DE1234906B - Mittel zum Schmieren von Ofenfoerderketten - Google Patents

Mittel zum Schmieren von Ofenfoerderketten

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Publication number
DE1234906B
DE1234906B DES86198A DES0086198A DE1234906B DE 1234906 B DE1234906 B DE 1234906B DE S86198 A DES86198 A DE S86198A DE S0086198 A DES0086198 A DE S0086198A DE 1234906 B DE1234906 B DE 1234906B
Authority
DE
Germany
Prior art keywords
lubricating
conveyor chains
furnace conveyor
percent
oil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DES86198A
Other languages
English (en)
Inventor
Gilbert Duane Blake
Rudolph J Holzinger
Lawton Eugene Reid
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Oil Corp
Original Assignee
Mobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mobil Oil Corp filed Critical Mobil Oil Corp
Publication of DE1234906B publication Critical patent/DE1234906B/de
Pending legal-status Critical Current

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    • C10M173/00—Lubricating compositions containing more than 10% water
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    • C10M2201/02—Water
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    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • C10M2219/083—Dibenzyl sulfide
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/042—Metal salts thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/043—Ammonium or amine salts thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04—Siloxanes with specific structure
    • C10M2229/041—Siloxanes with specific structure containing aliphatic substituents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/02—Groups 1 or 11
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/04—Groups 2 or 12
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01—Physico-chemical properties
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/08—Resistance to extreme temperature
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/12—Gas-turbines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/12—Gas-turbines
    • C10N2040/13—Aircraft turbines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/01—Emulsions, colloids, or micelles
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/015—Dispersions of solid lubricants
    • C10N2050/02—Dispersions of solid lubricants dissolved or suspended in a carrier which subsequently evaporates to leave a lubricant coating

