CN1697091A - 含有玻璃纤维的硅氧烷的电缆组件 - Google Patents
含有玻璃纤维的硅氧烷的电缆组件 Download PDFInfo
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- CN1697091A CN1697091A CNA2005100687772A CN200510068777A CN1697091A CN 1697091 A CN1697091 A CN 1697091A CN A2005100687772 A CNA2005100687772 A CN A2005100687772A CN 200510068777 A CN200510068777 A CN 200510068777A CN 1697091 A CN1697091 A CN 1697091A
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- 239000003365 glass fiber Substances 0.000 title claims abstract description 19
- 229920001296 polysiloxane Polymers 0.000 title description 12
- 229920002379 silicone rubber Polymers 0.000 claims abstract description 26
- 238000000034 method Methods 0.000 claims description 5
- 238000004132 cross linking Methods 0.000 claims description 4
- 238000009833 condensation Methods 0.000 claims description 3
- 230000005494 condensation Effects 0.000 claims description 3
- 230000001681 protective effect Effects 0.000 claims description 2
- -1 siloxanes Chemical class 0.000 description 24
- 239000000203 mixture Substances 0.000 description 16
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 10
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 10
- 239000000945 filler Substances 0.000 description 9
- 150000001875 compounds Chemical class 0.000 description 7
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 6
- 125000000217 alkyl group Chemical group 0.000 description 6
- 229920001971 elastomer Polymers 0.000 description 5
- 229910052697 platinum Inorganic materials 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- 239000000654 additive Substances 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 239000003431 cross linking reagent Substances 0.000 description 3
- 230000002708 enhancing effect Effects 0.000 description 3
- 229910000765 intermetallic Inorganic materials 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- 229910044991 metal oxide Inorganic materials 0.000 description 3
- 150000004706 metal oxides Chemical class 0.000 description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
- 235000012239 silicon dioxide Nutrition 0.000 description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- SRKIHTUUQJRNLX-UHFFFAOYSA-L CS(=O)C(C=[Pt+2]=CC)S(=O)C.[Cl-].[Cl-] Chemical compound CS(=O)C(C=[Pt+2]=CC)S(=O)C.[Cl-].[Cl-] SRKIHTUUQJRNLX-UHFFFAOYSA-L 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 239000012760 heat stabilizer Substances 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 239000012212 insulator Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 2
