CN1829678B - 含有银、钒和助催化剂金属的多金属氧化物及其用途 - Google Patents

含有银、钒和助催化剂金属的多金属氧化物及其用途 Download PDF

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CN1829678B
CN1829678B CN2004800215313A CN200480021531A CN1829678B CN 1829678 B CN1829678 B CN 1829678B CN 2004800215313 A CN2004800215313 A CN 2004800215313A CN 200480021531 A CN200480021531 A CN 200480021531A CN 1829678 B CN1829678 B CN 1829678B
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catalyst
catalyzer
weight
poly
silver
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CN1829678A (zh
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S·内托
H·希布施特
F·罗索夫斯基
S·施特克
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BASF SE
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/31—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting
    • C07C51/313—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting with molecular oxygen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F19/00—Metal compounds according to more than one of main groups C07F1/00 - C07F17/00
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/682—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium, tantalum or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/688—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/395—Thickness of the active catalytic layer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G31/00—Compounds of vanadium
    • C01G31/006—Compounds containing vanadium, with or without oxygen or hydrogen, and containing two or more other elements
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
    • C07C51/265—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting having alkyl side chains which are oxidised to carboxyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
    • C07F1/10—Silver compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0045—Drying a slurry, e.g. spray drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0221—Coating of particles
    • B01J37/0223—Coating of particles by rotation

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Furan Compounds (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
CN2004800215313A 2003-07-25 2004-07-23 含有银、钒和助催化剂金属的多金属氧化物及其用途 Expired - Fee Related CN1829678B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE10334132A DE10334132A1 (de) 2003-07-25 2003-07-25 Silber, Vanadium und ein Promotormetall enthaltendes Multimetalloxid und dessen Verwendung
DE10334132.3 2003-07-25
PCT/EP2004/008296 WO2005012216A1 (de) 2003-07-25 2004-07-23 Silber, vanadium und ein promotormetall enthaltendes multimetalloxid und dessen verwendung

Publications (2)

Publication Number Publication Date
CN1829678A CN1829678A (zh) 2006-09-06
CN1829678B true CN1829678B (zh) 2010-12-15

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CN2004800215313A Expired - Fee Related CN1829678B (zh) 2003-07-25 2004-07-23 含有银、钒和助催化剂金属的多金属氧化物及其用途

Country Status (14)

Country Link
US (1) US7462727B2 (enExample)
EP (1) EP1654211B1 (enExample)
JP (1) JP4330626B2 (enExample)
KR (1) KR20060066068A (enExample)
CN (1) CN1829678B (enExample)
BR (1) BRPI0412840A (enExample)
DE (1) DE10334132A1 (enExample)
IL (1) IL173063A0 (enExample)
IN (1) IN2006CH00292A (enExample)
MX (1) MXPA06000687A (enExample)
RU (1) RU2006105703A (enExample)
TW (1) TW200514750A (enExample)
WO (1) WO2005012216A1 (enExample)
ZA (1) ZA200601637B (enExample)

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DE10334132A1 (de) 2003-07-25 2005-04-07 Basf Ag Silber, Vanadium und ein Promotormetall enthaltendes Multimetalloxid und dessen Verwendung
DE102004014918A1 (de) 2004-03-26 2005-10-13 Basf Ag Katalysator mit einer Silber-Vanadiumoxidphase und einer Promotorphase
DE102004028930A1 (de) * 2004-06-15 2006-01-05 Basf Ag Silber, Vanadium und ein Element der Phosphorgruppe enthaltendes Multimetalloxid und dessen Verwendung
KR100714606B1 (ko) * 2005-02-25 2007-05-07 주식회사 엘지화학 불포화 알데히드 및/또는 불포화 산의 제조방법
DE102005061382A1 (de) * 2005-12-21 2007-06-28 Basf Ag Umwandlung eines Präkatalysators in eine katalytisch aktive Silber-Vanadiumoxid-Bronze
WO2007135104A1 (de) 2006-05-19 2007-11-29 Basf Se Herstellung von phthalsäureanhydrid durch gasphasenoxidation von o-xylol
JP5114474B2 (ja) 2006-05-19 2013-01-09 ビーエーエスエフ ソシエタス・ヨーロピア 主要反応器および後方反応器中でのｏ−キシロールの気相酸化による無水フタル酸の製造
DE102008011011A1 (de) * 2008-02-01 2009-08-06 Breimair, Josef, Dr. Katalysator für die katalytische Gasphasenoxidation von aromatischen Kohlenwasserstoffen zu Aldehyden, Carbonsäuren und/oder Carbonsäureanhydriden, insbesondere zu Phthalsäureanhydrid
EP2274265A1 (de) * 2008-04-07 2011-01-19 Basf Se Verfahren zum anfahren eines gasphasenoxidationsreaktors, der eine katalytisch aktive silber-vanadiumoxid-bronze enthält
US8187705B2 (en) * 2010-07-15 2012-05-29 Silberline Manufacturing Company, Inc. Manganese vanadium tantalum oxide and pigments having a black metallic effect coated with the same
WO2016100967A1 (en) * 2014-12-19 2016-06-23 Dimien Llc Vanadium oxide compositions and systems and methods for creating them
CN105126860B (zh) * 2015-07-31 2017-10-31 烟台智本知识产权运营管理有限公司 一种甲苯直接氧化催化剂及其制备方法
CN106552622B (zh) * 2015-09-28 2019-12-17 中国石化扬子石油化工有限公司 一种V-Ag-Si-O催化剂、其制备方法及其应用
CN108722397B (zh) * 2018-06-05 2021-11-26 青岛科技大学 一种高尔夫球状Ag/TiO2复合多孔微球及其制备方法
CN109046412B (zh) * 2018-08-23 2021-05-25 常州新日催化剂股份有限公司 一种正丁烷氧化制顺酐催化剂及其制备方法
EP3846935A1 (en) * 2018-09-05 2021-07-14 SABIC Global Technologies B.V. Vanadium oxide supported catalyst for alkane dehydrogenation
CN113926452A (zh) * 2020-06-29 2022-01-14 中国石油化工股份有限公司 一种钒银铋金属氧化物催化剂、制备方法及其应用
CN112221496B (zh) * 2020-10-13 2022-11-04 天津大学 多元金属氧化物基柴油机氧化催化器用催化剂及制备方法

