DE10245164B4 - Verfahren zur Umwandlung von Polysulfanen - Google Patents
Verfahren zur Umwandlung von Polysulfanen Download PDFInfo
- Publication number
- DE10245164B4 DE10245164B4 DE10245164.8A DE10245164A DE10245164B4 DE 10245164 B4 DE10245164 B4 DE 10245164B4 DE 10245164 A DE10245164 A DE 10245164A DE 10245164 B4 DE10245164 B4 DE 10245164B4
- Authority
- DE
- Germany
- Prior art keywords
- polysulfanes
- sulfur
- conversion
- catalytically active
- gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229910000057 polysulfane Inorganic materials 0.000 title claims abstract description 14
- 238000000034 method Methods 0.000 title claims abstract description 11
- 238000006243 chemical reaction Methods 0.000 title claims description 8
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 6
- 238000003786 synthesis reaction Methods 0.000 claims abstract description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 22
- 239000011593 sulfur Substances 0.000 claims description 22
- 229910052717 sulfur Inorganic materials 0.000 claims description 22
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 8
- 239000007787 solid Substances 0.000 claims description 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 4
- 239000010457 zeolite Substances 0.000 claims description 4
- 229910021536 Zeolite Inorganic materials 0.000 claims description 3
- 230000001476 alcoholic effect Effects 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims description 2
- 150000001414 amino alcohols Chemical class 0.000 claims description 2
- 229910021529 ammonia Inorganic materials 0.000 claims description 2
- 150000004679 hydroxides Chemical class 0.000 claims description 2
- 150000003568 thioethers Chemical class 0.000 claims description 2
- 239000003513 alkali Substances 0.000 claims 1
- 230000009466 transformation Effects 0.000 claims 1
- 238000000844 transformation Methods 0.000 claims 1
- 239000007789 gas Substances 0.000 description 14
- 239000007788 liquid Substances 0.000 description 6
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 238000005201 scrubbing Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- HYHCSLBZRBJJCH-UHFFFAOYSA-M sodium hydrosulfide Chemical compound [Na+].[SH-] HYHCSLBZRBJJCH-UHFFFAOYSA-M 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/16—Hydrogen sulfides
- C01B17/167—Separation
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/16—Hydrogen sulfides
- C01B17/168—Purification
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Treating Waste Gases (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Gas Separation By Absorption (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Priority Applications (13)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10245164.8A DE10245164B4 (de) | 2002-09-26 | 2002-09-26 | Verfahren zur Umwandlung von Polysulfanen |
| RU2005112707/15A RU2323874C2 (ru) | 2002-09-26 | 2003-08-26 | Способ превращения полисульфанов |
| AT03798130T ATE425121T1 (de) | 2002-09-26 | 2003-08-26 | Verfahren zur umwandlung von polysulfanen |
| US10/529,148 US7326393B2 (en) | 2002-09-26 | 2003-08-26 | Process for the conversion of polysulfanes |
| AU2003255483A AU2003255483A1 (en) | 2002-09-26 | 2003-08-26 | Process for the conversion of polysulfanes |
| PCT/EP2003/009432 WO2004028963A1 (en) | 2002-09-26 | 2003-08-26 | Process for the conversion of polysulfanes |
