DE1493380A1 - Verfahren zur Herstellung von Siloxanen - Google Patents
Verfahren zur Herstellung von SiloxanenInfo
- Publication number
- DE1493380A1 DE1493380A1 DE19651493380 DE1493380A DE1493380A1 DE 1493380 A1 DE1493380 A1 DE 1493380A1 DE 19651493380 DE19651493380 DE 19651493380 DE 1493380 A DE1493380 A DE 1493380A DE 1493380 A1 DE1493380 A1 DE 1493380A1
- Authority
- DE
- Germany
- Prior art keywords
- siloxane
- group
- general formula
- sio
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- -1 siloxanes Chemical class 0.000 title claims description 78
- 238000000034 method Methods 0.000 title claims description 11
- 238000004519 manufacturing process Methods 0.000 title claims description 3
- 239000000839 emulsion Substances 0.000 claims description 53
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims description 41
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 29
- 239000003921 oil Substances 0.000 claims description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 9
- 125000004432 carbon atom Chemical group C* 0.000 claims description 9
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 7
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 7
- 125000000217 alkyl group Chemical group 0.000 claims description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 5
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 5
- 229910052710 silicon Inorganic materials 0.000 claims description 5
- 229920002545 silicone oil Polymers 0.000 claims description 5
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- 229910052697 platinum Inorganic materials 0.000 claims description 3
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- 239000004215 Carbon black (E152) Substances 0.000 claims description 2
- 239000003054 catalyst Substances 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 229930195733 hydrocarbon Natural products 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims description 2
- 125000004122 cyclic group Chemical group 0.000 claims 3
- 229910052799 carbon Inorganic materials 0.000 claims 2
- 150000001721 carbon Chemical group 0.000 claims 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims 1
- 239000004205 dimethyl polysiloxane Substances 0.000 claims 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims 1
- 238000009958 sewing Methods 0.000 claims 1
- 238000009736 wetting Methods 0.000 description 25
- 239000004698 Polyethylene Substances 0.000 description 14
- 229920000573 polyethylene Polymers 0.000 description 14
- 239000007864 aqueous solution Substances 0.000 description 12
- 239000000203 mixture Substances 0.000 description 12
- 239000000080 wetting agent Substances 0.000 description 12
- 239000003995 emulsifying agent Substances 0.000 description 9
- 239000000243 solution Substances 0.000 description 7
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 5
- 239000004809 Teflon Substances 0.000 description 5
- 229920006362 Teflon® Polymers 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 5
- 239000007795 chemical reaction product Substances 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 229920001084 poly(chloroprene) Polymers 0.000 description 4
- IEQAICDLOKRSRL-UHFFFAOYSA-N 2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-(2-dodecoxyethoxy)ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethanol Chemical compound CCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO IEQAICDLOKRSRL-UHFFFAOYSA-N 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 3
- 238000007259 addition reaction Methods 0.000 description 3