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US4137259A (en) * 1976-07-09 1979-01-30 Stamicarbon, B.V. Catalytic gas phase oxidation of toluene to benzaldehyde and/or benzoic acid
DE19705326A1 (de) * 1997-02-12 1998-08-13 Basf Ag Verfahren zur selektiven Oxidation von nicht-cyclischen ungesättigten Kohlenwasserstoffen mittels Katalysatoren auf Basis von Silben-Vanadium-Mischoxiden
WO2000027753A1 (de) * 1998-11-10 2000-05-18 Basf Aktiengesellschaft Silber- und vanadiumoxid enthaltendes multimetalloxid und dessen verwendung
WO2001085337A1 (de) * 2000-05-08 2001-11-15 Basf Aktiengesellschaft Silber, vanadium und ein oder mehrere elemente der phosphorgruppe enthaltendes multimetalloxid und dessen verwendung

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DE10335346A1 (de) 2003-08-01 2005-02-24 Basf Ag Katalysator für Gasphasenoxidationen
DE102004014918A1 (de) 2004-03-26 2005-10-13 Basf Ag Katalysator mit einer Silber-Vanadiumoxidphase und einer Promotorphase
DE102004028930A1 (de) 2004-06-15 2006-01-05 Basf Ag Silber, Vanadium und ein Element der Phosphorgruppe enthaltendes Multimetalloxid und dessen Verwendung
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US4137259A (en) * 1976-07-09 1979-01-30 Stamicarbon, B.V. Catalytic gas phase oxidation of toluene to benzaldehyde and/or benzoic acid
DE19705326A1 (de) * 1997-02-12 1998-08-13 Basf Ag Verfahren zur selektiven Oxidation von nicht-cyclischen ungesättigten Kohlenwasserstoffen mittels Katalysatoren auf Basis von Silben-Vanadium-Mischoxiden
WO2000027753A1 (de) * 1998-11-10 2000-05-18 Basf Aktiengesellschaft Silber- und vanadiumoxid enthaltendes multimetalloxid und dessen verwendung
WO2001085337A1 (de) * 2000-05-08 2001-11-15 Basf Aktiengesellschaft Silber, vanadium und ein oder mehrere elemente der phosphorgruppe enthaltendes multimetalloxid und dessen verwendung

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HOLLES J H ET AL."A substrate-versatile catalyst for the selective oxidation oflight alkanes-I. Reactivity".JOURNAL OF CATALYSIS218.2003,21842-53. *

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Publication number Publication date
CN1829678A (zh) 2006-09-06
BRPI0412840A (pt) 2006-09-26
JP2007533577A (ja) 2007-11-22
IN2006CH00292A (enExample) 2007-07-06
EP1654211A1 (de) 2006-05-10
EP1654211B1 (de) 2013-05-15
US7462727B2 (en) 2008-12-09
KR20060066068A (ko) 2006-06-15
TW200514750A (en) 2005-05-01
DE10334132A1 (de) 2005-04-07
RU2006105703A (ru) 2006-08-27
US20060247446A1 (en) 2006-11-02
ZA200601637B (en) 2007-04-25
WO2005012216A1 (de) 2005-02-10
JP4330626B2 (ja) 2009-09-16
MXPA06000687A (es) 2006-04-19
IL173063A0 (en) 2006-06-11

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