CN87103471A - 在冷却润滑剂存在下机械加工铝和铝合金的方法以及冷却润滑剂浓缩物 - Google Patents

在冷却润滑剂存在下机械加工铝和铝合金的方法以及冷却润滑剂浓缩物 Download PDF

Info

Publication number
CN87103471A
CN87103471A CN87103471.9A CN87103471A CN87103471A CN 87103471 A CN87103471 A CN 87103471A CN 87103471 A CN87103471 A CN 87103471A CN 87103471 A CN87103471 A CN 87103471A
Authority
CN
China
Prior art keywords
cooling lubricant
alkyl
water
weight
compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN87103471.9A
Other languages
English (en)
Other versions
CN1010693B (zh
Inventor
埃利那·桑德伯格
罗尔伏·斯科尔德
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Berol Suisse S
Original Assignee
Berol Suisse S
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Berol Suisse S filed Critical Berol Suisse S
Publication of CN87103471A publication Critical patent/CN87103471A/zh
Publication of CN1010693B publication Critical patent/CN1010693B/zh
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F299/00—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
    • C08F299/02—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates
    • C08F299/026—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from the reaction products of polyepoxides and unsaturated monocarboxylic acids, their anhydrides, halogenides or esters with low molecular weight
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
    • C10M105/08—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen
    • C10M105/32—Esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00—Lubricating compositions containing more than 10% water
    • C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M101/00—Lubricating compositions characterised by the base-material being a mineral or fatty oil
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
    • C10M105/56—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing nitrogen
    • C10M105/58—Amines, e.g. polyalkylene polyamines, quaternary amines
    • C10M105/60—Amines, e.g. polyalkylene polyamines, quaternary amines having amino groups bound to an acyclic or cycloaliphatic carbon atom
    • C10M105/62—Amines, e.g. polyalkylene polyamines, quaternary amines having amino groups bound to an acyclic or cycloaliphatic carbon atom containing hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
    • C10M105/56—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing nitrogen
    • C10M105/70—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing nitrogen as ring hetero atom
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M111/00—Lubrication compositions characterised by the base-material being a mixture of two or more compounds covered by more than one of the main groups C10M101/00 - C10M109/00, each of these compounds being essential
    • C10M111/02—Lubrication compositions characterised by the base-material being a mixture of two or more compounds covered by more than one of the main groups C10M101/00 - C10M109/00, each of these compounds being essential at least one of them being a non-macromolecular organic compound
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
    • C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/04—Hydroxy compounds
    • C10M129/06—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
    • C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/16—Ethers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
    • C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/26—Carboxylic acids; Salts thereof
    • C10M129/28—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M129/30—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 7 or less carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
    • C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/26—Carboxylic acids; Salts thereof
    • C10M129/28—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M129/30—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 7 or less carbon atoms
    • C10M129/32—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 7 or less carbon atoms monocarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
    • C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/26—Carboxylic acids; Salts thereof
    • C10M129/28—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M129/30—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 7 or less carbon atoms
    • C10M129/36—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 7 or less carbon atoms containing hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
    • C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/26—Carboxylic acids; Salts thereof
    • C10M129/28—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M129/38—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 8 or more carbon atoms
    • C10M129/40—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 8 or more carbon atoms monocarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
    • C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/68—Esters
    • C10M129/70—Esters of monocarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
    • C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/68—Esters
    • C10M129/76—Esters containing free hydroxy or carboxyl groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
    • C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
    • C10M133/04—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M133/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M133/08—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
    • C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
    • C10M133/38—Heterocyclic nitrogen compounds
    • C10M133/40—Six-membered ring containing nitrogen and carbon only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
    • C10M145/18—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M145/24—Polyethers
    • C10M145/26—Polyoxyalkylenes
    • C10M145/36—Polyoxyalkylenes etherified
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
    • C10M145/18—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M145/24—Polyethers
    • C10M145/26—Polyoxyalkylenes
    • C10M145/38—Polyoxyalkylenes esterified
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00—Lubricating compositions containing more than 10% water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/02—Water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/003—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/022—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least two hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates
    • C10M2207/046—Hydroxy ethers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
    • C10M2207/122—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms monocarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
    • C10M2207/123—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms polycarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
    • C10M2207/124—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms containing hydroxy groups; Ethers thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C10M2207/126—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C10M2207/128—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids containing hydroxy groups; Ethers thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/129—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/18—Tall oil acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/22—Acids obtained from polymerised unsaturated acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/281—Esters of (cyclo)aliphatic monocarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/282—Esters of (cyclo)aliphatic oolycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/283—Esters of polyhydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/284—Esters of aromatic monocarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/286—Esters of polymerised unsaturated acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/287—Partial esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/287—Partial esters
    • C10M2207/288—Partial esters containing free carboxyl groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/287—Partial esters
    • C10M2207/289—Partial esters containing free hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C10M2207/402—Castor oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C10M2207/404—Fatty vegetable or animal oils obtained from genetically modified species
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/105—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing three carbon atoms only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/107—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of two or more specified different alkylene oxides covered by groups C10M2209/104 - C10M2209/106
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/108—Polyethers, i.e. containing di- or higher polyoxyalkylene groups etherified
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/109—Polyethers, i.e. containing di- or higher polyoxyalkylene groups esterified
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
    • C10M2215/0425—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/2203—Heterocyclic nitrogen compounds used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/221—Six-membered rings containing nitrogen and carbon only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/225—Heterocyclic nitrogen compounds the rings containing both nitrogen and oxygen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/225—Heterocyclic nitrogen compounds the rings containing both nitrogen and oxygen
    • C10M2215/226—Morpholines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/225—Heterocyclic nitrogen compounds the rings containing both nitrogen and oxygen
    • C10M2215/226—Morpholines
    • C10M2215/2265—Morpholines used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/30—Heterocyclic compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/30—Heterocyclic compounds
    • C10M2215/305—Heterocyclic compounds used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/241—Manufacturing joint-less pipes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/242—Hot working
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/243—Cold working
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/245—Soft metals, e.g. aluminum
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/246—Iron or steel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/247—Stainless steel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/01—Emulsions, colloids, or micelles
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2070/00—Specific manufacturing methods for lubricant compositions
    • C10N2070/02—Concentrating of additives

