CN1982320A - 有机钼化合物的制备方法 - Google Patents
有机钼化合物的制备方法 Download PDFInfo
- Publication number
- CN1982320A CN1982320A CNA2006101397979A CN200610139797A CN1982320A CN 1982320 A CN1982320 A CN 1982320A CN A2006101397979 A CNA2006101397979 A CN A2006101397979A CN 200610139797 A CN200610139797 A CN 200610139797A CN 1982320 A CN1982320 A CN 1982320A
- Authority
- CN
- China
- Prior art keywords
- reaction
- ammonia
- molybdenum
- ammonium molybdate
- general formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 60
- 239000005078 molybdenum compound Substances 0.000 title description 2
- 150000002752 molybdenum compounds Chemical class 0.000 title description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 64
- 238000006243 chemical reaction Methods 0.000 claims abstract description 43
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 35
- 239000011733 molybdenum Substances 0.000 claims abstract description 33
- 229910021529 ammonia Inorganic materials 0.000 claims abstract description 32
- 229940010552 ammonium molybdate Drugs 0.000 claims abstract description 29
- 235000018660 ammonium molybdate Nutrition 0.000 claims abstract description 29
- 239000011609 ammonium molybdate Substances 0.000 claims abstract description 29
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims abstract description 27
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 claims abstract description 27
- 239000003153 chemical reaction reagent Substances 0.000 claims abstract description 17
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 claims abstract description 11
- 150000001875 compounds Chemical class 0.000 claims abstract description 9
- VLAPMBHFAWRUQP-UHFFFAOYSA-L molybdic acid Chemical compound O[Mo](O)(=O)=O VLAPMBHFAWRUQP-UHFFFAOYSA-L 0.000 claims abstract description 8
- 239000000126 substance Substances 0.000 claims description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 15
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 13
- 238000001914 filtration Methods 0.000 claims description 10
- -1 polypropylene Polymers 0.000 claims description 8
- 229920002367 Polyisobutene Polymers 0.000 claims description 5
- 239000004743 Polypropylene Substances 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 5
- 229920013639 polyalphaolefin Polymers 0.000 claims description 5
- 229920001083 polybutene Polymers 0.000 claims description 5
- 229920001155 polypropylene Polymers 0.000 claims description 5
- 150000003973 alkyl amines Chemical class 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 239000012752 auxiliary agent Substances 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 229910052717 sulfur Inorganic materials 0.000 claims description 4
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 3
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 3
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 3
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 3
- 239000005642 Oleic acid Substances 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 125000003118 aryl group Chemical group 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 3
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 3
- 239000003784 tall oil Substances 0.000 claims description 3
- 125000004416 alkarylalkyl group Chemical group 0.000 claims description 2
- 239000010685 fatty oil Substances 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 2
- 150000002632 lipids Chemical class 0.000 claims description 2
- 125000002769 thiazolinyl group Chemical group 0.000 claims description 2
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 claims description 2
- 239000002994 raw material Substances 0.000 claims 5
- 125000004432 carbon atom Chemical group C* 0.000 claims 2
