CN85109088A - The manufacture method of thin-film transistor - Google Patents

The manufacture method of thin-film transistor Download PDF

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Publication number
CN85109088A
CN85109088A CN198585109088A CN85109088A CN85109088A CN 85109088 A CN85109088 A CN 85109088A CN 198585109088 A CN198585109088 A CN 198585109088A CN 85109088 A CN85109088 A CN 85109088A CN 85109088 A CN85109088 A CN 85109088A
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film
amorphous semiconductor
semiconductor films
deck
drain region
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CN198585109088A
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林久雄
野口隆
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Sony Corp
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Sony Corp
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/30Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
    • H01L21/302Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to change their surface-physical characteristics or shape, e.g. etching, polishing, cutting
    • H01L21/306Chemical or electrical treatment, e.g. electrolytic etching
    • H01L21/308Chemical or electrical treatment, e.g. electrolytic etching using masks
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/68Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
    • H01L29/76Unipolar devices, e.g. field effect transistors
    • H01L29/772Field effect transistors
    • H01L29/78Field effect transistors with field effect produced by an insulated gate
    • H01L29/786Thin film transistors, i.e. transistors with a channel being at least partly a thin film
    • H01L29/78606Thin film transistors, i.e. transistors with a channel being at least partly a thin film with supplementary region or layer in the thin film or in the insulated bulk substrate supporting it for controlling or increasing the safety of the device
    • H01L29/78618Thin film transistors, i.e. transistors with a channel being at least partly a thin film with supplementary region or layer in the thin film or in the insulated bulk substrate supporting it for controlling or increasing the safety of the device characterised by the drain or the source properties, e.g. the doping structure, the composition, the sectional shape or the contact structure
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/68Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
    • H01L29/76Unipolar devices, e.g. field effect transistors
    • H01L29/772Field effect transistors
    • H01L29/78Field effect transistors with field effect produced by an insulated gate
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/68Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
    • H01L29/76Unipolar devices, e.g. field effect transistors
    • H01L29/772Field effect transistors
    • H01L29/78Field effect transistors with field effect produced by an insulated gate
    • H01L29/786Thin film transistors, i.e. transistors with a channel being at least partly a thin film
    • H01L29/78651Silicon transistors
    • H01L29/7866Non-monocrystalline silicon transistors
    • H01L29/78672Polycrystalline or microcrystalline silicon transistor
    • H01L29/78675Polycrystalline or microcrystalline silicon transistor with normal-type structure, e.g. with top gate

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  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Ceramic Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Thin Film Transistor (AREA)
  • Recrystallisation Techniques (AREA)

Abstract

Thin-film transistor manufacture method: on anti-fixed substrate, form one deck polycrystalline semiconductor thin film; Predetermined ion is injected polycrystalline semiconductor thin film, to form one deck amorphous semiconductor films; On amorphous semiconductor films, form an one deck grid insulating film and a gate electrode; Utilize gate electrode and gate insulating film to mix, so that in amorphous semiconductor films, form source region and drain region as mask; Anneal to realize the solid state growth of amorphous semiconductor films, the impurity electricity is activated, to form source region and drain region.Said method can impel the annealing process of the solid state growth of amorphous semiconductor films, needn't separate with the annealing process that impels the impurity electricity to activate to form source region and drain region.