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Emergency Medicine (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Lubricants (AREA)
  • Forging (AREA)
  • Manufacture Of Alloys Or Alloy Compounds (AREA)
  • ing And Chemical Polishing (AREA)
  • Manufacture Of Metal Powder And Suspensions Thereof (AREA)
  • Heat Treatments In General, Especially Conveying And Cooling (AREA)

Abstract

在水基冷却润滑剂存在下机械加工铝或铝合 金，该冷却润滑剂具有稳定的溶液形态，其中作为润 滑剂和防腐剂含有(a)具有7～22个碳原子的疏水 基的羧基化合物及(b)分子量低于300的烷基烷醇 叔胺以及(c)分子量低于400并具有最高为6个碳原 子的烃基的混合物。羧基化合物和烷基烷醇叔胺的 用量选择，要使烷醇胺和羧基化合物之间的碱/酸 当量比低于1.0，最好低于0.9。其浓缩物用水稀释 后即可用作冷却润滑剂。

Description

本发明涉及在水基冷却润滑剂存在下机械加工铝和铝合金的方法以及用水稀释后可用作为冷却润滑剂的浓缩物。本发明技术特别适用于冷轧。
一般来说，煤油基冷却润滑剂适用于铝的冷轧，但其应用还存在许多不利因素，如烃的排放量大，火灾危险性大且冷却效果有限。冷却效果差又对生产能力产生不利影响。
因此已提出用含特定添加剂的水基乳液代替煤油基冷却润滑剂，其中的添加剂可降低（特别是在高压下）金属表面和加工工具之间的腐蚀和/或摩擦。特别是USP4，243，537和欧洲专利申请115，926提出了这种水基润滑体系，其中包括烷醇胺，羧酸和聚氧化烯的混合物作为润滑剂和防腐剂。USP3，374，171也公开了用于金属加工，如用于机械加工铁的类似润滑剂组合物。
尽管水基冷却润滑体系具有尽人皆知的优点，但还不能广泛用于轧制铝和铝合金，因为其中的润滑剂和防腐剂含量低，致使水锈蚀金属表面且对加工工具的润滑和/或防腐效果差。引起金属铝表面的水锈（即所谓的百锈）的主要原因是冷却润滑剂中添加的有关成分对铝的防腐效果差。尽管增加润滑剂和防腐剂的含量无疑会改善润滑和防腐效果，但在后续的热处理过程中又会有不希望出现的锈蚀问题，这是因为所用冷却润滑剂各成分的残余物已进行了转化，并会烧蚀金属表面。
轧制加工中难于解决的另一问题是在轧制金属表面上会出现轧痕和其它机械损伤，因为金属会从正在轧制的金属坯段上撒裂下来并焊接在轧辊上。在进一步轧制过程中这种不规则轧辊构型会损伤金属表面。
现已发现对铝或铝合金进行有效的冷轧或热轧加工，其中可得到令人满意的润滑和防腐效果，并且在后续的热处理中金属表面不会出现不希望有的锈蚀。本发明中这一效果是这样达到的，即在稳定溶液形态的水基冷却润滑剂存在下于至少20～70℃进行机械加工，润滑剂中含（a）通式为R1COOH的羧基化合物，其中R1为具有7～22个碳原子的疏水基团和（b）分子量低于300的烷基烷醇叔胺以及（c）分子量低于400并具有最高为6个碳原子的烃基的水溶性有机增溶剂且胺和羧基化合物之间的碱/酸当量比小于1.0。所谓的“稳定溶液”在本发明中是指在可预见的一段时间即至少1个月内不会分成两相或多相的溶液。
为获得上述优点，首要的是碱/酸当量比小于1.0最好小于0.9，优选为0.5～0.8以获得良好的润滑特性。EP-A-115，926和USP3，374，171公开的仅是当量比大大高于1.0的实施方案。在USP3，374，171中，水溶性烷醇胺诸如三乙醇胺在金属加工流体中用作防腐剂，羧酸可溶于其中且形成相应的盐。除作为防腐剂之外，烷醇胺还于机械零件上形成残余物。这意味着烷醇胺的摩尔用量须比羧酸更大。本发明中，为了避免形成退火残余物，铝表面上的所有残余物都必须降到最低限度。这是使用其用量使碱/酸当量比小于1.0的烷基烷醇叔胺来达到的。本发明的这一当量比一般可形成pH小于8的冷却润滑剂。在空气中，铝表面受到氧化且这一表面在pH＝约8.5～9时一般有一等电位点。本发明方法在等电位点的酸侧进行。
胺化合物的选择也是至关重要的。本发明的烷基烷醇叔胺既有助于形成溶液，又有利于获得防腐性能，同时还不会形成退火残余物。当将USP4，243，537公开的组合物用于铝轧制试验时，所得铝薄板呈现出机械损伤且其退火残余物量不合要求，板面颜色变暗。已发现这些结果至少是部分取决于三乙醇胺的使用。
实际试验表明，冷却润滑剂以稳定溶液形态而不是以乳液存在对轧制特性来说是非常重要的。可推测的是，本发明稳态溶液的动力学特性会得到提高，致使金属表面迅速形成均匀且覆盖良好的羧基和烷基烷醇叔胺保护层，从而阻碍了局部沉淀以及在后续热处理过程中会引起锈蚀的过量残余物的形成。另一重要优点是可避免轧制表面上出现机械损伤。
