CS119092A3 - Polyolefin coupling and the use thereof for joining polyolefin tubes - Google Patents
Polyolefin coupling and the use thereof for joining polyolefin tubes Download PDFInfo
- Publication number
- CS119092A3 CS119092A3 CS921190A CS119092A CS119092A3 CS 119092 A3 CS119092 A3 CS 119092A3 CS 921190 A CS921190 A CS 921190A CS 119092 A CS119092 A CS 119092A CS 119092 A3 CS119092 A3 CS 119092A3
- Authority
- CS
- Czechoslovakia
- Prior art keywords
- polyolefin
- coupling
- tubes
- heating
- coupling according
- Prior art date
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
- B29C66/73—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset
- B29C66/737—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the state of the material of the parts to be joined
- B29C66/7373—Joining soiled or oxidised materials
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C37/00—Component parts, details, accessories or auxiliary operations, not covered by group B29C33/00 or B29C35/00
- B29C37/0078—Measures or configurations for obtaining anchoring effects in the contact areas between layers
- B29C37/0082—Mechanical anchoring
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C61/00—Shaping by liberation of internal stresses; Making preforms having internal stresses; Apparatus therefor
- B29C61/06—Making preforms having internal stresses, e.g. plastic memory
- B29C61/0608—Making preforms having internal stresses, e.g. plastic memory characterised by the configuration or structure of the preforms
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C61/00—Shaping by liberation of internal stresses; Making preforms having internal stresses; Apparatus therefor
- B29C61/06—Making preforms having internal stresses, e.g. plastic memory
- B29C61/0608—Making preforms having internal stresses, e.g. plastic memory characterised by the configuration or structure of the preforms
- B29C61/0625—Preforms comprising incorporated or associated heating means
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
- B29C65/02—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
- B29C65/14—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using wave energy, i.e. electromagnetic radiation, or particle radiation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
- B29C65/02—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
- B29C65/14—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using wave energy, i.e. electromagnetic radiation, or particle radiation
- B29C65/1429—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using wave energy, i.e. electromagnetic radiation, or particle radiation characterised by the way of heating the interface
- B29C65/1464—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using wave energy, i.e. electromagnetic radiation, or particle radiation characterised by the way of heating the interface making use of several radiators
- B29C65/1467—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using wave energy, i.e. electromagnetic radiation, or particle radiation characterised by the way of heating the interface making use of several radiators at the same time, i.e. simultaneous welding
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
- B29C65/02—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
- B29C65/18—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using heated tools
- B29C65/22—Heated wire resistive ribbon, resistive band or resistive strip
- B29C65/221—Heated wire resistive ribbon, resistive band or resistive strip characterised by the type of heated wire, resistive ribbon, band or strip
- B29C65/222—Heated wire resistive ribbon, resistive band or resistive strip characterised by the type of heated wire, resistive ribbon, band or strip comprising at least a single heated wire
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
- B29C65/02—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
- B29C65/34—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using heated elements which remain in the joint, e.g. "verlorenes Schweisselement"
- B29C65/3404—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using heated elements which remain in the joint, e.g. "verlorenes Schweisselement" characterised by the type of heated elements which remain in the joint
- B29C65/342—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using heated elements which remain in the joint, e.g. "verlorenes Schweisselement" characterised by the type of heated elements which remain in the joint comprising at least a single wire, e.g. in the form of a winding
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
- B29C65/02—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
- B29C65/34—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using heated elements which remain in the joint, e.g. "verlorenes Schweisselement"
- B29C65/3404—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using heated elements which remain in the joint, e.g. "verlorenes Schweisselement" characterised by the type of heated elements which remain in the joint