- RZJRJXONCZWCBN-UHFFFAOYSA-N octadecane Chemical compound CCCCCCCCCCCCCCCCCC RZJRJXONCZWCBN-UHFFFAOYSA-N 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 150000003141 primary amines Chemical class 0.000 description 2
- 125000000467 secondary amino group Chemical class [H]N([*:1])[*:2] 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- FBEIPJNQGITEBL-UHFFFAOYSA-J tetrachloroplatinum Chemical compound Cl[Pt](Cl)(Cl)Cl FBEIPJNQGITEBL-UHFFFAOYSA-J 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- 229910052723 transition metal Inorganic materials 0.000 description 2
- NHOWDZOIZKMVAI-UHFFFAOYSA-N (2-chlorophenyl)(4-chlorophenyl)pyrimidin-5-ylmethanol Chemical compound C=1N=CN=CC=1C(C=1C(=CC=CC=1)Cl)(O)C1=CC=C(Cl)C=C1 NHOWDZOIZKMVAI-UHFFFAOYSA-N 0.000 description 1
- 125000006023 1-pentenyl group Chemical group 0.000 description 1
- DMWVYCCGCQPJEA-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhexane Chemical compound CC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)C DMWVYCCGCQPJEA-UHFFFAOYSA-N 0.000 description 1
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 1
- 125000001494 2-propynyl group Chemical group [H]C#CC([H])([H])* 0.000 description 1
- 125000000590 4-methylphenyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C([H])([H])[H] 0.000 description 1
- 125000006043 5-hexenyl group Chemical group 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- OVRIUYTVSITETF-UHFFFAOYSA-N C(C(=O)C)(=O)OC.C12=CC=C(CC1)C2.[Pt] Chemical compound C(C(=O)C)(=O)OC.C12=CC=C(CC1)C2.[Pt] OVRIUYTVSITETF-UHFFFAOYSA-N 0.000 description 1
- CGBFEZOPOFSTTA-UHFFFAOYSA-L Cl[Pt](C1C=CC=C1)(C1C=CC=C1)Cl Chemical compound Cl[Pt](C1C=CC=C1)(C1C=CC=C1)Cl CGBFEZOPOFSTTA-UHFFFAOYSA-L 0.000 description 1
- GYZFQLGZYUPQIN-UHFFFAOYSA-L Cl[Pt]Cl.CC1=CC=NC=C1 Chemical compound Cl[Pt]Cl.CC1=CC=NC=C1 GYZFQLGZYUPQIN-UHFFFAOYSA-L 0.000 description 1
- 101000731007 Homo sapiens Membrane-associated progesterone receptor component 2 Proteins 0.000 description 1
- 102100032400 Membrane-associated progesterone receptor component 2 Human genes 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 125000005428 anthryl group Chemical group [H]C1=C([H])C([H])=C2C([H])=C3C(*)=C([H])C([H])=C([H])C3=C([H])C2=C1[H] 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 229910052916 barium silicate Inorganic materials 0.000 description 1
