CN1800282A - 汽车用透明涂料组合物和使用它的多层涂膜的形成方法 - Google Patents
汽车用透明涂料组合物和使用它的多层涂膜的形成方法 Download PDFInfo
- Publication number
- CN1800282A CN1800282A CN200510132165.5A CN200510132165A CN1800282A CN 1800282 A CN1800282 A CN 1800282A CN 200510132165 A CN200510132165 A CN 200510132165A CN 1800282 A CN1800282 A CN 1800282A
- Authority
- CN
- China
- Prior art keywords
- coating composition
- clear coating
- mentioned
- compound
- soft segment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000008199 coating composition Substances 0.000 title claims abstract description 79
- 238000000576 coating method Methods 0.000 title claims abstract description 40
- 239000011248 coating agent Substances 0.000 title claims abstract description 37
- 238000000034 method Methods 0.000 title claims description 30
- -1 isocyanate compound Chemical class 0.000 claims abstract description 137
- 239000012948 isocyanate Substances 0.000 claims abstract description 69
- 239000000178 monomer Substances 0.000 claims abstract description 63
- 239000007787 solid Substances 0.000 claims abstract description 31
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 claims abstract description 19
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 13
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims abstract description 13
- 239000002253 acid Substances 0.000 claims description 98
- 229920005989 resin Polymers 0.000 claims description 85
- 239000011347 resin Substances 0.000 claims description 85
- 150000002513 isocyanates Chemical class 0.000 claims description 47
- 150000002148 esters Chemical class 0.000 claims description 46
- 150000001875 compounds Chemical class 0.000 claims description 33
- 230000015572 biosynthetic process Effects 0.000 claims description 25
- 239000004615 ingredient Substances 0.000 claims description 22
- 239000000758 substrate Substances 0.000 claims description 19
- CERQOIWHTDAKMF-UHFFFAOYSA-N alpha-methacrylic acid Natural products CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 11
- 238000010438 heat treatment Methods 0.000 claims description 10
- 230000007704 transition Effects 0.000 claims description 7
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract description 22
- 150000002596 lactones Chemical class 0.000 abstract description 9
- 239000004925 Acrylic resin Substances 0.000 abstract description 6
- 229920000178 Acrylic resin Polymers 0.000 abstract description 6
- 230000009477 glass transition Effects 0.000 abstract description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 abstract 1
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 18
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 16
- 239000005977 Ethylene Substances 0.000 description 15
- 239000003795 chemical substances by application Substances 0.000 description 14
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 13
- 239000000203 mixture Substances 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 11
- 230000002596 correlated effect Effects 0.000 description 11
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 10
- 229920000642 polymer Polymers 0.000 description 10
- 238000012360 testing method Methods 0.000 description 10
- 229920000877 Melamine resin Polymers 0.000 description 9
