DE1154242B - Nichtbraeunendes, durchsichtiges Phosphatglas - Google Patents
Nichtbraeunendes, durchsichtiges PhosphatglasInfo
- Publication number
- DE1154242B DE1154242B DEC22619A DEC0022619A DE1154242B DE 1154242 B DE1154242 B DE 1154242B DE C22619 A DEC22619 A DE C22619A DE C0022619 A DEC0022619 A DE C0022619A DE 1154242 B DE1154242 B DE 1154242B
- Authority
- DE
- Germany
- Prior art keywords
- glass
- percent
- weight
- pbo
- lead
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000005365 phosphate glass Substances 0.000 title claims description 4
- 239000011521 glass Substances 0.000 claims description 50
- 230000005855 radiation Effects 0.000 claims description 18
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 3
- 229910015902 Bi 2 O 3 Inorganic materials 0.000 claims description 2
- 229910006404 SnO 2 Inorganic materials 0.000 claims 1
- 239000000203 mixture Substances 0.000 description 22
- HTUMBQDCCIXGCV-UHFFFAOYSA-N lead oxide Chemical compound [O-2].[Pb+2] HTUMBQDCCIXGCV-UHFFFAOYSA-N 0.000 description 12
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 6
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 229910000464 lead oxide Inorganic materials 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 229910044991 metal oxide Inorganic materials 0.000 description 4
- 150000004706 metal oxides Chemical class 0.000 description 4
- 239000007800 oxidant agent Substances 0.000 description 4
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 229910052697 platinum Inorganic materials 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 239000011874 heated mixture Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- RLJMLMKIBZAXJO-UHFFFAOYSA-N lead nitrate Chemical compound [O-][N+](=O)O[Pb]O[N+]([O-])=O RLJMLMKIBZAXJO-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229910017604 nitric acid Inorganic materials 0.000 description 2
- 230000000737 periodic effect Effects 0.000 description 2
- 230000002285 radioactive effect Effects 0.000 description 2
- 239000005368 silicate glass Substances 0.000 description 2
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- VNDYJBBGRKZCSX-UHFFFAOYSA-L zinc bromide Chemical compound Br[Zn]Br VNDYJBBGRKZCSX-UHFFFAOYSA-L 0.000 description 2
- 240000002989 Euphorbia neriifolia Species 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- HUTDDBSSHVOYJR-UHFFFAOYSA-H bis[(2-oxo-1,3,2$l^{5},4$l^{2}-dioxaphosphaplumbetan-2-yl)oxy]lead Chemical compound [Pb+2].[Pb+2].[Pb+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O HUTDDBSSHVOYJR-UHFFFAOYSA-H 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 229910000420 cerium oxide Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000001010 compromised effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000005308 flint glass Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 238000007496 glass forming Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 238000010309 melting process Methods 0.000 description 1
- 125000005341 metaphosphate group Chemical group 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- FYWSTUCDSVYLPV-UHFFFAOYSA-N nitrooxythallium Chemical compound [Tl+].[O-][N+]([O-])=O FYWSTUCDSVYLPV-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
- WKMKTIVRRLOHAJ-UHFFFAOYSA-N oxygen(2-);thallium(1+) Chemical compound [O-2].[Tl+].[Tl+] WKMKTIVRRLOHAJ-UHFFFAOYSA-N 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052716 thallium Inorganic materials 0.000 description 1
- BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 description 1
- 229910003438 thallium oxide Inorganic materials 0.000 description 1