- 229910000476 molybdenum oxide Inorganic materials 0.000 claims 2
- OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 claims 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
- 150000002461 imidazolidines Chemical class 0.000 claims 1
- 229960004232 linoleic acid Drugs 0.000 claims 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims 1
- 238000002360 preparation method Methods 0.000 abstract description 6
- 230000008569 process Effects 0.000 abstract description 6
- 238000011065 in-situ storage Methods 0.000 abstract 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 51
- 239000000047 product Substances 0.000 description 20
- 239000003921 oil Substances 0.000 description 10
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 description 8
- 230000008901 benefit Effects 0.000 description 7
- 239000000376 reactant Substances 0.000 description 6
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- 150000001408 amides Chemical class 0.000 description 4
- 125000003827 glycol group Chemical group 0.000 description 4
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 235000011114 ammonium hydroxide Nutrition 0.000 description 3
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 3
- 239000000706 filtrate Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 230000035484 reaction time Effects 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 238000010923 batch production Methods 0.000 description 2
- 238000006471 dimerization reaction Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 238000005227 gel permeation chromatography Methods 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 125000001477 organic nitrogen group Chemical group 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 230000004044 response Effects 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 125000005208 trialkylammonium group Chemical group 0.000 description 2
- BCHZICNRHXRCHY-UHFFFAOYSA-N 2h-oxazine Chemical compound N1OC=CC=C1 BCHZICNRHXRCHY-UHFFFAOYSA-N 0.000 description 1
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- AOMUHOFOVNGZAN-UHFFFAOYSA-N N,N-bis(2-hydroxyethyl)dodecanamide Chemical compound CCCCCCCCCCCC(=O)N(CCO)CCO AOMUHOFOVNGZAN-UHFFFAOYSA-N 0.000 description 1
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 238000004176 ammonification Methods 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 208000012839 conversion disease Diseases 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 150000002193 fatty amides Chemical class 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000012074 organic phase Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 230000002277 temperature effect Effects 0.000 description 1
- 230000001550 time effect Effects 0.000 description 1
- 230000001131 transforming effect Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 125000005270 trialkylamine group Chemical group 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F11/00—Compounds containing elements of Groups 6 or 16 of the Periodic Table
- C07F11/005—Compounds containing elements of Groups 6 or 16 of the Periodic Table compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
- C10M2227/06—Organic compounds derived from inorganic acids or metal salts
- C10M2227/066—Organic compounds derived from inorganic acids or metal salts derived from Mo or W
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
Description
批 | H2O(g) | MoO3(g) | NH3(g) | 试剂(g) | NH3∶Mo(摩尔) | G油 | 产物(g) | IR | 己烷不溶物% | Mo% | N% | 沉淀物% |
