CN1802392B - 使用Ziegler-Natta催化剂制备聚丙烯的方法 - Google Patents
使用Ziegler-Natta催化剂制备聚丙烯的方法 Download PDFInfo
- Publication number
- CN1802392B CN1802392B CN2004800157074A CN200480015707A CN1802392B CN 1802392 B CN1802392 B CN 1802392B CN 2004800157074 A CN2004800157074 A CN 2004800157074A CN 200480015707 A CN200480015707 A CN 200480015707A CN 1802392 B CN1802392 B CN 1802392B
- Authority
- CN
- China
- Prior art keywords
- catalyst
- compound
- magnesium
- propylene
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/651—Pretreating with non-metals or metal-free compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F6/04—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins
- D01F6/06—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins from polypropylene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP03012906.8 | 2003-06-06 | ||
EP03012906A EP1484345A1 (en) | 2003-06-06 | 2003-06-06 | Process for the production of polypropylene using a Ziegler-Natta catalyst |
PCT/EP2004/006053 WO2004111098A2 (en) | 2003-06-06 | 2004-06-04 | Process for the production of polypropylene using a ziegler-natta catalyst |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1802392A CN1802392A (zh) | 2006-07-12 |
CN1802392B true CN1802392B (zh) | 2010-10-13 |
Family
ID=33155178
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2004800157074A Expired - Fee Related CN1802392B (zh) | 2003-06-06 | 2004-06-04 | 使用Ziegler-Natta催化剂制备聚丙烯的方法 |
Country Status (11)
Country | Link |
---|---|
US (1) | US7465775B2 (pt-PT) |
EP (2) | EP1484345A1 (pt-PT) |
JP (1) | JP2006527271A (pt-PT) |
KR (1) | KR100990923B1 (pt-PT) |
CN (1) | CN1802392B (pt-PT) |
AU (1) | AU2004247364A1 (pt-PT) |
BR (1) | BRPI0411063A (pt-PT) |
CA (1) | CA2526144A1 (pt-PT) |
EA (1) | EA011642B1 (pt-PT) |
ES (1) | ES2536477T3 (pt-PT) |
WO (1) | WO2004111098A2 (pt-PT) |
Families Citing this family (47)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1484345A1 (en) | 2003-06-06 | 2004-12-08 | Borealis Technology Oy | Process for the production of polypropylene using a Ziegler-Natta catalyst |
EP1717269A1 (en) | 2005-04-28 | 2006-11-02 | Borealis Technology Oy | Alpha-olefin homo-or copolymer compositions |
ES2588577T3 (es) * | 2005-12-30 | 2016-11-03 | Borealis Technology Oy | Partículas de catalizador |
EP1847555A1 (en) | 2006-04-18 | 2007-10-24 | Borealis Technology Oy | Multi-branched Polypropylene |
EP2845868A1 (en) * | 2006-05-31 | 2015-03-11 | Borealis Technology Oy | Oxidation state of Ti as means for increasing catalyst activity |
EP1886806B1 (en) * | 2006-07-10 | 2010-11-10 | Borealis Technology Oy | Biaxially oriented polypropylene film |
EP1883080B1 (en) | 2006-07-10 | 2009-01-21 | Borealis Technology Oy | Electrical insulation film |
EP1892264A1 (en) | 2006-08-25 | 2008-02-27 | Borealis Technology Oy | Extrusion coated substrate |
DE602006006061D1 (de) | 2006-08-25 | 2009-05-14 | Borealis Tech Oy | Polypropylenschaumstoff |
DE602006013137D1 (de) | 2006-09-25 | 2010-05-06 | Borealis Tech Oy | Koaxiales Kabel |
ES2326752T3 (es) * | 2006-12-18 | 2009-10-19 | Borealis Technology Oy | Terpolimero con punto de fusion elevado. |
