE2431556C3 (de) * | 1973-08-09 | 1988-02-11 | E.I. Du Pont De Nemours And Co., Wilmington, Del. | Copolymerisat mit regelloser Verteilung der einpolymerisierten Monomereinheiten |
DE2448342C3 (de) * | 1974-10-10 | 1984-05-30 | Ruhrchemie Ag, 4200 Oberhausen | Verfahren zur Herstellung von Copolymerisaten des Ethylens und ihre Verwendung |
DE2623006B2 (de) * | 1976-05-22 | 1978-04-13 | Ruhrchemie Ag, 4200 Oberhausen | Verwendung von Copolymerisate» des Äthylens als Schmelzkleber |
CH606252A5 (en, 2012) * | 1977-01-07 | 1978-10-31 | Ciba Geigy Ag | |
CH606253A5 (en, 2012) * | 1977-01-07 | 1978-10-31 | Ciba Geigy Ag | |
US4215204A (en) * | 1978-12-26 | 1980-07-29 | Ford Motor Company | Coating compositions including oligomeric hydroxy phosphate catalyst-d |
US4209595A (en) * | 1978-12-26 | 1980-06-24 | Ford Motor Company | Coating compositions including hydroxy functional acrylic organophosphate reactive catalyst |
US4241196A (en) * | 1979-11-13 | 1980-12-23 | Ford Motor Company | Coating composition catalyzed with phosphonic acid derivative - #1 |
US4233415A (en) * | 1979-11-13 | 1980-11-11 | Ford Motor Company | Coating composition catalyzed with phosphonic acid derivative-#2 |
US4276392A (en) * | 1979-11-13 | 1981-06-30 | Ford Motor Company | Coating composition catalyzed with phosphonic acid derivative - #3 |
US4469754A (en) * | 1980-09-10 | 1984-09-04 | E. I. Du Pont De Nemours And Company | Heat seal composition |
US4346196A (en) * | 1980-09-10 | 1982-08-24 | E. I. Du Pont De Nemours And Company | Heat seal composition comprising a blend of metal neutralized polymers |
US4283317A (en) * | 1980-09-15 | 1981-08-11 | E. I. Du Pont De Nemours And Company | Wax-free, hot melt adhesive compositions |
DE3109950A1 (de) * | 1981-03-14 | 1982-09-23 | Basf Ag, 6700 Ludwigshafen | Hartwachse aus terpolymerisaten des ethylens mit ungesaettigten carbonsaeuren und ungesaettigten carbonsaeureestern |
FR2504933A1 (fr) * | 1981-04-30 | 1982-11-05 | Charbonnages Ste Chimique | Compositions applicables a la fabrication de colles thermofusibles et leur procede de preparation |
FR2505325A1 (fr) * | 1981-05-08 | 1982-11-12 | Reisacher Fils Laboratoires A | Procede et solution pour eviter les odeurs de transpiration des pieds |
FR2505859A1 (fr) * | 1981-05-12 | 1982-11-19 | Charbonnages Ste Chimique | Metal enduit d'un film polymere et son procede d'obtention |
US4419495A (en) * | 1981-09-21 | 1983-12-06 | The Dow Chemical Company | Epoxy resin powder coatings having low gloss |
DE3404744A1 (de) * | 1984-02-10 | 1985-08-14 | Basf Ag, 6700 Ludwigshafen | Copolymerisate des ethylens mit carboxylgruppenhaltigen comonomeren |
DE3404743A1 (de) * | 1984-02-10 | 1985-08-14 | Basf Ag, 6700 Ludwigshafen | Copolymerisate des ethylens mit carboxylgruppenhaltigen comonomeren |
US5210166A (en) * | 1985-11-07 | 1993-05-11 | Basf Aktiengesellschaft | Copolymers of ethylene with polyalkylene glycol (meth)acrylates |
JPH0672165B2 (ja) | 1986-06-27 | 1994-09-14 | 住友化学工業株式会社 | 低分子量エチレンランダム共重合体 |
US4753846A (en) * | 1987-02-02 | 1988-06-28 | National Starch And Chemical Corporation | Adhesive compositions for use on vinyl substrates |