| BR0314663-4A BR0314663A (pt) | 2002-09-26 | 2003-08-26 | Processo para a conversão de polissulfanos |
| EP03798130A EP1542925B1 (en) | 2002-09-26 | 2003-08-26 | Process for the conversion of polysulfanes |
| DE60326604T DE60326604D1 (de) | 2002-09-26 | 2003-08-26 | Verfahren zur umwandlung von polysulfanen |
| CNB038230240A CN1292980C (zh) | 2002-09-26 | 2003-08-26 | 用于多硫烷转化的方法 |
| ES03798130T ES2323060T3 (es) | 2002-09-26 | 2003-08-26 | Proceso para la conversion de sulfanos. |
| JP2004538838A JP4423199B2 (ja) | 2002-09-26 | 2003-08-26 | ポリスルファンの変換法 |
| US11/976,717 US7604788B2 (en) | 2002-09-26 | 2007-10-26 | Process for the conversion of polysulfanes |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10245164.8A DE10245164B4 (de) | 2002-09-26 | 2002-09-26 | Verfahren zur Umwandlung von Polysulfanen |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE10245164A1 DE10245164A1 (de) | 2004-04-08 |
| DE10245164B4 true DE10245164B4 (de) | 2014-11-13 |
Family
ID=31984167
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE10245164.8A Expired - Fee Related DE10245164B4 (de) | 2002-09-26 | 2002-09-26 | Verfahren zur Umwandlung von Polysulfanen |
| DE60326604T Expired - Lifetime DE60326604D1 (de) | 2002-09-26 | 2003-08-26 | Verfahren zur umwandlung von polysulfanen |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE60326604T Expired - Lifetime DE60326604D1 (de) | 2002-09-26 | 2003-08-26 | Verfahren zur umwandlung von polysulfanen |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US7326393B2 (enExample) |
| EP (1) | EP1542925B1 (enExample) |
| JP (1) | JP4423199B2 (enExample) |
| CN (1) | CN1292980C (enExample) |
| AT (1) | ATE425121T1 (enExample) |
| AU (1) | AU2003255483A1 (enExample) |
| BR (1) | BR0314663A (enExample) |
| DE (2) | DE10245164B4 (enExample) |
| ES (1) | ES2323060T3 (enExample) |
| RU (1) | RU2323874C2 (enExample) |
| WO (1) | WO2004028963A1 (enExample) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7604788B2 (en) * | 2002-09-26 | 2009-10-20 | Evonik Degussa Gmbh | Process for the conversion of polysulfanes |
| DE102005043151A1 (de) * | 2005-09-10 | 2007-03-22 | Degussa Ag | Verfahren zur Herstellung von Methylmercaptan |
| EP2125613B1 (de) * | 2007-01-16 | 2016-10-12 | Basf Se | Verfahren und vorrichtung zur kontinuierlichen herstellung von schwefelwasserstoff |
| CN101594931B (zh) | 2007-01-16 | 2013-07-10 | 巴斯夫欧洲公司 | 连续生产硫化氢的方法和装置 |
| PL2125611T3 (pl) * | 2007-01-16 | 2017-04-28 | Basf Se | Reaktor i sposób wytwarzania siarkowodoru |
| US7947845B2 (en) | 2007-07-11 | 2011-05-24 | Basf Se | Process for purifying removal of acrylic acid, methacrylic acid N-vinylpyrrolidone or P-xylene crystals from their suspension in mother liquor |
| JP4968207B2 (ja) * | 2008-07-31 | 2012-07-04 | 住友化学株式会社 | 硫化水素ガスの精製方法。 |
| SG171866A1 (en) | 2008-12-23 | 2011-07-28 | Basf Se | Method for compressing gases containing hydrogen sulfide |
| RU2428374C2 (ru) * | 2009-08-10 | 2011-09-10 | Федеральное образовательное учреждение высшего профессионального образования"Астраханский государственный технический университет"ФГОУ ВПО"АГТУ" | Способ деструкции полисульфанов в товарной сере |
| EP2676926A1 (de) * | 2012-06-22 | 2013-12-25 | Evonik Industries AG | Reaktor und Verfahren zur Herstellung von Schwefelwasserstoff |
