DE1245956B - - Google Patents
Info
- Publication number
- DE1245956B DE1245956B DE1965G0042892 DEG0042892A DE1245956B DE 1245956 B DE1245956 B DE 1245956B DE 1965G0042892 DE1965G0042892 DE 1965G0042892 DE G0042892 A DEG0042892 A DE G0042892A DE 1245956 B DE1245956 B DE 1245956B
- Authority
- DE
- Germany
- Prior art keywords
- reaction
- parts
- temperature
- mixture
- added
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003054 catalyst Substances 0.000 claims description 35
- 238000006243 chemical reaction Methods 0.000 claims description 24
- 239000001257 hydrogen Substances 0.000 claims description 16
- 229910052739 hydrogen Inorganic materials 0.000 claims description 16
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 11
- MQIKJSYMMJWAMP-UHFFFAOYSA-N dicobalt octacarbonyl Chemical group [Co+2].[Co+2].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-] MQIKJSYMMJWAMP-UHFFFAOYSA-N 0.000 claims description 10
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 8
- -1 siloxanes Chemical class 0.000 claims description 8
- 238000007259 addition reaction Methods 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 6
- 229920000642 polymer Polymers 0.000 claims description 6
- 229910000077 silane Inorganic materials 0.000 claims description 6
- 239000000047 product Substances 0.000 claims description 4
- 239000006227 byproduct Substances 0.000 claims description 3
- 229930195733 hydrocarbon Natural products 0.000 claims description 3
- 150000002430 hydrocarbons Chemical class 0.000 claims description 3
- 230000015572 biosynthetic process Effects 0.000 claims description 2
- 150000002431 hydrogen Chemical class 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims description 2
- AQRLNPVMDITEJU-UHFFFAOYSA-N triethylsilane Chemical compound CC[SiH](CC)CC AQRLNPVMDITEJU-UHFFFAOYSA-N 0.000 claims 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 4
- 239000000463 material Substances 0.000 claims 4
- 239000011541 reaction mixture Substances 0.000 claims 3
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 claims 2
- 239000007795 chemical reaction product Substances 0.000 claims 2
- XNAFLNBULDHNJS-UHFFFAOYSA-N dichloro(phenyl)silicon Chemical compound Cl[Si](Cl)C1=CC=CC=C1 XNAFLNBULDHNJS-UHFFFAOYSA-N 0.000 claims 2
- 238000010438 heat treatment Methods 0.000 claims 2
- 229910052757 nitrogen Inorganic materials 0.000 claims 2
- JROIGMXXSNIIQY-UHFFFAOYSA-N 2,4,6,8-tetrakis(ethenyl)-2-methyl-1,3,5,7,2,4,6,8-tetraoxatetrasilocane Chemical compound C[Si]1(O[SiH](O[SiH](O[SiH](O1)C=C)C=C)C=C)C=C JROIGMXXSNIIQY-UHFFFAOYSA-N 0.000 claims 1
- 238000010521 absorption reaction Methods 0.000 claims 1
- 238000009835 boiling Methods 0.000 claims 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims 1
- 230000000052 comparative effect Effects 0.000 claims 1
- 239000004020 conductor Substances 0.000 claims 1
- DDJSWKLBKSLAAZ-UHFFFAOYSA-N cyclotetrasiloxane Chemical compound O1[SiH2]O[SiH2]O[SiH2]O[SiH2]1 DDJSWKLBKSLAAZ-UHFFFAOYSA-N 0.000 claims 1
- MMMAMXCZXJSWPK-UHFFFAOYSA-N dichloro-octyl-phenylsilane Chemical class CCCCCCCC[Si](Cl)(Cl)C1=CC=CC=C1 MMMAMXCZXJSWPK-UHFFFAOYSA-N 0.000 claims 1
- VDCSGNNYCFPWFK-UHFFFAOYSA-N diphenylsilane Chemical compound C=1C=CC=CC=1[SiH2]C1=CC=CC=C1 VDCSGNNYCFPWFK-UHFFFAOYSA-N 0.000 claims 1
- 230000008034 disappearance Effects 0.000 claims 1
- 238000002474 experimental method Methods 0.000 claims 1
- 238000005187 foaming Methods 0.000 claims 1
- 239000007789 gas Substances 0.000 claims 1
