DE102009035388B4 - Verfahren und Vorrichtung zur Umwandlung von Kohlenmonoxid und Wasser in Kohlendioxid und Wasserstoff, mit der Abtrennung eines oder mehrer Produkte - Google Patents
Verfahren und Vorrichtung zur Umwandlung von Kohlenmonoxid und Wasser in Kohlendioxid und Wasserstoff, mit der Abtrennung eines oder mehrer Produkte Download PDFInfo
- Publication number
- DE102009035388B4 DE102009035388B4 DE102009035388.7A DE102009035388A DE102009035388B4 DE 102009035388 B4 DE102009035388 B4 DE 102009035388B4 DE 102009035388 A DE102009035388 A DE 102009035388A DE 102009035388 B4 DE102009035388 B4 DE 102009035388B4
- Authority
- DE
- Germany
- Prior art keywords
- reactor
- hydrogen
- carbonate
- solvent
- carbon dioxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 title claims abstract description 92
- 229910002092 carbon dioxide Inorganic materials 0.000 title claims abstract description 46
- 239000001569 carbon dioxide Substances 0.000 title claims abstract description 44
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 31
- 239000001257 hydrogen Substances 0.000 title claims abstract description 31
- 229910002091 carbon monoxide Inorganic materials 0.000 title claims abstract description 27
- 238000000034 method Methods 0.000 title claims abstract description 27
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 title claims abstract description 26
- 238000000926 separation method Methods 0.000 title claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims description 13
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 title description 4
- 125000004435 hydrogen atom Chemical class [H]* 0.000 title 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims abstract description 29
- 239000007787 solid Substances 0.000 claims abstract description 27
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims abstract description 24
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000002904 solvent Substances 0.000 claims abstract description 24
- 239000007789 gas Substances 0.000 claims abstract description 20
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 claims abstract description 13
- 238000005979 thermal decomposition reaction Methods 0.000 claims abstract description 12
- 238000006243 chemical reaction Methods 0.000 claims description 37
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 21
- 239000000243 solution Substances 0.000 claims description 10
- 239000012071 phase Substances 0.000 claims description 7
- 238000001556 precipitation Methods 0.000 claims description 7
- 150000001768 cations Chemical class 0.000 claims description 5
- 150000002431 hydrogen Chemical class 0.000 claims description 5
- 239000002244 precipitate Substances 0.000 claims description 5
- 150000003839 salts Chemical class 0.000 claims description 5
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 3
- 239000012670 alkaline solution Substances 0.000 claims description 2
- 238000009835 boiling Methods 0.000 claims description 2
- 150000004679 hydroxides Chemical class 0.000 claims description 2
- 229910044991 metal oxide Inorganic materials 0.000 claims description 2
- 150000004706 metal oxides Chemical class 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims 3
- 239000002184 metal Substances 0.000 claims 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims 2
- 239000003513 alkali Substances 0.000 claims 1
- 150000001342 alkaline earth metals Chemical class 0.000 claims 1
- 239000007792 gaseous phase Substances 0.000 claims 1
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 description 8
- 238000002485 combustion reaction Methods 0.000 description 6
- 239000002737 fuel gas Substances 0.000 description 6
- 238000000354 decomposition reaction Methods 0.000 description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 238000013459 approach Methods 0.000 description 3