EP1939227B1 (en) * | 2006-12-28 | 2013-10-30 | Borealis Technology Oy | Catalyst preparation with phosphorous compound |
DE602006005508D1 (de) | 2006-12-28 | 2009-04-16 | Borealis Tech Oy | Verfahren zur Herstellung von verzweigtem Polypropylen |
RU2457290C2 (ru) * | 2007-03-26 | 2012-07-27 | Курарей Ко., Лтд. | Полипропиленовые волокна, способы их получения и их применение |
EP1990353B1 (en) * | 2007-05-08 | 2009-08-05 | Borealis Technology Oy | Electrical insulation film |
EP2030996A1 (en) | 2007-08-31 | 2009-03-04 | Borealis Technology Oy | Polyolefin compositions having improved optical and mechanical properties |
EP2147939A1 (en) | 2008-07-22 | 2010-01-27 | Borealis AG | Polypropylene composition with improved optics for film and moulding applications |
BR112012011265B1 (pt) | 2009-11-11 | 2020-12-01 | Borealis Ag | cabo e processo de produção do mesmo |
CN102666602B (zh) | 2009-11-11 | 2015-11-25 | 博瑞立斯有限公司 | 具有有利的电性能的可交联的聚合物组合物和电缆 |
US10246527B2 (en) | 2009-11-11 | 2019-04-02 | Borealis Ag | Polymer composition comprising a polyolefin produced in a high pressure process, a high pressure process and an article |
ES2534468T5 (es) | 2009-11-11 | 2022-10-31 | Borealis Ag | Composición polimérica y cable eléctrico que comprende la composición polimérica |
KR101959473B1 (ko) | 2010-03-17 | 2019-03-18 | 보레알리스 아게 | 유리한 전기적 특성을 갖는 와이어 및 케이블 용도의 중합체 조성물 |
CN102947895B (zh) | 2010-03-17 | 2017-03-08 | 北欧化工股份公司 | 具有优良电特性的用于电力电缆应用的聚合物组合物 |
ES2385142T3 (es) | 2010-04-21 | 2012-07-18 | Borealis Ag | Composición de copolímero o propileno/1-hexeno con ventana de sellado amplia |
EP2439238B1 (en) * | 2010-10-06 | 2012-12-05 | Borealis AG | Polypropylene with living hinge properties |
EP3591670A1 (en) | 2010-11-03 | 2020-01-08 | Borealis AG | A polymer composition and a power cable comprising the polymer composition |
KR102056952B1 (ko) | 2011-05-04 | 2019-12-17 | 보레알리스 아게 | 전기 장치용 중합체 조성물 |
KR101891366B1 (ko) | 2011-05-04 | 2018-08-23 | 보레알리스 아게 | 전기 장치용 중합체 조성물 |
EP2705087B1 (en) | 2011-05-04 | 2017-03-01 | Borealis AG | Polymer composition for electrical devices |
EP2521137B1 (en) | 2011-05-04 | 2014-12-17 | Borealis AG | Polymer composition for electrical and communication devices |
EP2565221B2 (en) | 2011-08-30 | 2018-08-08 | Borealis AG | Process for the manufacture of a capacitor film |
ES2727405T3 (es) * | 2011-12-30 | 2019-10-16 | Borealis Ag | Preparación de catalizadores de ZN PP libres de ftalato |
WO2013148669A1 (en) | 2012-03-26 | 2013-10-03 | Freeslate, Inc. | Parallel reactor systems and methods for preparing materials |
JP6030947B2 (ja) * | 2012-12-26 | 2016-11-24 | サン・トックス株式会社 | ポリオレフィン系無延伸多層フィルム |
ES2671929T3 (es) | 2013-04-30 | 2018-06-11 | Unchained Labs | Métodos de muestreo de recipientes no atmosféricos en un sistema de reactor paralelo |
US9611341B2 (en) | 2014-02-07 | 2017-04-04 | Eastman Chemical Company | Amorphous propylene-ethylene copolymers |
US10723824B2 (en) | 2014-02-07 | 2020-07-28 | Eastman Chemical Company | Adhesives comprising amorphous propylene-ethylene copolymers |
US10696765B2 (en) | 2014-02-07 | 2020-06-30 | Eastman Chemical Company | Adhesive composition comprising amorphous propylene-ethylene copolymer and propylene polymer |