- 239000000543 intermediate Substances 0.000 claims 1
- 230000002045 lasting effect Effects 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims 1
- 239000012299 nitrogen atmosphere Substances 0.000 claims 1
- 238000006116 polymerization reaction Methods 0.000 claims 1
- 238000010992 reflux Methods 0.000 claims 1
- 239000003566 sealing material Substances 0.000 claims 1
- 150000004756 silanes Chemical class 0.000 claims 1
- 239000007787 solid Substances 0.000 claims 1
- XVKXMTGNOIVVLP-UHFFFAOYSA-N triethyl(octyl)silane Chemical compound CCCCCCCC[Si](CC)(CC)CC XVKXMTGNOIVVLP-UHFFFAOYSA-N 0.000 claims 1
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 claims 1
- 229910017052 cobalt Inorganic materials 0.000 description 13
- 239000010941 cobalt Substances 0.000 description 13
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 13
- 239000000376 reactant Substances 0.000 description 10
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 8
- 229910052710 silicon Inorganic materials 0.000 description 8
- 150000003961 organosilicon compounds Chemical class 0.000 description 6
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 6
- 239000010703 silicon Substances 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 241000158147 Sator Species 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
- 229910052697 platinum Inorganic materials 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 150000001869 cobalt compounds Chemical class 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- VMAWODUEPLAHOE-UHFFFAOYSA-N 2,4,6,8-tetrakis(ethenyl)-2,4,6,8-tetramethyl-1,3,5,7,2,4,6,8-tetraoxatetrasilocane Chemical compound C=C[Si]1(C)O[Si](C)(C=C)O[Si](C)(C=C)O[Si](C)(C=C)O1 VMAWODUEPLAHOE-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- BWSPDMDWZLYMDQ-UHFFFAOYSA-N [Si].CC1=CC=CC=C1 Chemical compound [Si].CC1=CC=CC=C1 BWSPDMDWZLYMDQ-UHFFFAOYSA-N 0.000 description 1
- 125000005595 acetylacetonate group Chemical group 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 150000001868 cobalt Chemical class 0.000 description 1
- 229940011182 cobalt acetate Drugs 0.000 description 1
- GVPFVAHMJGGAJG-UHFFFAOYSA-L cobalt dichloride Chemical compound [Cl-].[Cl-].[Co+2] GVPFVAHMJGGAJG-UHFFFAOYSA-L 0.000 description 1
- QAHREYKOYSIQPH-UHFFFAOYSA-L cobalt(II) acetate Chemical compound [Co+2].CC([O-])=O.CC([O-])=O QAHREYKOYSIQPH-UHFFFAOYSA-L 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000006317 isomerization reaction Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 150000001282 organosilanes Chemical class 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0801—General processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/38—Polysiloxanes modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/48—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms
- C08G77/50—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms by carbon linkages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/60—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which all the silicon atoms are connected by linkages other than oxygen atoms
- C08G77/62—Nitrogen atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US34886764A | 1964-03-02 | 1964-03-02 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1245956B true DE1245956B (un) | 1967-08-03 |
Family
ID=23369893
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE1965G0042892 Pending DE1245956B (un) | 1964-03-02 | 1965-02-20 |