Description

The manufacture method of thin-film transistor
The present invention relates to the manufacture method of thin-film transistor (TFT), particularly be suitable for the manufacture method of polycrystalline SiTFT.
Polycrystalline SiTFT adopts the low temperature process manufacturing usually.As scheme shown in the IA, adopt low-pressure chemical vapor deposition method (LPCVD method), under 600 ℃ or lower temperature, polysilicon film 2 is deposited on the glass substrate 1.The fusing point of glass substrate is approximately 680 ℃ for instance.With Si +In the ion implanted polysilicon film 2 of the inactive element of this class electrical property, to form the amorphous silicon film 3 shown in Figure 1B.Resulting structure is annealed 500 ℃ to 600 ℃ temperature, makes amorphous silicon film 3 solid state growths, so amorphous silicon film 3 produces crystallization.The result forms the polysilicon film 4 shown in Fig. 1 C, and its crystallite dimension (not shown) is bigger than the crystallite dimension of polysilicon film 2.Shown in Fig. 1 D, the predetermined position of polysilicon film 4 is corroded, thereby obtain predetermined figure.Adopt process for chemical vapor deposition of materials with via, under about 400 ℃ temperature, on resulting structure, deposit one deck (SiO 2) (silicon dioxide) film 5, make it cover whole surface.Subsequently, at SiO 2Sputter last layer M on the film 5 0The film 6 of (molybdenum) class.To M 0Film 6 and SiO 2The predetermined position of film 5 corrodes in succession, thereby forms the M with predetermined pattern 0Gate electrode 7 and by SiO 2The gate insulating film 8 that figure is formed, SiO 2The figure of dielectric film and M 0Gate electrode figure is identical.Subsequently, adopt ion implantation, make mask, will inject polysilicon film 4 (representing the phosphonium ion of polysilicon film 4 at Fig. 1 E with circle) with high concentration such as the n type impurity of phosphorus (P) with gate electrode 7 and gate insulating film 8.Resulting structure is annealed in about 600 ℃ temperature, so that the impurity electricity is activated, the result forms the n shown in Fig. 1 F +Type source (district and drain region 9 and 10.Shown in Fig. 1 G, adopt process for chemical vapor deposition of materials with via, under about 400 ℃ of temperature, deposition one deck SiO 2 Film 11 is as passivating film, to cover whole surface.At last, to SiO 2The predetermined position of film 11 corrodes, and makes it form fairlead 11a and 11b.Al deposition is corroded at whole surperficial Shang , And,, make n type raceway groove polycrystalline SiTFT with this so that in fairlead 11a and 11b, form electrode 12 and 13.
The conventional method that adopts low temperature process to make polycrystalline SiTFT has following shortcoming.Impel the annealing process of the solid state growth of amorphous silicon film 3, must separate with the annealing process that impels the impurity electricity to activate, thereby make complex manufacturing processization to form source region and drain region 9 and 10.In addition, although there is the impurity that part ion injects at the crystal boundary place in polysilicon film 4, this part impurity that is positioned at the crystal boundary place is difficult to be activated by electricity by annealing process.Therefore, total activation efficiency of impurity is lower.Along with foreign ion injects polysilicon film 4, channelling can take place in dopant ion to a certain extent inevitably.Therefore, in annealing process subsequently, the impurity in source region and drain region 9 and 10 just can not be activated equably.
The prior art of thin-film transistor is illustrated in Japanese Applied Physics association the 45th lecture collected works (1984), and 14P-A-4 to 14P-A-6 number, the 407th to the 408th page.This piece list of references has been narrated owing to adopting ultra-thin polysilicon film technology to make the improvement of the polycrystalline SiTFT that transistor characteristic improved; Owing to adopt thermal oxidation technology, the improvement aspect solid-phase grain growth result and ultra-thin polysilicon film conductive characteristic; And adopt following technical process and the improvement of the transistor characteristic that obtains.This technical process is: form one deck Si with the plasma chemical vapor deposition method on ultra-thin polycrystalline SiTFT earlier 3N 4, then with the structure that obtains under 400 ℃ of temperature in hydrogen annealing.
The purpose of this invention is to provide a kind of method of making thin-film transistor, the method can be eliminated the shortcoming of above-mentioned conventional thin-film transistor.
In order to reach above-mentioned purpose of the present invention, the spy provides the method for making thin-film transistor as follows: form one deck polycrystalline semiconductor thin film on a substrate of being scheduled to; Predetermined ion is injected polycrystalline semiconductor thin film, to form one deck amorphous semiconductor films; On amorphous semiconductor films, form an one deck gate insulating film and a gate electrode; Utilize gate electrode and gate insulating film to mix, so that in amorphous semiconductor films, form source region and drain region as mask; Anneal,, simultaneously, the impurity electricity is activated, form source region and drain region to realize the solid state growth of amorphous semiconductor films.
By means of said method, impel the annealing process of amorphous semiconductor films solid state growth, needn't separate with the annealing process that impels the impurity electricity to activate to form source region and drain region.Therefore manufacturing process simplified.In addition, compare with the transistor of routine, the impurity in source region and drain region can be activated equably.
Figure 1A to 1G adopts traditional low temperature process to make the step cutaway view of conventional polycrystalline SiTFT in order to explanation.
