DE1194590B - Verfahren zur Herstellung von Metallen, insbesondere von Titan, Aluminium und Magnesium, durch Schmelzflusselektrolyse - Google Patents
Verfahren zur Herstellung von Metallen, insbesondere von Titan, Aluminium und Magnesium, durch SchmelzflusselektrolyseInfo
- Publication number
- DE1194590B DE1194590B DEE19886A DEE0019886A DE1194590B DE 1194590 B DE1194590 B DE 1194590B DE E19886 A DEE19886 A DE E19886A DE E0019886 A DEE0019886 A DE E0019886A DE 1194590 B DE1194590 B DE 1194590B
- Authority
- DE
- Germany
- Prior art keywords
- metal
- additives
- ammonia
- electrolysis
- halide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000005868 electrolysis reaction Methods 0.000 title claims description 32
- 229910052751 metal Inorganic materials 0.000 title claims description 28
- 239000002184 metal Substances 0.000 title claims description 28
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 title claims description 20
- 239000010936 titanium Substances 0.000 title claims description 19
- 229910052719 titanium Inorganic materials 0.000 title claims description 19
- 238000000034 method Methods 0.000 title claims description 18
- 238000004519 manufacturing process Methods 0.000 title claims description 14
- 229910052782 aluminium Inorganic materials 0.000 title claims description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims description 7
- 230000008569 process Effects 0.000 title claims description 7
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 title claims description 6
- 229910052749 magnesium Inorganic materials 0.000 title claims description 6
- 239000011777 magnesium Substances 0.000 title claims description 6
- 150000002739 metals Chemical class 0.000 title claims description 6
- 239000000654 additive Substances 0.000 claims description 48
- 150000001875 compounds Chemical class 0.000 claims description 36
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 20
- 239000000155 melt Substances 0.000 claims description 20
- 229910021529 ammonia Inorganic materials 0.000 claims description 15
- 239000003792 electrolyte Substances 0.000 claims description 11
- 238000010438 heat treatment Methods 0.000 claims description 11
- 230000001681 protective effect Effects 0.000 claims description 11
- 150000004820 halides Chemical class 0.000 claims description 8
- 229910001507 metal halide Inorganic materials 0.000 claims description 8
- 150000005309 metal halides Chemical class 0.000 claims description 8
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 3
- 229910052736 halogen Inorganic materials 0.000 claims description 3
- 150000002367 halogens Chemical class 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- 239000003513 alkali Substances 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 239000000463 material Substances 0.000 claims description 2
- 230000000996 additive effect Effects 0.000 description 28
- 239000011734 sodium Substances 0.000 description 16
- 239000007789 gas Substances 0.000 description 11
- 239000000203 mixture Substances 0.000 description 11
- ZHTOIEDMLUUKDZ-UHFFFAOYSA-J azane titanium(4+) tetrachloride Chemical compound N.[Cl-].[Cl-].[Cl-].[Cl-].[Ti+4] ZHTOIEDMLUUKDZ-UHFFFAOYSA-J 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 239000000779 smoke Substances 0.000 description 5
- 239000007857 degradation product Substances 0.000 description 4
- 230000006872 improvement Effects 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 229910001510 metal chloride Inorganic materials 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 230000000875 corresponding effect Effects 0.000 description 3
- 238000000151 deposition Methods 0.000 description 3
- 230000008021 deposition Effects 0.000 description 3
- 230000004907 flux Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- -1 TiCl 4 Chemical compound 0.000 description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
- 229910007926 ZrCl Inorganic materials 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000001465 metallisation Methods 0.000 description 2
- 229910052726 zirconium Inorganic materials 0.000 description 2
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 241001072332 Monia Species 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 229910052776 Thorium Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- 229910052770 Uranium Inorganic materials 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052790 beryllium Inorganic materials 0.000 description 1
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- HLJCWGPUCQTHFY-UHFFFAOYSA-H disodium;hexafluorotitanium(2-) Chemical compound [F-].[F-].[Na+].[Na+].F[Ti](F)(F)F HLJCWGPUCQTHFY-UHFFFAOYSA-H 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000289 melt material Substances 0.000 description 1
- 229910001509 metal bromide Inorganic materials 0.000 description 1
- 229910001512 metal fluoride Inorganic materials 0.000 description 1
- 229910001511 metal iodide Inorganic materials 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000000391 smoking effect Effects 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000008247 solid mixture Substances 0.000 description 1
- DNYWZCXLKNTFFI-UHFFFAOYSA-N uranium Chemical compound [U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U] DNYWZCXLKNTFFI-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrolytic Production Of Metals (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH7788959 | 1959-09-07 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1194590B true DE1194590B (de) | 1965-06-10 |
Family
ID=4536034
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEE19886A Pending DE1194590B (de) | 1959-09-07 | 1960-09-06 | Verfahren zur Herstellung von Metallen, insbesondere von Titan, Aluminium und Magnesium, durch Schmelzflusselektrolyse |
Country Status (6)
| Country | Link |
|---|---|
| AT (1) | AT240609B (enrdf_load_html_response) |
| BE (1) | BE594774A (enrdf_load_html_response) |
| DE (1) | DE1194590B (enrdf_load_html_response) |
| ES (1) | ES260858A1 (enrdf_load_html_response) |
| GB (1) | GB959189A (enrdf_load_html_response) |
| SE (1) | SE308953B (enrdf_load_html_response) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2798844A (en) * | 1955-02-10 | 1957-07-09 | Horizons Titanium Corp | Electrolyte for titanium production |
| US2813068A (en) * | 1951-12-21 | 1957-11-12 | Horizons Titanium Corp | Production of titanium by fused salt electrolysis |
| US2848395A (en) * | 1952-04-29 | 1958-08-19 | Du Pont | Electrolytic process for production of titanium |
| GB812817A (en) * | 1954-05-21 | 1959-04-29 | Solar Aircraft Co | Electrolytic production of titanium |
-
1960
- 1960-09-06 SE SE847260A patent/SE308953B/xx unknown
- 1960-09-06 AT AT679360A patent/AT240609B/de active
- 1960-09-06 DE DEE19886A patent/DE1194590B/de active Pending
- 1960-09-06 BE BE594774A patent/BE594774A/fr unknown
- 1960-09-07 GB GB3080360A patent/GB959189A/en not_active Expired
- 1960-09-07 ES ES0260858A patent/ES260858A1/es not_active Expired
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2813068A (en) * | 1951-12-21 | 1957-11-12 | Horizons Titanium Corp | Production of titanium by fused salt electrolysis |
| US2848395A (en) * | 1952-04-29 | 1958-08-19 | Du Pont | Electrolytic process for production of titanium |
| GB812817A (en) * | 1954-05-21 | 1959-04-29 | Solar Aircraft Co | Electrolytic production of titanium |
| US2798844A (en) * | 1955-02-10 | 1957-07-09 | Horizons Titanium Corp | Electrolyte for titanium production |
Also Published As
| Publication number | Publication date |
|---|---|
| BE594774A (fr) | 1961-03-06 |
| GB959189A (en) | 1964-05-27 |
| ES260858A1 (es) | 1961-02-01 |
| AT240609B (de) | 1965-06-10 |
| SE308953B (enrdf_load_html_response) | 1969-03-03 |
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