Country Status (3)
| Country | Link |
|---|---|
| DE (1) | DE1245956B (un) |
| FR (1) | FR1433631A (un) |
| GB (1) | GB1090122A (un) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6198735A (ja) * | 1984-10-22 | 1986-05-17 | Toshiba Silicone Co Ltd | エチリデンノルボルニル基含有ポリシロキサン |
| FR2618329B1 (fr) * | 1987-07-22 | 1997-03-28 | Dow Corning Sa | Procede de fabrication d'un anneau capable d'assurer la liberation d'un agent therapeutique, et anneau fabrique par ce procede |
| US5886115A (en) * | 1997-02-18 | 1999-03-23 | Rensselaer Polytechnic Institute | Process for the direct polymerization of allyl ethers, crotyl ethers and allyl alcohols |
-
1965
- 1965-02-20 DE DE1965G0042892 patent/DE1245956B/de active Pending
- 1965-03-01 GB GB865765A patent/GB1090122A/en not_active Expired
- 1965-03-02 FR FR7554A patent/FR1433631A/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| FR1433631A (fr) | 1966-04-01 |
| GB1090122A (en) | 1967-11-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP1679335B1 (de) | Siloxanblockcopolymere | |
| DE68919530T2 (de) | Verfahren und Zwischenprodukte für die Herstellung von Bis(aminoalkyl)polydiorganosiloxanen. | |
| DE3133869C1 (de) | Verfahren zur Addition von organischen Siliciumverbindungen mit SiH-Gruppen an Verbindungen mit olefinischen Doppelbindungen | |
| EP0011714B1 (de) | Verfahren zum Anlagern von Si-H-Verbindungen an aliphatische Mehrfachbindung | |
| DE1495918A1 (de) | Verfahren zur Herstellung von Organ?siliciumverbindungen mit organischem Rhodiumkomplex als Katalysator | |
| EP1460098B1 (de) | Verfahren zur Herstellung von organisch modifizierten Polyorganosiloxanen | |
| DE1570686A1 (de) | Verfahren zur Herstellung von Organosilizium-Verbindungen | |
| DE1495921B2 (de) | Verfahren zur katalytischen addition einer siliciumverbindung, die ein oder mehrere wasserstoffatome aufweist, die an silicium gebunden sind, an eine organische verbindung mit olefinischer oder acetylenischer mehrfachbindung | |
| DE1187240B (de) | Verfahren zur Herstellung von Organosiliciumverbindungen | |
| DE1283238B (de) | Verfahren zur Herstellung von Hydroxyalkyloxyalkylsiloxanen | |
| DE2305097A1 (de) | Acrylat- oder methacrylatsilane | |
| EP0626414A1 (de) | Organosiliciumreste aufweisende Phosphazene, Verfahren zu deren Herstellung und deren Verwendung | |
| DE2303155C2 (de) | Verfahren zur Herstellung cyclischer symmetrischer Polymethylpolyvinylpolysiloxane | |
| DE856222C (de) | Verfahren zur Polymerisation von Organosiloxanen | |
| DE3702631C2 (de) | Verfahren zur Herstellung primärer Aminosiloxane | |
| DE2307085A1 (de) | Platinkomplexe ungesaettigter siloxane und platinhaltige organopolysiloxane | |
| DE1495868B2 (de) | Verfahren zur Herstellung von Acyloxyalkylgruppen enthaltenden Organopolysiloxanen | |
| DE1127898B (de) | Verfahren zur Herstellung von ª‰-Cyanaethylphenyldichlorsilan | |
| DE2607714A1 (de) | Verfahren zur herstellung von organosiliciumprodukten | |
| DE1165028B (de) | Verfahren zur Herstellung von siliciumhaltigen Kohlenwasserstoffen durch Addition von Hydrogensilanen an ungesaettigte Kohlenwasserstoffe | |
| DE2163213A1 (de) | Verfahren zur Umwandlung von Silanen | |
| DE2251297A1 (de) | Verfahren zur herstellung von organosiliciumverbindungen | |
| DE1245956B (un) | ||
| DE69130433T2 (de) | Verfahren zur Herstellung von Cyclopentyl-trichlorosilan | |
| DE2345923C3 (de) | Verfahren zur Herstellung von halogensubstituierten linearen oder verzweigten OrganopolysUoxanen |