- B29C65/342—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using heated elements which remain in the joint, e.g. "verlorenes Schweisselement" characterised by the type of heated elements which remain in the joint comprising at least a single wire, e.g. in the form of a winding
- B29C65/3432—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using heated elements which remain in the joint, e.g. "verlorenes Schweisselement" characterised by the type of heated elements which remain in the joint comprising at least a single wire, e.g. in the form of a winding comprising several wires, e.g. in the form of several independent windings
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
- B29C65/56—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using mechanical means or mechanical connections, e.g. form-fits
- B29C65/58—Snap connection
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
- B29C65/66—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by liberation of internal stresses, e.g. shrinking of one of the parts to be joined
- B29C65/68—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by liberation of internal stresses, e.g. shrinking of one of the parts to be joined using auxiliary shrinkable elements
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/01—General aspects dealing with the joint area or with the area to be joined
- B29C66/05—Particular design of joint configurations
- B29C66/10—Particular design of joint configurations particular design of the joint cross-sections
- B29C66/11—Joint cross-sections comprising a single joint-segment, i.e. one of the parts to be joined comprising a single joint-segment in the joint cross-section
- B29C66/112—Single lapped joints
- B29C66/1122—Single lap to lap joints, i.e. overlap joints
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/01—General aspects dealing with the joint area or with the area to be joined
- B29C66/341—Measures for intermixing the material of the joint interlayer
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/50—General aspects of joining tubular articles; General aspects of joining long products, i.e. bars or profiled elements; General aspects of joining single elements to tubular articles, hollow articles or bars; General aspects of joining several hollow-preforms to form hollow or tubular articles
- B29C66/51—Joining tubular articles, profiled elements or bars; Joining single elements to tubular articles, hollow articles or bars; Joining several hollow-preforms to form hollow or tubular articles
- B29C66/52—Joining tubular articles, bars or profiled elements
- B29C66/522—Joining tubular articles
- B29C66/5221—Joining tubular articles for forming coaxial connections, i.e. the tubular articles to be joined forming a zero angle relative to each other
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/50—General aspects of joining tubular articles; General aspects of joining long products, i.e. bars or profiled elements; General aspects of joining single elements to tubular articles, hollow articles or bars; General aspects of joining several hollow-preforms to form hollow or tubular articles
- B29C66/51—Joining tubular articles, profiled elements or bars; Joining single elements to tubular articles, hollow articles or bars; Joining several hollow-preforms to form hollow or tubular articles
- B29C66/52—Joining tubular articles, bars or profiled elements
- B29C66/522—Joining tubular articles
- B29C66/5229—Joining tubular articles involving the use of a socket
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/50—General aspects of joining tubular articles; General aspects of joining long products, i.e. bars or profiled elements; General aspects of joining single elements to tubular articles, hollow articles or bars; General aspects of joining several hollow-preforms to form hollow or tubular articles
- B29C66/51—Joining tubular articles, profiled elements or bars; Joining single elements to tubular articles, hollow articles or bars; Joining several hollow-preforms to form hollow or tubular articles
- B29C66/52—Joining tubular articles, bars or profiled elements
- B29C66/522—Joining tubular articles
- B29C66/5229—Joining tubular articles involving the use of a socket
- B29C66/52297—Joining tubular articles involving the use of a socket said socket comprising slip-off prevention means
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
- B29C66/71—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the composition of the plastics material of the parts to be joined
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
- B29C66/73—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset
- B29C66/737—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the state of the material of the parts to be joined
- B29C66/7375—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the state of the material of the parts to be joined uncured, partially cured or fully cured
- B29C66/73751—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the state of the material of the parts to be joined uncured, partially cured or fully cured the to-be-joined area of at least one of the parts to be joined being uncured, i.e. non cross-linked, non vulcanized