- HMOQPOVBDRFNIU-UHFFFAOYSA-N barium(2+);dioxido(oxo)silane Chemical compound [Ba+2].[O-][Si]([O-])=O HMOQPOVBDRFNIU-UHFFFAOYSA-N 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 125000006267 biphenyl group Chemical group 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 235000012241 calcium silicate Nutrition 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 125000000596 cyclohexenyl group Chemical group C1(=CCCCC1)* 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 1
- 125000002433 cyclopentenyl group Chemical group C1(=CCCC1)* 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 125000001188 haloalkyl group Chemical group 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- UQEAIHBTYFGYIE-UHFFFAOYSA-N hexamethyldisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)C UQEAIHBTYFGYIE-UHFFFAOYSA-N 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- WKWOFMSUGVVZIV-UHFFFAOYSA-N n-bis(ethenyl)silyl-n-trimethylsilylmethanamine Chemical compound C[Si](C)(C)N(C)[SiH](C=C)C=C WKWOFMSUGVVZIV-UHFFFAOYSA-N 0.000 description 1
- 125000003136 n-heptyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
- 150000002978 peroxides Chemical group 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- RJISOXBAUVEBHP-UHFFFAOYSA-N platinum;pyridine Chemical compound [Pt].C1=CC=NC=C1 RJISOXBAUVEBHP-UHFFFAOYSA-N 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- BHRZNVHARXXAHW-UHFFFAOYSA-N sec-butylamine Chemical compound CCC(C)N BHRZNVHARXXAHW-UHFFFAOYSA-N 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229920005573 silicon-containing polymer Polymers 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000000547 substituted alkyl group Chemical group 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 125000005389 trialkylsiloxy group Chemical group 0.000 description 1
- 125000000725 trifluoropropyl group Chemical group [H]C([H])(*)C([H])([H])C(F)(F)F 0.000 description 1
- 125000003258 trimethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 230000010148 water-pollination Effects 0.000 description 1
- 125000005023 xylyl group Chemical group 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/14—Glass
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Insulated Conductors (AREA)
- Insulating Bodies (AREA)
- Reinforced Plastic Materials (AREA)
- Organic Insulating Materials (AREA)
Abstract
本发明涉及硅氧烷弹性体的电缆组件(K)，其包含平均长度为至少1米的玻璃纤维。
Description
技术领域
本发明涉及含有玻璃纤维的硅氧烷弹性体的电缆组件(K)及其制造方法。
背景技术
US-A-6,387,518中描述了安全电缆所用的填充硅橡胶。除金属氧化物外，所述硅橡胶还可含有玻璃纤维。在火灾中，含有该硅橡胶的绝缘体燃烧并与金属氧化物形成一种电绝缘的陶瓷，从而防止电缆电线间的短路，并使电缆的功能得以发挥。
这些玻璃纤维是用作填料。通常用作填料的短纤维线段，其长度范围为低于1毫米至最大几厘米。该填料对所述硅橡胶的电绝缘强度具有负面影响。
某些标准要求在火灾时电缆具有增强的柔性，由此导致陶瓷粉碎并且无法确保功能的发挥。
用云母带缠绕电线以增强机械性能是已知的。该方法的成本极其昂贵，无法与含硅橡胶的简单绝缘体相竞争。
发明内容
