CN86101573A - 用于矿物泡沫浮选的新型收集剂 - Google Patents
用于矿物泡沫浮选的新型收集剂 Download PDFInfo
- Publication number
- CN86101573A CN86101573A CN198686101573A CN86101573A CN86101573A CN 86101573 A CN86101573 A CN 86101573A CN 198686101573 A CN198686101573 A CN 198686101573A CN 86101573 A CN86101573 A CN 86101573A CN 86101573 A CN86101573 A CN 86101573A
- Authority
- CN
- China
- Prior art keywords
- alkyl
- flotation
- sulfenyl
- ore
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 229910052500 inorganic mineral Inorganic materials 0.000 title claims abstract description 76
- 239000011707 mineral Substances 0.000 title claims abstract description 76
- 238000009291 froth flotation Methods 0.000 title claims abstract description 21
- 238000005188 flotation Methods 0.000 claims abstract description 93
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 72
- -1 alkyl thioester Chemical class 0.000 claims abstract description 57
- 238000000034 method Methods 0.000 claims abstract description 56
- 239000000203 mixture Substances 0.000 claims abstract description 50
- 239000002253 acid Substances 0.000 claims abstract description 31
- 239000002184 metal Substances 0.000 claims abstract description 28
- 229910052751 metal Inorganic materials 0.000 claims abstract description 27
- 150000003973 alkyl amines Chemical class 0.000 claims abstract description 19
- RYYWUUFWQRZTIU-UHFFFAOYSA-K thiophosphate Chemical compound [O-]P([O-])([O-])=S RYYWUUFWQRZTIU-UHFFFAOYSA-K 0.000 claims abstract description 15
- 239000012991 xanthate Substances 0.000 claims abstract description 9
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 claims abstract description 8
- 125000001931 aliphatic group Chemical group 0.000 claims abstract description 7
- ZOOODBUHSVUZEM-UHFFFAOYSA-N ethoxymethanedithioic acid Chemical compound CCOC(S)=S ZOOODBUHSVUZEM-UHFFFAOYSA-N 0.000 claims abstract description 6
- FCSHMCFRCYZTRQ-UHFFFAOYSA-N N,N'-diphenylthiourea Chemical compound C=1C=CC=CC=1NC(=S)NC1=CC=CC=C1 FCSHMCFRCYZTRQ-UHFFFAOYSA-N 0.000 claims abstract description 5
- 238000011084 recovery Methods 0.000 claims description 35
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 27
- 125000000217 alkyl group Chemical group 0.000 claims description 24
- 150000001875 compounds Chemical class 0.000 claims description 18
- 239000006260 foam Substances 0.000 claims description 18
- HDFRDWFLWVCOGP-UHFFFAOYSA-N carbonothioic O,S-acid Chemical compound OC(S)=O HDFRDWFLWVCOGP-UHFFFAOYSA-N 0.000 claims description 17
- 239000011701 zinc Substances 0.000 claims description 16
- 239000004215 Carbon black (E152) Substances 0.000 claims description 14
- 150000002148 esters Chemical class 0.000 claims description 14
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 14
- 229930195733 hydrocarbon Natural products 0.000 claims description 14
- 239000001257 hydrogen Substances 0.000 claims description 13
- 229910052739 hydrogen Inorganic materials 0.000 claims description 13
- 150000007513 acids Chemical class 0.000 claims description 12
- 125000004646 sulfenyl group Chemical group S(*)* 0.000 claims description 12
- 125000003118 aryl group Chemical group 0.000 claims description 11
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 10
- 229910052725 zinc Inorganic materials 0.000 claims description 10
- 239000011734 sodium Substances 0.000 claims description 9
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 8
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 8
- 229910052976 metal sulfide Inorganic materials 0.000 claims description 8
- 229910052708 sodium Inorganic materials 0.000 claims description 8