- 238000004132 cross linking Methods 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- LDHQCZJRKDOVOX-UHFFFAOYSA-N 2-butenoic acid Chemical compound CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 7
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 7
- 238000006116 polymerization reaction Methods 0.000 description 7
- 239000002904 solvent Substances 0.000 description 7
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 6
- 230000007423 decrease Effects 0.000 description 6
- 235000019439 ethyl acetate Nutrition 0.000 description 6
- 238000011156 evaluation Methods 0.000 description 6
- JBFHTYHTHYHCDJ-UHFFFAOYSA-N gamma-caprolactone Chemical compound CCC1CCC(=O)O1 JBFHTYHTHYHCDJ-UHFFFAOYSA-N 0.000 description 6
- JQKFLNWRTBPECK-UHFFFAOYSA-N methoxymethane;propane-1,2-diol Chemical compound COC.CC(O)CO JQKFLNWRTBPECK-UHFFFAOYSA-N 0.000 description 6
- 239000003973 paint Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 238000004070 electrodeposition Methods 0.000 description 5
- YDNLNVZZTACNJX-UHFFFAOYSA-N isocyanatomethylbenzene Chemical compound O=C=NCC1=CC=CC=C1 YDNLNVZZTACNJX-UHFFFAOYSA-N 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 238000005507 spraying Methods 0.000 description 5
- LRRBANSQUYNJTH-UHFFFAOYSA-N 2-tert-butylperoxy-2-methylpropane;2-ethylhexanoic acid Chemical compound CCCCC(CC)C(O)=O.CC(C)(C)OOC(C)(C)C LRRBANSQUYNJTH-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 4
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 3
- 239000005058 Isophorone diisocyanate Substances 0.000 description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
- 125000002091 cationic group Chemical group 0.000 description 3
- 239000000428 dust Substances 0.000 description 3
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 3
- 125000005395 methacrylic acid group Chemical group 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 2
- WDQMWEYDKDCEHT-UHFFFAOYSA-N 2-ethylhexyl 2-methylprop-2-enoate Chemical group CCCCC(CC)COC(=O)C(C)=C WDQMWEYDKDCEHT-UHFFFAOYSA-N 0.000 description 2
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 229920006243 acrylic copolymer Polymers 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 description 2
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical compound NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 125000003700 epoxy group Chemical group 0.000 description 2
- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- LVHBHZANLOWSRM-UHFFFAOYSA-N itaconic acid Chemical compound OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 239000007870 radical polymerization initiator Substances 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 150000007970 thio esters Chemical class 0.000 description 2
- RSJKGSCJYJTIGS-UHFFFAOYSA-N undecane Chemical compound CCCCCCCCCCC RSJKGSCJYJTIGS-UHFFFAOYSA-N 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- PSGCQDPCAWOCSH-UHFFFAOYSA-N (4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl) prop-2-enoate Chemical compound C1CC2(C)C(OC(=O)C=C)CC1C2(C)C PSGCQDPCAWOCSH-UHFFFAOYSA-N 0.000 description 1
- PYOLJOJPIPCRDP-UHFFFAOYSA-N 1,1,3-trimethylcyclohexane Chemical compound CC1CCCC(C)(C)C1 PYOLJOJPIPCRDP-UHFFFAOYSA-N 0.000 description 1