本发明涉及含有平均长度至少为1米的玻璃纤维的硅氧烷弹性体的电缆组件(K)。
该电缆组件(K)不仅具有硅氧烷弹性体提高的机械性能，例如增强的抗拉强度，而且在火灾时通过硅氧烷弹性体与玻璃纤维的燃烧形成机械性能稳定的电绝缘陶瓷。因为陶瓷内掺入了玻璃纤维，其增加了陶瓷的强度，所以陶瓷尤其较不易破裂，这与钢筋在混凝土中的增强作用相类似。
在挤制电缆组件(K)时，可将玻璃纤维一同引入该硅橡胶内。在此期间不放慢挤制速度。
这些玻璃纤维在硅橡胶内可以任何方式配置。这些玻璃纤维优选为与导线平行安置，或以螺旋状环绕导线安置。
这些玻璃纤维的平均长度优选为至少10米，而且还可长达数千米。
电缆组件(K)为例如环绕导线的绝缘套、保护套、外套以及用以防火的型材，如结构型材。
该硅氧烷弹性体可通过硅橡胶交联制得。这可以是过氧化交联、缩合交联或加成交联。该硅橡胶优选为过氧化交联的硅橡胶组合物，其优选含有以下成分：
具有通式(I)单元的有机聚硅氧烷(A)：
RrSiO(4-r)/2 (I)
其中
R可相同或不同，且为经取代或未经取代的烃基；
r是0、1、2或3，且其平均值为1.9至2.1。
烃基R的实例为：烷基，如甲基、乙基、正丙基、异丙基、正丁基、异丁基、叔丁基、正戊基、异戊基、新戊基、叔戊基、己基，如正己基；庚基，如正庚基；辛基，如正辛基和异辛基，如2，2，4-三甲基戊基；壬基，如正壬基；癸基，如正癸基；十二烷基，如正十二烷基；十八烷基，如正十八烷基；环烷基，如环戊基、环己基、环庚基和甲基环己基；芳基，如苯基、联苯基、萘基、蒽基和苯蒽基；烷芳基，如邻-、间-、对甲苯基、二甲苯基和乙苯基；芳烷基，如苯甲基、α-和β-苯乙基。
经取代烃基R的实例为：卤代烷基，如3-氯丙基、3，3，3-三氟丙基和全氟己基乙基；卤代芳基，如对氯苯基和对氯苯甲基。
R基的其他实例为：乙烯基、烯丙基、甲基烯丙基、1-丙烯基、1-丁烯基、1-戊烯基、5-己烯基、丁二烯基、己二烯基、环戊烯基、环戊二烯基、环己烯基、乙炔基、炔丙基和1-丙炔基。
R基优选为氢原子和具有1至8个碳原子的烃基，特别优选为甲基、苯基或乙烯基。
烷基，尤其是甲基优选与有机聚硅氧烷(A)中所含至少70摩尔％，更优选为至少90摩尔％的硅原子键结。除硅键结甲基和/或3，3，3三氟丙基外，若有机聚硅氧烷还含有硅键结乙烯基和/或苯基，则后者的含量优选为0.001-30摩尔％。
有机聚硅氧烷(A)优选为主要含有二有机基硅氧烷单元，其含量更优选为至少95摩尔％。有机聚硅氧烷的端基可为三烷基甲硅烷氧基，尤其为三甲基甲硅烷氧基或二甲基乙烯基甲硅烷氧基；而一个或多个烷基也可被羟基或诸如甲氧基或乙氧基的烷氧基取代。
有机聚硅氧烷(A)可为液体或高粘性物质。有机聚硅氧烷(A)在25℃下的粘度优选为103至108平方毫米/秒。
硅橡胶组合物内所用的交联剂优选为过氧化物作为交联剂，如过氧化二苯甲酰、过氧化双(2，4-二氯苯甲酰)、过氧化二异丙苯和2，5-双(叔丁基过氧基)-2，5-二甲基己烷及其混合物，其中更优选为过氧化双(2，4-二氯苯甲酰)和2，5-双(叔丁基过氧基)-2，5-二甲基己烷。
此外，所用交联剂优选为过氧化双-4-甲基苯甲酰(＝PMBP)和2，5-二甲基己烷-过氧化-2，5-二叔丁基(＝DHBP)以1∶0.4至0.5∶1的比例，更优选以1∶0.4的比例混合的混合物。
此外，所述硅橡胶组合物优选含有增强性和/或非增强性填料。
增强性填料的实例为BET表面积为至少50平方米/克的热解型或沉积型二氧化硅。
所述二氧化硅填料可具有亲水性特性，或根据已知方法疏水化。例如，参考US-A-5,057,151。通常用基于有机聚硅氧烷组合物总重量1至20重量％的六甲基二硅氮烷和/或二乙烯基四甲基二硅氮烷以及0.5至5重量％的水实施疏水化处理，其中优选将这些试剂在亲水性二氧化硅逐渐掺入该组合物前，在一个诸如捏合器或内部混合器的适当混合装置内，加至已引入的有机聚硅氧烷(A)内。
非增强性填料的实例是：石英粉末、硅藻土、硅酸钙、硅酸锆、沸石、金属氧化物粉末，如氧化铝、氧化钛、氧化铁或氧化锌，硅酸钡、硫酸钡、碳酸钙、石膏以及塑料粉末，如聚丙烯腈粉末或聚四氟乙烯粉末。这此填料的BET表面积优选为低于50平方米/克。
可交联生成硅氧烷弹性体的硅橡胶组合物中，填料的含量基于100重量份有机聚硅氧烷(A)优选为1至200重量份，更优选为30至100重量份。
根据各种用途，可以在可硫化成硅氧烷弹性体的硅橡胶组合物中加入添加剂，例如加工助剂，如增塑剂、陶瓷化金属化合物、颜料和稳定剂，如热稳定剂。
陶瓷化金属化合物优选为选自氧化镁、氧化铝、氧化锡、氧化钙、氧化钛、氧化钡的金属氧化物，以及加热时生成氧化物的金属化合物：硼酸、硼酸锌，以及具有至少一个不饱和基团的铂络合物。
可用作添加剂的增塑剂的实例为：由三甲基甲硅烷基或羟基封端、25℃下的粘度最高为1000平方毫米/秒的聚二甲基硅氧烷，或二苯基硅烷二醇。
可用作添加剂的热稳定剂的实例为：过渡金属脂肪酸盐，如辛酸铁、过渡金属硅烷醇盐，如硅烷醇铁，以及铈(IV)化合物。
此外，所述硅橡胶优选为不含有其他物质。
用于制造硅橡胶的各个成分均可为这些成分中的一种，也可为这些成分中不同的至少两种的混合物。
此外，如EP-A-359215(作为参考并入)中所描述的传统缩合交联的有机聚硅氧烷或已知的加成交联的组合物也可用作硅橡胶。
所述硅橡胶可含有具有至少一个不饱和基团的铂络合物，如优选为铂-烯络合物、铂-醛络合物、铂-酮络合物、铂-乙烯基硅氧烷络合物、含有或不含可检测有机卤素的铂-1，3-二乙烯基-1，1，3，3-四甲基二硅氧烷络合物、铂-降冰片二烯-丙酮酸甲酯络合物、二氯化双(γ-甲基吡啶)铂、二氯化三亚甲基二吡啶铂、二氯化二环戊二烯基铂、二氯化二甲基亚硫酰基二亚乙基铂(II)、四氯化铂与烯烃和伯胺或仲胺或伯胺与仲胺的反应产物、溶解于1-辛烯中的四氯化铂与仲丁基胺的反应产物，其中更优选为铂-1，3-二乙烯基-1，1，3，3-四甲基二硅氧烷络合物。所述铂络合物的添加量以纯铂计为5至200ppm，优选为10至100ppm。也可使用这些铂络合物的混合物。
