BRPI0601942A - elastÈmeros de poliuretano microcelulares flexìveis de baixa densidade expandidos com dióxido de carbono - Google Patents

elastÈmeros de poliuretano microcelulares flexìveis de baixa densidade expandidos com dióxido de carbono

Info

Publication number
BRPI0601942A
BRPI0601942A BRPI0601942-0A BRPI0601942A BRPI0601942A BR PI0601942 A BRPI0601942 A BR PI0601942A BR PI0601942 A BRPI0601942 A BR PI0601942A BR PI0601942 A BRPI0601942 A BR PI0601942A
Authority
BR
Brazil
Prior art keywords
carbon dioxide
foams
isocyanate
polyurethane
water
Prior art date
Application number
BRPI0601942-0A
Other languages
English (en)
Inventor
Usama E Younes
David M Baily
Charles R Carpenter
Original Assignee
Bayer Materialscience Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer Materialscience Llc filed Critical Bayer Materialscience Llc
Publication of BRPI0601942A publication Critical patent/BRPI0601942A/pt

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
    • A—HUMAN NECESSITIES
    • A43—FOOTWEAR
    • A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B13/00—Soles; Sole-and-heel integral units
    • A43B13/02—Soles; Sole-and-heel integral units characterised by the material
    • A43B13/04—Plastics, rubber or vulcanised fibre
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4833—Polyethers containing oxyethylene units
    • C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
    • C08G18/4841—Polyethers containing oxyethylene units and other oxyalkylene units containing oxyethylene end groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6666—Compounds of group C08G18/48 or C08G18/52
    • C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6674—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/122—Hydrogen, oxygen, CO2, nitrogen or noble gases
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0008—Foam properties flexible
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0041—Foam properties having specified density
    • C08G2110/0066—≥ 150kg/m3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2410/00—Soles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
    • Y10T428/249978—Voids specified as micro

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)

Abstract

"ELASTÈMEROS DE POLIURETANO MICROCELULARES FLEXìVEIS DE BAIXA DENSIDADE EXPANDIDOS COM DIóXIDO DE CARBONO". A presente invenção refere-se a espumas flexíveis de poliuretano microcelulares tendo densidades não-superiores a 0,3 g/CM¬ 3¬, que são adequadas para uso como componentes de solas de sapato leves, são produzidas com dióxido de carbono em um montante tal que a mistura formadora de poliuretano tem uma densidade em expansão livre de cerca de 0,03 a cerca de 0,3 g/CM¬ 3¬. Pelo menos uma porção desse dióxido de carbono é dissolvido como gás em um ou ambos os componentes da reação. O montante de dióxido de carbono dissolvido deve ser tal que a densidade de espuma do isocianato e/ou do(s) componente(s) reativo(s)-a isocianato em que o dióxido de carbono é dissolvido seja de cerca de 0,1 a cerca de 0,8 g/CM¬ 3¬. Dióxido de carbono adicional pode ser formado pela reação de água com isocianato durante a reação de formação de poliuretano, mas o montante total de CO~ 2~ presente deve ser controlado para assegurar que a mistura formadora de poliuretano tenha uma densidade em expansão livre de cerca de 0,03 a 0,3 g/CM¬ 3¬. Uso de um componente reativo a isocianato preferido em que uma razão especificada de diol para triol é satisfeita torna possível usar mais água do que o esperado. Uso de um pré-polimero preferido torna possível produzir poliuretanos microcelulares tendo boas propriedades físicas somente com um diol. As espumas microecelulares produzidas possuem uma estrutura de célula uniforme e propriedades físicas melhoradas quando comparadas com espumas expandidas somente com água da mesma formulação básica e densidade. A dureza das espumas é mais adequada para aplicações de sola de sapato, particularmente para aplicações de entressoIas, em comparação com as espumas expandidas somente com água, a despeito do teor mais baixo de segmentos duros de uréia das espumas expandidas com C0~ 2~.
BRPI0601942-0A 2005-05-27 2006-05-29 elastÈmeros de poliuretano microcelulares flexìveis de baixa densidade expandidos com dióxido de carbono BRPI0601942A (pt)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US11/139,847 US7670501B2 (en) 2005-05-27 2005-05-27 Carbon dioxide blown low density, flexible microcellular polyurethane elastomers

Publications (1)

Publication Number Publication Date
BRPI0601942A true BRPI0601942A (pt) 2007-03-20

Family

ID=36954600

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0601942-0A BRPI0601942A (pt) 2005-05-27 2006-05-29 elastÈmeros de poliuretano microcelulares flexìveis de baixa densidade expandidos com dióxido de carbono

Country Status (12)