- 239000000443 aerosol Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000011888 foil Substances 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- UMEWSJNRBXKWKZ-UHFFFAOYSA-M sodium;1,4-dioxo-1,4-dipentoxybutane-2-sulfonate Chemical compound [Na+].CCCCCOC(=O)CC(S([O-])(=O)=O)C(=O)OCCCCC UMEWSJNRBXKWKZ-UHFFFAOYSA-M 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 125000003545 alkoxy group Chemical group 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 239000000976 ink Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- GGHPAKFFUZUEKL-UHFFFAOYSA-N sodium;hexadecyl hydrogen sulfate Chemical compound [Na+].CCCCCCCCCCCCCCCCOS(O)(=O)=O GGHPAKFFUZUEKL-UHFFFAOYSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- ATVJXMYDOSMEPO-UHFFFAOYSA-N 3-prop-2-enoxyprop-1-ene Chemical compound C=CCOCC=C ATVJXMYDOSMEPO-UHFFFAOYSA-N 0.000 description 1
- OVRKATYHWPCGPZ-UHFFFAOYSA-N 4-methyloxane Chemical group CC1CCOCC1 OVRKATYHWPCGPZ-UHFFFAOYSA-N 0.000 description 1
- IRLPACMLTUPBCL-KQYNXXCUSA-N 5'-adenylyl sulfate Chemical compound C1=NC=2C(N)=NC=NC=2N1[C@@H]1O[C@H](COP(O)(=O)OS(O)(=O)=O)[C@@H](O)[C@H]1O IRLPACMLTUPBCL-KQYNXXCUSA-N 0.000 description 1
- MWRSABPHNREIIX-UHFFFAOYSA-N 9,9-dimethyldecan-1-ol Polymers CC(C)(C)CCCCCCCCO MWRSABPHNREIIX-UHFFFAOYSA-N 0.000 description 1
- 241000269350 Anura Species 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- 241000004297 Draba Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical group [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- WPMWEFXCIYCJSA-UHFFFAOYSA-N Tetraethylene glycol monododecyl ether Chemical compound CCCCCCCCCCCCOCCOCCOCCOCCO WPMWEFXCIYCJSA-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 150000005840 aryl radicals Chemical class 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 230000001055 chewing effect Effects 0.000 description 1
- 239000010960 cold rolled steel Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 125000000118 dimethyl group Polymers [H]C([H])([H])* 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 235000021149 fatty food Nutrition 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 239000011799 hole material Substances 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 125000005394 methallyl group Chemical group 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000003961 organosilicon compounds Chemical class 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 125000000286 phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 1
- 229920000053 polysorbate 80 Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 125000005373 siloxane group Chemical group [SiH2](O*)* 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- GRTCBPGCHNWUOI-UHFFFAOYSA-M sodium;4-oxo-4-pentoxy-3-sulfobutanoate Chemical compound [Na+].CCCCCOC(=O)C(S(O)(=O)=O)CC([O-])=O GRTCBPGCHNWUOI-UHFFFAOYSA-M 0.000 description 1
- HHURSJAUVYNJBT-UHFFFAOYSA-M sodium;heptadecyl sulfate Chemical compound [Na+].CCCCCCCCCCCCCCCCCOS([O-])(=O)=O HHURSJAUVYNJBT-UHFFFAOYSA-M 0.000 description 1
- 235000014347 soups Nutrition 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000005504 styryl group Chemical group 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000002352 surface water Substances 0.000 description 1
- 239000012085 test solution Substances 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000004636 vulcanized rubber Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0834—Compounds having one or more O-Si linkage
- C07F7/0838—Compounds with one or more Si-O-Si sequences
- C07F7/0872—Preparation and treatment thereof
- C07F7/0876—Reactions involving the formation of bonds to a Si atom of a Si-O-Si sequence other than a bond of the Si-O-Si linkage
- C07F7/0878—Si-C bond
- C07F7/0879—Hydrosilylation reactions
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
- C09K23/54—Silicon compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0834—Compounds having one or more O-Si linkage
- C07F7/0838—Compounds with one or more Si-O-Si sequences
