CN1799108B - 用于制备导电聚合物的延迟氧化剂 - Google Patents
用于制备导电聚合物的延迟氧化剂 Download PDFInfo
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- CN1799108B CN1799108B CN2004800152333A CN200480015233A CN1799108B CN 1799108 B CN1799108 B CN 1799108B CN 2004800152333 A CN2004800152333 A CN 2004800152333A CN 200480015233 A CN200480015233 A CN 200480015233A CN 1799108 B CN1799108 B CN 1799108B
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- oxidant
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- QDVDVAOWCIPDPH-UHFFFAOYSA-N CC1(C)Oc2c[nH]cc2ON1 Chemical compound CC1(C)Oc2c[nH]cc2ON1 QDVDVAOWCIPDPH-UHFFFAOYSA-N 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G49/00—Compounds of iron
- C01G49/0009—Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
- C08G61/122—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
- C08G61/123—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds
- C08G61/124—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds with a five-membered ring containing one nitrogen atom in the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
- C08G61/122—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
- C08G61/123—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds
- C08G61/126—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds with a five-membered ring containing one sulfur atom in the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/02—Polyamines
- C08G73/026—Wholly aromatic polyamines
- C08G73/0266—Polyanilines or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/0605—Polycondensates containing five-membered rings, not condensed with other rings, with nitrogen atoms as the only ring hetero atoms
- C08G73/0611—Polycondensates containing five-membered rings, not condensed with other rings, with nitrogen atoms as the only ring hetero atoms with only one nitrogen atom in the ring, e.g. polypyrroles
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
- H01G11/48—Conductive polymers
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/40—Electric properties
Abstract
Description
体积比氧化剂:MP 62 | 9∶1 | 3∶1 | 2∶1 | 参考 |
贮存期 | 2h | 4h | 24h | 9min |
体积比氧化剂:MP 62 | 2∶1 | 参考 |
表面电阻 | 77Ω/方 | 145Ω/方 |
层厚度 | 230nm | 305nm |
比电导 | 565S/cm | 226S/cm |
贮存期 | 48h | 18min |
体积比氧化剂:MP 62 | 2∶1 | 参考 |
贮存期 | 48h | 3h |
表面电阻 | 974Ω/方 |
层厚度 | 155nm |
比电导 | 66S/cm |
贮存期 | 96h |
氧化剂:MP 62的体积比 | 2∶1 | 参考 |
在-15℃下的贮存期 | 96h | 2h |
在6℃下的贮存期(实施例2) | 24h | 9min |
离子交换剂 | MP 62 | MP 64 | MP 600WS | 参考 |
贮存期 | 16h | 16h | 2h | 18min |
混合物 | 新的混合物 | 24h陈化的混合物 | 72h陈化的混合物 |
电容 | 67μF | 67μF | 65μF |
等效串联电阻 | 63mΩ | 57mΩ | 61mΩ |
反应分步骤 | 反应常数 | |
单体氧化 | k0 | 0.15 l3mol-3h-1 |
k01 | 0.026 l2mol-2h-1 | |
端基氧化 | k1 | 3000 l1mol-1h-1 |
k11 | 105 l4mol-2h-1 | |
自由基结合 | k2 | 109 l1mol-1h-1 |
聚合氧化 | kD | 0.5 l1mol-1h-1 |
kD | 0.1 l1mol-1h-1 |
Claims (37)
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10314978 | 2003-04-02 | ||
DE10314978.3 | 2003-04-02 | ||
DE10324534A DE10324534A1 (de) | 2003-04-02 | 2003-05-28 | Retardierende Oxidationsmittel zur Herstellung leitfähiger Polymere |
DE10324534.0 | 2003-05-28 | ||
PCT/EP2004/002951 WO2004088672A1 (de) | 2003-04-02 | 2004-03-20 | Spezielle oxidationsmittel zur herstellung leitfähiger polymere |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1799108A CN1799108A (zh) | 2006-07-05 |
CN1799108B true CN1799108B (zh) | 2012-05-16 |
Family
ID=32980947
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2004800152333A Expired - Fee Related CN1799108B (zh) | 2003-04-02 | 2004-03-20 | 用于制备导电聚合物的延迟氧化剂 |
Country Status (5)