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
- B29C66/73—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset
- B29C66/737—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the state of the material of the parts to be joined
- B29C66/7375—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the state of the material of the parts to be joined uncured, partially cured or fully cured
- B29C66/73755—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the state of the material of the parts to be joined uncured, partially cured or fully cured the to-be-joined area of at least one of the parts to be joined being fully cured, i.e. fully cross-linked, fully vulcanized
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
- B29C66/73—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset
- B29C66/739—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of the parts to be joined being a thermoplastic or a thermoset
- B29C66/7392—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of at least one of the parts being a thermoplastic
- B29C66/73921—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of at least one of the parts being a thermoplastic characterised by the materials of both parts being thermoplastics
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/80—General aspects of machine operations or constructions and parts thereof
- B29C66/81—General aspects of the pressing elements, i.e. the elements applying pressure on the parts to be joined in the area to be joined, e.g. the welding jaws or clamps
- B29C66/818—General aspects of the pressing elements, i.e. the elements applying pressure on the parts to be joined in the area to be joined, e.g. the welding jaws or clamps characterised by the cooling constructional aspects, or by the thermal or electrical insulating or conducting constructional aspects of the welding jaws or of the clamps ; comprising means for compensating for the thermal expansion of the welding jaws or of the clamps
- B29C66/8187—General aspects of the pressing elements, i.e. the elements applying pressure on the parts to be joined in the area to be joined, e.g. the welding jaws or clamps characterised by the cooling constructional aspects, or by the thermal or electrical insulating or conducting constructional aspects of the welding jaws or of the clamps ; comprising means for compensating for the thermal expansion of the welding jaws or of the clamps characterised by the electrical insulating constructional aspects
- B29C66/81871—General aspects of the pressing elements, i.e. the elements applying pressure on the parts to be joined in the area to be joined, e.g. the welding jaws or clamps characterised by the cooling constructional aspects, or by the thermal or electrical insulating or conducting constructional aspects of the welding jaws or of the clamps ; comprising means for compensating for the thermal expansion of the welding jaws or of the clamps characterised by the electrical insulating constructional aspects of the welding jaws
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/90—Measuring or controlling the joining process
- B29C66/91—Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux
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Description
I “0 — — - t dO 1 i r ! > ° - ' ·—’ i ! O χ··3 i ra ' X> i ___, (_ z 6 m >· b í r~-c m ř 1 N ř t
Polyolefinová spojka anových trub její použití pro spojování polyolefi-
Oblast techniky
Vynález se týká polyolefinových spojek pro spojovánípolyolefinových trub a spojování polyolefinových trub těmitospojkami.
Dosavadní stav techniky
Známých spojek se v široké míre používá pro spojovánítrub až do průměru 355 mm. Takové spojky jsou hrdlového typua mají vnitřní topné články. Topný článek natavuje vnitřnípovrch spojky a protilehlé povrchy trub. Protilehlé povrchyjsou od sebe vzdáleny maximálně 1 až 2 mm v případě menšíchspojek, avšak rozměr 355 mm vyžaduje hydrulický přípravek nasestavení spojky a trub. V takovém případě je mezera praktickynulová. Zatavené povrchy spolu splynou a vytvoří se svarovýspoj mezi každou troubou a spojkou. Účelem vynálezu je poskytnout spojku, které lze použítspeciálně i když nikoliv výlučně, ke spojování trub velkéhoprůměru, například trub o průměru 500 mm nebo větším. V americkém patentovém spise číslo 4 775501 /RaychemCorporation/ a v evropském patentovém spise číslo O 19759/Raychem Corporation/ se popisuje způsob spojování polyethy-lenových trub spojkou, tvořenou zesilovaným polymerem, obsa-hujícím částicové vodivé plnidlo. Spojka je roztažena pod je-jí teplotou tavení /120 °C/. K regeneraci pro spojení s trou-bami se spojka zahřívá vedením elektrického proudu spojkouaž dojde k jejímu smrštění na spojované trouby. Spojka a trou-by se spojují tavným spojem. Ve dvou příkladech se uvádějípolyethylenové trouby o vnějším průměru 21 mm. Spojka dosa-huje své smršťovací teploty ve 30 až 45 sekundách a proud senechával procházet spojkou ještě po dobu další jedné minuty.