Fig. 2 A to 2C adopts the cutaway view of making n raceway groove polycrystalline SiTFT step according to the method for embodiments of the invention making thin-film transistor in order to explanation.
Most preferred embodiment
Make the embodiment of thin-film transistor method as the present invention, special is example to make polycrystalline SiTFT, is illustrated with reference to accompanying drawing.In 2A to Fig. 2 C, all meet with Figure 1A to 1G in identical reference number, all represent identical part, no longer give a detailed account below.
Adopt the low-pressure chemical vapor deposition method, in about 580 ℃ to 600 ℃ temperature range, deposition one layer thickness for example is 800 on glass substrate 1 , the polysilicon film 2 same with Figure 1A.
With the 40Kev(kilo electron volt) acceleration energy be 1 * 10 with dosage 15/ (centimetre) 2To 5 * 10 15/ (centimetre) 2Si +In the ion implanted polysilicon film 2, thereby form and the same amorphous silicon film 3 of Figure 1B.
Shown in Fig. 2 A, with the predetermined position corrosion of amorphous silicon film 3, with the figure that obtains to be scheduled to.Depositing a layer thickness with the low-pressure chemical vapor deposition method on whole exposed surface more for example is 1000
Figure 85109088_IMG2
, the SiO same with Fig. 1 D 2Film 5.At SiO 2Surface one layer thickness of film 5 for example is 3000
Figure 85109088_IMG3
M 0Film 6.
Shown in Fig. 2 B, M 0Film 6 and SiO 2The predetermined position of film 5 is corroded in succession, to form and same gate electrode 7 and the gate insulating film 8 of Fig. 1 E.After this, make mask with gate electrode 7 and gate insulating film 8, with P +Ion injects amorphous silicon film 3 (phosphonium ion of representing amorphous silicon film 3 at Fig. 2 B with circle).
Annealing in process is to carry out under about 600 ℃ temperature, makes amorphous silicon film 3 solid state growths, to form the polysilicon film 4 of one deck shown in Fig. 2 C.Simultaneously, the phosphonium ion electricity of doping is activated, to form n +Type source region and drain region 9 and 10.Form SiO then as passivating film 2Film 11 and electrode 12 and 13 are with the such n raceway groove polycrystalline SiTFT of preparation image pattern 1G.
According to the embodiment of introducing above as can be known, the solid state growth of amorphous silicon film 3 and the activation of impurity to form the process of source region and drain region 9 and 10, can realize in single annealing process.Therefore, compare, can save a step annealing technology, thereby simplify manufacturing process with the conventional method of Figure 1A to 1G.In above-mentioned annealing process, the activation of the solid state growth of amorphous silicon film 3 and the impurity of injection is carried out simultaneously.Therefore, compare with the transistor of routine, the impurity in source region and drain region 9 and 10 can be activated equably.
In above-mentioned annealing process, along with the solid state growth of amorphous silicon film 3, the phosphonium ion doped region that nucleus trends towards in film 3 forms.These nucleus grow into some small crystalss earlier, grow up to some big crystal grain then, therefore, compare with the transistor of routine, and the crystallite dimension in source region and drain region 9 and 10 has increased.So, because grain boundary area reduced than conventional transistor, so the degree that impurity will reduce along with grain boundary area and more effectively being activated.Utilize small crystals as seed crystal, crystal growth will be carried out along the direction on the surface that is parallel to amorphous silicon film 3.Utilize the above-mentioned solid phase growing method, at channel region 4a(Fig. 2 C) in the crystallite dimension of resulting polysilicon film 4, than in conventional transistor, being big.When thin-film transistor is worked, in channel region, will form raceway groove.Therefore, carrier mobility has been improved in the more conventional thin-film transistor of carrier mobility of the thin-film transistor of making of the present embodiment.
In the above-described embodiments, owing to adopt ion implantation that the impurity injection is occurred in Si to form source region and drain region 9 and 10 these processes +Ion implanted polysilicon film 2 is with after formation amorphous silicon film 3 these processes, and therefore, the channelling of the impurity of injection can not take place basically.Vertically distribute according to the impurity that is injected in the prepared thin-film transistor of present embodiment, than in conventional thin-film transistor, just being even.So, the impurity in source region and drain region 9 and 10, comparable being activated more equably in conventional thin-film transistor.
Introduced certain embodiments of the present invention above, but this invention is not limited to this example.Within spirit of the present invention and scope, various changes can be made and modification.For example, can use such as F +The ion of such electrical property inert element replaces Si +Make source ion implantation, polysilicon film 2 is transformed into amorphous film.Form the source ion implantation of source region and drain region 9 and 10, also be not only limited to P +, also can extend to the ion of other elements as required.Moreover the material of gate electrode 7 removes M 0Outside, also adopt tungsten such as W() such refractory metal, or refractory metal silicide.Polysilicon film 2 can replace with other polycrystalline semiconductor thin films.Polysilicon film 2 can replace the low-pressure chemical vapor deposition method to form such as glow discharge decomposition method (plasma CVD method) with other.Use glow discharge decomposition method, polysilicon film 2 can form under about 200 ℃ or lower temperature.