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical group C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 1
- IKYNWXNXXHWHLL-UHFFFAOYSA-N 1,3-diisocyanatopropane Chemical compound O=C=NCCCN=C=O IKYNWXNXXHWHLL-UHFFFAOYSA-N 0.000 description 1
- OVBFMUAFNIIQAL-UHFFFAOYSA-N 1,4-diisocyanatobutane Chemical compound O=C=NCCCCN=C=O OVBFMUAFNIIQAL-UHFFFAOYSA-N 0.000 description 1
- MWBSQVPLYJZPTG-UHFFFAOYSA-N 1-isocyanato-2-propan-2-ylbenzene Chemical class CC(C)C1=CC=CC=C1N=C=O MWBSQVPLYJZPTG-UHFFFAOYSA-N 0.000 description 1
- IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical compound C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical compound ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 description 1
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 1
- DXIJHCSGLOHNES-UHFFFAOYSA-N 3,3-dimethylbut-1-enylbenzene Chemical compound CC(C)(C)C=CC1=CC=CC=C1 DXIJHCSGLOHNES-UHFFFAOYSA-N 0.000 description 1
- CYUZOYPRAQASLN-UHFFFAOYSA-N 3-prop-2-enoyloxypropanoic acid Chemical compound OC(=O)CCOC(=O)C=C CYUZOYPRAQASLN-UHFFFAOYSA-N 0.000 description 1
- HOSGXJWQVBHGLT-UHFFFAOYSA-N 6-hydroxy-3,4-dihydro-1h-quinolin-2-one Chemical group N1C(=O)CCC2=CC(O)=CC=C21 HOSGXJWQVBHGLT-UHFFFAOYSA-N 0.000 description 1
- IWHLYPDWHHPVAA-UHFFFAOYSA-N 6-hydroxyhexanoic acid Chemical compound OCCCCCC(O)=O IWHLYPDWHHPVAA-UHFFFAOYSA-N 0.000 description 1
- FJNCXZZQNBKEJT-UHFFFAOYSA-N 8beta-hydroxymarrubiin Natural products O1C(=O)C2(C)CCCC3(C)C2C1CC(C)(O)C3(O)CCC=1C=COC=1 FJNCXZZQNBKEJT-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- GGZRYCRUHVSZEE-UHFFFAOYSA-N C1=CC=CC1.C1=CC=CC1.CC=CC(=O)O Chemical compound C1=CC=CC1.C1=CC=CC1.CC=CC(=O)O GGZRYCRUHVSZEE-UHFFFAOYSA-N 0.000 description 1
- RZTOWFMDBDPERY-UHFFFAOYSA-N Delta-Hexanolactone Chemical compound CC1CCCC(=O)O1 RZTOWFMDBDPERY-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- OUUQCZGPVNCOIJ-UHFFFAOYSA-M Superoxide Chemical compound [O-][O] OUUQCZGPVNCOIJ-UHFFFAOYSA-M 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- ISKQADXMHQSTHK-UHFFFAOYSA-N [4-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=C(CN)C=C1 ISKQADXMHQSTHK-UHFFFAOYSA-N 0.000 description 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 238000003916 acid precipitation Methods 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- BAPJBEWLBFYGME-UHFFFAOYSA-N acrylic acid methyl ester Natural products COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Substances C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 1
- VEZXCJBBBCKRPI-UHFFFAOYSA-N beta-propiolactone Chemical compound O=C1CCO1 VEZXCJBBBCKRPI-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- VIHAEDVKXSOUAT-UHFFFAOYSA-N but-2-en-4-olide Chemical compound O=C1OCC=C1 VIHAEDVKXSOUAT-UHFFFAOYSA-N 0.000 description 1
- 229930188620 butyrolactone Natural products 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 125000002843 carboxylic acid group Chemical group 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000012986 chain transfer agent Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- WCASXYBKJHWFMY-UHFFFAOYSA-N crotyl alcohol Chemical compound CC=CCO WCASXYBKJHWFMY-UHFFFAOYSA-N 0.000 description 1