Konce trubek vykázaly smrštění a jejich povrchy byly na-taveny. Výslechem je podstatné snížení světlosti trub a trubek V jediném příkladu v evropském patentovém spise číslo0 197759 mají trouby vnější průměr 21,3 mm a tloušťku stěny 2,8 mm. Podmínky ohřevu jsou stejné jako podle amerického pa-tentového spisu číslo 4 775501» V uvedeném evropském patentovémspise nejsou žádné výkresy.
Spojky, uváděné v patentových spisech shora uvedených /Raychem Corporation/ musí být elektricky vodivé a aby se toho do-sáhlo, obsahuje materiál uhlíkaté částice v koncentraci, zaru-čující elektrickou vodivost. Je známo, že tak vysoký obsah uh-líkatých částic může způsobit narušení žádoucích mechanickýchvlastností základního polymeru.
Podstata vynálezu
Podstatou vynálezu jsou spojky z polymerního materiálu,které nejsou elektricky vodivé. Schopnost smršťovací paměti jeaktivována odděleně identifikovatelným zdrojem tepla, napřík-lad vedením z topného článku, vytvořeného odporovým drátem,nebo radiací optického nebo infračerveného zdroje.
Podle vynálezu sestává spojka ke spojování trub z dutéhotělesa s otevřeným koncem z nevodivého zesilovaného polyolefinukteré byle radiálně rozšířeno čili expandováno tak, že předzahříváním má spojka první nejmenší vnitřní průměr a po zahří-vání má spojka druhý nejmenší vnitřní průměr, který je menšínež první nejmenší vnitřní průměr.
Podle vynálezu je způsob spojování trub z polyolefinovéhomateriálu navzájem založen na tom, že se uspořádají k sobě svý-mi konci a spojka se smrští a protilehlý vnitřní povrch spojkya vnější koncové- povrchy trub se zahřejí na teplotu svařování,přičemž spojka se zahřeje světelnou nebo infračervenou radiacíz prostředků uspořádaných po obvodě kolem spojky.
Spojka může mít topný článek nebo topné články, jimiž mů-že procházet elektrický proud. vestliže se použije spojky tohoto typu, je způsob stejný - 3 - jako sbore uvedeno, spojka je však zahřívána topnými články.
Provedení podle vynálezu je podrobně objasněno na praktic-kých příkladech provedení a pomocí připojených obrázků, ba obr.1 je svislý řez horní polovinou spojky podle prvního provedení,jež obklopuje konce dvou spojovaných trub. Na obr. 2 je zvět-šený řez z obr. 1 . Ks obr. 3 je svislý řez horní polovinouprovedeného spoje s použitím spojky podle obr. 1 . Ká obr, 4je svislý řez horní polovinou modifikované spojky. Na obr. 5 a6 je příčný a podélný řez druhého provedení spojky, uspořáda-né kolem dvou trub v poloze jejich spojování. Na obr, 7 je řez,odpovídající obr. 2, znázorňující provedený spoj za použitíspojky, znázorněné na obr. 5 e 6. Následující příklady objasňují vynález na případu spojekz polyethylenu, vynález je však použitelný i pro jiné polyole-finy, například pro polypropylen a pro polybutylen. Příklady provedení vynálezu
Spojka podle prvního provedení podle vynálezu je zhotovenaze 100 mm dlouhé trouby ze zesilovaného polyethylenu společnos-ti Wirsbo Bruks AB, Virsbo, Švédsklo, s vnitřním průměrem jeno málo menším než vnější průměr 90 mm trouby z nezesilovanéhopolyethylenu, určené ke spojování. Vnější průměr spojky je 110mm a tloušlka štěny 10 mm. Do vnějšího i vnitřního povrchu jevyříznut šroubovicový závit, aby byly povrchy vroubkované.Stoupání závitu je 2 mm a hloubka vroubku je rovněž 2 mm.