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Description

BUNDESREPUBLIK DEUTSCHLAND
DEUTSCHES
PATENTAMT
AUSLEGESCHRIFT
Int. Cl.:
ClOm
CIOM I69/00 A 06
Deutsche Kl.: 23 c-1/01
Nummer: 1 234 906
Aktenzeichen: S86198IVc/23c
Anmeldetag: 16. Juli 1963
Auslegetag: 23. Februar 1967
Zur Schmierung von Ofenförderketten wurden bisher Kohlenwasserstofföle, die eine geringe Menge öl enthielten, benutzt. Infolge der durch die zirkulierende heiße Luft in einem Ofen erzeugten Turbulenz werden feine Teilchen von Staub, Schmutz oder dem Fördermaterial auf den ölbenetzten Kettengliedern und Walzen abgelagert. Da auch das Kohlenwasserstofföl bei der hohen Temperatur des Ofens gespalten wird, bilden sich somit dicke Ablagerungsschichten auf den Ketten, die zu einer starken Belastung und Beanspruchung der Ketten führen. Diese Belastungen können sogar ein Verziehen und Brechen der Kette bewirken.
Es wurde nun gefunden, daß diese Ablagerungen nicht bzw. nur in geringem Umfang eintreten, wenn eine Wasser-in-öl-Emulsion als Mittel zum Schmieren von Ofenförderketten verwendet wird, die aus 0,1 bis 5 Gewichtsprozent eines üblichen Emulgiermittels, 0,1 bis 5 Gewichtsprozent eines üblichen Hochtemperaturstabilisierungsmittels und 0,5 bis 5 Gewichtsprozent eines festen Schmiermittels in feinteiliger Form besteht, wobei Emulgiermittel und Stabilistermittel zusammen eine HLB-Zahl von 2 bis 8 haben, die ölphase aus 85 bis 30 Gewichtsprozent eines Kohlenwasserstoffs mit einer Viskosität von 50 bis 1000 SUS bei 38° C besteht und der Wassergehalt 15 bis 70 Gewichtsprozent beträgt.
Das beanspruchte Schmiermittel eignet sich für Ausrüstungen, die erhöhten Temperaturen ausgesetzt sind, insbesondere für Ketten und andere Bauteile in staubigen öfen, die über lange Zeiträume bei Temperaturen von 204 bis 427° C betrieben werden. Die durch das Emulgiermittel und das Stabilisiermittel gebildete Emulsion sollte eine HLB-Zahl von allgemein etwa 2 bis 8 und vorzugsweise etwa 3 bis 7 haben. Das Emulgiermittel und das Stabilisiermittel können aus den Gruppen der nichtionischen, anionischen oder kationischen oberflächenaktiven Mittel ausgewählt werden.
Das verwendete öl ist ein Kohlenwasserstofföl mit einem Viskositätsbereich von 50 bis 1000 SUS bei 38° C. Jedoch wird der Viskositätsbereich von 80 bis 150 SUS bei 38° C bevorzugt. Das Öl verdampft und krackt im allgemeinen während der Schmierung der Ofenförderketten, und daher sollte der Conradson-Verkokungsrückstand allgemein weniger als etwa 0,25 °/u und vorzugsweise weniger als 0,05 %> betragen. Die ölphase der Emulsion, einschließlich des Emulgiermittels, soll etwa 85 bis 30 Gewichtsprozent, vorzugsweise etwa 70 bis 50 Gewichtsprozent, betragen. Eine besonders gute Schmiermittelzusammenstellun» wird erhalten, wenn man ein Weißöl Mittel zum Schmieren von Ofenförderketten
Anmelder:
Mobil Oil Company, New York, N. Y. (V. St. A.)
Vertreter:
Dr. E. Wiegand und Dipl.-Ing. W. Niemann,
Patentanwälte, München 15, Nußbaumstr. 10
Als Erfinder benannt:
Gilbert Duane Blake, Overland, Kan.;
Rudolph J. Holzinger, Haddonfield, N. J.;
Lawton Eugene Reid, Kansas City, Mo. (V. St. A.)
Beanspruchte Priorität:
V. St. v. Amerika vom 17. Juli 1962 (210 541)
mit den vorstehend angegebenen Eigenschaften verwendet.
Das Emulgiermittel kann eine anionische, nichtionische oder kationische Verbindung mit einer HLB-Zähl von etwa 2 bis 6, vorzugsweise 3 bis 5, sein. Verbindungen des anionischen Typs, die sich als besonders brauchbar erwiesen haben, sind oleophile Erdalkalipetroleumsulfonate, oleophile Erdalkali· naphthalinsulfonate, oleophile Erdalkali-C.,-CrK-AI~ kylphenate und Kalium-, Natrium-, Ammonium-. Calcium-, Barium-, Strontium- und Lithiumsalze von sauren Phosphaten, wobei diese Phosphate teilweise durch Veresterung mit etwa CH-C24-Alkylphenolen und Äthylenoxydderivaten (2 bis 12 Mol Äthylenoxyd) dieser Phenole neutralisiert worden sind. Verbindungen des nichtionischen Typs, die sich als brauchbar gezeigt haben, sind Teilester von Polyolen und C10-C24-FeHSaUrCn oder Teilester von Polyolen oder Wachssäuren, die durch Oxydation einer Mischung von Erdölkohlenwasserstoffen mit einer mittleren Kohlenstoffkettenlänge im Bereich von Q0 bis C50 hergestellt worden sind; solche Mischungen sind auch als Petrolatum oder mikrokristallines Wachs bekannt. Besonders gute Ergebnisse sind mit Teilestern von Sorbit und seinem Dehydratationsprodukt, z. B. Sorbitmonooleat, erhalten worden. Diese Emulgiermittel werden in einer Menge von 0,1 bis 0,5 Gewichtsprozent, vorzugsweise 0,3 bis 3,0 Gewichtsprozent, verwendet.
709 510/513
DES86198A 1962-07-17 1963-07-16 Mittel zum Schmieren von Ofenfoerderketten Pending DE1234906B (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US210541A US3213024A (en) 1962-07-17 1962-07-17 High temperature lubricant

Publications (1)

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DE1234906B true DE1234906B (de) 1967-02-23

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ID=22783299

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Application Number Title Priority Date Filing Date
DES86198A Pending DE1234906B (de) 1962-07-17 1963-07-16 Mittel zum Schmieren von Ofenfoerderketten

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Country Link
US (1) US3213024A (de)
DE (1) DE1234906B (de)
GB (1) GB1056042A (de)

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GB1056042A (en) 1967-01-25

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