DE112012003072T5 - Entschwefelungsmaterial, das Kupfer auf einem Zinkoxidträger umfasst - Google Patents
Entschwefelungsmaterial, das Kupfer auf einem Zinkoxidträger umfasst Download PDFInfo
- Publication number
- DE112012003072T5 DE112012003072T5 DE112012003072.9T DE112012003072T DE112012003072T5 DE 112012003072 T5 DE112012003072 T5 DE 112012003072T5 DE 112012003072 T DE112012003072 T DE 112012003072T DE 112012003072 T5 DE112012003072 T5 DE 112012003072T5
- Authority
- DE
- Germany
- Prior art keywords
- copper
- desulfurizing
- zinc oxide
- zinc
- material according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000000463 material Substances 0.000 title claims abstract description 96
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 title claims abstract description 86
- 239000011787 zinc oxide Substances 0.000 title claims abstract description 43
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 25
- 239000010949 copper Substances 0.000 title claims abstract description 24
- 229910052802 copper Inorganic materials 0.000 title claims abstract description 24
- 238000006477 desulfuration reaction Methods 0.000 claims abstract description 21
- 230000023556 desulfurization Effects 0.000 claims abstract description 21
- 239000005749 Copper compound Substances 0.000 claims abstract description 18
- 150000001880 copper compounds Chemical class 0.000 claims abstract description 18
- 230000003009 desulfurizing effect Effects 0.000 claims description 25
- 238000000034 method Methods 0.000 claims description 24
- 239000011230 binding agent Substances 0.000 claims description 17
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 13
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 12
- 229910052725 zinc Inorganic materials 0.000 claims description 12
- 239000011701 zinc Substances 0.000 claims description 12
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 10
- 238000001354 calcination Methods 0.000 claims description 10
- 229910052739 hydrogen Inorganic materials 0.000 claims description 10
- 229910052751 metal Inorganic materials 0.000 claims description 10
- 239000002184 metal Substances 0.000 claims description 10
- 239000011148 porous material Substances 0.000 claims description 10
- NKCVNYJQLIWBHK-UHFFFAOYSA-N carbonodiperoxoic acid Chemical compound OOC(=O)OO NKCVNYJQLIWBHK-UHFFFAOYSA-N 0.000 claims description 8
- 239000003054 catalyst Substances 0.000 claims description 8
- 239000007789 gas Substances 0.000 claims description 8
- 239000001257 hydrogen Substances 0.000 claims description 8
- 239000005751 Copper oxide Substances 0.000 claims description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 7
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 7
- 229910000431 copper oxide Inorganic materials 0.000 claims description 7
- 238000001035 drying Methods 0.000 claims description 7
- 150000002736 metal compounds Chemical class 0.000 claims description 7
- 229930195733 hydrocarbon Natural products 0.000 claims description 6
- 150000002430 hydrocarbons Chemical class 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 6
- 239000004215 Carbon black (E152) Substances 0.000 claims description 5
- 239000012876 carrier material Substances 0.000 claims description 5
- 239000012530 fluid Substances 0.000 claims description 5
- 239000008187 granular material Substances 0.000 claims description 5
- 229910052759 nickel Inorganic materials 0.000 claims description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 4
- 239000004568 cement Substances 0.000 claims description 4
- JJLJMEJHUUYSSY-UHFFFAOYSA-L Copper hydroxide Chemical compound [OH-].[OH-].[Cu+2] JJLJMEJHUUYSSY-UHFFFAOYSA-L 0.000 claims description 3
- 239000005750 Copper hydroxide Substances 0.000 claims description 3
- 239000004927 clay Substances 0.000 claims description 3
- 229910017052 cobalt Inorganic materials 0.000 claims description 3
- 239000010941 cobalt Substances 0.000 claims description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 3
- 229910001956 copper hydroxide Inorganic materials 0.000 claims description 3
- 229960001545 hydrotalcite Drugs 0.000 claims description 3
- 229910001701 hydrotalcite Inorganic materials 0.000 claims description 3
- 239000002243 precursor Substances 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 2
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 claims description 2
- OPQARKPSCNTWTJ-UHFFFAOYSA-L copper(ii) acetate Chemical compound [Cu+2].CC([O-])=O.CC([O-])=O OPQARKPSCNTWTJ-UHFFFAOYSA-L 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 238000000465 moulding Methods 0.000 claims description 2
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 claims 2