Na vnější povrch je navinut pocínovaný měděný drát s cel-kovým odporem 2,25 ohm. Ten tvoří topný článek. Článek možnoprovést různými /neznázorněnými/ způsoby. Například drát můžebýt navinut ve šroubové drážce na vnější straně velmi tenkéhoválcového dutého člene z polyethylenu, takže závity vinutí jsouvelmi těsně uspořádány u vnitřního povrchu člene. Po navinutičlánku může být kolem vnějšího povrchu člene vytvořen vstřiko-váním vnější plášl. Tento způsob zhotovování spojek je popsánav britském patentovém spise číslo 2 09055S B. řodle jiného provedení je topnv článek ve šroubové drážce, vyříznuté do vnitřního povrchu úseku trouby. Vnější povrch ne-ní závitem opstřen. Při dalším způsobu provedení, který jezvlášt vhodný, pokud jde o tlustší spojky, je použito ovoutopných článků, navinutých jak na vnějším, tak ne. vnitřním povr-chu spojky. Úsek trouby se dále roztáhne /expanduje/ k vytvoření spoj-ky. X tomu se používá například hydraulicky ovládaného expan-deru, typu dodávaného společností Pipe Lquipment Limited tak,aby vůle mezi vnitřním nejmenším průměrem trouby a vnějším po-vrchem polyethylenových trub, určených ke spojování, byla 2 až3 mm. Rozšíření čili expanze se může provádět za teploty okolínebo za zvýšené teploty přibližně až do 120 °C. Po rozšíření zazvýšené teploty se spojka rychle ochladí například ve vodě. Al-ternativně může být spojka rozšířena například použitím expan-deru typu dodávaného společnosti Jointkit Limited.
Na obr. 1 a 2 je spojka 10, sestavená se dvěma polyethyle-novými troubami 1 2, 14, uspořádanými konci k sobě k jejich vzá-jemnému spojení. Šroubový vnější závit 16 nese topný článek 18,navinutý na vroubkovaném vnějším povrchu. Vnitřní závit 20 jetaké znázorněn s mezerou 22 mezi vnitřním nejmenším průměremspojky a vnějším povrchem trouby 1 4. K aktivaci topného článku18 se používá elektrického proudu ze droje o napětí 40 V. Pou-žívá se časovaných pulzů a teplota vnějšího povrchu jednéz trub 12, 14 je sledována termočlánky. Pulzování brání překro-čení vnější teploty spojky 260 °C. Vnější povrch trouby trvalevzrůstá a když se dosáhne 140 °C, proud se vypne. Po vychladnu-tí se spojka a trouby rozřežou za účelem vyzkoušení stavu sva-rového spoje.
Trouby 12, 14, spojené spojkou 10 se podrobují zkoušce zapodmínek " zkoušky při 80 °C". To znamená, že vnitřně působíhydrostatický tlak k vyvození napětí ve stěně trouby 4 Lípa,přičemž sestava je ponořena ve .vodě, udržované na teolotě 80°C. Pro troubu SDR11 je tento hydrostatický tlak 0,8 ftiPa. V sou-časné době prodělává sestava 650 hodin zkušebních podmínek bez úniku. Celá zkouška byla úspěšně ukončena po 1000 hodinách bezúniku.