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/21—Cyclic compounds having at least one ring containing silicon, but no carbon in the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/42—Block-or graft-polymers containing polysiloxane sequences
- C08G77/46—Block-or graft-polymers containing polysiloxane sequences containing polyether sequences
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S516/00—Colloid systems and wetting agents; subcombinations thereof; processes of
- Y10S516/01—Wetting, emulsifying, dispersing, or stabilizing agents
- Y10S516/02—Organic and inorganic agents containing, except water
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Silicon Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US376549A US3299112A (en) | 1964-06-19 | 1964-06-19 | Siloxane wetting agents |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE1493380A1 true DE1493380A1 (de) | 1969-01-30 |
| DE1493380C3 DE1493380C3 (enExample) | 1974-03-07 |
Family
ID=23485453
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19651493380 Granted DE1493380A1 (de) | 1964-06-19 | 1965-06-19 | Verfahren zur Herstellung von Siloxanen |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US3299112A (enExample) |
| BE (1) | BE665645A (enExample) |
| DE (1) | DE1493380A1 (enExample) |
| GB (1) | GB1121831A (enExample) |
| NL (2) | NL6507928A (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008074565A1 (de) * | 2006-12-20 | 2008-06-26 | Evonik Goldschmidt Gmbh | Cyclische siloxane und deren verwendung |
Families Citing this family (114)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE638004A (enExample) * | 1962-10-02 | 1900-01-01 | ||
| US3359212A (en) * | 1964-06-19 | 1967-12-19 | Union Carbide Corp | Aqueous mixture and silicone oil in water emulsion containing siloxane wetting agents |
| GB1104153A (en) * | 1964-12-29 | 1968-02-21 | Ici Ltd | New polymers |
| US3545970A (en) * | 1968-04-29 | 1970-12-08 | Eastman Kodak Co | Photographic processes utilizing siloxane water spotting inhibitors |
| JPS5115740B1 (enExample) * | 1971-02-04 | 1976-05-19 | ||
| US3933407A (en) * | 1972-06-29 | 1976-01-20 | Tu Robert S | Articles coated with synergistic anti-fog coatings based on hydrophillic polymers and organosiloxane- oxyalkylene block copolymers |
| JPS5641437B2 (enExample) * | 1974-03-22 | 1981-09-28 | ||
| JPS6018525A (ja) * | 1983-07-11 | 1985-01-30 | Toshiba Silicone Co Ltd | ポリオルガノシロキサンの着臭防止方法 |
| US4765243A (en) * | 1987-06-02 | 1988-08-23 | Dow Corning Corporation | Method of printing on plastic substrate using a water-based ink |
| GB2218428A (en) * | 1988-05-03 | 1989-11-15 | Gnii Khim I T Elemento Orch So | Polysiloxane composition for treating cine film materials |
| CA1337459C (en) * | 1988-08-15 | 1995-10-31 | Lenin J. Petroff | Postemergent herbicide compositions containing silicone glycol adjuvants |
| US5017216A (en) * | 1988-08-15 | 1991-05-21 | Dow Corning Corporation | Postemergent herbicide compositions containing silicone glycol adjuvants |
| US5145978A (en) * | 1988-08-15 | 1992-09-08 | Dow Corning Corporation | Postemergent herbicide compositions containing silicone glycol adjuvants |
| US4849059A (en) * | 1988-09-13 | 1989-07-18 | Macdermid, Incorporated | Aqueous electroplating bath and method for electroplating tin and/or lead and a defoaming agent therefor |
| US4990175A (en) * | 1989-06-13 | 1991-02-05 | Dow Corning Corporation | Foliar applied herbicidal compositions containing a silicone glycolsilicone alkane terpolymer adjuvant |
| US4933002A (en) * | 1989-11-21 | 1990-06-12 | Dow Corning Corporation | Postemergent herbicide compositions containing acetoxy-terminated silicone glycol and dispersant |
| US5059704A (en) * | 1989-12-13 | 1991-10-22 | Dow Corning Corporation | Foliar-applied herbicidal compositions containing a silicone glycol-silicone alkane terpolymer adjuvant |