- 239000002803 fossil fuel Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000007791 liquid phase Substances 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- -1 alkali metal bicarbonates Chemical class 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000003795 desorption Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 150000004675 formic acid derivatives Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 229910000027 potassium carbonate Inorganic materials 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000012429 reaction media Substances 0.000 description 2
- 229910052701 rubidium Inorganic materials 0.000 description 2
- 238000005201 scrubbing Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910001413 alkali metal ion Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910001420 alkaline earth metal ion Inorganic materials 0.000 description 1
- 239000007853 buffer solution Substances 0.000 description 1
- ZMCUDHNSHCRDBT-UHFFFAOYSA-M caesium bicarbonate Chemical compound [Cs+].OC([O-])=O ZMCUDHNSHCRDBT-UHFFFAOYSA-M 0.000 description 1
- FJDQFPXHSGXQBY-UHFFFAOYSA-L caesium carbonate Chemical compound [Cs+].[Cs+].[O-]C([O-])=O FJDQFPXHSGXQBY-UHFFFAOYSA-L 0.000 description 1
- 229910000024 caesium carbonate Inorganic materials 0.000 description 1
- ATZQZZAXOPPAAQ-UHFFFAOYSA-M caesium formate Chemical compound [Cs+].[O-]C=O ATZQZZAXOPPAAQ-UHFFFAOYSA-M 0.000 description 1
- 125000005587 carbonate group Chemical group 0.000 description 1
- 230000006315 carbonylation Effects 0.000 description 1
- 238000005810 carbonylation reaction Methods 0.000 description 1
- 150000001733 carboxylic acid esters Chemical class 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229910000028 potassium bicarbonate Inorganic materials 0.000 description 1
- 235000015497 potassium bicarbonate Nutrition 0.000 description 1
- 239000011736 potassium bicarbonate Substances 0.000 description 1
- 235000011181 potassium carbonates Nutrition 0.000 description 1
- WFIZEGIEIOHZCP-UHFFFAOYSA-M potassium formate Chemical compound [K+].[O-]C=O WFIZEGIEIOHZCP-UHFFFAOYSA-M 0.000 description 1
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 229910000026 rubidium carbonate Inorganic materials 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- UIIMBOGNXHQVGW-UHFFFAOYSA-M sodium bicarbonate Substances [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
- C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Carbon And Carbon Compounds (AREA)
- Gas Separation By Absorption (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Treating Waste Gases (AREA)
Priority Applications (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102009035388.7A DE102009035388B4 (de) | 2009-07-30 | 2009-07-30 | Verfahren und Vorrichtung zur Umwandlung von Kohlenmonoxid und Wasser in Kohlendioxid und Wasserstoff, mit der Abtrennung eines oder mehrer Produkte |
| IN350DEN2012 IN2012DN00350A (enExample) | 2009-07-30 | 2010-06-25 | |
| EP10728652.8A EP2459480B1 (de) | 2009-07-30 | 2010-06-25 | Verfahren und vorrichtung zur umwandlung von kohlenmonoxid und wasser in kohlendioxid und wasserstoff, mit der abtrennung eines oder mehrer produkte |
| PCT/EP2010/059094 WO2011012385A1 (de) | 2009-07-30 | 2010-06-25 | Verfahren und vorrichtung zur umwandlung von kohlenmonoxid und wasser in kohlendioxid und wasserstoff, mit der abtrennung eines oder mehrer produkte |
| US13/387,170 US8623240B2 (en) | 2009-07-30 | 2010-06-25 | Method and apparatus for converting carbon monoxide and water into carbon dioxide and hydrogen, with removal of one or more products |
| CN201080033865.8A CN102471052B (zh) | 2009-07-30 | 2010-06-25 | 将一氧化碳和水转化成二氧化碳和氢并随之分离出一种或多种产物的方法和设备 |