- OIWOHHBRDFKZNC-UHFFFAOYSA-N cyclohexyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1CCCCC1 OIWOHHBRDFKZNC-UHFFFAOYSA-N 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- HANKSFAYJLDDKP-UHFFFAOYSA-N dihydrodicyclopentadiene Chemical compound C12CC=CC2C2CCC1C2 HANKSFAYJLDDKP-UHFFFAOYSA-N 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical class CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 1
- GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- CCGKOQOJPYTBIH-UHFFFAOYSA-N ethenone Chemical compound C=C=O CCGKOQOJPYTBIH-UHFFFAOYSA-N 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229940051250 hexylene glycol Drugs 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 150000002500 ions Chemical group 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 150000007974 melamines Chemical class 0.000 description 1
- 229930182817 methionine Natural products 0.000 description 1
- ZQMHJBXHRFJKOT-UHFFFAOYSA-N methyl 2-[(1-methoxy-2-methyl-1-oxopropan-2-yl)diazenyl]-2-methylpropanoate Chemical compound COC(=O)C(C)(C)N=NC(C)(C)C(=O)OC ZQMHJBXHRFJKOT-UHFFFAOYSA-N 0.000 description 1
- 239000003110 molding sand Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- WRAQQYDMVSCOTE-UHFFFAOYSA-N phenyl prop-2-enoate Chemical compound C=CC(=O)OC1=CC=CC=C1 WRAQQYDMVSCOTE-UHFFFAOYSA-N 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 229960000380 propiolactone Drugs 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000012756 surface treatment agent Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 1
- 229910000165 zinc phosphate Inorganic materials 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
- C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/14—Esterification
- C08F8/16—Lactonisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
- C08G18/6216—Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
- C08G18/622—Polymers of esters of alpha-beta ethylenically unsaturated carboxylic acids
- C08G18/6225—Polymers of esters of acrylic or methacrylic acid
- C08G18/6229—Polymers of hydroxy groups containing esters of acrylic or methacrylic acid with aliphatic polyalcohols
- C08G18/6233—Polymers of hydroxy groups containing esters of acrylic or methacrylic acid with aliphatic polyalcohols the monomers or polymers being esterified with carboxylic acids or lactones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/7806—Nitrogen containing -N-C=0 groups
- C08G18/7818—Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups
- C08G18/7831—Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups containing biuret groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/062—Copolymers with monomers not covered by C09D133/06
- C09D133/066—Copolymers with monomers not covered by C09D133/06 containing -OH groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
Description
含羟基丙烯酸树脂[*1] | a | b | c | d | e | f | g | h | |
单甲基醚丙二醇乙酸酯(溶剂)(g) | 508.0 | 508.0 | 508.0 | 508.0 | 598.0 | 508.0 | 508.0 | 508.0 | |
二甲苯(溶剂)(g) | 90.0 | 90.0 | 90.0 | 90.0 | 90.0 | 90.0 | 90.0 | ||
过氧化叔丁基-2-乙基己酸酯(聚合引发剂)(g) | 110 | 110 | 110 | 110 | 110 | 110 | 110 | 110 | |
苯乙烯(无内酯单体)(g) | 200.0 | 200.0 | 70.0 | 70.0 | 20.0 | 70.0 | 68.9 | 200.0 | |
丙烯酸正丁酯(无内酯单体)(g) | 288.5 | 204.3 | 43 | 120 | 140.0 | 312.0 | 122.0 | ||
甲基丙烯酸正丁酯(无内酯单体)(g) | 392 | 285 | 160 | 191 | |||||