| US5558806A (en) * | 1992-07-23 | 1996-09-24 | Osi Specialties, Inc. | Surfactant blend of a polyalkleneoxide polysiloxane and an organic compound having a short chain hydrophobic moiety |
| EP0612754B1 (de) * | 1993-02-25 | 1998-08-19 | Th. Goldschmidt AG | Organopolysiloxanpolyether und deren Verwendung als hydrolysestabile Netzmittel in wässrigen Systemen |
| US5504054A (en) * | 1993-03-30 | 1996-04-02 | Osi Specialties, Inc. | Super-spreading, low-foam surfactant for agricultural spray mixtures |
| US5658851A (en) * | 1993-10-13 | 1997-08-19 | Osi Specialties, Inc. | Lipophilic siloxanes as adjuvants for agriculture |
| US5561099A (en) * | 1993-10-13 | 1996-10-01 | Osi Specialties, Inc. | Alkylsiloxanes as adjuvants for agriculture |
| US5532224A (en) * | 1993-12-22 | 1996-07-02 | Alcon Laboratories, Inc. | Contact lens cleaning composition containing polyalklene oxide modified siloxanes |
| US5672641A (en) * | 1995-01-23 | 1997-09-30 | Ppg Industries, Inc. | Secondary coating compositions for glass fibers, glass fibers coated with the same and composites reinforced therewith |
| US5705562A (en) * | 1995-11-20 | 1998-01-06 | Dow Corning Corporation | Spontaneously formed clear silicone microemulsions |
| US6077317A (en) * | 1996-01-25 | 2000-06-20 | Lever Brothers Company, Division Of Conopco, Inc. | Prewash stain remover composition with siloxane based surfactant |
| US5623017A (en) * | 1996-02-08 | 1997-04-22 | Dow Corning Corporation | Clear silicone gels |
| US5986122A (en) * | 1996-11-18 | 1999-11-16 | Witco Corporation | Treatment of polyethers prior to hydrosilylation |
| US5759980A (en) * | 1997-03-04 | 1998-06-02 | Blue Coral, Inc. | Car wash |
| US6051730A (en) * | 1997-05-05 | 2000-04-18 | Rhodia Inc. | Surfactant clathrates and agricultural chemical formulations thereof |
| US6103847A (en) * | 1997-05-27 | 2000-08-15 | Witco Corporation | Siloxane-polyether copolymers with unsaturated functionalities, and process for making them |
| US6013711A (en) * | 1997-06-18 | 2000-01-11 | Ck Witco Corporation | Hydrophilic polysiloxane compositions |
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| US2846458A (en) * | 1956-05-23 | 1958-08-05 | Dow Corning | Organosiloxane ethers |
| US2868824A (en) * | 1956-08-09 | 1959-01-13 | Dow Corning | Polymeric organosiloxanes |
| US3007879A (en) * | 1958-02-14 | 1961-11-07 | Gen Mills Inc | Stabilized gums and methods of making them |
| US3012975A (en) * | 1958-05-01 | 1961-12-12 | Hercules Powder Co Ltd | Emulsifier for aqueous emulsion polymerization processes |
| US3172899A (en) * | 1959-06-29 | 1965-03-09 | Or")noe | |
| FR1353667A (fr) * | 1963-01-23 | 1964-02-28 | Union Carbide Corp | émulsions stables d'organopolysiloxanes dans l'eau |
-
0
- NL NL133334D patent/NL133334C/xx active
-
1964
- 1964-06-19 US US376549A patent/US3299112A/en not_active Expired - Lifetime
-
1965
- 1965-06-18 BE BE665645D patent/BE665645A/xx unknown
- 1965-06-19 DE DE19651493380 patent/DE1493380A1/de active Granted
- 1965-06-21 NL NL6507928A patent/NL6507928A/xx unknown
- 1965-06-21 GB GB26061/65A patent/GB1121831A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008074565A1 (de) * | 2006-12-20 | 2008-06-26 | Evonik Goldschmidt Gmbh | Cyclische siloxane und deren verwendung |
Also Published As
| Publication number | Publication date |
|---|---|
| GB1121831A (en) | 1968-07-31 |
| NL133334C (enExample) | 1900-01-01 |
| NL6507928A (enExample) | 1965-12-20 |
| BE665645A (enExample) | 1965-10-18 |
| DE1493380C3 (enExample) | 1974-03-07 |
| US3299112A (en) | 1967-01-17 |
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| C3 | Grant after two publication steps (3rd publication) | ||
| E77 | Valid patent as to the heymanns-index 1977 | ||
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