Jsk patrno z obr. 3, smrští se spojka 10 na troubě 12, 14 úplně, takže se vymezí původní vůle 22 a vroubkovaný vnitř-ní povrch spojky 1Q vnikne do původních vnějších povrchů trub1 2, 14, čímž mechanicky utěsní spojované povrchy. V místech 24, 26, 28 a 30 je patrno určité napěchování stěn trub 1 2, 1 4. Před svařením se povrchy trub neupravují, takže původnívnější povrchy nesou původní oxidovanou vrstvu. Spojka 10 ús-pěšně touto oxidovanou vrstvou proniká v průběhu vytváření tav-ného svarového spoje. Při modifikaci mohou být vroubky na vnitřním povrchu vy-puštěny a konce trubek musí být potom obvyklým způsobem očiš-těny dříve než jsou vytvářeny svarové spoje mezi protilehlýmiválcovými povrchy trub a spojky. ha obr. 4 je modifikovaný tvar spojky 10. Podle tohoto pro-vedení je kromě topného článku 18, navinutého na vnějším povr-chu, druhý topný článek, navinutý na vnitřním povrchu a drženýv poloze vnitřními zoubky 20 vnitřního závitu. Tohoto druhéhotopného článku 32 se používá tehdy, když tlouštka spojky by ji- ; nak vyžadovala nadměrné teplotní 'gradienty ve stěně spojky adlouhodobý ohřev, než by došlo k prohřátí vnitřního povrchu nateplotu svařování. í
Ohřevem stěny z obou stran je spojka vystavena rychlejšímu í ohřevu a rychleji získá svařovací teplotu na vnitřním povrchu. í U spojky o průměru 500 mm, kde je například standardní rozměro- | vý poměr 17, je tloušťka stěny přibližně 30 mm a u SDR11 je £ tloušťka stěny přibližně 46 mm. U spojek jakéhokoliv rozměru £ o tloušťce řekněme 30 mm a větší je výhodné použití dyou top- * i ných článků. |
Podle další neznázorněné modifikace může mít spojka pouze § jeden topný článek, uspořádaný podobně jako právě popsaný top- | ný článek 32. · i
Provedení spojky 40., znázorněné na obr. 5 až 7, je podobné ž jako v případě spojky 10 s tou. výjimkou, že šroubová drážka jevyříznuta do vnějšího povrchu bez aplikace topného článku napovrchu. - 6 - U trub 1 2, 1 4, sestavených se spojkou 40 podle obr. 5 3 6,je spojka 40 zahřívána radiací osmi 150 W lamp 42, zabudovanýchv reflektorech.
Teplota spojky a teplota vnějšího povrchu trouby se sledu-jí podobně, jako shora uvedeno. Fři vypnutí lamp teplota vnějšího povrchu trouby je trvale 140 °C. Spojka 40 se stane optickyčirou, jakmile dosáhne své vlastní teploty tavení, což umožnílepší pronikáni světla k povrchům trub a přestup tepla zářením účinnější. Na obr. 7 je dokončený spoj mezi dvěma troubami1 2 a 1 4. Popsané obr. nejsou v měřítku. Zesítovaný polyethylenmá vlastnost dosahování rozmezí tavení krystalů polyethylenu beztečení. Jeho molekulární struktura je trojrozměrnou sítí,která určuje chování kaučukovité pevné látky nad teplotou její-ho tavení. V této fázi se vytvářejí svarové spoje s nezesilova-ným povrchem polyethylenu.
Sxpanze zesítované spojky propůjčuje spojce charakteristi-ku smršťování teplem, která může zlepšovat kvalitu svarovýchsoojů tím, že je vynechána nutnost oškrabání povrchu trub předtavením. Taková úprava povrchu je důležitou avšak časově nároč-nou operací při běžném elektrickém tavení. Tepelně smrštěná spojka ze zesilovaného polyolefinu má vroubkovaný vnitřní povrch,který netaví povrch trouby a pronikne oxidovanou vnější slupkoutrouby a vytvoří svarový spoj s materiálem ležícím pod toutoslupkou.
Vynález je použitelný pro spojky větších rozměrů, napříkladpro spojky o průměru 500 mm a pro větší spojky. Takové spojkyby mohly být z běžné polyethylenové trouby, která se ozáří papr-ky gama k dosažení vhodné míry zesíťování. Alternativně se mohouspojky speciálně lisovat použitím polyethylenu, vhodného k liso-vání a zesilovány chemicky /například ve formě/ k získání koneč-né zesítěné spojky.