丙烯酸-2-乙基己酯(无内酯单体)(g) | 95.0 | 80 | 50.0 | ||||||
甲基丙烯酸-2-乙基己酯(无内酯单体)(g) | 74.5 | 74.5 | 80.0 | 80.0 | 182.1 | ||||
丙烯酸-2-羟基乙酯(无内酯单体)(g) | 100.0 | ||||||||
丙烯酸-4-羟基丁酯(无内酯单体)(g) | 437.0 | 365.0 | 345.0 | 435.0 | 275.0 | 437.0 | 437.0 | ||
丙烯酸-6-羟基己酯(无内酯单体)(g) | 521.2 | ||||||||
プラクセルFM-1(含内酯单体)(g) | 275.0 | ||||||||
プラクセルFM-2(含内酯单体)(g) | 50 | 100 | 70.0 | ||||||
プラクセルFM-5(含内酯单体)(g) | 280.0 | ||||||||
单体总量(g) | 1000.0 | 1000.0 | 1000.0 | 1000.0 | 1000.0 | 1000.0 | 1000.0 | 1000.0 | |
计算Tg(℃) | -25 | - | -11 | -18 | -40 | -23 | -35 | -12 | |
羟基值(mgKOH/g) | 170 | 170 | 150 | 150 | 251 | 170 | 170 | 170 | |
分子量(Mn) | 4700 | 4500 | 3900 | 4100 | 4700 | 4000 | 3900 | 4500 | |
分子量(Mw) | 13500 | 12800 | 9100 | 9200 | 11300 | 9400 | 9700 | 11000 | |
树脂固体组分(质量%) | 63.5 | 62.5 | 62.2 | 62.1 | 63.3 | 64.5 | 62.8 | 62.1 | |
内酯部分的含量(质量%) | 0 | 0 | 3.2 | 6.4 | 27.3 | 12.85 | 0 | 0 | |
树脂固体组分中的柔性链段部的含量(质量%) | 来自含内酯单体的柔性链段部的含量(质量%) | 0 | 0 | 1.95 | 3.91 | 16.74 | 7.89 | 0 | 0 |
来自无内酯单体的柔性链段部的含量(质量%) | 16.99 | 25.44 | 14.20 | 13.42 | 16.91 | 10.69 | 16.99 | 16.99 | |
总柔性链段部含量(质量%) | 16.99 | 25.44 | 16.15 | 17.33 | 33.65 | 18.58 | 16.99 | 16.99 |
含羟基丙烯酸树脂 | 内酯部含量(质量%) | 来自含内酯单体的柔性链段部的含量(质量%) | 来自无内酯单体的柔性链段部的含量(质量%) | 总柔性链段部含量(质量%) | 实施例(固体组分含量)(质量%)[*1] | 比较例(固体组分含量)(质量%)[*1] | |||||||
1 | 2 | 3 | 4 | 1 | 2 | 3 | 4 | 5 | |||||
含羟基丙烯酸树脂a | 0 | 0 | 17.0 | 17.0 | 64.4 | ||||||||
含羟基丙烯酸树脂b | 0 | 0 | 25.4 | 25.4 | 64.4 | ||||||||
含羟基丙烯酸树脂c | 3.18 | 1.95 | 142 | 16.2 | 66 | ||||||||
含羟基丙烯酸树脂d | 6.37 | 3 91 | 13.4 | 17.3 | 66 | ||||||||
含羟基丙烯酸树脂e | 27.3 | 16.74 | 16.9 | 33.7 | 53.8 | ||||||||
含羟基丙烯酸树脂f | 12.85 | 7.89 | 10.7 | 16.6 | 63.2 | 63.2 | |||||||
含羟基丙烯酸树脂g | 0 | 0 | 17.0 | 17.0 | 63.2 | ||||||||
含羟基丙烯酸树脂h | 0 | 0 | 17.0 | 17.0 | 63.2 | ||||||||
缩二脲型异氰酸酯固化剂 | 0 | 0 | 0.0 | 52.7 | 46.2 | 36.8 | 36.8 | 36.8 | |||||
异氰脲酸酯型异氰酸酯固化剂 | 0 | 0 | 0.0 | 50.0 | 35.6 | 35.6 | 34 | 34 | 36.8 | ||||
透明涂料组合物的固体组分总体中的内酯部的含量(质量%) | 0 | 0 | 2.1 | 4.2 | 14.69 | 8.1 | 8.1 | 0 | 0 | ||||
透明涂料组合物的固体组分总体中的柔性链段部的含量(质量%) | 来自含内酯单体的柔性链段部的含量(质量%) | 0.0 | 0.0 | 1.3 | 2.6 | 9.0 | 5.0 | 5.0 | 0.0 | 0.0 | |||
来自无内酯单体的柔性链段部的含量(质量%) | 10.9 | 16.4 | 9.4 | 8.9 | 9.1 | 6.8 | 6.8 | 10.7 | 10.7 | ||||
来自含羟基丙烯酸树脂的总柔性链段部的含量(质量%) | 10.9 | 16.4 | 10.7 | 11.4 | 18.1 | 11.7 | 11.7 | 10.7 | 10.7 | ||||
来自异氰酸酯固化剂的柔性链段部的含量(质量%) | 17.8 | 17.8 | 16.9 | 17.0 | 24.3 | 19.4 | 18.4 | 19.4 | 19.4 | ||||
合计 | 28.7 | 34.2 | 27.6 | 28.4 | 42.5 | 31.2 | 30.1 | 30.1 | 30.1 | ||||
涂膜的物性值 | 动态Tg(℃) | 45.9 | 46.7 | 47.9 | 45.2 | 52.1 | 50.3 | 46.1 | 47.9 | 64.7 | |||
交联密度(×10-3mol/cc) | 1.951 | 1.995 | 1.805 | 1.698 | 2.250 | 1.986 | 1.830 | 2.185 | 1.934 | ||||
耐酸性 | AB | AB | AB | AB | C | C | B | B | B | ||||
耐洗车擦伤性 | 95 | 96 | 96 | 96 | 98 | 95 | 96 | 96 | 95 | ||||
耐划伤性 | B | B | B | A | B | B | B | B | D |
Claims (5)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2004370987A JP4744871B2 (ja) | 2004-12-22 | 2004-12-22 | 自動車用クリヤー塗料組成物及びそれを用いた複層塗膜の形成方法 |
JP2004-370987 | 2004-12-22 | ||
JP2004370987 | 2004-12-22 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1800282A true CN1800282A (zh) | 2006-07-12 |
CN1800282B CN1800282B (zh) | 2010-05-12 |
Family
ID=35840931
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN200510132165.5A Expired - Fee Related CN1800282B (zh) | 2004-12-22 | 2005-12-22 | 汽车用透明涂料组合物和使用它的多层涂膜的形成方法 |