| RU2012107708/04A RU2542983C2 (ru) | 2009-07-30 | 2010-06-25 | Способ и установка для конверсии моноксида углерода и воды в диоксид углерода и водород с удалением одного или более продуктов |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102009035388.7A DE102009035388B4 (de) | 2009-07-30 | 2009-07-30 | Verfahren und Vorrichtung zur Umwandlung von Kohlenmonoxid und Wasser in Kohlendioxid und Wasserstoff, mit der Abtrennung eines oder mehrer Produkte |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE102009035388A1 DE102009035388A1 (de) | 2011-02-03 |
| DE102009035388B4 true DE102009035388B4 (de) | 2014-01-02 |
Family
ID=42357570
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE102009035388.7A Expired - Fee Related DE102009035388B4 (de) | 2009-07-30 | 2009-07-30 | Verfahren und Vorrichtung zur Umwandlung von Kohlenmonoxid und Wasser in Kohlendioxid und Wasserstoff, mit der Abtrennung eines oder mehrer Produkte |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US8623240B2 (enExample) |
| EP (1) | EP2459480B1 (enExample) |
| CN (1) | CN102471052B (enExample) |
| DE (1) | DE102009035388B4 (enExample) |
| IN (1) | IN2012DN00350A (enExample) |
| RU (1) | RU2542983C2 (enExample) |
| WO (1) | WO2011012385A1 (enExample) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107848794B (zh) | 2015-05-13 | 2021-08-24 | 耶路撒冷希伯来大学伊萨姆研究开发有限公司 | 用于储存和释放氢的方法和装置 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3772380A (en) * | 1970-03-12 | 1973-11-13 | Monsanto Co | Production of carboxylic acids and esters |
| US4145405A (en) * | 1976-03-10 | 1979-03-20 | Continental Oil Company | Production of a hydrogen-rich gas from a co-containing fuel gas |
| EP0299995B1 (en) * | 1987-01-27 | 1991-10-30 | ONSAGER, Olav-T. | Process for converting carbon monoxide and water to hydrogen and carbon dioxide |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3262973A (en) * | 1963-11-20 | 1966-07-26 | Standard Oil Co | Preparation of alkali metal formates in alcoholic medium |
| US4087373A (en) * | 1976-07-23 | 1978-05-02 | The United States Of America As Represented By The Secretary Of The Navy | Novel method for the production of hydrogen and hydrogen-carbon monoxide mixtures |
| US4137298A (en) * | 1977-12-21 | 1979-01-30 | Continental Oil Company | Production of a hydrogen-rich gas from a hydrogen, carbon monoxide and carbon dioxide-containing fuel gas |
| SU834993A1 (ru) * | 1978-06-16 | 1995-04-10 | Г.П. Черкасов | Способ получения катализатора для конверсии окиси углерода с водяным паром |
| US4372833A (en) * | 1981-04-14 | 1983-02-08 | University Of Georgia Research Foundation, Inc. | Photogeneration of active formate decomposition catalysts to produce hydrogen from formate and water |
| US6994839B2 (en) * | 2001-08-15 | 2006-02-07 | Ovonic Battery Company, Inc. | Carbonate recycling in a hydrogen producing reaction |
| US7700071B2 (en) * | 2004-01-23 | 2010-04-20 | Ovonic Battery Company, Inc. | Production of hydrogen via a base-facilitated reaction of carbon monoxide |
-
2009
- 2009-07-30 DE DE102009035388.7A patent/DE102009035388B4/de not_active Expired - Fee Related
-
2010
- 2010-06-25 CN CN201080033865.8A patent/CN102471052B/zh not_active Expired - Fee Related
- 2010-06-25 IN IN350DEN2012 patent/IN2012DN00350A/en unknown
- 2010-06-25 WO PCT/EP2010/059094 patent/WO2011012385A1/de not_active Ceased
- 2010-06-25 RU RU2012107708/04A patent/RU2542983C2/ru not_active IP Right Cessation
- 2010-06-25 US US13/387,170 patent/US8623240B2/en not_active Expired - Fee Related
- 2010-06-25 EP EP10728652.8A patent/EP2459480B1/de not_active Not-in-force
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3772380A (en) * | 1970-03-12 | 1973-11-13 | Monsanto Co | Production of carboxylic acids and esters |
| US4145405A (en) * | 1976-03-10 | 1979-03-20 | Continental Oil Company | Production of a hydrogen-rich gas from a co-containing fuel gas |