Ohřevu se dosahuje pomocí elektrických topných článků nebopomocí lamp nebo infračervených ohřívačů. Zkrácení doby ohřevuse dá dosáhnout předehřátím spojky /například na 100 °C/ zapnu-tím topného článku nebo topných článků nebo zahřátím spojkv v pe
Cl r.aoříklad před na ?sazemm na troubv. - 7 -
Průmyslová využitelnost rolyolefinová spojka vhodné pro spojování polyolefinových truc.
.-I
Claims (13)
1 . Polyolefinová spojka pro spojování trub, vyzna- čující se tím, že sestává z dutého tělesa s o-tevřeným koncem z nevodivého zesilovaného polyolefinovéhomateriálu, který je radiálně roztažen - expandován - při-čemž před obrátím má spojka první nejmenší vnitřní průměra po ohřátí má druhý nejmenší vnitřní průměr menší nežprvní nejmenší vnitřní průměr.
2. Polyolefinová spojka podle nároku 1,vyznaču- jící se tím, že vnitřní povrch tělesa je vroubekovaný.
3. Polyolefinová spojka podle nároku 1 nebo 2, vy z n a čující se tím, že májtopný článek nebo topnéčlánky k elektrickému ohřevu.
4. Polyolefinová spojka podle nároku 3> vyzna-čující se tím, že topný článek je ve šroubovédrážce ve vnitřním povrchu spojky.
5. Polyolefinová s-ojka podle nároku 3, v y z n a -čující se tím, že má dva topné články, jedenve šroubové drážce na vnějším povrchu a druhý ve šroubovédrážce na vnitřním povrchu.
6. Způsobnavzájem, v yby uspořádajíoodle nároku 1 spojování trub z polyolefinového materiáluznačující se tím, že se trou-svými konci k sobě a polyolefinová spojkanebo 2, která přivrácené konce trub na vněj- ší straně přemostuje, se zahřeje až do svého smrštění avnější povrchy trub se zahřejí na teplotu svařování, přičemžse spojka zahřívá světelným nebo infračerveným zářením zezdroje, umístěného kolem obvodu spojky.
7. Způsob navzájem, v y spojování trubznačujíc z polyolefinového materiálu í s e tím ze se - 9 - trouby uspořádají svými konci k sobě a polyolefinová spojka podle nároku 3 nebo 4, která přivrácené konce trub na vněj- ší stran·' přemosťuje, se smrští zapojením elektrického proudu do ohřívacích článků a vnitřní povrch spojky a protilehlé vnější povrchy trub se zahřejí na svařovací teplotu. s.
Polyolefinová spojka podle nároku 1 v provedení v pod- statě objasněném na obr. 1 a ž 3.