此外，本发明还涉及制造电缆组件(K)的方法，其中平均长度至少为1米的玻璃纤维是与硅橡胶一同挤制。
所述玻璃纤维优选沿挤制方向安置。
通过引入玻璃纤维而不必放慢挤制速度。
Claims (5)
1.硅氧烷弹性体的电缆组件(K)，其包含平均长度为至少1米的玻璃纤维。
2.如权利要求1的电缆组件(K)，其中所述玻璃纤维与导线平行安置，或以螺旋状环绕导线安置。
3.如权利要求1或2的电缆组件(K)，其是选自环绕导线的绝缘套、保护套、外套以及用以防火的型材。
4.如权利要求1至3之一的电缆组件(K)，其中所述硅氧烷弹性体是通过硅橡胶的过氧化交联、缩合交联或加成交联制得的。
5.用以制造电缆组件(K)的方法，其中将平均长度为至少1米的玻璃纤维与硅橡胶一同挤制。
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| DE102004022992.9 | 2004-05-10 | ||
| DE102004022992A DE102004022992A1 (de) | 2004-05-10 | 2004-05-10 | Kabelkomponenten aus Silicon mit Glasfasern |
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| CN1697091A true CN1697091A (zh) | 2005-11-16 |
| CN100346424C CN100346424C (zh) | 2007-10-31 |
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| US (1) | US7271341B2 (zh) |
| EP (1) | EP1595914A1 (zh) |
| JP (1) | JP4404804B2 (zh) |
| CN (1) | CN100346424C (zh) |
| DE (1) | DE102004022992A1 (zh) |
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| CN105848321A (zh) * | 2016-05-30 | 2016-08-10 | 沈兴线缆集团有限公司 | 一种油井抽油杆碳纤维加热电缆及其制造方法 |
| CN105968820A (zh) * | 2016-05-30 | 2016-09-28 | 沈兴线缆集团有限公司 | 加热电缆用高绝缘电阻耐高温陶瓷橡胶及其制备方法 |
| CN106102196A (zh) * | 2016-05-30 | 2016-11-09 | 沈兴线缆集团有限公司 | 一种油井抽油杆加热电缆及其制造方法 |
| CN114736518A (zh) * | 2021-01-08 | 2022-07-12 | 武汉楚辰新材料科技有限公司 | 纤维增强自固化硅橡胶及其制备方法 |
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| CN104464899A (zh) * | 2013-09-24 | 2015-03-25 | 江苏宝安电缆有限公司 | 一种陶瓷化防火耐火型柔性电缆 |
| CN111635635A (zh) * | 2020-06-28 | 2020-09-08 | 山西大学 | 一种粉煤灰基陶瓷化硅橡胶复合材料及其制备方法 |
| KR20240053879A (ko) | 2022-10-18 | 2024-04-25 | 평화오일씰공업주식회사 | 인휠 모터용 씰 및 이를 포함하는 인휠 모터용 씰링 장치 |
| KR20240053890A (ko) | 2022-10-18 | 2024-04-25 | 평화오일씰공업주식회사 | 인휠 모터용 씰링 장치 및 상기 씰링 장치와 더스트 커버를 포함하는 인휠 모터용 씰링 시스템 |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105848321A (zh) * | 2016-05-30 | 2016-08-10 | 沈兴线缆集团有限公司 | 一种油井抽油杆碳纤维加热电缆及其制造方法 |
| CN105968820A (zh) * | 2016-05-30 | 2016-09-28 | 沈兴线缆集团有限公司 | 加热电缆用高绝缘电阻耐高温陶瓷橡胶及其制备方法 |
| CN106102196A (zh) * | 2016-05-30 | 2016-11-09 | 沈兴线缆集团有限公司 | 一种油井抽油杆加热电缆及其制造方法 |
| CN105968820B (zh) * | 2016-05-30 | 2021-10-29 | 沈兴线缆集团有限公司 | 加热电缆用高绝缘电阻耐高温陶瓷橡胶及其制备方法 |
| CN114736518A (zh) * | 2021-01-08 | 2022-07-12 | 武汉楚辰新材料科技有限公司 | 纤维增强自固化硅橡胶及其制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| JP4404804B2 (ja) | 2010-01-27 |
| US20050247469A1 (en) | 2005-11-10 |
| EP1595914A1 (de) | 2005-11-16 |
| DE102004022992A1 (de) | 2005-12-08 |
| JP2005322653A (ja) | 2005-11-17 |
| CN100346424C (zh) | 2007-10-31 |
| US7271341B2 (en) | 2007-09-18 |
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