RU2542983C2 - Способ и установка для конверсии моноксида углерода и воды в диоксид углерода и водород с удалением одного или более продуктов - Google Patents
Способ и установка для конверсии моноксида углерода и воды в диоксид углерода и водород с удалением одного или более продуктов Download PDFInfo
- Publication number
- RU2542983C2 RU2542983C2 RU2012107708/04A RU2012107708A RU2542983C2 RU 2542983 C2 RU2542983 C2 RU 2542983C2 RU 2012107708/04 A RU2012107708/04 A RU 2012107708/04A RU 2012107708 A RU2012107708 A RU 2012107708A RU 2542983 C2 RU2542983 C2 RU 2542983C2
- Authority
- RU
- Russia
- Prior art keywords
- reactor
- carbon dioxide
- solvent
- hydrogen
- separated
- Prior art date
Links
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 title claims abstract description 93
- 229910002092 carbon dioxide Inorganic materials 0.000 title claims abstract description 49
- 239000001569 carbon dioxide Substances 0.000 title claims abstract description 46
- 238000006243 chemical reaction Methods 0.000 title claims abstract description 36
- 239000001257 hydrogen Substances 0.000 title claims abstract description 26
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 26
- 238000000034 method Methods 0.000 title claims abstract description 25
- 229910002091 carbon monoxide Inorganic materials 0.000 title claims abstract description 24
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 title claims abstract description 23
- 238000009434 installation Methods 0.000 title claims abstract 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims description 12
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title description 16
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 title description 2
- 239000007789 gas Substances 0.000 claims abstract description 25
- 239000002904 solvent Substances 0.000 claims abstract description 22
- 239000007787 solid Substances 0.000 claims abstract description 21
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims abstract description 17
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 claims abstract description 8
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims abstract description 8
- 238000005979 thermal decomposition reaction Methods 0.000 claims abstract description 7
- 238000000354 decomposition reaction Methods 0.000 claims abstract description 6
- 239000000126 substance Substances 0.000 claims abstract description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 21
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims description 20
- 238000001556 precipitation Methods 0.000 claims description 8
- 239000000243 solution Substances 0.000 claims description 8
- 150000001768 cations Chemical class 0.000 claims description 6
- 150000003839 salts Chemical class 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 2
- 239000012670 alkaline solution Substances 0.000 claims 1
- 150000004679 hydroxides Chemical class 0.000 claims 1
- 238000000926 separation method Methods 0.000 abstract description 2
- 238000006073 displacement reaction Methods 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 238000005265 energy consumption Methods 0.000 abstract 1
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 abstract 1
- 238000002485 combustion reaction Methods 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 5
- 239000002244 precipitate Substances 0.000 description 5
- 239000012071 phase Substances 0.000 description 4
- 125000005587 carbonate group Chemical group 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- 238000013459 approach Methods 0.000 description 2
- 238000003795 desorption Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 229910001413 alkali metal ion Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910001420 alkaline earth metal ion Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000007853 buffer solution Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 150000004675 formic acid derivatives Chemical class 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 239000012047 saturated solution Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
- C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Carbon And Carbon Compounds (AREA)
- Treating Waste Gases (AREA)
- Gas Separation By Absorption (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102009035388.7A DE102009035388B4 (de) | 2009-07-30 | 2009-07-30 | Verfahren und Vorrichtung zur Umwandlung von Kohlenmonoxid und Wasser in Kohlendioxid und Wasserstoff, mit der Abtrennung eines oder mehrer Produkte |
| DE102009035388.7 | 2009-07-30 | ||
| PCT/EP2010/059094 WO2011012385A1 (de) | 2009-07-30 | 2010-06-25 | Verfahren und vorrichtung zur umwandlung von kohlenmonoxid und wasser in kohlendioxid und wasserstoff, mit der abtrennung eines oder mehrer produkte |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2012107708A RU2012107708A (ru) | 2013-09-10 |