US10647795B2 (en) | 2014-02-07 | 2020-05-12 | Eastman Chemical Company | Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins |
US11267916B2 (en) | 2014-02-07 | 2022-03-08 | Eastman Chemical Company | Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins |
US10308740B2 (en) | 2014-02-07 | 2019-06-04 | Eastman Chemical Company | Amorphous propylene-ethylene copolymers |
US9714302B2 (en) | 2014-10-10 | 2017-07-25 | W. R. Grace & Co.—Conn. | Process for preparing spherical polymerization catalyst components for use in olefin polymerizations |
EP3212710B2 (en) | 2014-10-27 | 2023-12-27 | Borealis AG | Polymer composition for cable applications with advantageous electrical properties |
BR112018001471A2 (pt) | 2015-07-30 | 2018-09-11 | Borealis Ag | composição de polipropileno, processo para fabricação de uma composição de polipropileno, uso de uma composição de polipropileno, artigo, película, composição adesiva, e, processo para produzir um artigo |
JP6626990B2 (ja) * | 2016-04-22 | 2019-12-25 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | 3dプリンターのためのフィラメント用プロピレンターポリマー |
EP3445793B1 (en) * | 2016-04-22 | 2020-01-01 | Basell Poliolefine Italia S.r.l. | Propylene based filament for 3d printer |
JP6848059B2 (ja) * | 2017-06-30 | 2021-03-24 | 三井化学株式会社 | プロピレン系重合体、その製造方法、プロピレン系樹脂組成物および成形体 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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US4668753A (en) * | 1983-01-25 | 1987-05-26 | Mitsui Petrochemical Industries, Ltd. | Film-forming propylene copolymer, film thereof and process for production of the film |
EP1170307A1 (en) * | 2000-07-05 | 2002-01-09 | ATOFINA Research | Moulding of polyolefins having improved properties |
EP1072643B1 (en) * | 1999-07-27 | 2006-08-30 | Mitsui Chemicals, Inc. | Flexible resin composition and uses thereof |
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US4181762A (en) * | 1976-03-10 | 1980-01-01 | Brunswick Corporation | Fibers, yarns and fabrics of low modulus polymer |
DE4202663A1 (de) * | 1992-01-31 | 1993-08-05 | Alkor Gmbh | Kunststoffolie auf der basis eines polypropylenterpolymerisates, verfahren zu deren herstellung und verwendung |
CN1100069C (zh) * | 1994-05-12 | 2003-01-29 | 昭和电工株式会社 | 丙烯系聚合物及其制法 |
JP3497080B2 (ja) * | 1994-05-12 | 2004-02-16 | 昭和電工株式会社 | プロピレン系重合体の重合用触媒成分の製法 |
US6184328B1 (en) * | 1994-09-07 | 2001-02-06 | Showa Denko Kabushiki Kaisha | Propylene-based polymer, method for its production, composition thereof, catalyst component for polymerization, and method for its production |
JPH08198913A (ja) * | 1995-01-26 | 1996-08-06 | Sumitomo Chem Co Ltd | ポリプロピレンフイルム |
DE19813399A1 (de) * | 1998-03-26 | 1999-09-30 | Basf Ag | Statistische Propylencopolymerisate |
FR2776660B1 (fr) | 1998-03-27 | 2000-05-12 | Parke Davis | Diazepino-indoles de phosphodiesterases iv |
CN1227288C (zh) * | 2000-05-31 | 2005-11-16 | 巴塞尔技术有限公司 | 具有改善抗冲击强度和优秀光学特性的丙烯聚合物组合物 |
ATE328912T1 (de) * | 2001-06-20 | 2006-06-15 | Borealis Tech Oy | Herstellung eines katalysatorbestandteils zur olefinpolymerisation |