本发明冷却润滑剂的再一重要优点是易于进行过滤以除去加工过程中形成的杂质。因此本发明冷却润滑剂可重复使用，同时又不会有任何明显的污染，金属催化氧化降解或微生物降解等危险。
本发明的冷却润滑剂除含有羧基化合物（a），烷基烷醇叔胺（b）和增溶剂（c）而外，为了进一步提高润滑效果，还可含有（d）极性且主要为疏水性的非离子化合物。
作为羧基化合物中疏水基团R1，尽管也可为支化不饱和脂肪基，但优选的是衍生自直链饱和脂肪化合物，特别优选的是含8～17个碳原子的烷基。适宜羧酸的具体例子为壬酸，癸酸，月桂酸，棕榈酸，硬脂酸，油酸，椰子脂酸及其混合物。
疏水基团R1还可含杂原子如氧，硫和氮，这些杂原子包含在醚、硫醚、酯、羟基、羧基和酰胺基等官能团中。这类羧基化合物的具体例子为：
R7OCH2COOH;R7OC2H4COOH
Figure 87103471_IMG1
其中R8为具有1～4个碳原子的烷基或氢，R7为烃基，优选为脂肪烃基，R7和R8的选择应使R1的定义得到满足。
烷基烷醇叔胺（b）中含至少一个带羟基的取代基，因而为水溶性的或可形成胶粒。优选烷基烷醇叔胺为R2R3R4N，其中R2为具有1～4个碳原子的羟烷基或（A）nH，式中A为具有2～4个碳原子的亚烷氧基，n为1～3的整数，R3为具有1～6个碳原子的烷基，R4代表定义同R2和R3的基团。适宜烷基烷醇叔胺的具体例子为二乙醇乙基胺，二乙醇丙基胺，二乙醇丁基胺，二乙醇戊基胺，二乙醇己基胺和相应的二丙醇胺，以及乙醇二乙基胺，乙醇二丙基胺，乙醇二丁基胺和相应的丙醇胺。上述化合物也可用环氧乙烷，环氧丙烷或环氧丁烷进行烷氧基化。
一般来说，羧基化合物和烷醇胺的用量应使碱/酸当量比达到0.5～0.9，这通常可形成pH约为6～8的冷却润滑剂。已发现烷醇胺化合物相对于羧基化合物的用量不足时可提高润滑效果。因此，如果希望获得良好的润滑效果，建议选择烷醇胺和羧基化合物之间的碱/酸当量比为0.5至高达0.8。
增溶剂（c）为带有极性基如羟基和醚基的低分子量水溶性化合物，其分子量最好低于250，具体例子为乙二醇如单或双丁基乙二醇，单或双丙基乙二醇，单或双乙基乙二醇或二乙二醇，三乙二醇的相应单或双化合物的醚类以及戊醇，丁醇，丙醇和异丙醇等醇类，优选的是单或双乙二醇的单醚类。
主要有利于提高冷却润滑剂润滑效果的非离子化合物（d）的性质必须主要是疏水性的，即其HLB值小于10，最好小于9且优先选用基本上不溶于水的非离子化合物。适宜的化合物（d）为R5（B）mOR6，其中R5为具有8～24个碳原子的烃基或酰基，B为具有2～4个碳原子的氧亚烷基，R6为氢，具有1～4个碳原子的烷基或酰基，m为0～4的整数。
非离子化合物（d）既可为芳烃又可为脂肪烃，但优选用脂肪烃化合物，其中的优选具体例子为羟基化合物如辛醇，癸醇，十二（烷）醇，十四（烷）醇，十六（烷）醇，具有9～17个碳原子的羰基合成醇，壬基酚，辛基酚和十二烷基酚以及上述醇中每摩尔羟基化合物含1～4摩尔环氧乙烷的乙氧基化合物。这些羟基化合物可用通式表示为R5（B）mOH，其中R5，B和m同上述定义。
非离子化合物的其它具体例子为用H（B）mOR6烷氧基化或酯化的脂肪酸，其中B，R6和m同上述定义。这类化合物的具体例子为
C11H21COOC2H4OH;
C11H23COOCH3;
C9H19CO（OC2H4）O2CH3。
优选酯化合物为R5OR6，其中R5为具有8～24个碳原子的酰基，R6为具有1～4个碳原子的烷基。
除了上述成分而外，本发明水基冷却润滑剂还可含有常用的添加剂如杀菌剂，防沫剂，粘度调节剂，香料以及可补充润滑和防腐效果的其它添加剂。提高润滑效果的其它添加剂的具体例子为基于环氧乙烷和更高级环氧烷烃的聚合物。这些环氧烷烃既可任意偶联，又可嵌段偶联。
在根据本发明制备冷却润滑剂的过程中，优选是首先制得适当含下列成分的浓缩物。
成分    含量，%（重量）
羧基化合物    15～75，优选为20～45
烷基烷醇叔胺    3～60，优选为10～45
增溶剂    10～87，优选为10～68
非离子化合物    0～30，优选为2～30
杀菌剂，香料，粘度调节剂等    0～35，优选为0～15
水    0～72，优选为0～58
浓缩物用水稀释后即可制得备用的冷却润滑剂。适宜的组成如下。
成分    含量，%（重量）
羧基化合物    0.5～25，优选为2～15
烷基烷醇叔胺    0.1～20，优选为1～15
增溶剂    0.5～33，优选为1～18
非离子化合物    0.0～10，优选为0.2～10
常用添加剂如杀菌剂，香料，
粘度调节剂    0～5，优选为0.1～2
水    25～98.9，优选为40～95.7
备用溶液中水含量优选为70～95%（重量）。
本发明用下述实例作进一步说明。
实例
AA3004级退火铝薄板在单支座上用直径为159mm的轧辊于下述任何一种冷却润滑剂存在下进行冷轧。轧制过程中，薄板厚度从1.05mm减薄到0.63mm。必须的轧制力由将挤压力传给轧辊的液压系统的压力加以确定。轧制后用肉眼以0至1级标准对表面机械损伤进行评价，0表示表面合乎标准，即表面基本上无机械损伤。1表示表面不合乎标准，即表面有肉眼可见的机械损伤。将轧制后的铝薄板清扫干净并抹上足够的冷却润滑剂，之后将其在空气中于5小时内加热到360℃。加热后的外观用肉眼以0至4级标准一方面对变黑程度，另一方面对锈蚀表面比例进行评价。