- 108010037003 Buserelin Proteins 0.000 claims description 7
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 7
- CUWODFFVMXJOKD-UVLQAERKSA-N buserelin Chemical compound CCNC(=O)[C@@H]1CCCN1C(=O)[C@H](CCCN=C(N)N)NC(=O)[C@H](CC(C)C)NC(=O)[C@@H](COC(C)(C)C)NC(=O)[C@@H](NC(=O)[C@H](CO)NC(=O)[C@H](CC=1C2=CC=CC=C2NC=1)NC(=O)[C@H](CC=1NC=NC=1)NC(=O)[C@H]1NC(=O)CC1)CC1=CC=C(O)C=C1 CUWODFFVMXJOKD-UVLQAERKSA-N 0.000 claims description 7
- 229960002719 buserelin Drugs 0.000 claims description 7
- HIZCIEIDIFGZSS-UHFFFAOYSA-N carbonotrithioic acid Chemical compound SC(S)=S HIZCIEIDIFGZSS-UHFFFAOYSA-N 0.000 claims description 7
- 229910052750 molybdenum Inorganic materials 0.000 claims description 7
- 239000011733 molybdenum Substances 0.000 claims description 7
- 229920006395 saturated elastomer Polymers 0.000 claims description 7
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 6
- 229910052804 chromium Inorganic materials 0.000 claims description 6
- 239000011651 chromium Substances 0.000 claims description 6
- 125000000623 heterocyclic group Chemical class 0.000 claims description 6
- 229910052760 oxygen Inorganic materials 0.000 claims description 6
- 229910052717 sulfur Inorganic materials 0.000 claims description 6
- 229910052984 zinc sulfide Inorganic materials 0.000 claims description 6
- 229910052954 pentlandite Inorganic materials 0.000 claims description 5
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 5
- 125000004916 (C1-C6) alkylcarbonyl group Chemical group 0.000 claims description 4
- 229910052770 Uranium Inorganic materials 0.000 claims description 4
- 125000003545 alkoxy group Chemical group 0.000 claims description 4
- 125000002947 alkylene group Chemical group 0.000 claims description 4
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 4
- 229910052737 gold Inorganic materials 0.000 claims description 4
- 239000010931 gold Substances 0.000 claims description 4
- 150000002431 hydrogen Chemical class 0.000 claims description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 4
- XCAUINMIESBTBL-UHFFFAOYSA-N lead(ii) sulfide Chemical compound [Pb]=S XCAUINMIESBTBL-UHFFFAOYSA-N 0.000 claims description 4
- WGPCGCOKHWGKJJ-UHFFFAOYSA-N sulfanylidenezinc Chemical compound [Zn]=S WGPCGCOKHWGKJJ-UHFFFAOYSA-N 0.000 claims description 4
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 claims description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 3
- 229910052783 alkali metal Inorganic materials 0.000 claims description 3
- 239000002585 base Substances 0.000 claims description 3
- 229910052948 bornite Inorganic materials 0.000 claims description 3
- 229910052951 chalcopyrite Inorganic materials 0.000 claims description 3
- DVRDHUBQLOKMHZ-UHFFFAOYSA-N chalcopyrite Chemical compound [S-2].[S-2].[Fe+2].[Cu+2] DVRDHUBQLOKMHZ-UHFFFAOYSA-N 0.000 claims description 3
- 125000000853 cresyl group Chemical group C1(=CC=C(C=C1)C)* 0.000 claims description 3
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 claims description 3
- 229910052709 silver Inorganic materials 0.000 claims description 3
- 239000004332 silver Substances 0.000 claims description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical group [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
- 229910052785 arsenic Inorganic materials 0.000 claims description 2
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims description 2
- 229910052949 galena Inorganic materials 0.000 claims description 2
- 125000005842 heteroatom Chemical group 0.000 claims description 2
- 229910052698 phosphorus Inorganic materials 0.000 claims description 2
- 229910052697 platinum Inorganic materials 0.000 claims description 2
