DE1152540C2 - Verfahren zum Stabilisieren von Homo- oder Mischpolymerisaten von Olefinen durch Benzophenon-verbindungen - Google Patents
Verfahren zum Stabilisieren von Homo- oder Mischpolymerisaten von Olefinen durch Benzophenon-verbindungenInfo
- Publication number
- DE1152540C2 DE1152540C2 DE1959P0023568 DEP0023568A DE1152540C2 DE 1152540 C2 DE1152540 C2 DE 1152540C2 DE 1959P0023568 DE1959P0023568 DE 1959P0023568 DE P0023568 A DEP0023568 A DE P0023568A DE 1152540 C2 DE1152540 C2 DE 1152540C2
- Authority
- DE
- Germany
- Prior art keywords
- tert
- hydroxy
- brittle
- butyl
- copolymers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 7
- 150000001336 alkenes Chemical class 0.000 title claims description 6
- 150000008366 benzophenones Chemical class 0.000 title claims description 5
- 229920001577 copolymer Polymers 0.000 title claims description 5
- 230000008569 process Effects 0.000 title claims description 4
- 229920001519 homopolymer Polymers 0.000 title claims description 3
- 230000000087 stabilizing effect Effects 0.000 title claims description 3
- 229920000098 polyolefin Polymers 0.000 claims description 12
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 239000004215 Carbon black (E152) Substances 0.000 claims description 2
- 229930195733 hydrocarbon Natural products 0.000 claims description 2
- HXIQYSLFEXIOAV-UHFFFAOYSA-N 2-tert-butyl-4-(5-tert-butyl-4-hydroxy-2-methylphenyl)sulfanyl-5-methylphenol Chemical compound CC1=CC(O)=C(C(C)(C)C)C=C1SC1=CC(C(C)(C)C)=C(O)C=C1C HXIQYSLFEXIOAV-UHFFFAOYSA-N 0.000 description 11
- -1 polyethylene Polymers 0.000 description 11
- 238000012360 testing method Methods 0.000 description 8
- 239000004698 Polyethylene Substances 0.000 description 7
- QUAMTGJKVDWJEQ-UHFFFAOYSA-N octabenzone Chemical compound OC1=CC(OCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 QUAMTGJKVDWJEQ-UHFFFAOYSA-N 0.000 description 7
- 229920000573 polyethylene Polymers 0.000 description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 5
- 239000012760 heat stabilizer Substances 0.000 description 5
- ARVUDIQYNJVQIW-UHFFFAOYSA-N (4-dodecoxy-2-hydroxyphenyl)-phenylmethanone Chemical compound OC1=CC(OCCCCCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 ARVUDIQYNJVQIW-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 239000012963 UV stabilizer Substances 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 230000006641 stabilisation Effects 0.000 description 3
- 238000011105 stabilization Methods 0.000 description 3
- JQSSXIRDGUMPNP-UHFFFAOYSA-N (4-decoxy-2-hydroxyphenyl)-phenylmethanone Chemical compound OC1=CC(OCCCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 JQSSXIRDGUMPNP-UHFFFAOYSA-N 0.000 description 2
- CSGHZFMNVVSDIF-UHFFFAOYSA-N (4-hexadecoxy-2-hydroxyphenyl)-phenylmethanone Chemical compound OC1=CC(OCCCCCCCCCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 CSGHZFMNVVSDIF-UHFFFAOYSA-N 0.000 description 2
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 2
- ZXDDPOHVAMWLBH-UHFFFAOYSA-N 2,4-Dihydroxybenzophenone Chemical compound OC1=CC(O)=CC=C1C(=O)C1=CC=CC=C1 ZXDDPOHVAMWLBH-UHFFFAOYSA-N 0.000 description 2
- GSOYMOAPJZYXTB-UHFFFAOYSA-N 2,6-ditert-butyl-4-(3,5-ditert-butyl-4-hydroxyphenyl)phenol Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(C=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 GSOYMOAPJZYXTB-UHFFFAOYSA-N 0.000 description 2
- PFANXOISJYKQRP-UHFFFAOYSA-N 2-tert-butyl-4-[1-(5-tert-butyl-4-hydroxy-2-methylphenyl)butyl]-5-methylphenol Chemical compound C=1C(C(C)(C)C)=C(O)C=C(C)C=1C(CCC)C1=CC(C(C)(C)C)=C(O)C=C1C PFANXOISJYKQRP-UHFFFAOYSA-N 0.000 description 2
- MDWVSAYEQPLWMX-UHFFFAOYSA-N 4,4'-Methylenebis(2,6-di-tert-butylphenol) Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 MDWVSAYEQPLWMX-UHFFFAOYSA-N 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- POLSVAXEEHDBMJ-UHFFFAOYSA-N (2-hydroxy-4-octadecoxyphenyl)-phenylmethanone Chemical compound OC1=CC(OCCCCCCCCCCCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 POLSVAXEEHDBMJ-UHFFFAOYSA-N 0.000 description 1