US4892917A (en) * | 1987-02-02 | 1990-01-09 | National Starch And Chemical Corporation | Adhesive compositions for use on vinyl substrates |
US4911960A (en) * | 1988-01-19 | 1990-03-27 | National Starch And Chemical Corporation | Laminating adhesive for film/paper microwavable products |
US4939220A (en) * | 1988-03-17 | 1990-07-03 | National Starch And Chemical Investment Holding Corporation | Ethylene vinyl acetate-dioctyl maleate-2-ethylhexyl acrylate interpolymers |
US4908268A (en) * | 1988-03-17 | 1990-03-13 | National Starch And Chemical Corporation | Ethylene vinyl acetate-dioctyl maleate-2-ethylhexyl acrylate interpolymers |
US4961993A (en) * | 1988-03-17 | 1990-10-09 | National Starch And Chemical Investment Holding Corporation | Ethylene vinyl acetate-dioctyl maleate-2-ethylhexyl acrylate interpolymers |
DE3830007A1 (de) * | 1988-09-03 | 1990-03-15 | Basf Ag | Verfahren zur herstellung von aminmodifizierten ethylen-carbonsaeure-copolymerisaten, derartige copolymerisate und ihre verwendung fuer haftvermittler und kabelummantelungen |
DE4139601C2 (de) * | 1991-11-30 | 1994-09-08 | Hoechst Ag | Copolymerisate und ihre Verwendung als Gleit- und Trennmittel für die Verarbeitung thermoplastischer Kunststoffe |
CA2170744A1 (en) * | 1993-10-02 | 1995-04-13 | Hans-Joachim Muller | Ethylene-based copolymers and their use as viscosity improvers in petroleum distillates |
FR2743330A1 (fr) * | 1996-01-10 | 1997-07-11 | Atochem Elf Sa | Revetement de surfaces metalliques |
US6302993B1 (en) * | 1998-10-01 | 2001-10-16 | Lakeland Industries | Hazardous environment protective garments having a fusion bonded optically transparent facepiece with olefin terpolymer seams |
JP4526659B2 (ja) * | 2000-06-15 | 2010-08-18 | 日本テトラパック株式会社 | ストリップテープ |
DE10343901A1 (de) * | 2003-09-19 | 2005-04-14 | Basf Ag | Amidgruppenhaltige Ethylenterpolymere und ihre Verwendung |
FR2879619B1 (fr) | 2004-12-16 | 2007-07-13 | Arkema Sa | Composition adhesive a base de copolymeres ethyleniques, utilisable pour extrusion-couchage et extrusion-lamination sur divers supports |
FR3036116B1 (fr) | 2015-05-11 | 2019-03-22 | Arkema France | Composition adhesive a base de copolymeres ethyleniques, utilisable pour extrusion-couchage et extrusion-lamination sur divers supports |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2599123A (en) * | 1950-08-18 | 1952-06-03 | Du Pont | Copolymers of ethylene with an alkyl acrylate and an alkyl monoester of a butene-1,4-dioic acid |
BE576209A (en, 2012) * | 1958-02-27 |
-
0
- NL NL126214D patent/NL126214C/xx active
- NL NL278859D patent/NL278859A/xx unknown
- BE BE618157D patent/BE618157A/xx unknown
-
1961
- 1961-06-21 US US118521A patent/US3201374A/en not_active Expired - Lifetime
-
1962
- 1962-05-23 GB GB19902/62A patent/GB991568A/en not_active Expired
- 1962-05-24 AT AT428362A patent/AT260520B/de active
- 1962-05-24 DK DK235562AA patent/DK108199C/da active
- 1962-05-24 DE DE19621520493 patent/DE1520493B2/de active Pending
- 1962-05-25 CH CH639862A patent/CH447610A/de unknown
- 1962-05-25 SE SE5931/62A patent/SE318718B/xx unknown
- 1962-05-26 LU LU41788D patent/LU41788A1/xx unknown
- 1962-06-20 BR BR140214/62A patent/BR6240214D0/pt unknown
Also Published As
