CN1556678A - 含水果的食品的钙强化方法 - Google Patents
含水果的食品的钙强化方法 Download PDFInfo
- Publication number
- CN1556678A CN1556678A CNA028185692A CN02818569A CN1556678A CN 1556678 A CN1556678 A CN 1556678A CN A028185692 A CNA028185692 A CN A028185692A CN 02818569 A CN02818569 A CN 02818569A CN 1556678 A CN1556678 A CN 1556678A
- Authority
- CN
- China
- Prior art keywords
- calcium
- salt
- food
- acid
- fruit
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 title claims abstract description 66
- 239000011575 calcium Substances 0.000 title claims abstract description 66
- 229910052791 calcium Inorganic materials 0.000 title claims abstract description 66
- 235000013305 food Nutrition 0.000 title claims abstract description 41
- 238000000034 method Methods 0.000 title claims abstract description 35
- 235000013399 edible fruits Nutrition 0.000 title claims abstract description 25
- 159000000007 calcium salts Chemical class 0.000 claims abstract description 34
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims abstract description 15
- 239000001110 calcium chloride Substances 0.000 claims abstract description 15
- 229910001628 calcium chloride Inorganic materials 0.000 claims abstract description 15
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 240000001717 Vaccinium macrocarpon Species 0.000 claims abstract description 5
- 239000004410 anthocyanin Substances 0.000 claims abstract description 5
- 229930002877 anthocyanin Natural products 0.000 claims abstract description 5
- 235000010208 anthocyanin Nutrition 0.000 claims abstract description 5
- 150000004636 anthocyanins Chemical class 0.000 claims abstract description 5
- 239000012141 concentrate Substances 0.000 claims abstract description 5
- 239000004310 lactic acid Substances 0.000 claims abstract description 4
- 235000014655 lactic acid Nutrition 0.000 claims abstract description 4
- 150000007524 organic acids Chemical class 0.000 claims abstract description 3
- 235000008504 concentrate Nutrition 0.000 claims abstract 2
- 229960005069 calcium Drugs 0.000 claims description 64
- MKJXYGKVIBWPFZ-UHFFFAOYSA-L calcium lactate Chemical group [Ca+2].CC(O)C([O-])=O.CC(O)C([O-])=O MKJXYGKVIBWPFZ-UHFFFAOYSA-L 0.000 claims description 25
- 239000001527 calcium lactate Substances 0.000 claims description 23
- 235000011086 calcium lactate Nutrition 0.000 claims description 23
- 229960002401 calcium lactate Drugs 0.000 claims description 23
- 239000001506 calcium phosphate Substances 0.000 claims description 22
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 claims description 20
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 16
- 229910000389 calcium phosphate Inorganic materials 0.000 claims description 16
- 235000011010 calcium phosphates Nutrition 0.000 claims description 16
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 15
- -1 organic acid calcium salt Chemical class 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 9
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 8
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 8
- 244000078534 Vaccinium myrtillus Species 0.000 claims description 6
- 235000011389 fruit/vegetable juice Nutrition 0.000 claims description 6
- 235000013361 beverage Nutrition 0.000 claims description 5
- CQVAWTWGTHPABZ-UHFFFAOYSA-L calcium;dihydroxide;hydrate Chemical compound O.[OH-].[OH-].[Ca+2] CQVAWTWGTHPABZ-UHFFFAOYSA-L 0.000 claims description 5
- 235000015165 citric acid Nutrition 0.000 claims description 5
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 claims description 4
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 4
- 235000003095 Vaccinium corymbosum Nutrition 0.000 claims description 4
- 235000012545 Vaccinium macrocarpon Nutrition 0.000 claims description 4
- 235000017537 Vaccinium myrtillus Nutrition 0.000 claims description 4
- 235000002118 Vaccinium oxycoccus Nutrition 0.000 claims description 4
- 241000219095 Vitis Species 0.000 claims description 4
- 235000009754 Vitis X bourquina Nutrition 0.000 claims description 4
- 235000012333 Vitis X labruscana Nutrition 0.000 claims description 4
- 235000014787 Vitis vinifera Nutrition 0.000 claims description 4
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 4
- 150000003863 ammonium salts Chemical class 0.000 claims description 4
- 235000021014 blueberries Nutrition 0.000 claims description 4
- 235000004634 cranberry Nutrition 0.000 claims description 4
- 239000001103 potassium chloride Substances 0.000 claims description 4
- 235000011164 potassium chloride Nutrition 0.000 claims description 4
- 159000000000 sodium salts Chemical class 0.000 claims description 4
- 235000019739 Dicalciumphosphate Nutrition 0.000 claims description 3
- YNGQHHUHCOYPKT-UHFFFAOYSA-L azanium;calcium;phosphate Chemical compound [NH4+].[Ca+2].[O-]P([O-])([O-])=O YNGQHHUHCOYPKT-UHFFFAOYSA-L 0.000 claims description 3
