CN1880356B - 二氧化碳发泡的低密度挠性微孔聚氨酯弹性体 - Google Patents
二氧化碳发泡的低密度挠性微孔聚氨酯弹性体 Download PDFInfo
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- CN1880356B CN1880356B CN2006100841464A CN200610084146A CN1880356B CN 1880356 B CN1880356 B CN 1880356B CN 2006100841464 A CN2006100841464 A CN 2006100841464A CN 200610084146 A CN200610084146 A CN 200610084146A CN 1880356 B CN1880356 B CN 1880356B
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- Prior art keywords
- isocyanate
- reactive component
- polyvalent alcohol
- carbon dioxide
- reaction
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- 125000005843 halogen group Chemical group 0.000 description 1
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- GFMIDCCZJUXASS-UHFFFAOYSA-N hexane-1,1,6-triol Chemical compound OCCCCCC(O)O GFMIDCCZJUXASS-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Natural products OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- 235000012204 lemonade/lime carbonate Nutrition 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 239000008204 material by function Substances 0.000 description 1
- HOVAGTYPODGVJG-UHFFFAOYSA-N methyl beta-galactoside Natural products COC1OC(CO)C(O)C(O)C1O HOVAGTYPODGVJG-UHFFFAOYSA-N 0.000 description 1
- QATBRNFTOCXULG-UHFFFAOYSA-N n'-[2-(methylamino)ethyl]ethane-1,2-diamine Chemical compound CNCCNCCN QATBRNFTOCXULG-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229940059574 pentaerithrityl Drugs 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 239000012970 tertiary amine catalyst Substances 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 239000012974 tin catalyst Substances 0.000 description 1
- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical group [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- 229920006305 unsaturated polyester Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
- C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4833—Polyethers containing oxyethylene units
- C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
- C08G18/4841—Polyethers containing oxyethylene units and other oxyalkylene units containing oxyethylene end groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6666—Compounds of group C08G18/48 or C08G18/52
- C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
- C08G18/6674—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/122—Hydrogen, oxygen, CO2, nitrogen or noble gases
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0008—Foam properties flexible
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/0066—≥ 150kg/m3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2410/00—Soles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
- Y10T428/249978—Voids specified as micro
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Polyurethanes Or Polyureas (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/139,847 | 2005-05-27 | ||
| US11/139,847 US7670501B2 (en) | 2005-05-27 | 2005-05-27 | Carbon dioxide blown low density, flexible microcellular polyurethane elastomers |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1880356A CN1880356A (zh) | 2006-12-20 |
| CN1880356B true CN1880356B (zh) | 2011-08-10 |
Family
ID=36954600
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2006100841464A Expired - Fee Related CN1880356B (zh) | 2005-05-27 | 2006-05-26 | 二氧化碳发泡的低密度挠性微孔聚氨酯弹性体 |
Country Status (12)
| Country | Link |
|---|---|
| US (2) | US7670501B2 (enExample) |
| EP (1) | EP1726612B1 (enExample) |
| JP (1) | JP2006328401A (enExample) |
| KR (1) | KR101327721B1 (enExample) |
| CN (1) | CN1880356B (enExample) |
| AT (1) | ATE541884T1 (enExample) |
