DE10014844B4 - Verfahren zur Wiedergewinnung von Rhodium aus den Produkten der Hydroformylierung - Google Patents

Verfahren zur Wiedergewinnung von Rhodium aus den Produkten der Hydroformylierung Download PDF

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Publication number
DE10014844B4
DE10014844B4 DE10014844A DE10014844A DE10014844B4 DE 10014844 B4 DE10014844 B4 DE 10014844B4 DE 10014844 A DE10014844 A DE 10014844A DE 10014844 A DE10014844 A DE 10014844A DE 10014844 B4 DE10014844 B4 DE 10014844B4
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DE
Germany
Prior art keywords
rhodium
adsorbent
hydroformylation
products
hydrogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE10014844A
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German (de)
English (en)
Other versions
DE10014844A1 (de
Inventor
Ernst Wiebus
Kurt Schalapski
Michael Dr. Mertl
Rainer Dr. Lukas
Richard W. Dr. Fischer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Oxea Deutschland GmbH
Original Assignee
Celanese Chemicals Europe GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to DE10014844A priority Critical patent/DE10014844B4/de
Application filed by Celanese Chemicals Europe GmbH filed Critical Celanese Chemicals Europe GmbH
Priority to AT01915332T priority patent/ATE328859T1/de
Priority to DE50110038T priority patent/DE50110038D1/de
Priority to US10/239,096 priority patent/US6863872B2/en
Priority to JP2001570594A priority patent/JP2003528841A/ja
Priority to EP01915332A priority patent/EP1274671B1/de
Priority to ES01915332T priority patent/ES2264976T3/es
Priority to PCT/EP2001/002848 priority patent/WO2001072679A1/de
Publication of DE10014844A1 publication Critical patent/DE10014844A1/de
Application granted granted Critical
Publication of DE10014844B4 publication Critical patent/DE10014844B4/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
    • B01J31/4046—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals containing rhodium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/79—Separation; Purification; Stabilisation; Use of additives by solid-liquid treatment; by chemisorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
DE10014844A 2000-03-24 2000-03-24 Verfahren zur Wiedergewinnung von Rhodium aus den Produkten der Hydroformylierung Expired - Fee Related DE10014844B4 (de)

Priority Applications (8)

Application Number Priority Date Filing Date Title
DE10014844A DE10014844B4 (de) 2000-03-24 2000-03-24 Verfahren zur Wiedergewinnung von Rhodium aus den Produkten der Hydroformylierung
DE50110038T DE50110038D1 (de) 2000-03-24 2001-03-14 Verfahren zur wiedergewinnung von rhodium aus den produkten der hydroformylierung
US10/239,096 US6863872B2 (en) 2000-03-24 2001-03-14 Method for recovering rhodium from hydroformylation products
JP2001570594A JP2003528841A (ja) 2000-03-24 2001-03-14 ヒドロホルミル化の反応生成物からロジウムを回収する方法
AT01915332T ATE328859T1 (de) 2000-03-24 2001-03-14 Verfahren zur wiedergewinnung von rhodium aus den produkten der hydroformylierung
EP01915332A EP1274671B1 (de) 2000-03-24 2001-03-14 Verfahren zur wiedergewinnung von rhodium aus den produkten der hydroformylierung
ES01915332T ES2264976T3 (es) 2000-03-24 2001-03-14 Procedimiento para la recuperacion de rodio de los productos de la hidroformilacion.
PCT/EP2001/002848 WO2001072679A1 (de) 2000-03-24 2001-03-14 Verfahren zur wiedergewinnung von rhodium aus den produkten der hydroformylierung

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE10014844A DE10014844B4 (de) 2000-03-24 2000-03-24 Verfahren zur Wiedergewinnung von Rhodium aus den Produkten der Hydroformylierung

Publications (2)

Publication Number Publication Date
DE10014844A1 DE10014844A1 (de) 2001-10-04
DE10014844B4 true DE10014844B4 (de) 2005-09-22

Family

ID=7636326

Family Applications (2)

Application Number Title Priority Date Filing Date
DE10014844A Expired - Fee Related DE10014844B4 (de) 2000-03-24 2000-03-24 Verfahren zur Wiedergewinnung von Rhodium aus den Produkten der Hydroformylierung
DE50110038T Expired - Fee Related DE50110038D1 (de) 2000-03-24 2001-03-14 Verfahren zur wiedergewinnung von rhodium aus den produkten der hydroformylierung

Family Applications After (1)

Application Number Title Priority Date Filing Date
DE50110038T Expired - Fee Related DE50110038D1 (de) 2000-03-24 2001-03-14 Verfahren zur wiedergewinnung von rhodium aus den produkten der hydroformylierung