Claims (5)

1, a kind of method of making thin-film transistor is characterized in that: on a substrate of being scheduled to, form one deck polycrystalline semiconductor thin film; Predetermined ion is injected said polycrystalline semiconductor thin film, to form one deck amorphous semiconductor films; On said amorphous semiconductor films, form an one deck gate insulating film and a gate electrode; Utilize said gate electrode and gate insulating film to make mask, mix, so that in said amorphous semiconductor films, form source region and drain region; Anneal to realize the solid of said amorphous semiconductor films, the impurity electricity is activated, to form said source region and drain region to growth.
2, according to the method for claim 1, it is characterized in that: said polycrystalline semiconductor thin film comprises polysilicon film.
3, according to the method for claim 2, it is characterized in that: ion comprises that dosage is 1 * 10 15/ (centimetre) 2To 5 * 10 15/ (centimetre) 2Si +Ion.
4, according to the method for claim 2 or 3, it is characterized in that: said polysilicon film forms when substrate temperature is 580 ℃ to 600 ℃ with the low-pressure chemical vapor deposition method.
5, according to claim 1,2,3 or 4 method is characterized in that: said predetermined substrate comprises glass substrate.
CN198585109088A 1984-11-15 1985-11-15 The manufacture method of thin-film transistor Pending CN85109088A (en)

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JP59241239A JPH0824184B2 (en) 1984-11-15 1984-11-15 Method for manufacturing thin film transistor
JP241239/84 1984-11-15

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KR (1) KR930010978B1 (en)
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FR (1) FR2573248B1 (en)
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NL (1) NL194524C (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1293641C (en) * 1992-12-09 2007-01-03 株式会社半导体能源研究所 Electronic circuit
CN100461348C (en) * 2004-07-21 2009-02-11 三星电子株式会社 Silicon-based material layer, forming method, structure, device, emitter and display incorporating the silicon-based material layer
CN100559246C (en) * 1992-05-29 2009-11-11 株式会社半导体能源研究所 Active matrix liquid crystal display apparatus
CN104409635A (en) * 2014-12-16 2015-03-11 京东方科技集团股份有限公司 Organic thin film transistor and manufacturing method thereof, array substrate, and display unit

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5242507A (en) * 1989-04-05 1993-09-07 Boston University Impurity-induced seeding of polycrystalline semiconductors
US5242858A (en) * 1990-09-07 1993-09-07 Canon Kabushiki Kaisha Process for preparing semiconductor device by use of a flattening agent and diffusion
US5403756A (en) * 1991-11-20 1995-04-04 Sharp Kabushiki Kaisha Method of producing a polycrystalline semiconductor film without annealing, for thin film transistor
KR950003235B1 (en) * 1991-12-30 1995-04-06 주식회사 금성사 Semiconductor device structure
US5985741A (en) 1993-02-15 1999-11-16 Semiconductor Energy Laboratory Co., Ltd. Semiconductor device and method of fabricating the same

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US4177084A (en) * 1978-06-09 1979-12-04 Hewlett-Packard Company Method for producing a low defect layer of silicon-on-sapphire wafer
JPS558026A (en) * 1978-06-30 1980-01-21 Matsushita Electric Ind Co Ltd Semi-conductor device manufacturing method
JPS5856409A (en) * 1981-09-30 1983-04-04 Toshiba Corp Production of semiconductor device
JPS59165451A (en) * 1983-03-11 1984-09-18 Toshiba Corp Manufacture of semiconductor device
JPS61191070A (en) * 1985-02-20 1986-08-25 Toshiba Corp Manufacture of semiconductor device

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100559246C (en) * 1992-05-29 2009-11-11 株式会社半导体能源研究所 Active matrix liquid crystal display apparatus
CN1293641C (en) * 1992-12-09 2007-01-03 株式会社半导体能源研究所 Electronic circuit
CN100461348C (en) * 2004-07-21 2009-02-11 三星电子株式会社 Silicon-based material layer, forming method, structure, device, emitter and display incorporating the silicon-based material layer
CN104409635A (en) * 2014-12-16 2015-03-11 京东方科技集团股份有限公司 Organic thin film transistor and manufacturing method thereof, array substrate, and display unit
CN104409635B (en) * 2014-12-16 2017-02-22 京东方科技集团股份有限公司 Organic thin film transistor and manufacturing method thereof, array substrate, and display unit
US9728723B2 (en) 2014-12-16 2017-08-08 Boe Technology Group Co., Ltd. Organic thin film transistor and manufacturing method thereof, array substrate
US10050200B2 (en) 2014-12-16 2018-08-14 Boe Technology Group Co., Ltd. Organic thin film transistor and manufacturing method thereof, array substrate

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GB2167899B (en) 1988-04-27
NL8503123A (en) 1986-06-02
JPH0824184B2 (en) 1996-03-06
FR2573248A1 (en) 1986-05-16
FR2573248B1 (en) 1991-06-21
NL194524C (en) 2002-06-04
JPS61119079A (en) 1986-06-06
KR860004455A (en) 1986-06-23
GB2167899A (en) 1986-06-04
KR930010978B1 (en) 1993-11-18
NL194524B (en) 2002-02-01
DE3540452C2 (en) 1999-07-29
DE3540452A1 (en) 1986-06-05
GB8527737D0 (en) 1985-12-18

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