CN1880356B - 二氧化碳发泡的低密度挠性微孔聚氨酯弹性体 - Google Patents

二氧化碳发泡的低密度挠性微孔聚氨酯弹性体 Download PDF

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Publication number
CN1880356B
CN1880356B CN2006100841464A CN200610084146A CN1880356B CN 1880356 B CN1880356 B CN 1880356B CN 2006100841464 A CN2006100841464 A CN 2006100841464A CN 200610084146 A CN200610084146 A CN 200610084146A CN 1880356 B CN1880356 B CN 1880356B
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China
Prior art keywords
isocyanate
reactive component
polyvalent alcohol
carbon dioxide
reaction
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Expired - Fee Related
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CN2006100841464A
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English (en)
Chinese (zh)
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CN1880356A (zh
Inventor
U·E·尤尼斯
D·M·贝利
C·R·卡朋特
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Covestro LLC
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Bayer MaterialScience LLC
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
    • A—HUMAN NECESSITIES
    • A43—FOOTWEAR
    • A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B13/00—Soles; Sole-and-heel integral units
    • A43B13/02—Soles; Sole-and-heel integral units characterised by the material
    • A43B13/04—Plastics, rubber or vulcanised fibre
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4833—Polyethers containing oxyethylene units
    • C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
    • C08G18/4841—Polyethers containing oxyethylene units and other oxyalkylene units containing oxyethylene end groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6666—Compounds of group C08G18/48 or C08G18/52
    • C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6674—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/122—Hydrogen, oxygen, CO2, nitrogen or noble gases
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0008—Foam properties flexible
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0041—Foam properties having specified density
    • C08G2110/0066—≥ 150kg/m3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2410/00—Soles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
    • Y10T428/249978—Voids specified as micro

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
CN2006100841464A 2005-05-27 2006-05-26 二氧化碳发泡的低密度挠性微孔聚氨酯弹性体 Expired - Fee Related CN1880356B (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/139,847 2005-05-27
US11/139,847 US7670501B2 (en) 2005-05-27 2005-05-27 Carbon dioxide blown low density, flexible microcellular polyurethane elastomers

Publications (2)

Publication Number Publication Date
CN1880356A CN1880356A (zh) 2006-12-20
CN1880356B true CN1880356B (zh) 2011-08-10

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CN2006100841464A Expired - Fee Related CN1880356B (zh) 2005-05-27 2006-05-26 二氧化碳发泡的低密度挠性微孔聚氨酯弹性体

Country Status (12)

Country Link
US (2) US7670501B2 (enExample)
EP (1) EP1726612B1 (enExample)
JP (1) JP2006328401A (enExample)
KR (1) KR101327721B1 (enExample)
CN (1) CN1880356B (enExample)
AT (1) ATE541884T1 (enExample)
BR (1) BRPI0601942A (enExample)
CA (1) CA2547103A1 (enExample)
ES (1) ES2378674T3 (enExample)
PL (1) PL1726612T3 (enExample)
PT (1) PT1726612E (enExample)
TW (1) TW200710113A (enExample)

