CN1863841B - 用于预制稳定剂和聚合物多元醇的新型不饱和大分子单体 - Google Patents

用于预制稳定剂和聚合物多元醇的新型不饱和大分子单体 Download PDF

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Publication number
CN1863841B
CN1863841B CN2004800292659A CN200480029265A CN1863841B CN 1863841 B CN1863841 B CN 1863841B CN 2004800292659 A CN2004800292659 A CN 2004800292659A CN 200480029265 A CN200480029265 A CN 200480029265A CN 1863841 B CN1863841 B CN 1863841B
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alcohol
mixture
polymer polyatomic
preformed stabilizers
ethylenically unsaturated
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Expired - Fee Related
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CN2004800292659A
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Chinese (zh)
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CN1863841A (zh
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R·L·阿德金斯
S·居勒切尔
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Covestro LLC
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Bayer MaterialScience LLC
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/63—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers
    • C08G18/635—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers onto unsaturated polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/2805—Compounds having only one group containing active hydrogen
    • C08G18/2815—Monohydroxy compounds
    • C08G18/283—Compounds containing ether groups, e.g. oxyalkylated monohydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4833—Polyethers containing oxyethylene units
    • C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
    • C08G18/485—Polyethers containing oxyethylene units and other oxyalkylene units containing mixed oxyethylene-oxypropylene or oxyethylene-higher oxyalkylene end groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/63—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers
    • C08G18/636—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers characterised by the presence of a dispersion-stabiliser
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7614—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring
    • C08G18/7628—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring containing at least one isocyanate or isothiocyanate group linked to the aromatic ring by means of an aliphatic group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2603—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen
    • C08G65/2606—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen containing hydroxyl groups
    • C08G65/2612—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen containing hydroxyl groups containing aromatic or arylaliphatic hydroxyl groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2101/00—Manufacture of cellular products
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0008—Foam properties flexible
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0083—Foam properties prepared using water as the sole blowing agent

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Treatments Of Macromolecular Shaped Articles (AREA)
  • Polymerisation Methods In General (AREA)
  • Polyethers (AREA)
  • Polyurethanes Or Polyureas (AREA)
CN2004800292659A 2003-10-16 2004-10-13 用于预制稳定剂和聚合物多元醇的新型不饱和大分子单体 Expired - Fee Related CN1863841B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US10/687,156 US20050085613A1 (en) 2003-10-16 2003-10-16 Novel unsaturated macromers for preformed stabilizers and polymer polyols
US10/687,156 2003-10-16
PCT/US2004/033652 WO2005042616A2 (en) 2003-10-16 2004-10-13 Unsaturated macromers for preparing preformed stabilizers and polymer polyols

Publications (2)

Publication Number Publication Date
CN1863841A CN1863841A (zh) 2006-11-15
CN1863841B true CN1863841B (zh) 2010-12-22

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CN2004800292659A Expired - Fee Related CN1863841B (zh) 2003-10-16 2004-10-13 用于预制稳定剂和聚合物多元醇的新型不饱和大分子单体

Country Status (11)

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US (1) US20050085613A1 (enExample)
EP (1) EP1675885B1 (enExample)
JP (1) JP2007509207A (enExample)
CN (1) CN1863841B (enExample)
AT (1) ATE388185T1 (enExample)
BR (1) BRPI0415287A (enExample)
CA (1) CA2542073A1 (enExample)
DE (1) DE602004012306T2 (enExample)
ES (1) ES2300869T3 (enExample)
MX (1) MXPA06004034A (enExample)
WO (1) WO2005042616A2 (enExample)

