CN1799108A - 用于制备导电聚合物的延迟氧化剂 - Google Patents
用于制备导电聚合物的延迟氧化剂 Download PDFInfo
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- CN1799108A CN1799108A CNA2004800152333A CN200480015233A CN1799108A CN 1799108 A CN1799108 A CN 1799108A CN A2004800152333 A CNA2004800152333 A CN A2004800152333A CN 200480015233 A CN200480015233 A CN 200480015233A CN 1799108 A CN1799108 A CN 1799108A
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G49/00—Compounds of iron
- C01G49/0009—Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
- C08G61/122—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
- C08G61/123—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds
- C08G61/124—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds with a five-membered ring containing one nitrogen atom in the ring
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
- C08G61/122—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
- C08G61/123—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds
- C08G61/126—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds with a five-membered ring containing one sulfur atom in the ring
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- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/02—Polyamines
- C08G73/026—Wholly aromatic polyamines
- C08G73/0266—Polyanilines or derivatives thereof
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- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/0605—Polycondensates containing five-membered rings, not condensed with other rings, with nitrogen atoms as the only ring hetero atoms
- C08G73/0611—Polycondensates containing five-membered rings, not condensed with other rings, with nitrogen atoms as the only ring hetero atoms with only one nitrogen atom in the ring, e.g. polypyrroles
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
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Abstract
Description
体积比氧化剂:MP 62 | 9∶1 | 3∶1 | 2∶1 | 参考 |
贮存期 | 2h | 4h | 24h | 9min |
体积比氧化剂:MP 62 | 2∶1 | 参考 |
表面电阻 | 77Ω/方 | 145Ω/方 |
层厚度 | 230nm | 305nm |
比电导 | 565S/cm | 226S/cm |
贮存期 | 48h | 18min |
体积比氧化剂:MP 62 | 2∶1 | 参考 |
贮存期 | 48h | 3h |
表面电阻 | 974Ω/方 |
层厚度 | 155nm |
比电导 | 66S/cm |
贮存期 | 96h |
氧化剂:MP 62的体积比 | 2∶1 | 参考 |
在-15℃下的贮存期 | 96h | 2h |
在6℃下的贮存期(实施例2) | 24h | 9min |
离子交换剂 | MP 62 | MP 64 | MP 600WS | 参考 |
贮存期 | 16h | 16h | 2h | 18min |
混合物 | 新的混合物 | 24h陈化的混合物 | 72h陈化的混合物 |
电容 | 67μF | 67μF | 65μF |
等效串联电阻 | 63mΩ | 57mΩ | 61mΩ |
反应分步骤 | 反应常数 | |
单体氧化 | k0 | 0.15 l3mol-3h-1 |
k01 | 0.026 l2mol-2h-1 | |
端基氧化 | k1 | 3000 l1mol-1h-1 |
k11 | 105 l4mol-2h-1 | |
自由基结合 | k2 | 109 l1mol-1h-1 |
聚合氧化 | kD | 0.5 l1mol-1h-1 |
kD | 0.1 l1mol-1h-1 |
Claims (37)
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
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DE10314978 | 2003-04-02 | ||
DE10314978.3 | 2003-04-02 | ||
DE10324534A DE10324534A1 (de) | 2003-04-02 | 2003-05-28 | Retardierende Oxidationsmittel zur Herstellung leitfähiger Polymere |
DE10324534.0 | 2003-05-28 | ||
PCT/EP2004/002951 WO2004088672A1 (de) | 2003-04-02 | 2004-03-20 | Spezielle oxidationsmittel zur herstellung leitfähiger polymere |
Publications (2)
Publication Number | Publication Date |
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CN1799108A true CN1799108A (zh) | 2006-07-05 |
CN1799108B CN1799108B (zh) | 2012-05-16 |
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CN2004800152333A Expired - Fee Related CN1799108B (zh) | 2003-04-02 | 2004-03-20 | 用于制备导电聚合物的延迟氧化剂 |
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Country | Link |
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JP (1) | JP2010209342A (zh) |
CN (1) | CN1799108B (zh) |
DE (1) | DE10324534A1 (zh) |
MY (1) | MY142357A (zh) |
TW (1) | TWI331599B (zh) |
Cited By (1)
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WO2020224630A1 (zh) * | 2019-05-09 | 2020-11-12 | 深圳新宙邦科技股份有限公司 | 一种导电聚合物、电容器及其制备方法 |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
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DE102004022110A1 (de) | 2004-05-05 | 2005-12-01 | H.C. Starck Gmbh | Verfahren zur Herstellung von Elektrolytkondensatoren |
DE102008023008A1 (de) | 2008-05-09 | 2009-11-12 | H.C. Starck Gmbh | Neuartige Polythiophene-Polyanion-Komplexe in unpolaren organischen Lösungsmitteln |
WO2015192596A1 (en) * | 2014-06-17 | 2015-12-23 | Chien-Chung Han | Composition and method for forming electroactive polymer solution or coating comprising conjugated heteroaromatic polymer, electroactive polymer solution, capacitor and antistatic object comprising the electroactive coating, and solid electrolytic capacitor and method for fabricating the same |
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JPS6323933A (ja) * | 1986-07-17 | 1988-02-01 | Tokuyama Soda Co Ltd | イオン交換体の製造方法 |
DE59010247D1 (de) * | 1990-02-08 | 1996-05-02 | Bayer Ag | Neue Polythiophen-Dispersionen, ihre Herstellung und ihre Verwendung |
CN1101161A (zh) * | 1993-09-30 | 1995-04-05 | 中国科学院化学研究所 | 导电聚合物复合膜及其制备方法 |
US6072027A (en) * | 1997-11-18 | 2000-06-06 | The Dow Chemical Company | Process for preparing an electrically conductive polymer |
JP4513044B2 (ja) * | 2000-08-22 | 2010-07-28 | 日本ケミコン株式会社 | 固体電解コンデンサおよびその製造方法 |
JP2002138137A (ja) * | 2000-11-01 | 2002-05-14 | Tayca Corp | 導電性高分子製造用酸化剤 |
DE10058116A1 (de) * | 2000-11-22 | 2002-05-23 | Bayer Ag | Polythiophene |
-
2003
- 2003-05-28 DE DE10324534A patent/DE10324534A1/de not_active Withdrawn
-
2004
- 2004-03-20 CN CN2004800152333A patent/CN1799108B/zh not_active Expired - Fee Related
- 2004-03-31 MY MYPI20041177A patent/MY142357A/en unknown
- 2004-04-01 TW TW093108992A patent/TWI331599B/zh not_active IP Right Cessation
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2010
- 2010-04-27 JP JP2010102359A patent/JP2010209342A/ja active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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WO2020224630A1 (zh) * | 2019-05-09 | 2020-11-12 | 深圳新宙邦科技股份有限公司 | 一种导电聚合物、电容器及其制备方法 |
Also Published As
Publication number | Publication date |
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TW200500303A (en) | 2005-01-01 |
JP2010209342A (ja) | 2010-09-24 |
TWI331599B (en) | 2010-10-11 |
CN1799108B (zh) | 2012-05-16 |
DE10324534A1 (de) | 2004-10-14 |
MY142357A (en) | 2010-11-30 |
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