DE112012000636T5 - Elektrodenmaterial mit Kern-Hülle-Aufbau - Google Patents
Elektrodenmaterial mit Kern-Hülle-Aufbau Download PDFInfo
- Publication number
- DE112012000636T5 DE112012000636T5 DE112012000636T DE112012000636T DE112012000636T5 DE 112012000636 T5 DE112012000636 T5 DE 112012000636T5 DE 112012000636 T DE112012000636 T DE 112012000636T DE 112012000636 T DE112012000636 T DE 112012000636T DE 112012000636 T5 DE112012000636 T5 DE 112012000636T5
- Authority
- DE
- Germany
- Prior art keywords
- outer shell
- active material
- composite
- battery
- shell
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000011258 core-shell material Substances 0.000 title description 8
- 239000007772 electrode material Substances 0.000 title description 3
- 239000011149 active material Substances 0.000 claims abstract description 65
- 239000002131 composite material Substances 0.000 claims abstract description 26
- 239000007788 liquid Substances 0.000 claims abstract description 21
- 229910018091 Li 2 S Inorganic materials 0.000 claims abstract description 17
- 150000002500 ions Chemical class 0.000 claims abstract description 17
- 150000001875 compounds Chemical class 0.000 claims abstract description 13
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052744 lithium Inorganic materials 0.000 claims abstract description 10
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims abstract description 9
- 229910004298 SiO 2 Inorganic materials 0.000 claims abstract description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 8
- 229910012305 LiPON Inorganic materials 0.000 claims abstract description 8
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052700 potassium Inorganic materials 0.000 claims abstract description 8
- 239000011591 potassium Substances 0.000 claims abstract description 8
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 8
- 239000011734 sodium Substances 0.000 claims abstract description 8
- 239000011521 glass Substances 0.000 claims description 22
- 239000011246 composite particle Substances 0.000 claims description 11
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 6
- 239000011777 magnesium Substances 0.000 claims description 6
- 229910052749 magnesium Inorganic materials 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 239000011230 binding agent Substances 0.000 claims description 4
- 229910003002 lithium salt Inorganic materials 0.000 claims description 4
- 159000000002 lithium salts Chemical class 0.000 claims description 4
- 239000004020 conductor Substances 0.000 claims description 3
- 239000003792 electrolyte Substances 0.000 claims description 3
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims 2
- 229910001416 lithium ion Inorganic materials 0.000 claims 2
- -1 SiO2 Chemical class 0.000 abstract description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- 229910001216 Li2S Inorganic materials 0.000 abstract 1
- 229910007302 Li2S: P2S5 Inorganic materials 0.000 abstract 1
- 229910004600 P2S5 Inorganic materials 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 229910052681 coesite Inorganic materials 0.000 abstract 1
- 229910052593 corundum Inorganic materials 0.000 abstract 1
- 229910052906 cristobalite Inorganic materials 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 229910052682 stishovite Inorganic materials 0.000 abstract 1
- 229910052905 tridymite Inorganic materials 0.000 abstract 1
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 1
- 239000011257 shell material Substances 0.000 description 72
- 239000011324 bead Substances 0.000 description 58
- 239000011162 core material Substances 0.000 description 46
- 239000000463 material Substances 0.000 description 25
- 239000007789 gas Substances 0.000 description 16
- 239000002245 particle Substances 0.000 description 16
- 239000002243 precursor Substances 0.000 description 11
- 238000000034 method Methods 0.000 description 10
- 238000006243 chemical reaction Methods 0.000 description 6
- 238000009792 diffusion process Methods 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 239000004005 microsphere Substances 0.000 description 6
- 239000011148 porous material Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 238000010586 diagram Methods 0.000 description 4
- 239000011325 microbead Substances 0.000 description 4
- 230000001681 protective effect Effects 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000003570 air Substances 0.000 description 3
- 239000000956 alloy Substances 0.000 description 3