| BR (1) | BRPI0601942A (enExample) |
| CA (1) | CA2547103A1 (enExample) |
| ES (1) | ES2378674T3 (enExample) |
| PL (1) | PL1726612T3 (enExample) |
| PT (1) | PT1726612E (enExample) |
| TW (1) | TW200710113A (enExample) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080058468A1 (en) * | 2006-08-31 | 2008-03-06 | Bayer Materialscience Llc | Low density rigid reinforced polyurethanes and a process for their production |
| JP2010540737A (ja) * | 2007-10-02 | 2010-12-24 | ビーエーエスエフ ソシエタス・ヨーロピア | 低密度ポリウレタンフォーム及びこれを靴底に使用する方法 |
| US8713818B2 (en) * | 2008-01-24 | 2014-05-06 | Brown Shoe Company, Inc. | Cushioned shoe construction |
| JP5597380B2 (ja) * | 2009-10-09 | 2014-10-01 | 株式会社ダイフレックス | 手塗り施工用塗工剤 |
| JP5571414B2 (ja) * | 2010-03-04 | 2014-08-13 | 株式会社イノアックコーポレーション | マットレス用ポリウレタンフォーム |
| EP2465657A1 (de) | 2010-12-16 | 2012-06-20 | Basf Se | Verfahren zur Herstellung niederdichter Polyurethanformkörper |
| JP2014524965A (ja) | 2011-07-25 | 2014-09-25 | ノボマー， インコーポレイテッド | ポリウレタンに使用するための脂肪族ポリカーボネート |
| US9522973B2 (en) * | 2012-10-02 | 2016-12-20 | Covestro Llc | Polyurethane and polyisocyanurate rigid foams for roofing insulation |
| ES2752043T3 (es) | 2012-11-07 | 2020-04-02 | Saudi Aramco Tech Co | Composiciones de espuma de poliuretano de gran resistencia y métodos |
| CN105579484B (zh) * | 2013-02-26 | 2019-06-04 | 霍尼韦尔国际公司 | 含有卤代烯烃发泡剂的聚氨酯泡沫预混物和由其制造的泡沫 |
| EP2970615B1 (en) * | 2013-03-15 | 2017-05-17 | Dow Global Technologies LLC | Low pressure process for frothing polyurethane or polyisocyanurate |
| US20160115288A1 (en) * | 2013-05-13 | 2016-04-28 | Novomer, Inc. | Co2 containing foams and related methods |
| JP6253942B2 (ja) * | 2013-10-10 | 2017-12-27 | ヤマハ株式会社 | 発泡ウレタンゴム及び発泡ウレタンゴム形成用組成物 |
| TR201901665T4 (tr) * | 2015-03-09 | 2019-02-21 | Basf Se | Soğuk ortamda mükemmel esnekli̇k gösteren poli̇üretan döküm parçalar. |
| JPWO2017104600A1 (ja) * | 2015-12-16 | 2018-10-04 | 株式会社ブリヂストン | 軟質ポリウレタンフォーム、及びシート用パッド |
| IT201700051624A1 (it) * | 2017-05-12 | 2018-11-12 | U Invest S R L | Scarpa di sicurezza defaticante. |
| CN107987253A (zh) * | 2017-12-14 | 2018-05-04 | 山东诺威体育产业有限公司 | 道路防撞护栏用聚氨酯微孔弹性体组合料及制备方法 |
| BR112020012516A2 (pt) * | 2017-12-20 | 2020-11-24 | Basf Se | processo de produção de espumas, espuma de poliuretano, materiais híbridos, métodos de reciclagem de espuma e de reciclagem de materiais híbridos, uso de espuma, uso de poliuretano flexível, elemento de acolchoamento, palmilha para calçados e calçados |
| WO2019224235A1 (de) * | 2018-05-22 | 2019-11-28 | Basf Polyurethanes Gmbh | Polyurethanelastomer |
| EP4058494B1 (en) * | 2019-11-12 | 2024-07-31 | Huntsman International LLC | In-situ formation of low density thermoplastic polyurethane flexible foams |
| CN112898939B (zh) * | 2019-12-03 | 2023-04-28 | Sika技术股份公司 | 低总voc含量的无底漆快速固化的聚氨酯组合物 |
| US20230250220A1 (en) * | 2020-07-10 | 2023-08-10 | Basf Se | Process for preparing a crosslinked thermoplastic polyurethane and articles thereof |
| WO2023092543A1 (en) * | 2021-11-29 | 2023-06-01 | Dow Global Technologies Llc | Polyurethane composition, product therefrom and method for preparing the same |
| CN115417966B (zh) * | 2022-10-12 | 2024-02-13 | 伟建实业(苏州)有限公司 | 一种海绵发泡的配方及其制备方法 |
| TWI867848B (zh) * | 2023-11-16 | 2024-12-21 | 華碩科技股份有限公司 | 不黃變聚氨酯中底組成物及其製品 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1225199A1 (en) * | 2001-01-18 | 2002-07-24 | Bayer Antwerpen N.V. | Carbon dioxide blown low density, flexible microcellular elastomers suitable for preparing shoe components |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3916873C2 (de) | 1988-05-27 | 2003-01-09 | Elastogran Gmbh | Verfahren zur Herstellung von zellhaltigen Kunststoffen nach dem Polyisocyanat-polyadditionsverfahren und eine Katalysatorkombination hierfür |