- 239000011591 potassium Chemical group 0.000 claims description 2
- 229910052700 potassium Chemical group 0.000 claims description 2
- 239000002002 slurry Substances 0.000 claims description 2
- 229910052727 yttrium Inorganic materials 0.000 claims description 2
- 229910019142 PO4 Inorganic materials 0.000 claims 1
- NVIVJPRCKQTWLY-UHFFFAOYSA-N cobalt nickel Chemical compound [Co][Ni][Co] NVIVJPRCKQTWLY-UHFFFAOYSA-N 0.000 claims 1
- 229910052961 molybdenite Inorganic materials 0.000 claims 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 1
- 239000010452 phosphate Substances 0.000 claims 1
- LFGREXWGYUGZLY-UHFFFAOYSA-N phosphoryl Chemical group [P]=O LFGREXWGYUGZLY-UHFFFAOYSA-N 0.000 claims 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims 1
- DNYWZCXLKNTFFI-UHFFFAOYSA-N uranium Chemical compound [U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U] DNYWZCXLKNTFFI-UHFFFAOYSA-N 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
- GUUGRSWKHNNQRI-UHFFFAOYSA-N S(=O)(=O)(O)P(=O)O Chemical compound S(=O)(=O)(O)P(=O)O GUUGRSWKHNNQRI-UHFFFAOYSA-N 0.000 abstract 1
- 235000010755 mineral Nutrition 0.000 description 71
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 44
- 239000010949 copper Substances 0.000 description 42
- 229910052742 iron Inorganic materials 0.000 description 21
- 239000012141 concentrate Substances 0.000 description 17
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 16
- 229910052802 copper Inorganic materials 0.000 description 14
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 13
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 13
- 239000011133 lead Substances 0.000 description 13
- 229910044991 metal oxide Inorganic materials 0.000 description 13
- 239000001103 potassium chloride Substances 0.000 description 13
- 235000011164 potassium chloride Nutrition 0.000 description 13
- 239000000523 sample Substances 0.000 description 13
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 11
- 229910052799 carbon Inorganic materials 0.000 description 11
- 239000007788 liquid Substances 0.000 description 10
- 239000007789 gas Substances 0.000 description 9
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 8
- 125000004432 carbon atom Chemical group C* 0.000 description 8
- 238000002474 experimental method Methods 0.000 description 8
- QWENMOXLTHDKDL-UHFFFAOYSA-N pentoxymethanedithioic acid Chemical compound CCCCCOC(S)=S QWENMOXLTHDKDL-UHFFFAOYSA-N 0.000 description 8
- 239000007787 solid Substances 0.000 description 8
- 238000005987 sulfurization reaction Methods 0.000 description 8
- 239000000463 material Substances 0.000 description 7
- 229910052759 nickel Inorganic materials 0.000 description 7
- 150000001721 carbon Chemical group 0.000 description 6
- NAGJZTKCGNOGPW-UHFFFAOYSA-N dithiophosphoric acid Chemical compound OP(O)(S)=S NAGJZTKCGNOGPW-UHFFFAOYSA-N 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 4
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 4
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 4
- 235000011941 Tilia x europaea Nutrition 0.000 description 4
- 150000001408 amides Chemical class 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 4
- 230000002349 favourable effect Effects 0.000 description 4
- 150000002430 hydrocarbons Chemical class 0.000 description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 4
- 239000004571 lime Substances 0.000 description 4
- 229910052683 pyrite Inorganic materials 0.000 description 4
- NIFIFKQPDTWWGU-UHFFFAOYSA-N pyrite Chemical compound [Fe+2].[S-][S-] NIFIFKQPDTWWGU-UHFFFAOYSA-N 0.000 description 4