- 229910045601 alloy Inorganic materials 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- 150000004678 hydrides Chemical class 0.000 description 2
- 238000000137 annealing Methods 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 229910001423 beryllium ion Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000007771 core particle Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000010416 ion conductor Substances 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000007773 negative electrode material Substances 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 239000010420 shell particle Substances 0.000 description 1
- 239000005368 silicate glass Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/362—Composites
- H01M4/366—Composites as layered products
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
- H01M4/381—Alkaline or alkaline earth metals elements
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
- H01M4/381—Alkaline or alkaline earth metals elements
- H01M4/382—Lithium
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
- H01M2004/027—Negative electrodes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Composite Materials (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Secondary Cells (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13/018,989 US20160111715A9 (en) | 2008-06-20 | 2011-02-01 | Electrode material with core-shell structure |
| US13/018,989 | 2011-02-01 | ||
| PCT/US2012/021501 WO2012106102A1 (en) | 2011-02-01 | 2012-01-17 | Electrode material with core-shell structure |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE112012000636T5 true DE112012000636T5 (de) | 2013-11-14 |
Family
ID=46577617
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE112012000636T Withdrawn DE112012000636T5 (de) | 2011-02-01 | 2012-01-17 | Elektrodenmaterial mit Kern-Hülle-Aufbau |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US20160111715A9 (enExample) |
| JP (1) | JP2014505340A (enExample) |
| CN (1) | CN103329315A (enExample) |
| DE (1) | DE112012000636T5 (enExample) |
| WO (1) | WO2012106102A1 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102018213272A1 (de) * | 2018-08-08 | 2020-02-13 | Bayerische Motoren Werke Aktiengesellschaft | Anodenanordnung für eine Lithiumionensekundärbatterie, Lithiumionensekundärbatterie, Arbeitsvorrichtung und Verfahren zum Herstellen einer Anodenanordnung |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9325001B2 (en) * | 2011-02-02 | 2016-04-26 | Toyota Jidosha Kabushiki Kaisha | Composite active material, method for producing composite active material, and battery |
| DE102012220428A1 (de) * | 2011-11-09 | 2013-05-16 | Chemetall Gmbh | Li2S@C beschichtetes Lithiummetallprodukt, Verfahren zu dessen Herstellung und Verwendung |
| DE102012203139A1 (de) * | 2012-02-29 | 2013-08-29 | Robert Bosch Gmbh | Feststoffzelle |
| US8597838B2 (en) | 2012-05-03 | 2013-12-03 | Ut-Battelle, Llc | Lithium sulfide compositions for battery electrolyte and battery electrode coatings |
| KR101382869B1 (ko) * | 2012-06-04 | 2014-04-08 | 현대자동차주식회사 | 배터리용 복합형 고체 고이온전도체 및 이를 이용한 리튬황배터리 |
| US20130344391A1 (en) * | 2012-06-18 | 2013-12-26 | Sila Nanotechnologies Inc. | Multi-shell structures and fabrication methods for battery active materials with expansion properties |
| US10374221B2 (en) * | 2012-08-24 | 2019-08-06 | Sila Nanotechnologies, Inc. | Scaffolding matrix with internal nanoparticles |
| WO2014186634A2 (en) | 2013-05-15 | 2014-11-20 | Quantumscape Corporation | Solid state catholyte or electrolyte for battery using liampbsc (m = si, ge, and/or sn) |
| US9761861B1 (en) | 2013-06-25 | 2017-09-12 | Quantumscape Corporation | Pulse plating of lithium material in electrochemical devices |
| JP6359836B2 (ja) | 2014-02-07 | 2018-07-18 | 信越化学工業株式会社 | 非水電解質二次電池用負極材、非水電解質二次電池用負極及びその製造方法並びに非水電解質二次電池 |
| KR102546284B1 (ko) | 2014-03-14 | 2023-06-21 | 그룹14 테크놀로지스, 인코포레이티드 | 용매의 부재하의 졸-겔 중합을 위한 신규한 방법 및 그러한 방법으로부터의 가변형 탄소 구조의 생성 |
| US9859560B2 (en) | 2014-06-04 | 2018-01-02 | Quantumscape Corporation | Electrode materials with mixed particle sizes |
| US10116003B2 (en) | 2015-02-03 | 2018-10-30 | Quantumscape Corporation | Metal sulfide anolytes for electrochemical cells |
| US10177365B2 (en) | 2015-03-05 | 2019-01-08 | Uchicago Argonne, Llc | Metal fluoride passivation coatings prepared by atomic layer deposition for Li-ion batteries |
| KR20180021797A (ko) | 2015-06-24 | 2018-03-05 | 콴텀스케이프 코포레이션 | 복합 전해질 |