RD-1-59RD-1-61RD-1-63RD-1-65RD-1-66RD-1-68RD-1-69RD-1-70RD-1-71RD-1-72RD-1-73RD-1-74RD-1-75RD-1-76RD-1-77RD-1-78RD-1-79RD-1-80RD-1-81RD-1-82RD-1-83RD-1-84DG-1-62DG-1-64DG-1-66DG-1-70DG-1-71DG-1-74DG-1-75DG-1-77DG-1-78 | 167.1167.1167.1167.1163.0154.8146.1136.5154.0118.4102.888.783.173.062.962.464.064.062.462.962.968.710566.766.7133.4133.4133.4133.4133.4p133.4 | 68.868.868.868.870.771.070.970.384.469.470.072.073.071.670.870.272.072.075.275.875.877.3118.280.580.5161161161161161161 | 81.581.581.581.583.784.184.083.2100.082.282.985.377.976.471.362.464.064.062.462.962.964.0810566.766.7133.4133.4133.4133.4133.4133.4 | 5505505505505505505505506625505505505505505505505506550455025505505508605500550011300110001004090001100011000 | 2.942.942.942.942.942.942.942.942.942.942.942.942.652.652.502.212.212.212.062.062.062.062.212.062.062.062.062.062.062.062.06 | 40404040404040404040404040414040404045454060404996969494 | 629724623630652650630602617641640610579987604615118213011066106912781226 | 0.130.130.150.250.210.170.120.080.070.150.10.060.10.210.130.40.060.150.150.130.080.250.0940.460.270.120.4910.470.160.13 | 0.040.040.040.050.090.040.030.030.040.040.030.040.050.000.030.030.020.010.030.070.150.070.050.040.110.040.0250.037 | 7.47.37.37.37.57.57.57.687.47.77.57.57.57.57.57.77.77.87.58.17.97.88.287.98.19.19.88.18.4 | 3.43.4332.7333.13.332.72.73.23.23.43.53.23.23.13.33.53.33.63.42.733.23.33.32.83.1 | 0.10.0750.10.10.150.150.150.150.150.250.250.40.50.0250.150.10.250.050.30.350.350.10.30.30.30.075<0.050.50.650.30.15 |
现有技术美国专利第5,412,130号 | 本发明 |
基本由椰油二乙醇酰胺和椰油甘油一酯组成的椰油二乙醇胺反应产物 | 314.6g | 900g |
来源于50∶50的油酸∶亚油酸的1-(2-羟乙基)-2-咪唑啉 | 27.4g | 0g |
三氧化钼 | 49.9g | 161g |
水 | 63.4g | 133.4g |
含29.4%氨的氨水 | 0 | 133.4g |
7小时@80C;己烷不溶物结果 | 0.25% | 无需预反应 |
9小时@80C;己烷不溶物结果 | 0.07% | 无需预反应 |
1.5小时真空汽提@90C | 25至35分钟真空汽提@90C | |
2小时真空汽提@135C | 20至30分钟真空汽提@148C | |
最终的己烷不溶物 | <0.10 | 0.04 |
钼% | 8.6%Mo | 9.6%Mo |
总反应时间 | 12.5小时 | 1小时 |
Claims (18)
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US72026005P | 2005-09-23 | 2005-09-23 | |
US60/720,260 | 2005-09-23 | ||
US11/385,291 | 2006-03-21 | ||
US11/385,291 US7205423B1 (en) | 2005-09-23 | 2006-03-21 | Process for the preparation of organo-molybdenum compounds |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1982320A true CN1982320A (zh) | 2007-06-20 |
CN1982320B CN1982320B (zh) | 2012-03-21 |
Family
ID=37087743
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2006101397979A Active CN1982320B (zh) | 2005-09-23 | 2006-09-25 | 有机钼化合物的制备方法 |
Country Status (10)
Country | Link |
---|---|
US (1) | US7205423B1 (zh) |
EP (1) | EP1770153B1 (zh) |
JP (1) | JP4812580B2 (zh) |
CN (1) | CN1982320B (zh) |
AT (1) | ATE419322T1 (zh) |
DE (1) | DE602006004523D1 (zh) |
ES (1) | ES2320692T3 (zh) |
PL (1) | PL1770153T3 (zh) |
SI (1) | SI1770153T1 (zh) |
WO (1) | WO2007038086A2 (zh) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101674974B (zh) * | 2007-03-06 | 2013-01-30 | R.T.范德比尔特公司 | 钼化合物 |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2961823B1 (fr) | 2010-06-25 | 2013-06-14 | Total Raffinage Marketing | Compositions lubrifiantes pour transmissions automobiles |
US9222050B1 (en) | 2012-02-29 | 2015-12-29 | Rand Innovations, Llc | Lubricant composition, method of preparing the same, and firearm cleaner including the same |
US9228151B1 (en) | 2012-11-07 | 2016-01-05 | Rand Innovations, Llc | Lubricant additive composition, lubricant, and method of preparing the same |
FR3014898B1 (fr) | 2013-12-17 | 2016-01-29 | Total Marketing Services | Composition lubrifiante a base de triamines grasses |
CN104844656A (zh) * | 2015-03-24 | 2015-08-19 | 上海交通大学 | 一种非硫磷有机钼化合物及其制备方法和应用 |
KR101878913B1 (ko) * | 2015-04-28 | 2018-07-16 | (주)포스코엠텍 | 몰리브덴 정광으로부터 삼산화몰리브덴의 제조방법 |
US9534186B1 (en) | 2015-06-17 | 2017-01-03 | Chevron Oronite Company Llc | Multifunctional molybdenum containing compounds, method of making and using, and lubricating oil compositions containing same |