Country Status (5)
Country | Link |
---|---|
US (1) | US8138258B2 (zh) |
JP (1) | JP4744871B2 (zh) |
CN (1) | CN1800282B (zh) |
FR (1) | FR2879615B1 (zh) |
GB (1) | GB2421734B (zh) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113845831A (zh) * | 2021-10-14 | 2021-12-28 | Ppg涂料(天津)有限公司 | 清漆组合物 |
CN114381155A (zh) * | 2020-10-06 | 2022-04-22 | 丰田自动车株式会社 | 电子束固化型涂料组合物 |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4368395B2 (ja) * | 2007-08-22 | 2009-11-18 | Basfコーティングスジャパン株式会社 | 塗料組成物、塗装仕上げ方法及び塗装物品 |
US7863375B2 (en) * | 2008-10-08 | 2011-01-04 | Toyota Motor Engineering & Manufacturing North America, Inc. | Self-stratifying automotive topcoat compositions and processes |
US8299170B2 (en) * | 2008-10-08 | 2012-10-30 | Toyota Motor Engineering & Manufacturing North America, Inc. | Self-stratifying coating |
JP2012097173A (ja) * | 2010-11-01 | 2012-05-24 | Dic Corp | 耐傷性に優れるコーティング樹脂組成物 |
CN103725128B (zh) * | 2013-12-12 | 2016-07-06 | 江苏普兰纳涂料有限公司 | 双组份pp汽车饰件用单工序面漆 |
Family Cites Families (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0245577A (ja) | 1988-08-04 | 1990-02-15 | Nippon Paint Co Ltd | 熱硬化性組成物 |
JPH0819315B2 (ja) | 1990-04-05 | 1996-02-28 | 日本ペイント株式会社 | 熱硬化性樹脂組成物 |
US5322861A (en) * | 1991-10-01 | 1994-06-21 | Mitsubishi Kasei Corporation | Ultraviolet-hardening urethane acrylate oligomer |
JPH05202335A (ja) | 1992-01-24 | 1993-08-10 | Nippon Paint Co Ltd | 熱硬化性塗料組成物 |
EP0749448B1 (en) * | 1993-09-03 | 2001-05-30 | ARCO Chemical Technology, L.P. | Use of pyrazole-blocked polyisocyanates in one-component clear coatings |
JP3413265B2 (ja) * | 1993-12-28 | 2003-06-03 | 三菱レイヨン株式会社 | 熱硬化被覆組成物 |
DE4407409A1 (de) | 1994-03-05 | 1995-09-07 | Basf Lacke & Farben | Beschichtungsmittel auf Basis eines hydroxylgruppenhaltigen Polyacrylatharzes und seine Verwendung in Verfahren zur Herstellung einer Mehrschichtlackierung |
GB9406815D0 (en) | 1994-04-06 | 1994-05-25 | Ici Plc | Polymer |
JPH09132753A (ja) | 1995-11-07 | 1997-05-20 | Aisin Chem Co Ltd | 熱硬化性塗料組成物 |
US5849835A (en) * | 1995-12-19 | 1998-12-15 | Ppg Industries, Inc. | Polyisocyanate cured ultradurable glossy coating compositions |
DE19828935A1 (de) * | 1998-06-29 | 1999-12-30 | Basf Ag | Hochviskose Polyisocyanate enthaltende Zusammensetzungen |
ES2205948T3 (es) * | 1998-11-17 | 2004-05-01 | Vantico Ag | Composiciones reticulante para polimeros que contienen carboxilo, en sistemas curables por calor. |
JP2003082031A (ja) * | 2001-09-13 | 2003-03-19 | Kansai Paint Co Ltd | 共重合体およびこの重合体を用いた耐擦り傷性塗料組成物 |
JP2003253191A (ja) * | 2002-02-28 | 2003-09-10 | Nippon Paint Co Ltd | クリヤー塗料組成物及び複層塗膜形成方法 |
US7157536B2 (en) * | 2004-01-19 | 2007-01-02 | E. I. Du Pont De Nemours And Company | Coating composition for ambient cure containing an alkoxylated amine |
JP4477483B2 (ja) * | 2004-12-22 | 2010-06-09 | 日本ペイント株式会社 | 硬化性樹脂組成物、クリヤー塗料組成物及びそれを用いた複層塗膜の形成方法 |
JP4902115B2 (ja) * | 2004-12-22 | 2012-03-21 | 日本ペイント株式会社 | 硬化性樹脂組成物、クリヤー塗料組成物及びそれを用いた複層塗膜の形成方法 |
JP2007196982A (ja) | 2005-12-26 | 2007-08-09 | Bridgestone Corp | ストラットマウント |
-
2004
- 2004-12-22 JP JP2004370987A patent/JP4744871B2/ja active Active
-
2005
- 2005-12-21 GB GB0526080A patent/GB2421734B/en active Active