| EP2676927A1 (de) * | 2012-06-22 | 2013-12-25 | Evonik Industries AG | Reaktor und Verfahren zur Herstellung von Schwefelwasserstoff |
| EP2676925A1 (de) * | 2012-06-22 | 2013-12-25 | Evonik Industries AG | Reaktor und Verfahren zur Herstellung von Schwefelwasserstoff |
| EP2676928A1 (de) | 2012-06-22 | 2013-12-25 | Evonik Industries AG | Reaktor und Verfahren zur Herstellung von Schwefelwasserstoff |
| EP2765127A1 (de) | 2013-02-06 | 2014-08-13 | Evonik Industries AG | Verfahren zur Abtrennung von Acrolein aus dem Prozessgas einer heterogen katalysierten Oxidation von Propen |
| US10773958B2 (en) | 2014-03-21 | 2020-09-15 | Chevron Phillips Chemical Company Lp | Processes for removing polysulfanes and elemental sulfur from hydrogen sulfide |
| JP7121049B2 (ja) * | 2017-12-25 | 2022-08-17 | 住友化学株式会社 | 硫化水素の製造方法及び硫黄の回収方法 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1578230A (en) * | 1976-08-02 | 1980-11-05 | Standard Oil Co | Process for removal of hydrogen sulphide and hydrogen polysulphide from liquid sulphur |
| US5030438A (en) * | 1986-07-10 | 1991-07-09 | Societe Nationale Elf Aquitaine (Production) | Catalytic removal of hydrogen sulfides from liquid sulfur |
| US5686056A (en) * | 1996-02-05 | 1997-11-11 | Bechtel Group, Inc. | Methods and apparatus for purifying hydrogen sulfide |
| US6149887A (en) * | 1995-09-15 | 2000-11-21 | Stork Engineers & Contractors B.V. | Method and apparatus for degassing sulfur |
| EP1542924B1 (fr) * | 2002-09-06 | 2006-02-01 | Arkema | Procede de purificatin d un gaz de synthese a base de sulfur e dhydrogene |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2479781A (en) * | 1945-08-31 | 1949-08-23 | Phillips Petroleum Co | Purification of hydrogen sulfide |
| US2474066A (en) * | 1946-01-04 | 1949-06-21 | Barium Reduction Corp | Method of making hydrogen sulfide |
| US2784055A (en) * | 1951-05-04 | 1957-03-05 | North Thames Gas Board | Process for the treatment of gases rich in hydrogen sulphide |
| DE1768826B1 (de) | 1968-07-04 | 1971-08-26 | Degussa | Verfahren zur Gewinnung von niederen aliphatischen Mercaptanen |
| SU618341A1 (ru) * | 1976-06-15 | 1978-08-05 | Институт Газа Ан Украинской Сср | Способ получени восстановительного газа |
| US4444259A (en) * | 1982-01-15 | 1984-04-24 | Schwall Joseph A | Apparatus and method for purging hydrogen sulfide gases from well water |
| DE4014018A1 (de) * | 1990-05-01 | 1991-11-07 | Metallgesellschaft Ag | Verfahren zum reinigen eines h(pfeil abwaerts)2(pfeil abwaerts)s und co(pfeil abwaerts)2(pfeil abwaerts) enthaltenden gases |
| CN1030905C (zh) * | 1992-02-27 | 1996-02-07 | 天津市化工厂 | 硫化氢连续发生和精制工艺 |
| US5622682A (en) * | 1994-04-06 | 1997-04-22 | Atmi Ecosys Corporation | Method for concentration and recovery of halocarbons from effluent gas streams |
| DE19654516C1 (de) * | 1996-12-27 | 1998-10-01 | Degussa | Verfahren zur Auftrennung des Produktgasgemisches der katalytischen Synthese von Methylmercaptan |
-
2002
- 2002-09-26 DE DE10245164.8A patent/DE10245164B4/de not_active Expired - Fee Related
-
2003
- 2003-08-26 AU AU2003255483A patent/AU2003255483A1/en not_active Abandoned
- 2003-08-26 AT AT03798130T patent/ATE425121T1/de not_active IP Right Cessation
- 2003-08-26 JP JP2004538838A patent/JP4423199B2/ja not_active Expired - Fee Related
- 2003-08-26 BR BR0314663-4A patent/BR0314663A/pt not_active Application Discontinuation
