ATE328859T1 - Verfahren zur wiedergewinnung von rhodium aus den produkten der hydroformylierung - Google Patents

Verfahren zur wiedergewinnung von rhodium aus den produkten der hydroformylierung

Info

Publication number
ATE328859T1
ATE328859T1 AT01915332T AT01915332T ATE328859T1 AT E328859 T1 ATE328859 T1 AT E328859T1 AT 01915332 T AT01915332 T AT 01915332T AT 01915332 T AT01915332 T AT 01915332T AT E328859 T1 ATE328859 T1 AT E328859T1
Authority
AT
Austria
Prior art keywords
hydroformylation products
recovering rhodium
rhodium
feed material
recovering
Prior art date
Application number
AT01915332T
Other languages
German (de)
English (en)
Inventor
Ernst Wiebus
Kurt Schalapski
Michael Mertl
Rainer Lukas
Richard Fischer
Original Assignee
Celanese Chem Europe Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Celanese Chem Europe Gmbh filed Critical Celanese Chem Europe Gmbh
Application granted granted Critical
Publication of ATE328859T1 publication Critical patent/ATE328859T1/de

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20Carbonyls
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40Regeneration or reactivation
    • B01J31/4015Regeneration or reactivation of catalysts containing metals
    • B01J31/4023Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/4038Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
    • B01J31/4046Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals containing rhodium
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78Separation; Purification; Stabilisation; Use of additives
    • C07C45/79Separation; Purification; Stabilisation; Use of additives by solid-liquid treatment; by chemisorption
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04Alumina
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08Silica
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18Carbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32Addition reactions to C=C or C-C triple bonds
    • B01J2231/321Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/822Rhodium
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/584Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
AT01915332T 2000-03-24 2001-03-14 Verfahren zur wiedergewinnung von rhodium aus den produkten der hydroformylierung ATE328859T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE10014844A DE10014844B4 (de) 2000-03-24 2000-03-24 Verfahren zur Wiedergewinnung von Rhodium aus den Produkten der Hydroformylierung

Publications (1)

Publication Number Publication Date
ATE328859T1 true ATE328859T1 (de) 2006-06-15

Family

ID=7636326

Family Applications (1)

Application Number Title Priority Date Filing Date
AT01915332T ATE328859T1 (de) 2000-03-24 2001-03-14 Verfahren zur wiedergewinnung von rhodium aus den produkten der hydroformylierung

Country Status (7)

Country Link
US (1) US6863872B2 (enExample)
EP (1) EP1274671B1 (enExample)
JP (1) JP2003528841A (enExample)
AT (1) ATE328859T1 (enExample)
DE (2) DE10014844B4 (enExample)
ES (1) ES2264976T3 (enExample)
WO (1) WO2001072679A1 (enExample)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102004059292A1 (de) * 2004-12-09 2006-06-14 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von Alkoholen aus Olefinen durch Hydroformylierung und Hydrierung
DE102009001230A1 (de) 2009-02-27 2010-09-02 Evonik Oxeno Gmbh Verfahren zur Abtrennung und teilweiser Rückführung von Übergangsmetallen bzw. deren katalytisch wirksamen Komplexverbindungen aus Prozessströmen
JP5608046B2 (ja) * 2010-11-02 2014-10-15 北興化学工業株式会社 アルデヒドの精製方法

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1954315C3 (de) * 1969-10-29 1975-08-14 Basf Ag, 6700 Ludwigshafen Verfahren zur Abtrennung von Metallcarbonylkatalysatoren aus Oxoreaktionsge mischen
DE1954815A1 (de) 1969-10-31 1971-10-07 Licentia Gmbh Springrollenanzeigesystem mit eingebauten Fotowiderstaenden
AT312559B (de) * 1972-01-07 1974-01-10 Basf Ag Verfahren zur Abscheidung von Rhodium aus Rhodiumcarbonylkomplexe enthaltenden Lösungen und Überführung des abgescheidenen Rhodiums in lösliche Rhodiumcarbonylkomplexe
DE2311388A1 (de) * 1973-03-08 1974-09-12 Erdoelchemie Gmbh Rhodium-katalysatoren
US3899442A (en) * 1974-01-31 1975-08-12 Us Agriculture Recovery and reactivation of rhodium hydroformylation catalysts
US3978148A (en) * 1975-07-21 1976-08-31 E. I. Du Pont De Nemours And Company Process for removal of rhodium compounds from process streams
US4388279A (en) * 1981-06-03 1983-06-14 Uop Inc. Recovery of metal values from organic reaction products
JPS63162044A (ja) 1986-12-25 1988-07-05 Daicel Chem Ind Ltd 触媒の分離方法
JPS63197543A (ja) 1987-02-10 1988-08-16 Kansai Coke & Chem Co Ltd 第8族貴金属錯体の回収用吸着剤および回収方法
JPS63196537A (ja) * 1987-02-10 1988-08-15 Kansai Coke & Chem Co Ltd ヒドロホルミル化化合物の製造法
JP2993032B2 (ja) 1990-03-01 1999-12-20 三菱化学株式会社 第8族貴金属の分離回収法
JP3073080B2 (ja) * 1991-11-29 2000-08-07 京セラミタ株式会社 画像形成装置

Also Published As

Publication number Publication date
US6863872B2 (en) 2005-03-08
EP1274671A1 (de) 2003-01-15
ES2264976T3 (es) 2007-02-01
DE50110038D1 (de) 2006-07-20
EP1274671B1 (de) 2006-06-07
WO2001072679A1 (de) 2001-10-04
US20030049188A1 (en) 2003-03-13
DE10014844B4 (de) 2005-09-22
JP2003528841A (ja) 2003-09-30
DE10014844A1 (de) 2001-10-04

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