Country | Link |
---|---|
JP (1) | JP2010209342A (zh) |
CN (1) | CN1799108B (zh) |
DE (1) | DE10324534A1 (zh) |
MY (1) | MY142357A (zh) |
TW (1) | TWI331599B (zh) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102004022110A1 (de) | 2004-05-05 | 2005-12-01 | H.C. Starck Gmbh | Verfahren zur Herstellung von Elektrolytkondensatoren |
DE102008023008A1 (de) | 2008-05-09 | 2009-11-12 | H.C. Starck Gmbh | Neuartige Polythiophene-Polyanion-Komplexe in unpolaren organischen Lösungsmitteln |
JP2017508857A (ja) * | 2014-06-17 | 2017-03-30 | ポリム テクノロジー コーポレーションPolym Technology Corporation | 共役複素芳香環重合体を含む電気活性重合体溶液または塗膜を形成する組成物および方法、電気活性重合体溶液、電気活性塗膜を含むコンデンサ(キャパシタ)および帯電防止体、および固体電解質コンデンサとその製造方法 |
CN111909362A (zh) * | 2019-05-09 | 2020-11-10 | 深圳新宙邦科技股份有限公司 | 一种导电聚合物、电容器及其制备方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5300575A (en) * | 1990-02-08 | 1994-04-05 | Bayer Aktiengesellschaft | Polythiophene dispersions, their production and their use |
CN1101161A (zh) * | 1993-09-30 | 1995-04-05 | 中国科学院化学研究所 | 导电聚合物复合膜及其制备方法 |
CN1279699A (zh) * | 1997-11-18 | 2001-01-10 | 陶氏化学公司 | 制备导电聚合物的方法 |
CN1354192A (zh) * | 2000-11-22 | 2002-06-19 | 拜尔公司 | 聚噻吩 |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6323933A (ja) * | 1986-07-17 | 1988-02-01 | Tokuyama Soda Co Ltd | イオン交換体の製造方法 |
JP4513044B2 (ja) * | 2000-08-22 | 2010-07-28 | 日本ケミコン株式会社 | 固体電解コンデンサおよびその製造方法 |
JP2002138137A (ja) * | 2000-11-01 | 2002-05-14 | Tayca Corp | 導電性高分子製造用酸化剤 |
-
2003
- 2003-05-28 DE DE10324534A patent/DE10324534A1/de not_active Withdrawn
-
2004
- 2004-03-20 CN CN2004800152333A patent/CN1799108B/zh not_active Expired - Fee Related
- 2004-03-31 MY MYPI20041177A patent/MY142357A/en unknown
- 2004-04-01 TW TW093108992A patent/TWI331599B/zh not_active IP Right Cessation
-
2010
- 2010-04-27 JP JP2010102359A patent/JP2010209342A/ja active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5300575A (en) * | 1990-02-08 | 1994-04-05 | Bayer Aktiengesellschaft | Polythiophene dispersions, their production and their use |
CN1101161A (zh) * | 1993-09-30 | 1995-04-05 | 中国科学院化学研究所 | 导电聚合物复合膜及其制备方法 |
CN1279699A (zh) * | 1997-11-18 | 2001-01-10 | 陶氏化学公司 | 制备导电聚合物的方法 |
CN1354192A (zh) * | 2000-11-22 | 2002-06-19 | 拜尔公司 | 聚噻吩 |
Also Published As
Publication number | Publication date |
---|---|
DE10324534A1 (de) | 2004-10-14 |
TW200500303A (en) | 2005-01-01 |
TWI331599B (en) | 2010-10-11 |
MY142357A (en) | 2010-11-30 |
CN1799108A (zh) | 2006-07-05 |
JP2010209342A (ja) | 2010-09-24 |
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Owner name: H.C. H. C. STARCK CLEVIOS GMBH Free format text: FORMER OWNER: H.C. STARCK GMBH + CO. KG. Effective date: 20141113 Owner name: HERAEUS PRECIOUS METALS GMBH + CO.KG Free format text: FORMER OWNER: HERAEUS CLEVIOS GMBH Effective date: 20141113 Owner name: HERAEUS CLEVIOS GMBH Free format text: FORMER OWNER: H.C. H. C. STARCK CLEVIOS GMBH Effective date: 20141113 |
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Effective date of registration: 20141113 Address after: Hanau Patentee after: HERAEUS PRECIOUS METALS GmbH & Co.KG Address before: Hanau Patentee before: Heraeus Clavet Aus LLC Effective date of registration: 20141113 Address after: Hanau Patentee after: Heraeus Clavet Aus LLC Address before: Goslar, Germany Patentee before: H.C. Starck Clevios GmbH Effective date of registration: 20141113 Address after: Goslar, Germany Patentee after: H.C. Starck Clevios GmbH Address before: German Goslar Patentee before: H.C. STARCK GmbH |
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