- 239000011028 pyrite Substances 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000000725 suspension Substances 0.000 description 4
- KOPMZTKUZCNGFY-UHFFFAOYSA-N 1,1,1-triethoxybutane Chemical compound CCCC(OCC)(OCC)OCC KOPMZTKUZCNGFY-UHFFFAOYSA-N 0.000 description 3
- BRUZQRBVNRKLJG-UHFFFAOYSA-N 2-methylpropyl carbamate Chemical compound CC(C)COC(N)=O BRUZQRBVNRKLJG-UHFFFAOYSA-N 0.000 description 3
- KBRSJPHSCOAFDR-UHFFFAOYSA-N 3-chloro-6-methyl-5,5-dioxo-11h-benzo[c][2,1]benzothiazepin-11-ol Chemical compound O=S1(=O)N(C)C2=CC=CC=C2C(O)C2=CC=C(Cl)C=C21 KBRSJPHSCOAFDR-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 239000005864 Sulphur Substances 0.000 description 3
- 150000001335 aliphatic alkanes Chemical class 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- 125000005907 alkyl ester group Chemical group 0.000 description 3
- 239000004411 aluminium Substances 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 125000003710 aryl alkyl group Chemical group 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 229910017052 cobalt Inorganic materials 0.000 description 3
- 239000010941 cobalt Substances 0.000 description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 3
- 150000001924 cycloalkanes Chemical class 0.000 description 3
- 150000001925 cycloalkenes Chemical class 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 150000004706 metal oxides Chemical class 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 150000002894 organic compounds Chemical class 0.000 description 3
- 125000000962 organic group Chemical group 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 239000005077 polysulfide Substances 0.000 description 3
- 229920001021 polysulfide Polymers 0.000 description 3
- 150000008117 polysulfides Polymers 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical group CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- RMVRSNDYEFQCLF-UHFFFAOYSA-N thiophenol Chemical compound SC1=CC=CC=C1 RMVRSNDYEFQCLF-UHFFFAOYSA-N 0.000 description 3
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 description 3
- WVYWICLMDOOCFB-UHFFFAOYSA-N 4-methyl-2-pentanol Chemical compound CC(C)CC(C)O WVYWICLMDOOCFB-UHFFFAOYSA-N 0.000 description 2
- KDCGOANMDULRCW-UHFFFAOYSA-N 7H-purine Chemical compound N1=CNC2=NC=NC2=C1 KDCGOANMDULRCW-UHFFFAOYSA-N 0.000 description 2
- UJOBWOGCFQCDNV-UHFFFAOYSA-N 9H-carbazole Chemical compound C1=CC=C2C3=CC=CC=C3NC2=C1 UJOBWOGCFQCDNV-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 2
- 244000241257 Cucumis melo Species 0.000 description 2
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 2
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 2
- 229910002555 FeNi Inorganic materials 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 2
- KYQCOXFCLRTKLS-UHFFFAOYSA-N Pyrazine Chemical compound C1=CN=CC=N1 KYQCOXFCLRTKLS-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
- 241000907663 Siproeta stelenes Species 0.000 description 2
- 238000003723 Smelting Methods 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical group OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 2
- DZBUGLKDJFMEHC-UHFFFAOYSA-N acridine Chemical compound C1=CC=CC2=CC3=CC=CC=C3N=C21 DZBUGLKDJFMEHC-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 150000001345 alkine derivatives Chemical class 0.000 description 2
- 125000002877 alkyl aryl group Chemical group 0.000 description 2
- 125000004448 alkyl carbonyl group Chemical group 0.000 description 2
- 125000000304 alkynyl group Chemical group 0.000 description 2
- 150000001412 amines Chemical group 0.000 description 2