| JP7071264B2 (ja) | 2015-12-04 | 2022-05-18 | クアンタムスケイプ バテリー, インク. | リチウム、リン、硫黄、及びヨウ素含有電解質及びカソライト組成物、電気化学装置用の電解質膜、並びにこれらの電解質及びカソライトを製造するアニーリング方法 |
| WO2018044952A1 (en) | 2016-08-29 | 2018-03-08 | Quantumscape Corporation | Catholytes for solid state rechargeable batteries, battery architectures suitable for use with these catholytes, and methods of making and using the same |
| WO2018165606A1 (en) | 2017-03-10 | 2018-09-13 | Quantumscape Corporation | Metal negative electrode ultrasonic charging |
| KR102148511B1 (ko) | 2017-09-01 | 2020-08-27 | 주식회사 엘지화학 | 음극 활물질의 제조방법 및 이를 이용한 음극 활물질 및 리튬 이차전지 |
| US10256459B1 (en) * | 2017-09-18 | 2019-04-09 | Nanotek Instruments, Inc. | Surface-stabilized and prelithiated anode active materials for lithium batteries and production method |
| US10673063B2 (en) | 2017-09-21 | 2020-06-02 | Global Graphene Group, Inc. | Process for prelithiating an anode active material for a lithium battery |
| DE102017218388A1 (de) | 2017-10-13 | 2019-04-18 | Volkswagen Aktiengesellschaft | Steigerung der Lebensdauer von siliziumbasierten negativen Elektroden durch Partikel mit Siliziumoxid- und LiPON-Beschichtung |
| US11158856B2 (en) * | 2018-05-01 | 2021-10-26 | Uchicago Argonne, Llc | Composite bilayer coatings for high capacity cathodes and anodes |
| WO2020257503A1 (en) * | 2019-06-18 | 2020-12-24 | Conamix Inc. | Selectively permeable nanostructured materials for lithium anode compositions |
| CN114665097B (zh) * | 2022-04-20 | 2024-06-25 | 蜂巢能源科技股份有限公司 | 一种无钴正极材料及其制备方法和应用 |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6358643B1 (en) * | 1994-11-23 | 2002-03-19 | Polyplus Battery Company | Liquid electrolyte lithium-sulfur batteries |
| US6025094A (en) * | 1994-11-23 | 2000-02-15 | Polyplus Battery Company, Inc. | Protective coatings for negative electrodes |
| US6214061B1 (en) * | 1998-05-01 | 2001-04-10 | Polyplus Battery Company, Inc. | Method for forming encapsulated lithium electrodes having glass protective layers |
| JP2003059492A (ja) * | 2001-08-17 | 2003-02-28 | Matsushita Electric Ind Co Ltd | リチウム二次電池およびその製造方法 |
| US6911280B1 (en) * | 2001-12-21 | 2005-06-28 | Polyplus Battery Company | Chemical protection of a lithium surface |
| KR100570637B1 (ko) * | 2003-05-21 | 2006-04-12 | 삼성에스디아이 주식회사 | 리튬 이차 전지용 음극 활물질 및 그의 제조 방법 |
| JP2006216374A (ja) * | 2005-02-03 | 2006-08-17 | Sony Corp | 負極材料およびそれを用いた電池 |
| EP1760045A1 (en) * | 2005-09-03 | 2007-03-07 | Degussa GmbH | Nanoscale silicon particles |
| JP5124975B2 (ja) * | 2006-04-24 | 2013-01-23 | 三菱化学株式会社 | リチウムイオン二次電池用負極材料およびその製造方法 |
| CN101501790A (zh) * | 2006-06-06 | 2009-08-05 | 康乃尔研究基金会有限公司 | 含有内部空隙的纳米结构金属氧化物及其使用方法 |
| KR100814880B1 (ko) * | 2006-11-22 | 2008-03-18 | 삼성에스디아이 주식회사 | 리튬 이차 전지용 음극 활물질, 이의 제조 방법 및 이를포함하는 리튬 이차 전지 |
| JP5511128B2 (ja) * | 2007-06-07 | 2014-06-04 | 三星エスディアイ株式会社 | 非水二次電池用負極材料及び非水二次電池 |
| CN101849306B (zh) * | 2007-09-06 | 2013-06-12 | 佳能株式会社 | 锂离子储存/释放材料的制备方法、锂离子储存/释放材料、使用该材料的电极结构体和储能器件 |
| US8057900B2 (en) * | 2008-06-20 | 2011-11-15 | Toyota Motor Engineering & Manufacturing North America, Inc. | Material with core-shell structure |
| US20100156353A1 (en) * | 2008-12-18 | 2010-06-24 | Quantumsphere, Inc. | Lithium nanoparticle compositions for use in electrochemical applications |
| KR101093705B1 (ko) * | 2009-04-29 | 2011-12-19 | 삼성에스디아이 주식회사 | 리튬 이차 전지 |
| US20100285358A1 (en) * | 2009-05-07 | 2010-11-11 | Amprius, Inc. | Electrode Including Nanostructures for Rechargeable Cells |
| JP2013127945A (ja) * | 2011-11-15 | 2013-06-27 | Toyota Motor Corp | 非水電解液二次電池の製造方法及び非水電解液二次電池 |
-
2011
- 2011-02-01 US US13/018,989 patent/US20160111715A9/en not_active Abandoned
-
2012
- 2012-01-17 JP JP2013552540A patent/JP2014505340A/ja active Pending
- 2012-01-17 WO PCT/US2012/021501 patent/WO2012106102A1/en not_active Ceased
- 2012-01-17 DE DE112012000636T patent/DE112012000636T5/de not_active Withdrawn
- 2012-01-17 CN CN2012800054458A patent/CN103329315A/zh active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102018213272A1 (de) * | 2018-08-08 | 2020-02-13 | Bayerische Motoren Werke Aktiengesellschaft | Anodenanordnung für eine Lithiumionensekundärbatterie, Lithiumionensekundärbatterie, Arbeitsvorrichtung und Verfahren zum Herstellen einer Anodenanordnung |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103329315A (zh) | 2013-09-25 |
| WO2012106102A1 (en) | 2012-08-09 |
| US20160111715A9 (en) | 2016-04-21 |
| US20120196186A1 (en) | 2012-08-02 |
| JP2014505340A (ja) | 2014-02-27 |
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