- 2003-08-26 WO PCT/EP2003/009432 patent/WO2004028963A1/en not_active Ceased
- 2003-08-26 ES ES03798130T patent/ES2323060T3/es not_active Expired - Lifetime
- 2003-08-26 US US10/529,148 patent/US7326393B2/en not_active Expired - Lifetime
- 2003-08-26 RU RU2005112707/15A patent/RU2323874C2/ru active
- 2003-08-26 EP EP03798130A patent/EP1542925B1/en not_active Expired - Lifetime
- 2003-08-26 CN CNB038230240A patent/CN1292980C/zh not_active Expired - Fee Related
- 2003-08-26 DE DE60326604T patent/DE60326604D1/de not_active Expired - Lifetime
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1578230A (en) * | 1976-08-02 | 1980-11-05 | Standard Oil Co | Process for removal of hydrogen sulphide and hydrogen polysulphide from liquid sulphur |
| US5030438A (en) * | 1986-07-10 | 1991-07-09 | Societe Nationale Elf Aquitaine (Production) | Catalytic removal of hydrogen sulfides from liquid sulfur |
| US6149887A (en) * | 1995-09-15 | 2000-11-21 | Stork Engineers & Contractors B.V. | Method and apparatus for degassing sulfur |
| US5686056A (en) * | 1996-02-05 | 1997-11-11 | Bechtel Group, Inc. | Methods and apparatus for purifying hydrogen sulfide |
| EP1542924B1 (fr) * | 2002-09-06 | 2006-02-01 | Arkema | Procede de purificatin d un gaz de synthese a base de sulfur e dhydrogene |
Non-Patent Citations (3)
| Title |
|---|
| FEHER, F.; Laue, W.: Beiträge zur Chemie des Schwefels. XXIX. Über die Darstellung von Rohsulfanen. In: Z. anorg. allg. Chem., Vol. 288, 1956, Nr. 1-2, S. 103-112. - ISSN 0044-2313 * |
| FEHER, F.; Winkelhaus, G.: Beiträge zur Chemie des Schwefels. 40. Zur Thermochemie der Sulfane: Bildungsenthalpien und Bindungsenergien. In: Z. anorg. allg. Chem., Vol. 292, 1957, Nr. 4, S. 210-223. - ISSN 0044-2313 * |
| GMELIN-INSTITUT [Hrsg.]: Gmelins Handbuch der Anorganischen Chemie, System-Nummer 9, Schwefel, Teil B, Lieferung 1, Hydride und Oxyde des Schwefels. 8. Aufl. Weinheim: Verlag Chemie, 1953. S. 133-155 (Wasserstoffpolysulfide). * |
Also Published As
| Publication number | Publication date |
|---|---|
| EP1542925B1 (en) | 2009-03-11 |
| BR0314663A (pt) | 2005-08-02 |
| RU2005112707A (ru) | 2006-01-27 |
| WO2004028963A1 (en) | 2004-04-08 |
| EP1542925A1 (en) | 2005-06-22 |
| US7326393B2 (en) | 2008-02-05 |
| JP2006500309A (ja) | 2006-01-05 |
| RU2323874C2 (ru) | 2008-05-10 |
| DE10245164A1 (de) | 2004-04-08 |
| AU2003255483A1 (en) | 2004-04-19 |
| ATE425121T1 (de) | 2009-03-15 |
| DE60326604D1 (de) | 2009-04-23 |
| ES2323060T3 (es) | 2009-07-06 |
| US20050265913A1 (en) | 2005-12-01 |
| JP4423199B2 (ja) | 2010-03-03 |
| CN1684905A (zh) | 2005-10-19 |
| CN1292980C (zh) | 2007-01-03 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8127 | New person/name/address of the applicant |
Owner name: DEGUSSA GMBH, 40474 DUESSELDORF, DE |
|
| 8127 | New person/name/address of the applicant |
Owner name: EVONIK DEGUSSA GMBH, 40474 DUESSELDORF, DE |
|
| 8110 | Request for examination paragraph 44 | ||
| 8125 | Change of the main classification |
Ipc: C01B 17/16 AFI20051017BHDE |
|
| R016 | Response to examination communication | ||
| R016 | Response to examination communication | ||
| R016 | Response to examination communication | ||
| R018 | Grant decision by examination section/examining division | ||
| R020 | Patent grant now final | ||
| R119 | Application deemed withdrawn, or ip right lapsed, due to non-payment of renewal fee |