- HJIAMFHSAAEUKR-UHFFFAOYSA-N (2-hydroxyphenyl)-phenylmethanone Chemical class OC1=CC=CC=C1C(=O)C1=CC=CC=C1 HJIAMFHSAAEUKR-UHFFFAOYSA-N 0.000 description 1
- JAFUHGPESJSRJX-UHFFFAOYSA-N (4-ethoxy-2-hydroxyphenyl)-phenylmethanone Chemical compound OC1=CC(OCC)=CC=C1C(=O)C1=CC=CC=C1 JAFUHGPESJSRJX-UHFFFAOYSA-N 0.000 description 1
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- PBLNBZIONSLZBU-UHFFFAOYSA-N 1-bromododecane Chemical compound CCCCCCCCCCCCBr PBLNBZIONSLZBU-UHFFFAOYSA-N 0.000 description 1
- VMKOFRJSULQZRM-UHFFFAOYSA-N 1-bromooctane Chemical compound CCCCCCCCBr VMKOFRJSULQZRM-UHFFFAOYSA-N 0.000 description 1
- GACQLWFABDKVAX-UHFFFAOYSA-N 2,3,6-tritert-butyl-4-phenylphenol Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(C=2C=CC=CC=2)=C1C(C)(C)C GACQLWFABDKVAX-UHFFFAOYSA-N 0.000 description 1
- ASLNDVUAZOHADR-UHFFFAOYSA-N 2-butyl-3-methylphenol Chemical compound CCCCC1=C(C)C=CC=C1O ASLNDVUAZOHADR-UHFFFAOYSA-N 0.000 description 1
- WJQOZHYUIDYNHM-UHFFFAOYSA-N 2-tert-Butylphenol Chemical compound CC(C)(C)C1=CC=CC=C1O WJQOZHYUIDYNHM-UHFFFAOYSA-N 0.000 description 1
- YYYDGUUYXRVUPC-UHFFFAOYSA-N C(CCCCCCCCCCCCCCCCC)OC1=CC(=C(C(=O)C2=C(C=C(C=C2)OCCCCCCCCCCCCCCCCCC)O)C=C1)O Chemical compound C(CCCCCCCCCCCCCCCCC)OC1=CC(=C(C(=O)C2=C(C=C(C=C2)OCCCCCCCCCCCCCCCCCC)O)C=C1)O YYYDGUUYXRVUPC-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 239000013036 UV Light Stabilizer Substances 0.000 description 1
- 229920001938 Vegetable gum Polymers 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 150000005840 aryl radicals Chemical class 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000008570 general process Effects 0.000 description 1
- 150000002430 hydrocarbons Chemical group 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- DXGLGDHPHMLXJC-UHFFFAOYSA-N oxybenzone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 DXGLGDHPHMLXJC-UHFFFAOYSA-N 0.000 description 1
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000035900 sweating Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
- C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
- C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
- C07C45/70—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction with functional groups containing oxygen only in singly bound form
- C07C45/71—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction with functional groups containing oxygen only in singly bound form being hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
- C07C49/76—Ketones containing a keto group bound to a six-membered aromatic ring
- C07C49/84—Ketones containing a keto group bound to a six-membered aromatic ring containing ether groups, groups, groups, or groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
- C08K5/132—Phenols containing keto groups, e.g. benzophenones
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US762274A US3006959A (en) | 1958-09-22 | 1958-09-22 | 2-hydroxy-4-n-dodecyloxybenzophenone |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE1152540B DE1152540B (de) | 1963-08-08 |
| DE1152540C2 true DE1152540C2 (de) | 1973-08-30 |
Family
ID=25064578
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19591794302D Pending DE1794302B1 (de) | 1958-09-22 | 1959-09-22 | Verfahren zum Stabilisieren von Homo- oder Mischpolymerisaten von Olefinen durch Benzophenonverbindungen |
| DE1959P0023568 Expired DE1152540C2 (de) | 1958-09-22 | 1959-09-22 | Verfahren zum Stabilisieren von Homo- oder Mischpolymerisaten von Olefinen durch Benzophenon-verbindungen |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19591794302D Pending DE1794302B1 (de) | 1958-09-22 | 1959-09-22 | Verfahren zum Stabilisieren von Homo- oder Mischpolymerisaten von Olefinen durch Benzophenonverbindungen |