- 229910052717 sulfur Inorganic materials 0.000 description 23
- 239000011593 sulfur Substances 0.000 description 23
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 22
- 239000002250 absorbent Substances 0.000 description 10
- 230000002745 absorbent Effects 0.000 description 10
- 238000011068 loading method Methods 0.000 description 8
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 8
- 229910052753 mercury Inorganic materials 0.000 description 8
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 7
- 238000010521 absorption reaction Methods 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 238000002459 porosimetry Methods 0.000 description 6
- -1 cracked naphtha Substances 0.000 description 5
- 238000000326 densiometry Methods 0.000 description 5
- 238000005486 sulfidation Methods 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- QMMFVYPAHWMCMS-UHFFFAOYSA-N Dimethyl sulfide Chemical compound CSC QMMFVYPAHWMCMS-UHFFFAOYSA-N 0.000 description 3
- XFWJKVMFIVXPKK-UHFFFAOYSA-N calcium;oxido(oxo)alumane Chemical compound [Ca+2].[O-][Al]=O.[O-][Al]=O XFWJKVMFIVXPKK-UHFFFAOYSA-N 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000003345 natural gas Substances 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- CETBSQOFQKLHHZ-UHFFFAOYSA-N Diethyl disulfide Chemical compound CCSSCC CETBSQOFQKLHHZ-UHFFFAOYSA-N 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
- 229910003294 NiMo Inorganic materials 0.000 description 2
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 2
- JJWKPURADFRFRB-UHFFFAOYSA-N carbonyl sulfide Chemical compound O=C=S JJWKPURADFRFRB-UHFFFAOYSA-N 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 150000002898 organic sulfur compounds Chemical class 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 238000004375 physisorption Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 150000003464 sulfur compounds Chemical class 0.000 description 2
- 238000011144 upstream manufacturing Methods 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 235000004035 Cryptotaenia japonica Nutrition 0.000 description 1
- 206010013786 Dry skin Diseases 0.000 description 1
- 239000004113 Sepiolite Substances 0.000 description 1
- 102000007641 Trefoil Factors Human genes 0.000 description 1
- 235000015724 Trifolium pratense Nutrition 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 150000001869 cobalt compounds Chemical class 0.000 description 1
- 229910000428 cobalt oxide Inorganic materials 0.000 description 1
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000002737 fuel gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 239000003949 liquefied natural gas Substances 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- 229910001960 metal nitrate Inorganic materials 0.000 description 1
- 150000002816 nickel compounds Chemical class 0.000 description 1
- 229910000480 nickel oxide Inorganic materials 0.000 description 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- UOURRHZRLGCVDA-UHFFFAOYSA-D pentazinc;dicarbonate;hexahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Zn+2].[Zn+2].[Zn+2].[Zn+2].[Zn+2].[O-]C([O-])=O.[O-]C([O-])=O UOURRHZRLGCVDA-UHFFFAOYSA-D 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000010079 rubber tapping Methods 0.000 description 1
- 229910052624 sepiolite Inorganic materials 0.000 description 1
- 235000019355 sepiolite Nutrition 0.000 description 1
- 239000002594 sorbent Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000000629 steam reforming Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- WMXCDAVJEZZYLT-UHFFFAOYSA-N tert-butylthiol Chemical compound CC(C)(C)S WMXCDAVJEZZYLT-UHFFFAOYSA-N 0.000 description 1
- RAOIDOHSFRTOEL-UHFFFAOYSA-N tetrahydrothiophene Chemical compound C1CCSC1 RAOIDOHSFRTOEL-UHFFFAOYSA-N 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 229930192474 thiophene Natural products 0.000 description 1
- ZSDSQXJSNMTJDA-UHFFFAOYSA-N trifluralin Chemical compound CCCN(CCC)C1=C([N+]([O-])=O)C=C(C(F)(F)F)C=C1[N+]([O-])=O ZSDSQXJSNMTJDA-UHFFFAOYSA-N 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 150000003752 zinc compounds Chemical class 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
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- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0063—Granulating
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01D2256/24—Hydrocarbons
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01D2256/24—Hydrocarbons
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
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- Chemical & Material Sciences (AREA)
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- Analytical Chemistry (AREA)