9. Polyolefinová spojka podle nároku 1 v provedení v pod- statě objasněném na obr. 4.
10. Polyolefinová spojka podle nároku 1 v provedení v pod- statě objasněném na obr. ?, 6 a 7.
11. Způsob podle nároku 6 v podstatě popsaný na obr. 5 sš 7.
12. Způsob podle nároku 7 v podstatě popsaný se zřetelemna obr. 1 a 2.
13. Způsob podle nároku 12,vyznačující setím, že se používá spojky podle obr. 4«
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB9109123A GB2255041B (en) | 1991-04-24 | 1991-04-24 | Polyolefin coupler for joining polyolefin pipes |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CS119092A3 true CS119092A3 (en) | 1992-11-18 |
| CZ279082B6 CZ279082B6 (en) | 1994-12-15 |
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| US (1) | US5328210A (cs) |
| EP (1) | EP0510803B1 (cs) |
| JP (1) | JP2770643B2 (cs) |
| CA (1) | CA2066919C (cs) |
| CZ (1) | CZ279082B6 (cs) |
| DE (2) | DE69216279D1 (cs) |
| ES (1) | ES2099208T3 (cs) |
| GB (1) | GB2255041B (cs) |
| GR (1) | GR3023020T3 (cs) |
| HU (1) | HU214065B (cs) |
| PL (1) | PL169226B1 (cs) |
| SK (1) | SK278475B6 (cs) |
| TR (1) | TR28690A (cs) |
| YU (1) | YU48662B (cs) |
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| RU2235188C2 (ru) * | 2002-08-28 | 2004-08-27 | Научно-исследовательское учреждение Институт физики прочности и материаловедения СО РАН | Способ ремонта внутренней поверхности труб и способ изготовления бандажа для ремонта внутренней поверхности труб |
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| CN104110539B (zh) * | 2013-07-22 | 2016-11-23 | 广东美的制冷设备有限公司 | 空调器及防拆卸接管装置 |
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1991
- 1991-04-24 GB GB9109123A patent/GB2255041B/en not_active Expired - Fee Related
-
1992
- 1992-03-19 DE DE69216279A patent/DE69216279D1/de not_active Expired - Fee Related
- 1992-03-19 DE DE69216279T patent/DE69216279T4/de not_active Expired - Lifetime
- 1992-03-19 EP EP92302356A patent/EP0510803B1/en not_active Expired - Lifetime
- 1992-03-19 ES ES92302356T patent/ES2099208T3/es not_active Expired - Lifetime
- 1992-04-10 TR TR00393/92A patent/TR28690A/xx unknown
- 1992-04-14 YU YU38692A patent/YU48662B/sh unknown
- 1992-04-17 SK SK1190-92A patent/SK278475B6/sk unknown
- 1992-04-17 CZ CS921190A patent/CZ279082B6/cs not_active IP Right Cessation
- 1992-04-22 HU HU9201344A patent/HU214065B/hu not_active IP Right Cessation
- 1992-04-23 PL PL92294313A patent/PL169226B1/pl unknown
- 1992-04-23 JP JP4103302A patent/JP2770643B2/ja not_active Expired - Lifetime
- 1992-04-23 CA CA002066919A patent/CA2066919C/en not_active Expired - Fee Related
- 1992-04-24 US US07/873,270 patent/US5328210A/en not_active Expired - Fee Related
-
1997
- 1997-04-02 GR GR970400692T patent/GR3023020T3/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CZ279082B6 (en) | 1994-12-15 |
| ES2099208T3 (es) | 1997-05-16 |
| JP2770643B2 (ja) | 1998-07-02 |
| GR3023020T3 (en) | 1997-07-30 |
| HU9201344D0 (en) | 1992-07-28 |
| SK278475B6 (en) | 1997-07-09 |
| GB2255041B (en) | 1995-04-19 |
| DE69216279T4 (de) | 1998-03-05 |
| PL169226B1 (pl) | 1996-06-28 |
| EP0510803B1 (en) | 1997-01-02 |
| JPH05133494A (ja) | 1993-05-28 |
| GB9109123D0 (en) | 1991-06-12 |
| CA2066919A1 (en) | 1992-10-25 |
| YU38692A (sh) | 1995-10-03 |
| TR28690A (tr) | 1997-01-08 |
| YU48662B (sh) | 1999-06-15 |
| US5328210A (en) | 1994-07-12 |
| HUT64614A (en) | 1994-01-28 |
| DE69216279D1 (de) | 1997-02-13 |
| GB2255041A (en) | 1992-10-28 |
| CA2066919C (en) | 1997-05-06 |
| HU214065B (en) | 1997-12-29 |
| EP0510803A3 (en) | 1993-08-18 |
| EP0510803A2 (en) | 1992-10-28 |
| DE69216279T2 (de) | 1997-08-21 |
| PL294313A1 (cs) | 1993-02-08 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| IF00 | In force as of 2000-06-30 in czech republic | ||
| MM4A | Patent lapsed due to non-payment of fee |
Effective date: 20030417 |