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US20090281206A1 (en) * 2006-07-05 2009-11-12 Dow Global Technologies Inc. Copolymer polyols and a process for the production thereof
KR100839061B1 (ko) * 2006-12-15 2008-06-19 금호석유화학 주식회사 무수말레인산을 이용한 폴리머 폴리올을 위한 제조용 안정제
DE102007057147A1 (de) 2007-11-28 2009-06-04 Evonik Goldschmidt Gmbh Verfahren zur Alkoxylierung mit DMC-Katalysatoren im Schlaufenreaktor mit Strahlsauger
AU2009259994B2 (en) * 2008-06-19 2014-03-20 Centre National De La Recherche Scientifique Melt dispersion process for making polymer polyols
EP2264082A1 (de) * 2009-06-19 2010-12-22 BYK-Chemie GmbH Terminal ungesättigte, glycidol-basierte Markomonomere, daraus erhältliche Polymere, Herstellung und Verwendung
JP2011162726A (ja) * 2010-02-12 2011-08-25 Jsr Corp 硬化性樹脂組成物、硬化物、フィルム、および重合体
WO2012154393A2 (en) 2011-05-12 2012-11-15 Dow Global Technologies Llc Stabilizer polymerization process and process for making polymer polyols
US8984690B2 (en) * 2011-07-29 2015-03-24 Dreamwell, Ltd. Mattress and side rail assembly with high airflow
WO2014055282A1 (en) 2012-10-05 2014-04-10 Dow Global Technologies Llc Macromer and process for making polymer polyols
CN104045791A (zh) * 2013-03-11 2014-09-17 中国石油化工集团公司 聚合物多元醇的制备方法
CN110156949B (zh) 2014-04-30 2021-11-23 巴斯夫欧洲公司 制备聚合物多元醇分散体的方法及其中稳定剂的用途
HUE050534T2 (hu) 2014-04-30 2020-12-28 Basf Se Eljárás polimer poliol elõállítására
HUE045929T2 (hu) 2014-11-27 2020-01-28 Basf Se Polimer poliolok elõállítása telítetlen poliolokban, polimer poliolok és alkalmazásuk
US10975215B2 (en) 2016-03-31 2021-04-13 Dow Global Technologies Llc Process making polymer polyol having monodisperse dispersed polymer particles
WO2018018462A1 (en) 2016-07-27 2018-02-01 Basf Se Stabiliser for polyolefin-in-polyether polyol dispersions
US10526484B2 (en) 2017-12-20 2020-01-07 Covestro Llc Dithiocarbonate containing polyols as polymer polyol stabilizers
CN109320711A (zh) * 2018-10-10 2019-02-12 上海东大化学有限公司 一种枯烯基聚羧酸系减水剂聚醚大单体及其制备方法和应用
CN109734848A (zh) * 2018-12-26 2019-05-10 万华化学集团股份有限公司 一种聚合物多元醇及其制备方法
CN113439096A (zh) 2019-02-07 2021-09-24 陶氏环球技术有限责任公司 用于制备共聚物多元醇的方法
EP3921351B1 (en) 2019-02-07 2026-01-07 Dow Global Technologies LLC Monomer recovery process
MX2022008252A (es) 2020-01-06 2022-07-21 Dow Global Technologies Llc Macromero y proceso para elaborar polioles de polimero.
CN114479050B (zh) * 2020-10-23 2023-08-04 中国石油化工股份有限公司 一种稳定剂前体及其制备方法和应用
CN112940197B (zh) * 2021-02-03 2023-05-16 湖北工业大学 一种降粘抗泥型混凝土用聚合物及其制备方法
CN115703864B (zh) * 2021-08-09 2023-12-19 中国科学院化学研究所 一种用于低极性和非极性溶剂的大分子稳定剂及其制备方法和应用
US20230102722A1 (en) * 2021-09-01 2023-03-30 Covestro Llc Processes for producing filled polyol compositions
CN116410459B (zh) * 2021-12-31 2026-02-06 万华化学集团股份有限公司 一种大分子稳定剂的制备方法及应用
US12006413B2 (en) 2022-01-12 2024-06-11 Covestro Llc Polymer polyols, processes for their preparation, and the use thereof to produce foams exhibiting resistance to combustion

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Publication number Publication date
ATE388185T1 (de) 2008-03-15
EP1675885B1 (en) 2008-03-05
BRPI0415287A (pt) 2006-12-19
JP2007509207A (ja) 2007-04-12
DE602004012306D1 (de) 2008-04-17
WO2005042616A3 (en) 2005-06-23
MXPA06004034A (es) 2006-06-28
CN1863841A (zh) 2006-11-15
DE602004012306T2 (de) 2009-05-20
EP1675885A2 (en) 2006-07-05
WO2005042616A2 (en) 2005-05-12
US20050085613A1 (en) 2005-04-21
CA2542073A1 (en) 2005-05-12
ES2300869T3 (es) 2008-06-16

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