- 239000012780 transparent material Substances 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 229940102001 zinc bromide Drugs 0.000 description 1
Classifications
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F7/00—Shielded cells or rooms
- G21F7/02—Observation devices permitting vision but shielding the observer
- G21F7/03—Windows, e.g. shielded
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/12—Silica-free oxide glass compositions
- C03C3/16—Silica-free oxide glass compositions containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/12—Silica-free oxide glass compositions
- C03C3/16—Silica-free oxide glass compositions containing phosphorus
- C03C3/17—Silica-free oxide glass compositions containing phosphorus containing aluminium or beryllium
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
- C03C4/08—Compositions for glass with special properties for glass selectively absorbing radiation of specified wave lengths
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F7/00—Shielded cells or rooms
- G21F7/02—Observation devices permitting vision but shielding the observer
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- General Engineering & Computer Science (AREA)
- High Energy & Nuclear Physics (AREA)
- Glass Compositions (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US849055A US3149234A (en) | 1959-10-27 | 1959-10-27 | High density, soft phosphate glass, method, and gamma radiation shielding window |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1154242B true DE1154242B (de) | 1963-09-12 |
Family
ID=25304955
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEC22619A Pending DE1154242B (de) | 1959-10-27 | 1960-10-25 | Nichtbraeunendes, durchsichtiges Phosphatglas |
Country Status (8)
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3408212A (en) * | 1965-06-04 | 1968-10-29 | Fairchild Camera Instr Co | Low melting oxide glass |
| US3499774A (en) * | 1966-03-28 | 1970-03-10 | Glass Container Ind Research C | Mercury-containing phosphate glass |
| US3955991A (en) * | 1967-03-02 | 1976-05-11 | American Optical Corporation | Absorptive glass |
| USRE30141E (en) * | 1972-12-19 | 1979-11-06 | Ernst Leitz Wetzlar Gmbh | Inorganic vitreous detector material |
| JPS5911880B2 (ja) * | 1980-11-13 | 1984-03-19 | 高エネルギ−物理学研究所長 | 透明放射線遮蔽材料およびその製造法 |
| US4405724A (en) * | 1982-11-04 | 1983-09-20 | Corning Glass Works | Mercury thallium fluorophosphate glasses |
| JPS61251537A (ja) * | 1985-03-26 | 1986-11-08 | Ohara Inc | 異常部分分散性光学ガラス |
| JPH0769462B2 (ja) * | 1989-12-01 | 1995-07-31 | 動力炉・核燃料開発事業団 | 放射線遮蔽構造 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE951759C (de) * | 1952-10-29 | 1956-10-31 | Jenaer Glaswerk Schott & Gen | Verfahren zur Herstellung bleihaltiger Phosphatglaeser |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE580295C (de) * | 1930-09-19 | 1933-07-08 | Ig Farbenindustrie Ag | Phosphatglaeser |
| BE459672A (US07816562-20101019-C00012.png) * | 1941-11-24 | |||
| US2875346A (en) * | 1945-02-12 | 1959-02-24 | George S Monk | Overall optical viewer |
| CA604566A (en) * | 1945-02-12 | 1960-09-06 | Government Of Canada, As Represented By Atomic Energy Of Canada Limited | Radiation absorbing optical viewing system |
| GB580873A (en) * | 1945-03-19 | 1946-09-23 | British Thomson Houston Co Ltd | Improved soft glass compositions |
| US2577627A (en) * | 1947-05-01 | 1951-12-04 | American Optical Corp | Glass composition and method of making same |
| US2518194A (en) * | 1948-11-03 | 1950-08-08 | Silverman Alexander | Phosphate glass |
| NL84348C (US07816562-20101019-C00012.png) * | 1954-03-01 |