Publication number | Publication date |
---|---|
DK108199C (da) | 1967-10-09 |
GB991568A (en) | 1965-05-12 |
US3201374A (en) | 1965-08-17 |
AT260520B (de) | 1968-03-11 |
CH447610A (de) | 1967-11-30 |
NL126214C (en, 2012) | 1900-01-01 |
SE318718B (en, 2012) | 1969-12-15 |
DE1520493A1 (de) | 1969-07-24 |
NL278859A (en, 2012) | 1900-01-01 |
BR6240214D0 (pt) | 1973-01-11 |
BE618157A (en, 2012) | 1900-01-01 |
LU41788A1 (en, 2012) | 1962-07-28 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
DE1520493B2 (de) | Verfahren zum herstellen von aethylencopolymerisaten | |
DE2718716C2 (en, 2012) | ||
EP0003235B1 (de) | Wasserlösliche Copolymerisate auf der Basis von hydrophilen äthylenisch ungesättigten Monomeren;Verfahren zur Herstellung dieser Copolymerisate und ihre Verwendung | |
DE3006175C3 (de) | Überzugsharzmasse in Form einer wäßrigen Dispersion | |
EP0687277B1 (de) | Verfahren zur herstellung von kern-hülle-copolymerisat-dispersionen, deren hülle hydrolisierbare, siliciumorganische comonomere enthält | |
DE2330328B2 (de) | Alkylacrylat, Acrylsäure und/oder Methacrylsäure enthaltende Copolymerisate und deren Verwendung | |
DE746788C (de) | Verfahren zur Herstellung von Polymerisationsprodukten aus Vinylestern | |
DE2649544B2 (de) | Druckempfindlicher Klebstoff auf Basis eines Acrylsäurealkylester-Copolymerisats und eines Metalloxidchelats | |
DE2743979C3 (de) | Verfahren zur Herstellung von mit einer Selbstklebemasse auf Basis vernetzter Polyacrylsäure-Derivate beschichteten Produkten | |
DE1520492A1 (de) | AEthylenmischpolymerisat und Verfahren zu dessen Herstellung | |
DE1069874B (de) | Verfahren zur Herstellung von Mischpolymeren | |
DE2938967A1 (de) | Verfahren zur herstellung waessriger vinylchlorid-vinylester-aethylen-copolymerisatemulsionen und ihre verwendung | |
DE2626072A1 (de) | Mit copolymerem vinyliden-material beschichteter polyolefin-film und verfahren zum herstellen desselben | |
DE69606064T2 (de) | Verfahren zur herstellung von hohlen acrylat polymer mikrokugeln | |
DE2906968A1 (de) | Bindemittel fuer druckempfindliche klebstoffe und verfahren zu dessen herstellung | |
DE2223630C2 (de) | Wäßrige Dispersionen von alkalisch vernetzbaren Copolymeren | |
DE2047182B2 (de) | Klebstoff auf Basis von Polychloropren | |
DE1520493C (de) | Verfahren zum Herstellen von Äthylen copolymerisaten | |
DE3303930A1 (de) | Verwendung einer waessrigen poly(meth)acrylat-sekundaerdispersion als verdickendes bindemittel fuer buntsteinputz | |
DE3911945A1 (de) | Waessrige kunstharzdispersionen | |
DE3138497C2 (en, 2012) | ||
DE2144972C3 (de) | Verfahren zur Herstellung von Siloxan-Acrylat-Copolymeren | |
DE1595413A1 (de) | Verfahren zur Herstellung neuer Copolymerisate des Vinylidenchlorids | |
DE2416991A1 (de) | Loesungen druckempfindlicher harze mit verbesserter viskositaet und fliessverhalten sowie diese verwendende druckempfindliche filme | |
DE1745089C2 (de) | Fluorhaltiges Copolymerisat, ein Verfahren zu dessen Herstellung und dessen Verwendung für Rückseitenbeschichtungen mit geringer Adhäsion in druckempfindlichen Klebestreifen |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
E77 | Valid patent as to the heymanns-index 1977 |