Country Status (8)
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3098842A (en) * | 1961-08-17 | 1963-07-23 | Du Pont | Stabilized polyolefins |
| US3096302A (en) * | 1961-09-13 | 1963-07-02 | Eastman Kodak Co | Heat and light stable polypropylene compositions |
| US3320207A (en) * | 1961-12-21 | 1967-05-16 | American Cyanamid Co | Process for applying ultraviolet absorbers to textile materials |
| NL290916A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1962-04-04 | |||
| US3219621A (en) * | 1962-04-30 | 1965-11-23 | Celanese Corp | Stabilization of oxymethylene copolymers by 2-hydroxy benzophenones |
| US3370036A (en) * | 1962-07-02 | 1968-02-20 | Phillips Petroleum Co | Stabilization of polymers with uv stabilizers and antioxidants |
| DE1292393B (de) * | 1965-10-12 | 1969-04-10 | Huels Chemische Werke Ag | Stabilisieren von ungesaettigten AEthylen-ª-Olefin-Kautschuken |
| US3322705A (en) * | 1966-02-15 | 1967-05-30 | Argus Chem | Polyolefins stabilized with mixtures comprising a 2-hydroxy, 4-benzyloxy benzophenone, thiodipropionate and metal salt of a monocarboxylic acid |
| US3399169A (en) * | 1966-05-05 | 1968-08-27 | American Cyanamid Co | 2-hydroxy-4-alkoxy-4'-alkylbenzophenones and polymers stabilized therewith |
| US3548005A (en) * | 1966-05-05 | 1970-12-15 | American Cyanamid Co | Chlorinated benzophenone light stabilizers |
| US3445424A (en) * | 1967-12-18 | 1969-05-20 | Phillips Petroleum Co | Stabilization of polymers with uv stabilizers and antioxidants |
| US3658910A (en) * | 1970-02-11 | 1972-04-25 | Carlisle Chemical Works | Liquid 2-hydroxy-4-alkoxybenzophenones |
| US4062800A (en) * | 1976-08-16 | 1977-12-13 | Eastman Kodak Company | Bichromophoric benzoxazole-styrene ester and amide ultraviolet stabilizers and their use in organic compositions |
| US6214915B1 (en) | 1998-12-10 | 2001-04-10 | General Electric Company | Stabilized thermoplastic compositions |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1012610B (de) * | 1951-03-09 | 1957-07-25 | Gen Aniline & Film Corp | Verfahren zur Herstellung von Dioxy-dialkoxybenzophenonen |
| US2843563A (en) * | 1955-01-27 | 1958-07-15 | Eastman Kodak Co | Polyethylene compositions stabilized with acyl derivatives of 1, 2, 4-trihydroxybenzene |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2693492A (en) * | 1954-11-02 | - dihydroxy - | ||
| US2675366A (en) * | 1951-05-24 | 1954-04-13 | American Cyanamid Co | Stabilization of polyethylene |
| GB726392A (en) * | 1952-08-09 | 1955-03-16 | Gen Electric | Improvements relating to radio directional apparatus |
| US2777828A (en) * | 1953-04-03 | 1957-01-15 | American Cyanamid Co | Stabilization of mixtures of unsaturated polyesters and copolymerizable monomers by means of hydroxy substituted benzophenones |
| US2819247A (en) * | 1953-06-10 | 1958-01-07 | American Cyanamid Co | Flame-resistant polyester resinous compositions containing combined halogens and phosporus and process of preparation |
| NL95971C (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1955-09-27 | |||
| US2822340A (en) * | 1955-10-12 | 1958-02-04 | American Cyanamid Co | Flame resistant polyester resinous compositions containing combined halogens and phosphorous and certain alkaline earth metal salts and the process of preparing the same |
| US2789140A (en) * | 1955-12-29 | 1957-04-16 | Gen Aniline & Film Corp | Process of preparing tetra substituted 2, 2', 4, 4'-benzophenones |
| US2861053A (en) * | 1957-11-07 | 1958-11-18 | Eastman Kodak Co | Polyolefin compositions containing certain 2-hydroxy-4-alkoxy benzophenones |
| US2887466A (en) * | 1958-02-14 | 1959-05-19 | Eastman Kodak Co | Polyethylene compositions containing 2-hydroxy-5-octylbenzophenone |
-
0
- NL NL127157D patent/NL127157C/xx active