Country Link
US (2) US7670501B2 (pt)
EP (1) EP1726612B1 (pt)
JP (1) JP2006328401A (pt)
KR (1) KR101327721B1 (pt)
CN (1) CN1880356B (pt)
AT (1) ATE541884T1 (pt)
BR (1) BRPI0601942A (pt)
CA (1) CA2547103A1 (pt)
ES (1) ES2378674T3 (pt)
PL (1) PL1726612T3 (pt)
PT (1) PT1726612E (pt)
TW (1) TW200710113A (pt)

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US20080058468A1 (en) * 2006-08-31 2008-03-06 Bayer Materialscience Llc Low density rigid reinforced polyurethanes and a process for their production
WO2009047149A1 (de) * 2007-10-02 2009-04-16 Basf Se Niederdichte polyurethanschaumstoffe und deren verwendung in schuhsohlen
US8713818B2 (en) * 2008-01-24 2014-05-06 Brown Shoe Company, Inc. Cushioned shoe construction
JP5597380B2 (ja) * 2009-10-09 2014-10-01 株式会社ダイフレックス 手塗り施工用塗工剤
JP5571414B2 (ja) * 2010-03-04 2014-08-13 株式会社イノアックコーポレーション マットレス用ポリウレタンフォーム
EP2465657A1 (de) 2010-12-16 2012-06-20 Basf Se Verfahren zur Herstellung niederdichter Polyurethanformkörper
JP2014524965A (ja) 2011-07-25 2014-09-25 ノボマー， インコーポレイテッド ポリウレタンに使用するための脂肪族ポリカーボネート
US9522973B2 (en) * 2012-10-02 2016-12-20 Covestro Llc Polyurethane and polyisocyanurate rigid foams for roofing insulation
CN109021209A (zh) 2012-11-07 2018-12-18 沙特阿美技术公司 高强度聚氨酯泡沫组合物及方法
EP4223814A3 (en) * 2013-02-26 2023-08-23 Honeywell International Inc. Polyurethane foam premixes containing halogenated olefin blowing agents and foams made from same
WO2014143541A1 (en) * 2013-03-15 2014-09-18 Dow Global Technologies Llc Low pressure process for frothing polyurethane or polyisocyanurate
US20160115288A1 (en) * 2013-05-13 2016-04-28 Novomer, Inc. Co2 containing foams and related methods
JP6253942B2 (ja) * 2013-10-10 2017-12-27 ヤマハ株式会社 発泡ウレタンゴム及び発泡ウレタンゴム形成用組成物
TR201901665T4 (tr) * 2015-03-09 2019-02-21 Basf Se Soğuk ortamda mükemmel esnekli̇k gösteren poli̇üretan döküm parçalar.
CN108368228A (zh) * 2015-12-16 2018-08-03 株式会社普利司通 软质聚氨酯泡沫和座垫
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CN107987253A (zh) * 2017-12-14 2018-05-04 山东诺威体育产业有限公司 道路防撞护栏用聚氨酯微孔弹性体组合料及制备方法
US11945904B2 (en) * 2017-12-20 2024-04-02 Basf Se Flexible polyurethane foams
WO2019224235A1 (de) * 2018-05-22 2019-11-28 Basf Polyurethanes Gmbh Polyurethanelastomer
CN114630851B (zh) * 2019-11-12 2024-05-28 亨茨曼国际有限公司 低密度热塑性聚氨酯软质泡沫的原位形成
CN112898939B (zh) * 2019-12-03 2023-04-28 Sika技术股份公司 低总voc含量的无底漆快速固化的聚氨酯组合物
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WO2023092543A1 (en) * 2021-11-29 2023-06-01 Dow Global Technologies Llc Polyurethane composition, product therefrom and method for preparing the same
CN115417966B (zh) * 2022-10-12 2024-02-13 伟建实业(苏州)有限公司 一种海绵发泡的配方及其制备方法

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Also Published As

Publication number Publication date
TW200710113A (en) 2007-03-16
EP1726612B1 (en) 2012-01-18
EP1726612A3 (en) 2008-07-02
ATE541884T1 (de) 2012-02-15
PT1726612E (pt) 2012-03-15
CN1880356A (zh) 2006-12-20
PL1726612T3 (pl) 2012-06-29
CA2547103A1 (en) 2006-11-27
US8178591B2 (en) 2012-05-15
US20100124652A1 (en) 2010-05-20
US20060270746A1 (en) 2006-11-30
JP2006328401A (ja) 2006-12-07
KR101327721B1 (ko) 2013-11-11
US7670501B2 (en) 2010-03-02
KR20060122758A (ko) 2006-11-30
EP1726612A2 (en) 2006-11-29
ES2378674T3 (es) 2012-04-16
CN1880356B (zh) 2011-08-10

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Legal Events

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B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B08F Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette]

Free format text: REFERENTE A 10A ANUIDADE.

B08K Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette]

Free format text: EM VIRTUDE DO ARQUIVAMENTO PUBLICADO NA RPI 2385 DE 20-09-2016 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDO O ARQUIVAMENTO DO PEDIDO DE PATENTE, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.