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US20080058468A1 (en) * 2006-08-31 2008-03-06 Bayer Materialscience Llc Low density rigid reinforced polyurethanes and a process for their production
EP2195363B1 (de) * 2007-10-02 2017-08-30 Basf Se Niederdichte polyurethanschaumstoffe und deren verwendung in schuhsohlen
US8713818B2 (en) * 2008-01-24 2014-05-06 Brown Shoe Company, Inc. Cushioned shoe construction
JP5597380B2 (ja) * 2009-10-09 2014-10-01 株式会社ダイフレックス 手塗り施工用塗工剤
JP5571414B2 (ja) * 2010-03-04 2014-08-13 株式会社イノアックコーポレーション マットレス用ポリウレタンフォーム
EP2465657A1 (de) 2010-12-16 2012-06-20 Basf Se Verfahren zur Herstellung niederdichter Polyurethanformkörper
ES2749324T3 (es) 2011-07-25 2020-03-19 Saudi Aramco Tech Co Composiciones poliméricas y métodos
US9522973B2 (en) * 2012-10-02 2016-12-20 Covestro Llc Polyurethane and polyisocyanurate rigid foams for roofing insulation
EP3584267A1 (en) 2012-11-07 2019-12-25 Saudi Aramco Technologies Company High strength polyurethane foam compositions and methods
KR102473838B1 (ko) * 2013-02-26 2022-12-02 허니웰 인터내셔날 인코포레이티드 할로겐화 올레핀 발포제를 함유하는 폴리우레탄 폼 프리믹스 및 이로부터 제조되는 폼
EP2970615B1 (en) * 2013-03-15 2017-05-17 Dow Global Technologies LLC Low pressure process for frothing polyurethane or polyisocyanurate
KR20160006775A (ko) * 2013-05-13 2016-01-19 노보머, 인코포레이티드 Co₂ 포함 폼 및 관련 방법
JP6253942B2 (ja) * 2013-10-10 2017-12-27 ヤマハ株式会社 発泡ウレタンゴム及び発泡ウレタンゴム形成用組成物
EP3268408B1 (de) * 2015-03-09 2018-12-05 Basf Se Polyurethanformkörper mit herausragender kälteflexibilität
EP3392282A4 (en) * 2015-12-16 2018-10-24 Bridgestone Corporation Soft polyurethane foam and seat pad
IT201700051624A1 (it) * 2017-05-12 2018-11-12 U Invest S R L Scarpa di sicurezza defaticante.
CN107987253A (zh) * 2017-12-14 2018-05-04 山东诺威体育产业有限公司 道路防撞护栏用聚氨酯微孔弹性体组合料及制备方法
MX2020006558A (es) * 2017-12-20 2020-09-24 Basf Se Nuevas espumas de poliuretano flexibles.
WO2019224235A1 (de) * 2018-05-22 2019-11-28 Basf Polyurethanes Gmbh Polyurethanelastomer
ES2991469T3 (es) * 2019-11-12 2024-12-03 Huntsman Int Llc Formación en el sitio de espumas flexibles de poliuretano termoplástico de baja densidad
CN112898939B (zh) * 2019-12-03 2023-04-28 Sika技术股份公司 低总voc含量的无底漆快速固化的聚氨酯组合物
US20230250220A1 (en) * 2020-07-10 2023-08-10 Basf Se Process for preparing a crosslinked thermoplastic polyurethane and articles thereof
WO2023092543A1 (en) * 2021-11-29 2023-06-01 Dow Global Technologies Llc Polyurethane composition, product therefrom and method for preparing the same
CN115417966B (zh) * 2022-10-12 2024-02-13 伟建实业(苏州)有限公司 一种海绵发泡的配方及其制备方法
TWI867848B (zh) * 2023-11-16 2024-12-21 華碩科技股份有限公司 不黃變聚氨酯中底組成物及其製品
WO2026013529A1 (en) 2024-07-10 2026-01-15 Stemma S.R.L. Plant and method for the controlled introduction of a blowing agent into a reagent of a polyurethane mixture

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Publication number Publication date
US20100124652A1 (en) 2010-05-20
KR101327721B1 (ko) 2013-11-11
EP1726612A2 (en) 2006-11-29
CA2547103A1 (en) 2006-11-27
JP2006328401A (ja) 2006-12-07
PT1726612E (pt) 2012-03-15
BRPI0601942A (pt) 2007-03-20
EP1726612B1 (en) 2012-01-18
US7670501B2 (en) 2010-03-02
EP1726612A3 (en) 2008-07-02
PL1726612T3 (pl) 2012-06-29
US20060270746A1 (en) 2006-11-30
KR20060122758A (ko) 2006-11-30
TW200710113A (en) 2007-03-16
US8178591B2 (en) 2012-05-15
ATE541884T1 (de) 2012-02-15
CN1880356A (zh) 2006-12-20
ES2378674T3 (es) 2012-04-16

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