- 125000004103 aminoalkyl group Chemical group 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- SKKTUOZKZKCGTB-UHFFFAOYSA-N butyl carbamate Chemical compound CCCCOC(N)=O SKKTUOZKZKCGTB-UHFFFAOYSA-N 0.000 description 2
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 description 2
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- BUGICWZUDIWQRQ-UHFFFAOYSA-N copper iron sulfane Chemical compound S.[Fe].[Cu] BUGICWZUDIWQRQ-UHFFFAOYSA-N 0.000 description 2
- 125000000753 cycloalkyl group Chemical group 0.000 description 2
- 239000012990 dithiocarbamate Substances 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 238000007667 floating Methods 0.000 description 2
- 239000004088 foaming agent Substances 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
- 229910052745 lead Inorganic materials 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N methanol Natural products OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 2
- 239000011859 microparticle Substances 0.000 description 2
- YNTOKMNHRPSGFU-UHFFFAOYSA-N n-Propyl carbamate Chemical compound CCCOC(N)=O YNTOKMNHRPSGFU-UHFFFAOYSA-N 0.000 description 2
- 229920001206 natural gum Polymers 0.000 description 2
- 229910052763 palladium Inorganic materials 0.000 description 2
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 2
- 235000011007 phosphoric acid Nutrition 0.000 description 2
- 239000011297 pine tar Substances 0.000 description 2
- 229940068124 pine tar Drugs 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- 238000010298 pulverizing process Methods 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 125000002813 thiocarbonyl group Chemical group *C(*)=S 0.000 description 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 2
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
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- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910001727 uranium mineral Inorganic materials 0.000 description 1
- 210000003462 vein Anatomy 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 229910000010 zinc carbonate Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/01—Organic compounds containing nitrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/012—Organic compounds containing sulfur
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/014—Organic compounds containing phosphorus
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2201/00—Specified effects produced by the flotation agents
- B03D2201/02—Collectors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2203/00—Specified materials treated by the flotation agents; Specified applications
- B03D2203/02—Ores
Landscapes
- Manufacture And Refinement Of Metals (AREA)
- Investigating Or Analysing Biological Materials (AREA)
- Degasification And Air Bubble Elimination (AREA)
- Saccharide Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US80302685A | 1985-11-29 | 1985-11-29 | |
| US803,026 | 1985-11-29 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN86101573A true CN86101573A (zh) | 1987-06-03 |
Family
ID=25185373
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN198686101573A Pending CN86101573A (zh) | 1985-11-29 | 1986-02-17 | 用于矿物泡沫浮选的新型收集剂 |
Country Status (15)
| Country | Link |
|---|---|
| JP (1) | JPS62129161A (fi) |
| CN (1) | CN86101573A (fi) |
| AU (1) | AU586471B2 (fi) |
| BR (1) | BR8607003A (fi) |
| ES (1) | ES8706047A1 (fi) |
| FI (1) | FI873287A0 (fi) |
| PH (1) | PH24537A (fi) |
| PL (1) | PL147930B1 (fi) |
| RU (1) | RU1837985C (fi) |
| SE (1) | SE8702988L (fi) |
| WO (1) | WO1987003221A1 (fi) |
| YU (1) | YU45765B (fi) |
| ZA (1) | ZA861171B (fi) |
| ZM (1) | ZM1486A1 (fi) |