标准，级    暗色程度    锈蚀表面，%
0    完好，无暗色    0
1    可辨识出暗色    1～5
2    出现轻微暗色    6～15
3    出现明显暗色    16～50
4    出现强烈暗色    51～100
在可接受的退火残余物下对暗色程度和锈蚀表面进行总评价。0～1级表示极佳，2～3级表示非常合乎标准，4～5级表示正好合乎标准，6～8级表示低于标准。所谓“正好合乎标准”（合格）意指从退火残余物观点来看，铝薄板恰好合乎商品规格。
为了确定冷却润滑剂对铁的腐蚀作用，将测试用的“铸铁船”放在用特定量冷却润滑剂浸渍过的滤纸上达24小时。再将1500平方厘米面积上有126个交点的栅格置于滤纸上，并测试每一栅格交点出现的腐蚀度。然后用锈蚀的交点数与交点总数之比来表示的铁的腐蚀情况。
白锈的确定方法是，用冷却润滑剂在铝薄板上涂层，然后将薄板重叠并在-20℃下冷却1小时，之后在室温空气中将其暴露2小时。再将薄板于10小时内加热到80℃。并用评价铁锈蚀的方式对白锈进行评价。
用基本上无水的浓缩物制得本发明的下列润滑剂，并将其用于本实例中的冷轧操作。所有冷却润滑剂在20℃下均呈稳定的溶液形态。
冷却润滑剂1
成分    含量，%（重量）
月桂酸    3.2
C4H9N（C2H4OH）21.5
C14H29O（C2H4O）2H 0.7
丁基二乙二醇    9.0
水    其余
碱/酸当量比    0.58
冷却润滑剂2
成分    含量，%（重量）
壬酸    6.0
C4H9N（C2H4OH）23.5
C12-14H25-29O（C2H4O）2H 1.5
丁基二乙二醇    3.6
水    其余
碱/酸当量比    0.57
冷却润滑剂3
成分    含量，%（重量）
月桂酸    6.0
C4H9N（C2H4OH）23.4
C12-14H25-29O（C2H4O）2H 1.5
丁基二乙二醇    4.4
水    其余
碱/酸当量比    0.70
冷却润滑剂4
成分    含量，%（重量）
月桂酸    6.0
C4H9N（C2H4OH）23.9
C12-14H25-29O（C2H4O）2H 1.5
丁基二乙二醇    2.7
水    其余
碱/酸当量比    0.81
冷却润滑剂5
成分    含量，%（重量）
月桂酸    8.0
C4H9N（C2H4OH）24.5
C12-14H25-29O（C2H4O）2H 1.3
丁基二乙二醇    6.7
水    其余
碱/酸当量比    0.70
冷却润滑剂6
成分    含量，%（重量）
月桂酸    6.7
C4H9N（C2H4OH）23.8
C12-14H25-29OH 1.7
丁基二乙二醇    7.8
水    其余
碱/酸当量比    0.70
冷却润滑剂7
成分    含量，%（重量）
月桂酸    6.7
C4H9N（C2H4OH）23.7
C11H23COOCH31.7
丁基二乙二醇    8.0
水    其余
碱/酸当量比    0.69
冷却润滑剂8
成分    含量，%（重量）
C11H23COOH（支化） 6.0
C4H9N（C2H4OH）23.0
C12H25O（C2H4O）2H 1.0
丁基二乙二醇    5.9
水    其余
碱/酸当量比    0.62
冷却润滑剂9
成分    含量，%（重量）
月桂酸    6.0
C4H9N（C2H4OH）23.4
C14H29O（C2H4O）2H 1.0
丁基二乙二醇    3.8
水    其余
碱/酸当量比    0.70
冷却润滑剂10
成分    含量，%（重量）
月桂酸    6.7
二亚乙基乙醇胺+EO（环氧乙烷）    3.8
C12-14H25-29OH 1.4
丁基二乙二醇    8.2
水    其余
碱/酸当量比    0.70
冷却润滑剂11
成分    含量，%（重量）
月桂酸    4.0
丁基二乙醇胺    2.7
月桂酸甲酯    1.0
丁基二乙二醇    4.8
水    其余
碱/酸当量比    0.84
冷却润滑剂12
成分    含量，%（重量）
月桂酸    6.9
丁基二乙醇胺    3.9
C12-14H25-29OH 1.4
戊基二乙二醇    7.9
水    其余
碱/酸当量比    0.70
冷却润滑剂13
成分    含量，%（重量）
壬酸    7.4
C12-14H25-29OH 0.9
2，2-二甲基氨基甲基丙醇    3.6
丁基二乙二醇    5.0
水    其余
碱/酸当量比    0.67
冷却润滑剂14
成分    含量，%（重量）
月桂酸    6.2
2，2-二甲基氨基甲基丙醇    2.5
丁基二乙二醇    7.1
C12-14H25-29OH 1.2
水    其余
碱/酸当量比    0.69
冷却润滑剂15
成分    含量，%（重量）
月桂酸    8.21
C4H9N（C2H4OH）25.12
丁基二乙二醇    6.67