Country Status (7)

Country Link
US (1) US6863872B2 (enExample)
EP (1) EP1274671B1 (enExample)
JP (1) JP2003528841A (enExample)
AT (1) ATE328859T1 (enExample)
DE (2) DE10014844B4 (enExample)
ES (1) ES2264976T3 (enExample)
WO (1) WO2001072679A1 (enExample)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102004059292A1 (de) * 2004-12-09 2006-06-14 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von Alkoholen aus Olefinen durch Hydroformylierung und Hydrierung
DE102009001230A1 (de) 2009-02-27 2010-09-02 Evonik Oxeno Gmbh Verfahren zur Abtrennung und teilweiser Rückführung von Übergangsmetallen bzw. deren katalytisch wirksamen Komplexverbindungen aus Prozessströmen
JP5608046B2 (ja) * 2010-11-02 2014-10-15 北興化学工業株式会社 アルデヒドの精製方法

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2311388A1 (de) * 1973-03-08 1974-09-12 Erdoelchemie Gmbh Rhodium-katalysatoren
US3899442A (en) * 1974-01-31 1975-08-12 Us Agriculture Recovery and reactivation of rhodium hydroformylation catalysts
US3978148A (en) * 1975-07-21 1976-08-31 E. I. Du Pont De Nemours And Company Process for removal of rhodium compounds from process streams
US4131640A (en) * 1972-01-07 1978-12-26 Basf Aktiengesellschaft Separating rhodium from solution containing rhodium carbonyl complexes and converting the separated rhodium into soluble rhodium carbonyl complexes
US4388279A (en) * 1981-06-03 1983-06-14 Uop Inc. Recovery of metal values from organic reaction products
JPS63196537A (ja) * 1987-02-10 1988-08-15 Kansai Coke & Chem Co Ltd ヒドロホルミル化化合物の製造法
DE69210557T2 (de) * 1991-11-29 1996-09-19 Mita Industrial Co Ltd Bilderzeugungsgerät

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1954315C3 (de) * 1969-10-29 1975-08-14 Basf Ag, 6700 Ludwigshafen Verfahren zur Abtrennung von Metallcarbonylkatalysatoren aus Oxoreaktionsge mischen
DE1954815A1 (de) 1969-10-31 1971-10-07 Licentia Gmbh Springrollenanzeigesystem mit eingebauten Fotowiderstaenden
JPS63162044A (ja) 1986-12-25 1988-07-05 Daicel Chem Ind Ltd 触媒の分離方法
JPS63197543A (ja) 1987-02-10 1988-08-16 Kansai Coke & Chem Co Ltd 第８族貴金属錯体の回収用吸着剤および回収方法
JP2993032B2 (ja) 1990-03-01 1999-12-20 三菱化学株式会社 第８族貴金属の分離回収法

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4131640A (en) * 1972-01-07 1978-12-26 Basf Aktiengesellschaft Separating rhodium from solution containing rhodium carbonyl complexes and converting the separated rhodium into soluble rhodium carbonyl complexes
DE2311388A1 (de) * 1973-03-08 1974-09-12 Erdoelchemie Gmbh Rhodium-katalysatoren
US3899442A (en) * 1974-01-31 1975-08-12 Us Agriculture Recovery and reactivation of rhodium hydroformylation catalysts
US3978148A (en) * 1975-07-21 1976-08-31 E. I. Du Pont De Nemours And Company Process for removal of rhodium compounds from process streams
US4388279A (en) * 1981-06-03 1983-06-14 Uop Inc. Recovery of metal values from organic reaction products
JPS63196537A (ja) * 1987-02-10 1988-08-15 Kansai Coke & Chem Co Ltd ヒドロホルミル化化合物の製造法
DE69210557T2 (de) * 1991-11-29 1996-09-19 Mita Industrial Co Ltd Bilderzeugungsgerät

Also Published As

Publication number Publication date
US6863872B2 (en) 2005-03-08
EP1274671A1 (de) 2003-01-15
ES2264976T3 (es) 2007-02-01
ATE328859T1 (de) 2006-06-15
DE50110038D1 (de) 2006-07-20
EP1274671B1 (de) 2006-06-07
WO2001072679A1 (de) 2001-10-04
US20030049188A1 (en) 2003-03-13
JP2003528841A (ja) 2003-09-30
DE10014844A1 (de) 2001-10-04

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8327 Change in the person/name/address of the patent owner

Owner name: OXEA DEUTSCHLAND GMBH, 46147 OBERHAUSEN, DE

8339 Ceased/non-payment of the annual fee