| ZW (1) | ZW4286A1 (fi) |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5700369A (en) * | 1997-01-14 | 1997-12-23 | Guangzhou Institute Of Geochemistry Chinese Academy Of Sciences | Process for adsorboaggregational flotation of Carlin type natural gold ore dressing |
| CN101337206B (zh) * | 2008-08-13 | 2011-02-02 | 中南大学 | 硫化矿浮选捕收剂及二酰基双硫脲应用方法和制备方法 |
| CN101455996B (zh) * | 2007-12-10 | 2012-04-25 | 北京有色金属研究总院 | 单斜磁黄铁矿与方铅矿浮选分离工艺 |
| CN101549326B (zh) * | 2009-05-15 | 2012-07-04 | 江西理工大学 | 一种难选铜锌硫化矿浮选分离的工艺 |
| CN104624384A (zh) * | 2015-02-02 | 2015-05-20 | 山东建筑大学 | 一种低温型铁矿浮选捕收剂及其制备方法和应用 |
| CN104826742A (zh) * | 2015-05-19 | 2015-08-12 | 烟台恒邦化工助剂有限公司 | 一种硫化矿的复合捕收剂及其制备方法 |
| CN105792942A (zh) * | 2013-10-09 | 2016-07-20 | 佐治亚-太平洋化工品有限公司 | 捕收剂组合物及其制备和应用方法 |
| CN108160336A (zh) * | 2017-12-26 | 2018-06-15 | 中国地质科学院矿产综合利用研究所 | 一种碲铋矿浮选抑制剂及其制备方法和应用 |
| CN109158217A (zh) * | 2018-06-29 | 2019-01-08 | 昆明理工大学 | 一种硫化铜矿的浮选捕收剂 |
| CN111266195A (zh) * | 2020-03-05 | 2020-06-12 | 中南大学 | 一种氧化锌矿浮选组合捕收剂及其应用 |
| CN112657682A (zh) * | 2021-03-16 | 2021-04-16 | 矿冶科技集团有限公司 | 硫化矿浮选捕收剂及其应用和硫化矿浮选方法 |
| CN113262882A (zh) * | 2021-07-21 | 2021-08-17 | 北京矿冶研究总院 | 阳离子捕收剂、制备方法及在磷矿反浮选中的应用 |
| CN113692318A (zh) * | 2019-04-19 | 2021-11-23 | 诺力昂化学品国际有限公司 | 包含n-酰化氨基酸的捕集剂组合物和处理非硫化矿的方法 |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1268565A (en) * | 1985-11-29 | 1990-05-01 | Richard R. Klimpel | Collector compositions for the froth flotation of mineral values |
| EP0298392A3 (de) * | 1987-07-07 | 1991-01-09 | Henkel Kommanditgesellschaft auf Aktien | Verfahren zur Gewinnung von Mineralen aus sulfidischen aus Erzen durch Flotation und Mittel zu seiner Durchführung |
| ZA906138B (en) * | 1989-08-04 | 1991-05-29 | Broken Hill Pty Co Ltd | Ion flotation with non-ionic reagents |
| FR2994534B1 (fr) * | 2012-08-20 | 2015-06-26 | Ceca Sa | Collecteurs pour enrichissement de minerais |
| CN115155824B (zh) * | 2022-07-05 | 2024-01-26 | 中南大学 | 一种从含锡细泥中回收锡的选矿方法 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1833740A (en) * | 1926-03-19 | 1931-11-24 | Peter C Reilly | Process of ore flotation |
| US2011176A (en) * | 1930-03-01 | 1935-08-13 | Minerals Separation North Us | Ore concentration |
| US2070634A (en) * | 1935-07-05 | 1937-02-16 | Du Pont | Xanthic formates |
| US2185591A (en) * | 1938-08-24 | 1940-01-02 | American Cyanamid Co | Dispersible thiocarbanilide |
| US2501269A (en) * | 1946-06-26 | 1950-03-21 | Minerec Corp | Froth flotation of sulfide ores |
| US2691635A (en) * | 1953-05-20 | 1954-10-12 | Dow Chemical Co | Process for the manufacture of dialkyl thionocarbamates |
| US3328442A (en) * | 1963-12-18 | 1967-06-27 | Massachusetts College Of Pharm | Anti-radiation compounds and their preparation |
| US3397238A (en) * | 1965-11-16 | 1968-08-13 | Pfizer & Co C | Process for the preparation of alkyl ethers of amino-alcohols |
| US4086273A (en) * | 1976-04-14 | 1978-04-25 | The Dow Chemical Company | Process for making beta-aminoethyl sulfides from aliphatic mercaptans and 2-oxazolines |
| CA1105156A (en) * | 1978-10-11 | 1981-07-14 | William A. Rickelton | Flotation of sulfide minerals |
| US4326067A (en) * | 1980-12-03 | 1982-04-20 | The Dow Chemical Company | Process for making N-(2-aminoethyl)amides |
| CN85107378A (zh) * | 1984-09-13 | 1987-03-18 | 陶氏化学公司 | 从原煤中回收有用煤的起泡剂组合物和泡沫浮选方法 |
| CA1268565A (en) * | 1985-11-29 | 1990-05-01 | Richard R. Klimpel | Collector compositions for the froth flotation of mineral values |
-
1986
- 1986-02-14 PH PH33416A patent/PH24537A/en unknown
- 1986-02-14 ES ES552034A patent/ES8706047A1/es not_active Expired
- 1986-02-17 ZA ZA861171A patent/ZA861171B/xx unknown