水    其余
碱/酸当量比    0.77
冷却润滑剂16
成分    含量，%（重量）
月桂酸    5.67
C4H9N（C2H4OH）23.55
丁基二乙二醇    4.63
C12-14H25-29OH 1.13
水    其余
碱/酸当量比    0.78
冷却润滑剂17
成分    含量，%（重量）
壬酸    8.62
C4H9N（C2H4OH）26.38
丁基二乙二醇    3.00
水    其余
碱/酸当量比    0.71
冷却润滑剂18
成分    含量，%（重量）
月桂酸    9.0
C4H9N（C2H4OH）26.0
丁基二乙二醇    3.0
水    其余
碱/酸当量比    0.79
冷却润滑剂19
成分    含量，%（重量）
癸酸    8.6
2，2-二甲基氨基甲基丙醇    3.6
丁基二乙二醇    7.0
水    其余
碱/酸当量比    0.61
冷却润滑剂20
成分    含量，%（重量）
棕榈酸    7.06
2，2-二甲基氨基甲基丙醇    3.06
壬酸    1.00
C4H9N（C2H4OH）21.00
C12-24H25-29OH 0.53
丁基二乙二醇    7.31
水    其余
碱/酸当量比    0.93
为了对比，制成下列冷却润滑剂。在20～70℃范围内，它们均呈乳液状态。冷却润滑剂A，B及C按照USP4243537方法制备，而D和E则按照EP-A-115926方法制备。
冷却润滑剂A
成分    含量，%（重量）
油酸    2
三乙醇胺    1
聚（亚烷基）二醇（UCON    5H    B100）10
水    其余
碱/酸当量比    0.95
冷却润滑剂B
成分    含量，%（重量）
油酸    2
三乙醇胺    1
聚（亚烷基）二醇（UCON    5H    B100）10
Figure 87103471_IMG2
水    其余
碱/酸当量比    0.95
冷却润滑剂C
成分    含量，%（重量）
油酸    2.0
三乙醇胺    1.6
聚（亚烷基）二醇（UCON    5H    B100）10
水    其余
碱/酸当量比    1.5
冷却润滑剂D
成分    含量，%（重量）
月桂酸    1.5
三乙醇胺    1.5
聚（亚烷基）二醇（Pluronic    17R2）    10
Figure 87103471_IMG3
水    其余
碱/酸当量比    1.9
冷却润滑剂E
成分    含量，%（重量）
油酸    1.0
三乙醇胺    0.8
聚（亚烷基）二醇（Pluronic    17R2）    5.0
水    其余
碱/酸当量比    1.5
冷却    加压    退火    铁    白锈    机械
润滑剂    kN    残余物    腐蚀    %    外观
A    13.3    5    5    20    1
B    13.5    8    4    6    1
C    14.0    8    0.1    12    1
D    16.5    5    0    0    1
E    14.5    5    4    30    1
1    14.7    1    1    0    0
2    14.3    2    0    0    0
3    14.3    3    0    0    0
4    14.4    2    0    0    0
5    13.2    3    0    0    0
-续-
冷却    加压    退火    铁    白锈    机械
润滑剂    kN    残余物    腐蚀    %    外观
6    13.4    3    0    0    0
7    13.5    2    0    0    0
8    14.0    3    0    0    0
9    13.4    2    0    0    0
10    13.5    3    0    1    0
11    12.5    2    0    5    0
12    13.0    3    0    4    0
13    14.5    1    0    0    0
14    14.5    1    0    0    0
15    13.1    3    0    0    0
16    13.5    2    0    0    0
17    13.2    2    0    0    0
18    13.2    2    0    0    0
19    13.0    1    0    0    0
20    14.1    2    0    2    0
从这一试验结果清楚看出，与现有已知技术相比，用本发明提出的冷却润滑剂轧制的铝表面具有较好的机械外观。铁腐蚀和白锈均很轻微，一般说远低于用参比组分制成的冷却润滑剂。此外，采用本发明的冷却润滑剂时其退火残余物很少，在各种情况下均远低于对比试验。