-
0
- NL NL120811D patent/NL120811C/xx active
- NL NL256504D patent/NL256504A/xx unknown
-
1959
- 1959-10-27 US US849055A patent/US3149234A/en not_active Expired - Lifetime
-
1960
- 1960-10-17 GB GB35519/60A patent/GB903450A/en not_active Expired
- 1960-10-25 FR FR842070A patent/FR1275108A/fr not_active Expired
- 1960-10-25 DE DEC22619A patent/DE1154242B/de active Pending
- 1960-10-26 CH CH1199260A patent/CH400471A/fr unknown
- 1960-10-26 BE BE596419A patent/BE596419A/fr unknown
-
1964
- 1964-12-31 OA OA51991A patent/OA02627A/xx unknown
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE951759C (de) * | 1952-10-29 | 1956-10-31 | Jenaer Glaswerk Schott & Gen | Verfahren zur Herstellung bleihaltiger Phosphatglaeser |
Also Published As
| Publication number | Publication date |
|---|---|
| NL256504A (US07816562-20101019-C00012.png) | |
| BE596419A (fr) | 1961-04-26 |
| US3149234A (en) | 1964-09-15 |
| CH400471A (fr) | 1965-10-15 |
| NL120811C (US07816562-20101019-C00012.png) | |
| OA02627A (fr) | 1970-12-15 |
| GB903450A (en) | 1962-08-15 |
| FR1275108A (fr) | 1961-11-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE691356C (de) | Verfahren zur Herstellung von optischen Glaesern hoher Brechungszahlen und niedrigerStreuung | |
| DE2719250C3 (de) | Optisches Glas mit einem Brechungsindex von 1^7 bis 1,98 und einer Abbe-Zahl von 18 bis 46 | |
| DE1496091A1 (de) | Phototropische Glaskoerper | |
| DE2034393B2 (de) | Anwendung des Verfahrens zur Erhöhung der mechanischen Festigkeit eines Glases durch Austausch von Natriumionen gegen Kaliumionen auf ein Glas, das verkürzte Austauschzeiten ermöglicht | |
| DE3222567A1 (de) | Szintillationsglas | |
| DE1621002B2 (de) | Infrarotdurchlaessiges germanium und selen sowie antimon oder tellur enthaltendes glas und seine verwendung in einem infrarotdetektor | |
| DE816129C (de) | Lichtempfindliches Glas | |
| DE3635834C2 (US07816562-20101019-C00012.png) | ||
| DE1154242B (de) | Nichtbraeunendes, durchsichtiges Phosphatglas | |
| DE1496092A1 (de) | Waermeabsorbierende Glaeser mit verbesserten physikalischen Eigenschaften | |
| DE2824797C2 (de) | Glaszusammensetzung im System TiO↓2↓-BaO-ZnO-ZrO↓2↓-CaO-MgO-SiO↓2↓-Na↓2↓O/K↓2↓O mit einem Brechungsindex von über 2,10 | |
| DE654973C (de) | Borosilicatglas | |
| DE1496082A1 (de) | Phototropischer Silikatglaskoerper | |
| DE1496089B2 (de) | Verfahren zur Herstellung von Glasgegenständen mit phototropen Eigenschaften | |
| DE1421923B2 (US07816562-20101019-C00012.png) | ||
| DE2002365B2 (de) | Verfahren zum herstellen eines laserglases mit einem hohen beschaedigungs-schwellenwert und verringerter neigung zur mikrophasentrennung und entgalsung, sowie nach diesem verfahren hergestellte laserglaeser | |
| DE1596917B2 (de) | Schnell umschlagendes phototropes Glas auf der Basis eines Tonerde Borat glases mit Zusätzen an Silberhalogeniden und Kupferoxid und Verfahren zu seiner Herstellung | |
| DE1764929C3 (de) | Nd hoch 3+ -dotiertes Laserglas | |
| DE1088675B (de) | Kieselsaeure-Tonerde-Erdalkalioxyd-Glas | |
| DE1496561A1 (de) | Glas,insbesondere als Werkstoff fuer optische,im IR-Bereich durchlaessige Bauelemente | |
| DE2346778A1 (de) | Flussmittel zum giessen von stahl | |
| DE1193211B (de) | Mikro-Glaskuegelchen zur Verwendung als Kern-brennstoff in Reaktoren | |
| DE2144106A1 (en) | Colourless uv transparent good weathering glass - contains oxides of zinc aluminium and barium | |
| DE1258563B (de) | Glas, insbesondere als Werkstoff zur Herstellung optischer Bauelemente | |
| DE817942C (de) | Roentgenstrahlen absorbierendes Schutzglas |