- 1986-02-17 ZW ZW42/86A patent/ZW4286A1/xx unknown
- 1986-02-17 CN CN198686101573A patent/CN86101573A/zh active Pending
- 1986-02-17 YU YU22986A patent/YU45765B/sh unknown
- 1986-02-17 ZM ZM14/86A patent/ZM1486A1/xx unknown
- 1986-02-17 PL PL1986257990A patent/PL147930B1/pl unknown
- 1986-02-18 WO PCT/US1986/000341 patent/WO1987003221A1/en active Application Filing
- 1986-02-18 AU AU54598/86A patent/AU586471B2/en not_active Ceased
- 1986-02-18 BR BR8607003A patent/BR8607003A/pt not_active IP Right Cessation
- 1986-09-03 JP JP61207633A patent/JPS62129161A/ja active Pending
-
1987
- 1987-07-24 RU SU874203123A patent/RU1837985C/ru active
- 1987-07-28 FI FI873287A patent/FI873287A0/fi not_active Application Discontinuation
- 1987-07-28 SE SE8702988A patent/SE8702988L/xx not_active Application Discontinuation
Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5700369A (en) * | 1997-01-14 | 1997-12-23 | Guangzhou Institute Of Geochemistry Chinese Academy Of Sciences | Process for adsorboaggregational flotation of Carlin type natural gold ore dressing |
| CN101455996B (zh) * | 2007-12-10 | 2012-04-25 | 北京有色金属研究总院 | 单斜磁黄铁矿与方铅矿浮选分离工艺 |
| CN101337206B (zh) * | 2008-08-13 | 2011-02-02 | 中南大学 | 硫化矿浮选捕收剂及二酰基双硫脲应用方法和制备方法 |
| CN101549326B (zh) * | 2009-05-15 | 2012-07-04 | 江西理工大学 | 一种难选铜锌硫化矿浮选分离的工艺 |
| CN105792942B (zh) * | 2013-10-09 | 2019-04-16 | 佐治亚-太平洋化工品有限公司 | 捕收剂组合物及其制备和应用方法 |
| CN105792942A (zh) * | 2013-10-09 | 2016-07-20 | 佐治亚-太平洋化工品有限公司 | 捕收剂组合物及其制备和应用方法 |
| CN110180682A (zh) * | 2013-10-09 | 2019-08-30 | 英格维蒂南卡罗来纳有限责任公司 | 捕收剂组合物及其制备和应用方法 |
| CN104624384A (zh) * | 2015-02-02 | 2015-05-20 | 山东建筑大学 | 一种低温型铁矿浮选捕收剂及其制备方法和应用 |
| CN104826742A (zh) * | 2015-05-19 | 2015-08-12 | 烟台恒邦化工助剂有限公司 | 一种硫化矿的复合捕收剂及其制备方法 |
| CN104826742B (zh) * | 2015-05-19 | 2016-12-07 | 烟台恒邦化工助剂有限公司 | 一种硫化矿的复合捕收剂及其制备方法 |
| CN108160336A (zh) * | 2017-12-26 | 2018-06-15 | 中国地质科学院矿产综合利用研究所 | 一种碲铋矿浮选抑制剂及其制备方法和应用 |
| CN109158217A (zh) * | 2018-06-29 | 2019-01-08 | 昆明理工大学 | 一种硫化铜矿的浮选捕收剂 |
| CN113692318A (zh) * | 2019-04-19 | 2021-11-23 | 诺力昂化学品国际有限公司 | 包含n-酰化氨基酸的捕集剂组合物和处理非硫化矿的方法 |
| CN111266195A (zh) * | 2020-03-05 | 2020-06-12 | 中南大学 | 一种氧化锌矿浮选组合捕收剂及其应用 |
| CN112657682A (zh) * | 2021-03-16 | 2021-04-16 | 矿冶科技集团有限公司 | 硫化矿浮选捕收剂及其应用和硫化矿浮选方法 |
| CN112657682B (zh) * | 2021-03-16 | 2021-07-09 | 矿冶科技集团有限公司 | 硫化矿浮选捕收剂及其应用和硫化矿浮选方法 |
| CN113262882A (zh) * | 2021-07-21 | 2021-08-17 | 北京矿冶研究总院 | 阳离子捕收剂、制备方法及在磷矿反浮选中的应用 |
| CN113262882B (zh) * | 2021-07-21 | 2021-09-17 | 北京矿冶研究总院 | 阳离子捕收剂、制备方法及在磷矿反浮选中的应用 |
Also Published As
| Publication number | Publication date |
|---|---|
| SE8702988D0 (sv) | 1987-07-28 |
| YU45765B (sh) | 1992-07-20 |
| PL147930B1 (en) | 1989-08-31 |
| BR8607003A (pt) | 1987-12-01 |
| PH24537A (en) | 1990-08-03 |
| AU5459886A (en) | 1987-07-01 |
| ZM1486A1 (en) | 1988-01-29 |
| ES552034A0 (es) | 1987-06-01 |
| RU1837985C (ru) | 1993-08-30 |
| YU22986A (en) | 1988-06-30 |
| ZA861171B (en) | 1987-10-28 |
| PL257990A1 (en) | 1987-06-15 |
| FI873287A (fi) | 1987-07-28 |
| ZW4286A1 (en) | 1987-09-09 |
| SE8702988L (sv) | 1987-07-28 |
| JPS62129161A (ja) | 1987-06-11 |
| AU586471B2 (en) | 1989-07-13 |
| ES8706047A1 (es) | 1987-06-01 |
| FI873287A0 (fi) | 1987-07-28 |
| WO1987003221A1 (en) | 1987-06-04 |
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Legal Events
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| C06 | Publication | ||
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| SE01 | Entry into force of request for substantive examination | ||
| C01 | Deemed withdrawal of patent application (patent law 1993) | ||
| WD01 | Invention patent application deemed withdrawn after publication |