Claims (9)

1、在含有润滑剂和防腐剂的水基冷却润滑剂存在下机械加工铝或铝合金的方法，其特点是，该冷却润滑剂至少在20～70℃温度范围内呈稳态溶液，其中作为润滑剂和防腐剂含有(a)通式为R1COOH的羧基化合物，其中R1为具有7～22个碳原子的疏水基团和(b)分子量低于300的烷基烷醇叔胺，以及(c)分子量低于400并具有最高为6个碳原子的烃基的水溶性有机增溶剂，胺和羧基化合物之间的碱/酸当量比小于1.0，优选小于0.9。
2、权利要求1或2提出的方法，其特点是，冷却润滑剂尚含有（d）极性的且主要为疏水性的非离子化合物。
3、权利要求3提出的方法，其特点是，化合物（d）通式为R5（B）mOR6，其中R5为具有8～24个碳原子的烃基或酰基，B为具有2～4个碳原子的氧亚烷基，R6为氢，具有1～4个碳原子的烷基或酰基，m为0至4的整数。
4、权利要求1～3提出的任一方法，其特点是，烷基烷醇叔胺（b）通式为R2R3R4N，其中R2为具有1～4个碳原子的羟烷基，或为具有通式（A）nH的基，式中A为具有2～4个碳原子的亚烷基氧基，n为1至3的整数，R3为具有1～6个碳原子的烷基，R4的含义如同R2或R3。
5、权利要求1～4提出的方法，其特点是，羧基化合物（a）的疏水基R1为脂肪族烃基。
6、权利要求1～5提出的方法，其特点是，烷醇胺和羧基化合物之间的碱/酸当量比为0.5至高达0.8。
7、权利要求1～6提出的方法，其特点是，冷却润滑剂所含羧基化合物（a）的含量为0.5～25，最好为2～15%（重量），所含烷基烷醇叔胺（b）的含量为0.1～20，最好为1～15%（重量），所含增溶剂（c）的含量为0.5～33，最好为1～18%（重量）。
8、权利要求3～7提出的方法，其特点是，冷却润滑剂所含非离子化合物（d）的含量最高为10，最好为0.2～10%（重量）。
9、用水稀释后适用于权利要求1～9提出的方法的浓缩物，其特点是，具有下列组成：
成分  含量，%（重量）
羧基化合物（a）  15～75，优选为20～75
烷醇胺（b）  3～60，优选为10～60
增溶剂（c）  10～87，优选为10～68
非离子化合物（d）  0～30，优选为2～30
常用的添加剂，诸如
杀菌剂，香料，粘度
调节剂等  0～35，优选为0～15
水  0～72，优选为0～58
CN87103471A 1986-05-13 1987-05-13 在冷却润滑剂存在下机械加工铝和铝合金的方法以及冷却润滑剂浓缩物 Expired CN1010693B (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH8602236-5 1986-05-13
SE8602236A SE452627B (sv) 1986-05-13 1986-05-13 Forfarande vid mekanisk bearbetning av metaller i nervaro av ett vattenbaserat kylsmorjmedel samt koncentrat av kylsmorjmedlet

Publications (2)

Publication Number Publication Date
CN87103471A true CN87103471A (zh) 1988-02-03
CN1010693B CN1010693B (zh) 1990-12-05

Family

ID=20364551

Family Applications (2)

Application Number Title Priority Date Filing Date
CN87103471A Expired CN1010693B (zh) 1986-05-13 1987-05-13 在冷却润滑剂存在下机械加工铝和铝合金的方法以及冷却润滑剂浓缩物
CN87103469A Expired CN1010692B (zh) 1986-05-13 1987-05-13 在冷却润滑剂存在下机械加工铝和铝合金的方法以及冷却润滑剂浓缩物

Family Applications After (1)

Application Number Title Priority Date Filing Date
CN87103469A Expired CN1010692B (zh) 1986-05-13 1987-05-13 在冷却润滑剂存在下机械加工铝和铝合金的方法以及冷却润滑剂浓缩物

Country Status (13)

Country Link
US (2) US4828736A (zh)
EP (2) EP0252534B1 (zh)
JP (2) JPS62277495A (zh)
KR (2) KR870011234A (zh)
CN (2) CN1010693B (zh)
AT (2) ATE56040T1 (zh)
AU (2) AU588686B2 (zh)
CA (2) CA1285548C (zh)
DE (2) DE3764560D1 (zh)
ES (2) ES2018005B3 (zh)
GR (2) GR3001112T3 (zh)
NO (2) NO169596C (zh)
SE (1) SE452627B (zh)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109211764A (zh) * 2018-09-18 2019-01-15 张家港市达标检测服务有限公司 一种盐雾腐蚀试验箱
CN111849599A (zh) * 2020-07-03 2020-10-30 浙江物得宝尔新材料有限公司 一种水溶性润滑液及铝冷轧的加工方法
CN111909769A (zh) * 2020-07-03 2020-11-10 浙江物得宝尔新材料有限公司 一种水溶性润滑液及铝冷轧的加工方法
CN116694386A (zh) * 2023-04-04 2023-09-05 南通科星化工股份有限公司 一种轴承磨削液及其制备方法与应用