- IT IT619255D patent/IT619255A/it unknown
- NL NL243485D patent/NL243485A/xx unknown
- BE BE582206D patent/BE582206A/xx unknown
-
1958
- 1958-09-22 US US762274A patent/US3006959A/en not_active Expired - Lifetime
-
1959
- 1959-09-03 DK DK313359AA patent/DK106760C/da active
- 1959-09-10 FR FR804759A patent/FR1235032A/fr not_active Expired
- 1959-09-18 GB GB31810/59A patent/GB918464A/en not_active Expired
- 1959-09-22 DE DE19591794302D patent/DE1794302B1/de active Pending
- 1959-09-22 DE DE1959P0023568 patent/DE1152540C2/de not_active Expired
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1012610B (de) * | 1951-03-09 | 1957-07-25 | Gen Aniline & Film Corp | Verfahren zur Herstellung von Dioxy-dialkoxybenzophenonen |
| US2843563A (en) * | 1955-01-27 | 1958-07-15 | Eastman Kodak Co | Polyethylene compositions stabilized with acyl derivatives of 1, 2, 4-trihydroxybenzene |
Also Published As
| Publication number | Publication date |
|---|---|
| NL127157C (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | |
| DK106760C (da) | 1967-03-13 |
| IT619255A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | |
| US3006959A (en) | 1961-10-31 |
| NL243485A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | |
| GB918464A (en) | 1963-02-13 |
| DE1794302B1 (de) | 1971-11-18 |
| FR1235032A (fr) | 1960-07-01 |
| BE582206A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | |
| DE1152540B (de) | 1963-08-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE1152540C2 (de) | Verfahren zum Stabilisieren von Homo- oder Mischpolymerisaten von Olefinen durch Benzophenon-verbindungen | |
| DE2728862C3 (de) | Stabilisierte Formmassen auf der Basis von Vinylchlorid-Polymerisaten | |
| DE1173241B (de) | Formmassen aus Polymerisaten mindestens eines aliphatischen ª-Monoolefins mit 2 bis10 Kohlenstoffatomen | |
| DE1234023B (de) | Verfahren zum Stabilisieren von isotaktischem Polypropylen | |
| DE1270799B (de) | Stabilisieren halogenhaltiger Polymerisate | |
| DE1288604B (de) | Stabilisieren von organischen Stoffen gegen Zersetzung durch Sauerstoff in der Waerme | |
| DE1106954B (de) | Gegen die Einwirkung von ultraviolettem Licht stabilisierte Formmasse aus Polyolefinen | |
| DE1153520B (de) | Stabilisierte Formmassen aus stereoregulaeren Polymerisaten von ª-Olefinen | |
| DE1230214B (de) | Verfahren zur Herstellung von Formmassen aus kristallinen Olefinpolymerisaten | |
| DE1151114B (de) | Verfahren zum Stabilisieren von Polymerisaten aus ª-Olefinen | |
| DE1153894B (de) | Stabilisierung von Polyolefinen | |
| DE1469809C3 (de) | Thermoplastische Massen | |
| DE3587983T2 (de) | Verfahren zum Pflanzenschutz durch stabilisierte Polymerfilme. | |
| DE1494180A1 (de) | Verfahren zum Vulkanisieren von gesaettigten Olefinpolymeren und-copolymeren | |
| DE1186623B (de) | Formmassen aus Homo- oder Mischpolymerisaten von alpha-Olefinen | |
| DE69119970T2 (de) | Copolymerzusammensetzungen enthaltend ein Copolymer und ein oder mehrere Gleitmittelzusätze | |
| DE1147753B (de) | Gegen Licht stabilisierte Formmassen aus festen Polymeren eines ª‡-Olefins mit wenigstens 3 Kohlenstoffatomen | |
| DE1265409B (de) | Verfahren zum Stabilisieren von Polyolefinen | |
| DE1793192A1 (de) | Neue Antioxydantien,ihre Verwendung in polymeren Massen und Verfahren zu ihrer Herstellung | |
| DE1161011B (de) | Verfahren zum Stabilisieren von kristallinen Polyolefinen | |
| DE1206150B (de) | Ozonschutzmittel fuer Kautschuk | |
| DE1643559B1 (de) | Substituierte 2-Hydroxybenzyl-4-hydroxyphenyl-sulfide und ihre Verwendung | |
| DE1163017B (de) | Verfahren zum Stabilisieren von Polyolefinen | |
| US1830749A (en) | Method of compounding rubber | |
| DE1148069B (de) | Synergistisches Oxydationsschutzmittel fuer Kautschuk |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C2 | Grant after previous publication (2nd publication) |