- 2005-12-22 CN CN200510132165.5A patent/CN1800282B/zh not_active Expired - Fee Related
- 2005-12-22 US US11/313,786 patent/US8138258B2/en not_active Expired - Fee Related
- 2005-12-22 FR FR0513117A patent/FR2879615B1/fr not_active Expired - Fee Related
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114381155A (zh) * | 2020-10-06 | 2022-04-22 | 丰田自动车株式会社 | 电子束固化型涂料组合物 |
CN113845831A (zh) * | 2021-10-14 | 2021-12-28 | Ppg涂料(天津)有限公司 | 清漆组合物 |
Also Published As
Publication number | Publication date |
---|---|
GB2421734B (en) | 2008-08-20 |
FR2879615B1 (fr) | 2014-07-25 |
US20060147639A1 (en) | 2006-07-06 |
US8138258B2 (en) | 2012-03-20 |
FR2879615A1 (fr) | 2006-06-23 |
JP4744871B2 (ja) | 2011-08-10 |
CN1800282B (zh) | 2010-05-12 |
GB2421734A (en) | 2006-07-05 |
JP2006176634A (ja) | 2006-07-06 |
GB0526080D0 (en) | 2006-02-01 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN1800282A (zh) | 汽车用透明涂料组合物和使用它的多层涂膜的形成方法 | |
KR100642174B1 (ko) | 클리어 도장 스테인레스 강판 | |
RU2669610C2 (ru) | Двухкомпонентная красочная композиция и способ образования многослойного покрытия с ее применением | |
CN1047782C (zh) | 热固性覆盖组合物 | |
US10011738B2 (en) | Clear paint composition for hot stamping film and painting method using the same | |
CN100471670C (zh) | 层合膜 | |
CN1891768A (zh) | 涂料组合物和形成多层涂布膜的方法以及使用该涂料组合物的涂布制品 | |
JP2009046642A (ja) | 塗料組成物、塗装仕上げ方法及び塗装物品 | |
GB2435192A (en) | Curable resin composition, clear coating composition, and multilayer coating film forming method using same | |
CN100339163C (zh) | 一种生产涂布复合涂膜的方法 | |
CN1133330A (zh) | 含有氨基甲酸酯和丙烯酰胺功能组分的涂层组合物 | |
CN1196756C (zh) | 涂料用树脂组合物 | |
CN107936814A (zh) | 一种poss 改性的高硬度聚氨酯净味木器漆 | |
CN104312420A (zh) | 车灯真空镀膜用紫外光-热双重固化底漆及使用方法 | |
JPH10503787A (ja) | 硬化性樹脂組成物、塗料組成物、塗膜形成方法及び塗装物 | |
JP5324726B2 (ja) | クリヤー塗料組成物及びそれを用いた複層塗膜の形成方法 | |
JP4894190B2 (ja) | 塗料組成物、塗装仕上げ方法及び塗装物品 | |
JP6762209B2 (ja) | アクリル樹脂及びメラミン樹脂を主体樹脂とするトップコート用塗料組成物 | |
EP2647679B1 (en) | Clear coating composition and method for forming multilayer coating film that uses same | |
US20080107904A1 (en) | Hydroxyl-Containing Resin Composition for Coating Materials, Coating Composition, Coating Finishing Method, and Coated Article | |
KR100558086B1 (ko) | 하이솔리드 투명 도료의 제조방법 | |
WO2019107570A1 (ja) | 塗料組成物及び複層塗膜の形成方法 | |
JP3863718B2 (ja) | クリヤー塗料組成物、塗膜形成方法および積層塗膜 | |
JP4477483B2 (ja) | 硬化性樹脂組成物、クリヤー塗料組成物及びそれを用いた複層塗膜の形成方法 | |
JPH04114069A (ja) | 熱硬化性塗料組成物 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C41 | Transfer of patent application or patent right or utility model | ||
C56 | Change in the name or address of the patentee | ||
CP03 | Change of name, title or address |
Address after: Osaka Japan Patentee after: NIPPON PAINT HOLDINGS CO.,LTD. Patentee after: Toyota Motor Corp. Address before: Osaka Patentee before: NIPPON PAINT Co.,Ltd. Patentee before: Toyota Motor Corp. |
|
TR01 | Transfer of patent right |
Effective date of registration: 20160113 Address after: Osaka Japan Patentee after: NIPPON PAINT AUTOMOTIVE COATINGS CO.,LTD. Patentee after: Toyota Motor Corp. Address before: Osaka Japan Patentee before: NIPPON PAINT HOLDINGS CO.,LTD. Patentee before: Toyota Motor Corp. |
|
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20100512 |
|
CF01 | Termination of patent right due to non-payment of annual fee |