EP1302486A1 (en) * | 2001-10-09 | 2003-04-16 | Borealis Technology Oy | Process for the production of propylene copolymers |
EP1323747A1 (en) * | 2001-12-19 | 2003-07-02 | Borealis Technology Oy | Production of olefin polymerisation catalysts |
EP1403292B1 (en) * | 2002-09-30 | 2016-04-13 | Borealis Polymers Oy | Process for preparing an olefin polymerisation catalyst component with improved high temperature activity |
EP1712571B1 (en) | 2002-10-07 | 2008-04-09 | Dow Global Technologies Inc. | Highly crystalline polypropylene with low xylene solubles |
JP3885034B2 (ja) * | 2003-03-12 | 2007-02-21 | 東邦キャタリスト株式会社 | オレフィン類重合用固体触媒成分の調製方法 |
EP1484345A1 (en) | 2003-06-06 | 2004-12-08 | Borealis Technology Oy | Process for the production of polypropylene using a Ziegler-Natta catalyst |
-
2003
- 2003-06-06 EP EP03012906A patent/EP1484345A1/en not_active Withdrawn
-
2004
- 2004-06-04 JP JP2006508279A patent/JP2006527271A/ja active Pending
- 2004-06-04 CA CA002526144A patent/CA2526144A1/en not_active Abandoned
- 2004-06-04 US US10/559,484 patent/US7465775B2/en not_active Expired - Fee Related
- 2004-06-04 BR BRPI0411063-3A patent/BRPI0411063A/pt not_active IP Right Cessation
- 2004-06-04 ES ES04736049.0T patent/ES2536477T3/es not_active Expired - Lifetime
- 2004-06-04 AU AU2004247364A patent/AU2004247364A1/en not_active Abandoned
- 2004-06-04 WO PCT/EP2004/006053 patent/WO2004111098A2/en active Application Filing
- 2004-06-04 KR KR1020057023424A patent/KR100990923B1/ko active IP Right Grant
- 2004-06-04 EA EA200501657A patent/EA011642B1/ru not_active IP Right Cessation
- 2004-06-04 CN CN2004800157074A patent/CN1802392B/zh not_active Expired - Fee Related
- 2004-06-04 EP EP04736049.0A patent/EP1631601B1/en not_active Revoked
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4668753A (en) * | 1983-01-25 | 1987-05-26 | Mitsui Petrochemical Industries, Ltd. | Film-forming propylene copolymer, film thereof and process for production of the film |
EP1072643B1 (en) * | 1999-07-27 | 2006-08-30 | Mitsui Chemicals, Inc. | Flexible resin composition and uses thereof |
EP1170307A1 (en) * | 2000-07-05 | 2002-01-09 | ATOFINA Research | Moulding of polyolefins having improved properties |
Non-Patent Citations (2)
Title |
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EP 1170307 A,全文. |
WO 0300754 A,权利要求和实施例. |
Also Published As
Publication number | Publication date |
---|---|
EA200501657A1 (ru) | 2006-06-30 |
KR100990923B1 (ko) | 2010-11-01 |
CA2526144A1 (en) | 2004-12-23 |
US20060235172A1 (en) | 2006-10-19 |
WO2004111098A3 (en) | 2005-08-04 |
US7465775B2 (en) | 2008-12-16 |
WO2004111098A2 (en) | 2004-12-23 |
BRPI0411063A (pt) | 2006-08-01 |
ES2536477T3 (es) | 2015-05-25 |
CN1802392A (zh) | 2006-07-12 |
JP2006527271A (ja) | 2006-11-30 |
EA011642B1 (ru) | 2009-04-28 |
EP1484345A1 (en) | 2004-12-08 |
EP1631601B1 (en) | 2015-04-29 |
AU2004247364A1 (en) | 2004-12-23 |
EP1631601A2 (en) | 2006-03-08 |
KR20060028685A (ko) | 2006-03-31 |
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CF01 | Termination of patent right due to non-payment of annual fee | ||
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Granted publication date: 20101013 Termination date: 20210604 |