| US5246977A (en) | 1990-05-04 | 1993-09-21 | The Dow Chemical Company | Microcellular polyurethane polymers prepared from isocyanate-terminated poly(oxytetramethylene) glycol prepolymers |
| DE69508427T2 (de) * | 1994-11-28 | 1999-07-22 | Bayer Ag, 51373 Leverkusen | Verfahren und vorrichtung zur schaumherstellung mittels unter druck gelöstem kohlendioxid |
| US5670601A (en) | 1995-06-15 | 1997-09-23 | Arco Chemical Technology, L.P. | Polyurethane elastomers having improved green strength and demold time and polyoxyalkylene polyols suitable for their preparation |
| US5856372A (en) * | 1996-05-23 | 1999-01-05 | Arco Chemical Technology, L.P. | Microcellular elastomers with improved processability and properties |
| US5917913A (en) * | 1996-12-04 | 1999-06-29 | Wang; Ynjiun Paul | Portable electronic authorization devices and methods therefor |
| US6003135A (en) * | 1997-06-04 | 1999-12-14 | Spyrus, Inc. | Modular security device |
| US6022903A (en) * | 1998-07-09 | 2000-02-08 | Arco Chemical Technology L.P. | Permanent gas blown microcellular polyurethane elastomers |
| US6460138B1 (en) * | 1998-10-05 | 2002-10-01 | Flashpoint Technology, Inc. | User authentication for portable electronic devices using asymmetrical cryptography |
| EP1454240B1 (en) * | 2002-05-13 | 2006-02-08 | Trek 2000 International Ltd | System and apparatus for compressing and decompressing data stored to a portable data storage device |
| EP1466932A1 (en) | 2003-04-11 | 2004-10-13 | Huntsman International Llc | Chain extender useful in the manufacture of polyurethanes and the corresponding polyurethanes |
-
2005
- 2005-05-27 US US11/139,847 patent/US7670501B2/en not_active Expired - Fee Related
-
2006
- 2006-05-16 CA CA 2547103 patent/CA2547103A1/en not_active Abandoned
- 2006-05-17 PL PL06010160T patent/PL1726612T3/pl unknown
- 2006-05-17 ES ES06010160T patent/ES2378674T3/es active Active
- 2006-05-17 EP EP20060010160 patent/EP1726612B1/en not_active Not-in-force
- 2006-05-17 AT AT06010160T patent/ATE541884T1/de active
- 2006-05-17 PT PT06010160T patent/PT1726612E/pt unknown
- 2006-05-25 JP JP2006145243A patent/JP2006328401A/ja not_active Withdrawn
- 2006-05-26 CN CN2006100841464A patent/CN1880356B/zh not_active Expired - Fee Related
- 2006-05-26 TW TW095118683A patent/TW200710113A/zh unknown
- 2006-05-26 KR KR1020060047396A patent/KR101327721B1/ko not_active Expired - Fee Related
- 2006-05-29 BR BRPI0601942-0A patent/BRPI0601942A/pt not_active IP Right Cessation
-
2010
- 2010-01-19 US US12/657,309 patent/US8178591B2/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1225199A1 (en) * | 2001-01-18 | 2002-07-24 | Bayer Antwerpen N.V. | Carbon dioxide blown low density, flexible microcellular elastomers suitable for preparing shoe components |
Also Published As
| Publication number | Publication date |
|---|---|
| PL1726612T3 (pl) | 2012-06-29 |
| CA2547103A1 (en) | 2006-11-27 |
| KR101327721B1 (ko) | 2013-11-11 |
| US20100124652A1 (en) | 2010-05-20 |
| EP1726612A2 (en) | 2006-11-29 |
| US8178591B2 (en) | 2012-05-15 |
| US7670501B2 (en) | 2010-03-02 |
| KR20060122758A (ko) | 2006-11-30 |
| BRPI0601942A (pt) | 2007-03-20 |
| CN1880356A (zh) | 2006-12-20 |
| ES2378674T3 (es) | 2012-04-16 |
| ATE541884T1 (de) | 2012-02-15 |
| PT1726612E (pt) | 2012-03-15 |
| JP2006328401A (ja) | 2006-12-07 |
| EP1726612B1 (en) | 2012-01-18 |
| US20060270746A1 (en) | 2006-11-30 |
| EP1726612A3 (en) | 2008-07-02 |
| TW200710113A (en) | 2007-03-16 |
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