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SE445357B (sv) * 1984-10-30 1986-06-16 Berol Kemi Ab Forfarande vid mekanisk bearbetning av kobolthaltig metall samt koncentrat avsett att efter spedning med vatten anvendas vid forfarandet
US5259970A (en) * 1989-06-30 1993-11-09 Idemitsu Kosan Co., Ltd. Aqueous composition containing water dispersed in a lubricating base oil and at least two surfactants
EP0405479B1 (en) * 1989-06-30 1994-08-31 Idemitsu Kosan Company Limited Aqueous Composition
US5174914A (en) * 1991-01-16 1992-12-29 Ecolab Inc. Conveyor lubricant composition having superior compatibility with synthetic plastic containers
US5244589A (en) * 1991-01-16 1993-09-14 Ecolab Inc. Antimicrobial lubricant compositions including a fatty acid and a quaternary
US5399274A (en) * 1992-01-10 1995-03-21 Marcus; R. Steven Metal working lubricant
JP3406407B2 (ja) * 1994-11-21 2003-05-12 新日本石油株式会社 圧延用潤滑剤組成物
US5723418A (en) * 1996-05-31 1998-03-03 Ecolab Inc. Alkyl ether amine conveyor lubricants containing corrosion inhibitors
BR9702232A (pt) * 1996-05-31 1999-02-23 Ecolab Inc Lubrificante para transportador a base de alquil éter amina
US5932526A (en) * 1997-06-20 1999-08-03 Ecolab, Inc. Alkaline ether amine conveyor lubricant
SE514315C2 (sv) * 1998-09-07 2001-02-12 Rolf Skoeld Ett förfarande för mekanisk bearbetning av en metall, som innehåller koppar eller aluminium
US6436883B1 (en) * 2001-04-06 2002-08-20 Huntsman Petrochemical Corporation Hydraulic and gear lubricants
US6562768B1 (en) 2001-08-13 2003-05-13 Ronnie L. Gregston Composition for and method of cutting internal threads on the surface of a hole in a workpiece
US7018959B2 (en) * 2003-10-29 2006-03-28 Miller Environmental Water-based metal working fluid
US20050107270A1 (en) * 2003-11-19 2005-05-19 Gernon Michael D. Alkyl ethanolamines for the control of mycobacteria in functional fluid
JP5329126B2 (ja) * 2008-05-27 2013-10-30 Ｊｆｅスチール株式会社 ラミネート金属板ｄｉ成形用水性クーラントおよびラミネート金属板のｄｉ成形方法
JP5576615B2 (ja) * 2009-03-11 2014-08-20 出光興産株式会社 金属加工油剤
JP5487516B2 (ja) * 2009-10-07 2014-05-07 協同油脂株式会社 水溶性金属加工油剤
US8609254B2 (en) 2010-05-19 2013-12-17 Sanford Process Corporation Microcrystalline anodic coatings and related methods therefor
US8512872B2 (en) 2010-05-19 2013-08-20 Dupalectpa-CHN, LLC Sealed anodic coatings
JP5717471B2 (ja) * 2011-03-07 2015-05-13 ユシロ化学工業株式会社 水溶性金属加工油剤組成物
JP5683330B2 (ja) * 2011-03-07 2015-03-11 ユシロ化学工業株式会社 水溶性金属加工油剤組成物
CN109825357A (zh) * 2011-12-28 2019-05-31 奎克化学（中国）有限公司 用于铝冷轧的水溶液润滑剂
CN103639208A (zh) * 2013-12-19 2014-03-19 邹平齐星工业铝材有限公司 热轧铝板质量控制方法
JP5785625B2 (ja) * 2014-01-14 2015-09-30 出光興産株式会社 金属加工油剤
ES2907604T3 (es) 2016-01-22 2022-04-25 Larry Lindland Refrigerante de polioxialquilenglicol de alto peso molecular para el esmerilado de vidrio
CN108311637A (zh) * 2017-01-17 2018-07-24 郭玉盼 一种强硬型壳铸造工艺
CN110452766B (zh) * 2019-08-23 2021-12-21 广州市联诺化工科技有限公司 一种铝合金加工用全合成环保切削液及其制备方法
FR3136778A1 (fr) * 2022-06-20 2023-12-22 Totalenergies Onetech Lubrifiant aqueux pour le travail des metaux