| EP0299995B1 (en) * | 1987-01-27 | 1991-10-30 | ONSAGER, Olav-T. | Process for converting carbon monoxide and water to hydrogen and carbon dioxide |
Also Published As
| Publication number | Publication date |
|---|---|
| DE102009035388A1 (de) | 2011-02-03 |
| CN102471052A (zh) | 2012-05-23 |
| EP2459480A1 (de) | 2012-06-06 |
| CN102471052B (zh) | 2015-11-25 |
| RU2542983C2 (ru) | 2015-02-27 |
| EP2459480B1 (de) | 2014-05-07 |
| IN2012DN00350A (enExample) | 2015-07-10 |
| US8623240B2 (en) | 2014-01-07 |
| US20120126178A1 (en) | 2012-05-24 |
| WO2011012385A1 (de) | 2011-02-03 |
| RU2012107708A (ru) | 2013-09-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP3488028B1 (de) | Verfahren zur elektrochemischen herstellung von ammoniak | |
| EP3710617B1 (de) | Elektrochemische herstellung von kohlenstoffmonoxid und/oder synthesegas | |
| EP2697188A1 (de) | Verfahren und anlage zur herstellung von methanol aus inertenreichem synthesegas | |
| DE102017200435A1 (de) | Verfahren und Vorrichtung zur Herstellung von Kohlenwasserstoffen | |
| EP4031640B1 (de) | Anlage und verfahren zur herstellung von synthetischen kraftstoffen ohne frischwasser | |
| DE102013113946A1 (de) | System und Verfahren zur CO2 - Erfassung mittels eines H2- Separators, der Wärmeentschwefelungstechnologie verwendet. | |
| DE102009035388B4 (de) | Verfahren und Vorrichtung zur Umwandlung von Kohlenmonoxid und Wasser in Kohlendioxid und Wasserstoff, mit der Abtrennung eines oder mehrer Produkte | |
| WO1995001217A1 (de) | Verfahren zur getrennten entfernung von schwefelverbindungen und co2 aus gas | |
| WO2021089183A1 (de) | Verfahren und anlage zur herstellung von monoethylenglycol | |
| DE102009035387B4 (de) | Verfahren und Anordnung zur Umwandlung von Kohlenmonoxid und Wasser in Kohlendioxid und Wasserstoff mit der Abtrennung von zumindest einem Produktgas | |
| EP3466869B1 (de) | Verfahren zur kombinierten herstellung von methanol und von ammoniak | |
| DE102016122374A1 (de) | Vollintegrierter Ammoniak-Harnstoff-Komplex | |
| DE19955150A1 (de) | Verfahren zur Erzeugung von Wasserstoff | |
| DE2455694A1 (de) | Verfahren zur herstellung eines wasserstoff und kohlenmonoxid enthaltenden gases | |
| DE102004038491B4 (de) | Verfahren zur Umsetzung von Biomasse in gasförmige Produkte | |
| EP4066921A1 (de) | Verfahren und anlage zum herstellen von methanol und ammoniak | |
| EP2620426B1 (de) | Verfahren zur Herstellung von Harnstoff aus Abfällen, vorzugsweise Hausmüll, beliebiger Zusammensetzung | |
| EP4428099A1 (de) | Verfahren und vorrichtung zur synthese von ammoniak | |
| EP4606764A1 (de) | Bereitstellung und reformierung von methanol | |
| DE102021004440A1 (de) | Verfahren zur Herstellung von Ammoniak aus Stickstoff und Wasserstoff | |
| EP4428100A1 (de) | Verfahren und vorrichtung zur synthese von ammoniak | |
| DE102006036332A1 (de) | Verfahren zur Herstellung von Biodieselkraftstoff | |
| EP4635908A1 (de) | Verfahren und anlage zur gewinnung eines wasserstoffprodukts unter verwendung von ammoniak | |
| DE102016204331A1 (de) | Verfahren zur Herstellung von Ammoniak aus Rohgas | |
| EP4166499A2 (de) | Verfahren zur erzeugung von wasserstoff und kohlendioxid aus organischen substanzen |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OP8 | Request for examination as to paragraph 44 patent law | ||
| R016 | Response to examination communication | ||
| R016 | Response to examination communication | ||
| R016 | Response to examination communication | ||
| R018 | Grant decision by examination section/examining division | ||
| R020 | Patent grant now final | ||
| R020 | Patent grant now final |
Effective date: 20141003 |
|
| R119 | Application deemed withdrawn, or ip right lapsed, due to non-payment of renewal fee |