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- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
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Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB1112606.7A GB201112606D0 (en) | 2011-07-22 | 2011-07-22 | Desulphurisation materials |
| GBGB-1112606.7 | 2011-07-22 | ||
| PCT/GB2012/050808 WO2013014415A1 (en) | 2011-07-22 | 2012-04-12 | Desulphurisation material comprising copper supported on zinc oxide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE112012003072T5 true DE112012003072T5 (de) | 2014-04-17 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
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| DE112012003072.9T Pending DE112012003072T5 (de) | 2011-07-22 | 2012-04-12 | Entschwefelungsmaterial, das Kupfer auf einem Zinkoxidträger umfasst |
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| US (2) | US9539536B2 (ru) |
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| GB (2) | GB201112606D0 (ru) |
| RU (1) | RU2594283C2 (ru) |
| WO (1) | WO2013014415A1 (ru) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| WO2015159910A1 (ja) * | 2014-04-16 | 2015-10-22 | ニッソーファイン株式会社 | 乾燥剤組成物 |
| CN105582879B (zh) * | 2014-10-24 | 2018-05-11 | 中国石油化工股份有限公司 | 硫砷净化剂及其制备方法 |
| CN104437074B (zh) * | 2014-12-31 | 2017-03-01 | 沈阳三聚凯特催化剂有限公司 | 一种同时脱除硫化氢和羰基硫的脱硫剂 |
| SG10201604013RA (en) | 2015-05-28 | 2016-12-29 | Evonik Degussa Gmbh | Hydrogen-assisted adsorption of sulphur compounds from olefin mixtures |
| CN106622253A (zh) * | 2016-12-23 | 2017-05-10 | 温州大学 | CuO/ZnO复合纳米催化剂及其制备方法与应用 |
| FR3067265B1 (fr) * | 2017-06-13 | 2019-07-26 | IFP Energies Nouvelles | Procede de preparation de solides a partir d'un melange d'au moins une poudre de malachite et une poudre d'oxyde et utilisation de ces solides |
| CN110586028B (zh) * | 2019-10-08 | 2021-11-19 | 中国石油化工股份有限公司 | 一种脱硫剂及其制备方法和应用 |
| JP7288420B2 (ja) * | 2020-06-10 | 2023-06-07 | 石塚硝子株式会社 | 硫黄系悪臭の消臭剤 |
| CN111545055B (zh) * | 2020-06-18 | 2022-02-11 | 中国科学院大学 | 类水滑石衍生复合氧化物材料的应用 |
| JP7493718B2 (ja) * | 2020-07-08 | 2024-06-03 | 株式会社重松製作所 | シアン化水素ガス吸着材及び防毒マスク |
| CN113856704B (zh) * | 2021-11-16 | 2023-04-07 | 四川轻化工大学 | 一种高效降解抗生素的光催化剂及其制备方法和应用 |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2053477A5 (ru) | 1969-07-07 | 1971-04-16 | Azote & Prod Chim | |
| US4071609A (en) | 1975-07-09 | 1978-01-31 | The New Jersey Zinc Company | Method for preparing particulate zinc oxide shapes of high surface area and improved strength |
| GB8714232D0 (en) * | 1987-06-17 | 1987-07-22 | Ici Plc | Sulphur compounds removal |
| JP3114325B2 (ja) | 1992-02-14 | 2000-12-04 | 村田機械株式会社 | ファクシミリ装置 |
| GB9405269D0 (en) * | 1994-03-17 | 1994-04-27 | Ici Plc | Absorbents |
| JP4161147B2 (ja) * | 1998-03-27 | 2008-10-08 | 大阪瓦斯株式会社 | 水素製造装置 |
| US6887445B2 (en) * | 1998-08-04 | 2005-05-03 | M-I L.L.C. | Process for sulfur scavenging |
| UA49430C2 (en) * | 2001-12-06 | 2006-12-15 | Alvigo Ks Res And Production C | Catalyst for removal of organic and inorganic compounds of sulfur from gas or vapor, process for removal of sulfuric compounds from gases and method for removal of sulfuric compounds from vapor, for example, benzene |
| EP1843840B1 (en) * | 2005-01-06 | 2019-05-22 | Research Triangle Institute | Zinc oxide-based sorbents and process for preparing and using same |
| DE102005004368A1 (de) | 2005-01-31 | 2006-08-03 | Süd-Chemie AG | Entschwefelungskatalysator |
| AT505700B1 (de) | 2007-08-27 | 2009-12-15 | Mettop Gmbh | Verfahren zum betreiben von kupfer-elektrolysezellen |
| GB0804570D0 (en) * | 2008-03-12 | 2008-04-16 | Johnson Matthey Plc | Desulphurisation materials |
| GB0804572D0 (en) | 2008-03-12 | 2008-04-16 | Johnson Matthey Plc | Preparation of desulphurisation materials |
| GB0916161D0 (en) * | 2009-09-15 | 2009-10-28 | Johnson Matthey Plc | Desulphurisation process |
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2011
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Also Published As
| Publication number | Publication date |
|---|---|
| WO2013014415A1 (en) | 2013-01-31 |
| US20170072381A1 (en) | 2017-03-16 |
| US9539536B2 (en) | 2017-01-10 |
| CN103687667B (zh) | 2016-08-17 |
| GB2493046B (en) | 2014-01-22 |
| JP6043350B2 (ja) | 2016-12-14 |
| BR112014001139B1 (pt) | 2020-02-18 |
| RU2014106733A (ru) | 2015-08-27 |
| BR112014001139A2 (pt) | 2017-02-21 |
| JP2014521497A (ja) | 2014-08-28 |
| GB2493046A (en) | 2013-01-23 |
| DK179793B1 (en) | 2019-06-25 |
| US20140161701A1 (en) | 2014-06-12 |
| GB201112606D0 (en) | 2011-09-07 |
| GB201208044D0 (en) | 2012-06-20 |
| RU2594283C2 (ru) | 2016-08-10 |
| US10569251B2 (en) | 2020-02-25 |
| DK201470028A (en) | 2014-01-21 |
| CN103687667A (zh) | 2014-03-26 |
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