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3006849A (en) * 1958-10-14 1961-10-31 Standard Oil Co Lubricant composition
US3374171A (en) * 1967-04-25 1968-03-19 Mobil Oil Corp Aqueous lubricant compositions containing an alkanolamine, a saturated organic acid and a polyoxyalkylene glycol
US4243537A (en) * 1978-08-08 1981-01-06 Aluminum Company Of America Synthetic metal working lubricant
US4259206A (en) * 1979-08-22 1981-03-31 Mobil Oil Corporation Metal working lubricant containing an alkanolamine and a cycloaliphatic acid
US4452711A (en) * 1983-01-20 1984-06-05 Aluminum Company Of America Aqueous metalworking lubricant containing polyoxypropylene-polyoxyethylene-polyoxypropylene block copolymers
US4452712A (en) * 1983-01-20 1984-06-05 Aluminum Company Of America Metalworking with an aqueous synthetic lubricant containing polyoxypropylene-polyoxyethylene-polyoxypropylene block copolymers
CA1210384A (en) * 1983-01-20 1986-08-26 Joseph T. Laemmle Metalworking with an aqueous synthetic lubricant containing polyoxypropylene-polyoxyethylene- polyoxypropylene block copolymers
DE3676315D1 (de) * 1985-02-04 1991-02-07 Ge Chemicals Inc Metallbearbeitungsfluessigkeitzusammensetzung.
CA1290316C (en) * 1985-06-27 1991-10-08 Alain Louis Pierre Lenack Aqueous fluids
US4636321A (en) * 1985-09-30 1987-01-13 Reynolds Metals Company Water soluble lubricant

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109211764A (zh) * 2018-09-18 2019-01-15 张家港市达标检测服务有限公司 一种盐雾腐蚀试验箱
CN111849599A (zh) * 2020-07-03 2020-10-30 浙江物得宝尔新材料有限公司 一种水溶性润滑液及铝冷轧的加工方法
CN111909769A (zh) * 2020-07-03 2020-11-10 浙江物得宝尔新材料有限公司 一种水溶性润滑液及铝冷轧的加工方法
CN116694386A (zh) * 2023-04-04 2023-09-05 南通科星化工股份有限公司 一种轴承磨削液及其制备方法与应用

Also Published As

Publication number Publication date
CA1285263C (en) 1991-06-25
AU588686B2 (en) 1989-09-21
ES2018006B3 (es) 1991-03-16
NO169597B (no) 1992-04-06
SE452627B (sv) 1987-12-07
CA1285548C (en) 1991-07-02
CN87103469A (zh) 1988-03-09
ES2018005B3 (es) 1991-03-16
EP0252533A1 (en) 1988-01-13
ATE56040T1 (de) 1990-09-15
JPS62288693A (ja) 1987-12-15
NO871941D0 (no) 1987-05-11
AU588687B2 (en) 1989-09-21
EP0252534A1 (en) 1988-01-13
SE8602236D0 (sv) 1986-05-13
NO169597C (no) 1992-07-15
KR870011233A (ko) 1987-12-21
DE3764561D1 (de) 1990-10-04
KR870011234A (ko) 1987-12-21
CN1010693B (zh) 1990-12-05
US4828737A (en) 1989-05-09
AU7273487A (en) 1987-11-19
EP0252533B1 (en) 1990-08-29
NO169596C (no) 1992-07-15
EP0252534B1 (en) 1990-08-29
CN1010692B (zh) 1990-12-05
GR3001111T3 (en) 1992-05-12
GR3001112T3 (en) 1992-05-12
NO871942L (no) 1987-11-16
US4828736A (en) 1989-05-09
AU7273587A (en) 1987-11-19
NO871942D0 (no) 1987-05-11
DE3764560D1 (de) 1990-10-04
NO169596B (no) 1992-04-06
NO871941L (no) 1987-11-16
ATE56041T1 (de) 1990-09-15
JPS62277495A (ja) 1987-12-02

Similar Documents

Publication Publication Date Title
CN87103471A (zh) 在冷却润滑剂存在下机械加工铝和铝合金的方法以及冷却润滑剂浓缩物
CN1246426C (zh) 使用痕量油的切削研磨系统用油组合物
CN1208440C (zh) 冷冻机油组合物
CN1069339C (zh) 润滑剂组合物和控制流体润滑性的方法
CN1678721A (zh) 轴承用润滑油
CN1099406C (zh) 烷氧基乙酸衍生物
CN1244670C (zh) 冷却装置
CN1109736C (zh) 含有未转化羟基的多元醇酯组合物
CN1207375C (zh) 稳定的氢化处理及氢化脱蜡润滑剂组合物
CN86102119A (zh) 用于钢的冷轧润滑油
CN1922125A (zh) 烷基缩醛化合物、制备该化合物的方法以及润滑油组合物
CN87108239A (zh) 碱土金属烃基酚盐及其磁化衍生物，它们的制备和应用
CN86104443A (zh) 水基液体
CN101035883A (zh) 极微量油剂供给式切削·研削加工用油剂组合物
CN86101764A (zh) 用于金属材料的冷轧润滑油
CN1013685B (zh) 用于控制粘度的含过渡金属元素的润滑剂组合物
CN1717500A (zh) 可铸造镁合金
CN1084551A (zh) 功能液
CN1108456C (zh) 用于冷冻机的压缩机
CN86101976A (zh) 冷轧制机润滑剂
CN101061206A (zh) 苯并三唑组合物
CN1671828A (zh) 润滑油添加剂,包含这种添加剂的润滑油组合物,以及这种添加剂和组合物的生产方法
CN1589311A (zh) 合成喷气式发动机燃料和柴油机燃料及其制备方法
CN1671826A (zh) 组合物
CN1073200A (zh) 二冲程发动机润滑剂及其使用方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C13 Decision
GR02 Examined patent application
C14 Grant of patent or utility model
GR01 Patent grant
C19 Lapse of patent right due to non-payment of the annual fee
CF01 Termination of patent right due to non-payment of annual fee