| RU2542983C2 true RU2542983C2 (ru) | 2015-02-27 |
Family
ID=42357570
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2012107708/04A RU2542983C2 (ru) | 2009-07-30 | 2010-06-25 | Способ и установка для конверсии моноксида углерода и воды в диоксид углерода и водород с удалением одного или более продуктов |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US8623240B2 (enExample) |
| EP (1) | EP2459480B1 (enExample) |
| CN (1) | CN102471052B (enExample) |
| DE (1) | DE102009035388B4 (enExample) |
| IN (1) | IN2012DN00350A (enExample) |
| RU (1) | RU2542983C2 (enExample) |
| WO (1) | WO2011012385A1 (enExample) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2016181401A1 (en) * | 2015-05-13 | 2016-11-17 | Yissum Research Development Company Of The Hebrew University Of Jerusalem Ltd. | Methods and devices for storage and release of hydrogen |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4087373A (en) * | 1976-07-23 | 1978-05-02 | The United States Of America As Represented By The Secretary Of The Navy | Novel method for the production of hydrogen and hydrogen-carbon monoxide mixtures |
| US4137298A (en) * | 1977-12-21 | 1979-01-30 | Continental Oil Company | Production of a hydrogen-rich gas from a hydrogen, carbon monoxide and carbon dioxide-containing fuel gas |
| US4372833A (en) * | 1981-04-14 | 1983-02-08 | University Of Georgia Research Foundation, Inc. | Photogeneration of active formate decomposition catalysts to produce hydrogen from formate and water |
| WO1988005422A1 (en) * | 1987-01-27 | 1988-07-28 | Onsager Olav T | Process for converting carbon monoxide and water to hydrogen and carbon dioxide |
| SU834993A1 (ru) * | 1978-06-16 | 1995-04-10 | Г.П. Черкасов | Способ получения катализатора для конверсии окиси углерода с водяным паром |
| US20040028603A1 (en) * | 2001-08-15 | 2004-02-12 | Benjamin Reichman | Carbonate recycling in a hydrogen producing reaction |
| WO2006098854A2 (en) * | 2005-03-14 | 2006-09-21 | Ovonic Battery Company, Inc. | Production of hydrogen via a base-facilitated reaction of carbon monoxide |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3262973A (en) * | 1963-11-20 | 1966-07-26 | Standard Oil Co | Preparation of alkali metal formates in alcoholic medium |
| US3772380A (en) * | 1970-03-12 | 1973-11-13 | Monsanto Co | Production of carboxylic acids and esters |
| US4067958A (en) * | 1976-03-10 | 1978-01-10 | Continental Oil Company | Production of a hydrogen-rich gas from a co-containing fuel gas |
-
2009
- 2009-07-30 DE DE102009035388.7A patent/DE102009035388B4/de not_active Expired - Fee Related
-
2010
- 2010-06-25 RU RU2012107708/04A patent/RU2542983C2/ru not_active IP Right Cessation
- 2010-06-25 US US13/387,170 patent/US8623240B2/en not_active Expired - Fee Related
- 2010-06-25 CN CN201080033865.8A patent/CN102471052B/zh not_active Expired - Fee Related
- 2010-06-25 EP EP10728652.8A patent/EP2459480B1/de not_active Not-in-force
- 2010-06-25 WO PCT/EP2010/059094 patent/WO2011012385A1/de not_active Ceased
- 2010-06-25 IN IN350DEN2012 patent/IN2012DN00350A/en unknown
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4087373A (en) * | 1976-07-23 | 1978-05-02 | The United States Of America As Represented By The Secretary Of The Navy | Novel method for the production of hydrogen and hydrogen-carbon monoxide mixtures |
| US4137298A (en) * | 1977-12-21 | 1979-01-30 | Continental Oil Company | Production of a hydrogen-rich gas from a hydrogen, carbon monoxide and carbon dioxide-containing fuel gas |
| SU834993A1 (ru) * | 1978-06-16 | 1995-04-10 | Г.П. Черкасов | Способ получения катализатора для конверсии окиси углерода с водяным паром |
| US4372833A (en) * | 1981-04-14 | 1983-02-08 | University Of Georgia Research Foundation, Inc. | Photogeneration of active formate decomposition catalysts to produce hydrogen from formate and water |
| WO1988005422A1 (en) * | 1987-01-27 | 1988-07-28 | Onsager Olav T | Process for converting carbon monoxide and water to hydrogen and carbon dioxide |
| US20040028603A1 (en) * | 2001-08-15 | 2004-02-12 | Benjamin Reichman | Carbonate recycling in a hydrogen producing reaction |
| WO2006098854A2 (en) * | 2005-03-14 | 2006-09-21 | Ovonic Battery Company, Inc. | Production of hydrogen via a base-facilitated reaction of carbon monoxide |
Also Published As
| Publication number | Publication date |
|---|---|
| EP2459480B1 (de) | 2014-05-07 |
| IN2012DN00350A (enExample) | 2015-07-10 |
| DE102009035388B4 (de) | 2014-01-02 |
| CN102471052A (zh) | 2012-05-23 |
| EP2459480A1 (de) | 2012-06-06 |
| RU2012107708A (ru) | 2013-09-10 |
| CN102471052B (zh) | 2015-11-25 |
| DE102009035388A1 (de) | 2011-02-03 |
| US8623240B2 (en) | 2014-01-07 |
| WO2011012385A1 (de) | 2011-02-03 |
| US20120126178A1 (en) | 2012-05-24 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | The patent is invalid due to non-payment of fees |
Effective date: 20170626 |