FR3039165B1 (fr) | 2015-07-23 | 2018-11-30 | Total Marketing Services | Composition lubrifiante a fuel eco longue duree |
FR3039836B1 (fr) | 2015-08-06 | 2017-09-15 | Total Marketing Services | Compositions lubrifiantes pour prevenir ou diminuer le pre-allumage dans un moteur |
FR3048433B1 (fr) | 2016-03-03 | 2020-03-13 | Total Marketing Services | Composition lubrifiante a base d'amines neutralisees et de molybdene |
FR3065007B1 (fr) | 2017-04-11 | 2019-07-05 | Total Marketing Services | Composition lubrifiante notamment pour limiter le frottement |
CN107384513A (zh) * | 2017-07-26 | 2017-11-24 | 山东源根石油化工有限公司 | 一种环保型减摩抗氧非硫磷有机钨添加剂以及含有该添加剂的润滑油 |
FR3091874A1 (fr) | 2019-01-22 | 2020-07-24 | Total Marketing Services | Complexe dinucléaire de molybdène et son utilisation dans des compositions lubrifiantes |
FR3108914B1 (fr) | 2020-04-01 | 2022-07-01 | Total Marketing Services | Composition lubrifiante comprenant un composé 2,5-dimercapto-1,3,4-thiadiazole alkyl polycarboxylate |
CN112961721B (zh) * | 2020-12-30 | 2022-09-20 | 徐州振峰新材料科技有限公司 | 一种润滑油用含石墨烯的润滑防护添加剂 |
FR3118630B1 (fr) | 2021-01-06 | 2024-04-19 | Total Marketing Services | Composition lubrifiante ayant une stabilité à froid et des propriétés fuel eco améliorées |
FR3126711A1 (fr) | 2021-09-03 | 2023-03-10 | Totalenergies Marketing Services | Composition lubrifiante présentant des propriétés d’épaississement à froid améliorées |
FR3135465A1 (fr) | 2022-05-11 | 2023-11-17 | Totalenergies Onetech | Composition lubrifiante présentant une stabilité d’émulsion améliorée |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3285942A (en) * | 1962-03-06 | 1966-11-15 | Exxon Research Engineering Co | Preparation of glycol molybdate complexes |
US4164473A (en) * | 1977-10-20 | 1979-08-14 | Exxon Research & Engineering Co. | Organo molybdenum friction reducing antiwear additives |
US4889647A (en) * | 1985-11-14 | 1989-12-26 | R. T. Vanderbilt Company, Inc. | Organic molybdenum complexes |
US5137647A (en) * | 1991-12-09 | 1992-08-11 | R. T. Vanderbilt Company, Inc. | Organic molybdenum complexes |
US5412130A (en) * | 1994-06-08 | 1995-05-02 | R. T. Vanderbilt Company, Inc. | Method for preparation of organic molybdenum compounds |
AU755638B2 (en) * | 1999-03-15 | 2002-12-19 | Shell Internationale Research Maatschappij B.V. | Grease composition for constant velocity joints |
-
2006
- 2006-03-21 US US11/385,291 patent/US7205423B1/en active Active
- 2006-09-19 WO PCT/US2006/036465 patent/WO2007038086A2/en active Application Filing
- 2006-09-20 EP EP06121001A patent/EP1770153B1/en active Active
- 2006-09-20 SI SI200630248T patent/SI1770153T1/sl unknown
- 2006-09-20 PL PL06121001T patent/PL1770153T3/pl unknown
- 2006-09-20 DE DE602006004523T patent/DE602006004523D1/de active Active
- 2006-09-20 AT AT06121001T patent/ATE419322T1/de not_active IP Right Cessation
- 2006-09-20 ES ES06121001T patent/ES2320692T3/es active Active
- 2006-09-21 JP JP2006255555A patent/JP4812580B2/ja active Active
- 2006-09-25 CN CN2006101397979A patent/CN1982320B/zh active Active
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101674974B (zh) * | 2007-03-06 | 2013-01-30 | R.T.范德比尔特公司 | 钼化合物 |
Also Published As
Publication number | Publication date |
---|---|
DE602006004523D1 (de) | 2009-02-12 |
US7205423B1 (en) | 2007-04-17 |
EP1770153B1 (en) | 2008-12-31 |
JP2007084545A (ja) | 2007-04-05 |
CN1982320B (zh) | 2012-03-21 |
US20070073073A1 (en) | 2007-03-29 |
WO2007038086A2 (en) | 2007-04-05 |
ATE419322T1 (de) | 2009-01-15 |
WO2007038086A3 (en) | 2007-07-12 |
EP1770153A1 (en) | 2007-04-04 |
JP4812580B2 (ja) | 2011-11-09 |
PL1770153T3 (pl) | 2009-06-30 |
SI1770153T1 (sl) | 2009-06-30 |
ES2320692T3 (es) | 2009-05-27 |
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