- 235000001465 calcium Nutrition 0.000 claims description 3
- SLMHDVBWFGHGSP-UHFFFAOYSA-K calcium;potassium;phosphate Chemical compound [K+].[Ca+2].[O-]P([O-])([O-])=O SLMHDVBWFGHGSP-UHFFFAOYSA-K 0.000 claims description 3
- QXJJQWWVWRCVQT-UHFFFAOYSA-K calcium;sodium;phosphate Chemical compound [Na+].[Ca+2].[O-]P([O-])([O-])=O QXJJQWWVWRCVQT-UHFFFAOYSA-K 0.000 claims description 3
- NEFBYIFKOOEVPA-UHFFFAOYSA-K dicalcium phosphate Chemical compound [Ca+2].[Ca+2].[O-]P([O-])([O-])=O NEFBYIFKOOEVPA-UHFFFAOYSA-K 0.000 claims description 3
- 229940038472 dicalcium phosphate Drugs 0.000 claims description 3
- 229910000390 dicalcium phosphate Inorganic materials 0.000 claims description 3
- 150000003014 phosphoric acid esters Chemical class 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- 238000005728 strengthening Methods 0.000 claims description 3
- 229940078499 tricalcium phosphate Drugs 0.000 claims description 3
- 229910000391 tricalcium phosphate Inorganic materials 0.000 claims description 3
- 235000019731 tricalcium phosphate Nutrition 0.000 claims description 3
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 2
- 241000167854 Bourreria succulenta Species 0.000 claims description 2
- 235000015001 Cucumis melo var inodorus Nutrition 0.000 claims description 2
- 240000002495 Cucumis melo var. inodorus Species 0.000 claims description 2
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 claims description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 2
- 235000016623 Fragaria vesca Nutrition 0.000 claims description 2
- 240000009088 Fragaria x ananassa Species 0.000 claims description 2
- 235000011363 Fragaria x ananassa Nutrition 0.000 claims description 2
- 235000001537 Ribes X gardonianum Nutrition 0.000 claims description 2
- 235000001535 Ribes X utile Nutrition 0.000 claims description 2
- 235000016919 Ribes petraeum Nutrition 0.000 claims description 2
- 244000281247 Ribes rubrum Species 0.000 claims description 2
- 235000002355 Ribes spicatum Nutrition 0.000 claims description 2
- 235000017848 Rubus fruticosus Nutrition 0.000 claims description 2
- 240000007651 Rubus glaucus Species 0.000 claims description 2
- 235000011034 Rubus glaucus Nutrition 0.000 claims description 2
- 235000009122 Rubus idaeus Nutrition 0.000 claims description 2
- 244000111447 Rubus phoenicolasius Species 0.000 claims description 2
- 235000003963 Rubus phoenicolasius Nutrition 0.000 claims description 2
- 244000151637 Sambucus canadensis Species 0.000 claims description 2
- 235000018735 Sambucus canadensis Nutrition 0.000 claims description 2
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 2
- 241001593968 Vitis palmata Species 0.000 claims description 2
- 239000001361 adipic acid Substances 0.000 claims description 2
- 235000011037 adipic acid Nutrition 0.000 claims description 2
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
- 235000021029 blackberry Nutrition 0.000 claims description 2
- 235000007123 blue elder Nutrition 0.000 claims description 2
- 235000019693 cherries Nutrition 0.000 claims description 2
- 235000007124 elderberry Nutrition 0.000 claims description 2
- 235000008995 european elder Nutrition 0.000 claims description 2
- 239000001530 fumaric acid Substances 0.000 claims description 2
- 235000011087 fumaric acid Nutrition 0.000 claims description 2
- 239000000174 gluconic acid Substances 0.000 claims description 2
- 235000012208 gluconic acid Nutrition 0.000 claims description 2
- 239000001630 malic acid Substances 0.000 claims description 2
- 235000011090 malic acid Nutrition 0.000 claims description 2
- 239000000049 pigment Substances 0.000 claims description 2
- 230000035945 sensitivity Effects 0.000 claims description 2
- 239000011975 tartaric acid Substances 0.000 claims description 2
- 235000002906 tartaric acid Nutrition 0.000 claims description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 2
- 235000014106 fortified food Nutrition 0.000 claims 2
- 235000015203 fruit juice Nutrition 0.000 abstract description 10
- 235000021019 cranberries Nutrition 0.000 abstract 1
- 235000020357 syrup Nutrition 0.000 abstract 1
- 239000006188 syrup Substances 0.000 abstract 1
- 235000019640 taste Nutrition 0.000 description 16
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 5
- 239000000460 chlorine Substances 0.000 description 5
- 229910052801 chlorine Inorganic materials 0.000 description 5
- 239000000796 flavoring agent Substances 0.000 description 5
- 235000019634 flavors Nutrition 0.000 description 5
- 235000013336 milk Nutrition 0.000 description 4
- 239000008267 milk Substances 0.000 description 4
- 210000004080 milk Anatomy 0.000 description 4
- 235000005979 Citrus limon Nutrition 0.000 description 3
- 244000131522 Citrus pyriformis Species 0.000 description 3
- 235000019658 bitter taste Nutrition 0.000 description 3
- 239000001362 calcium malate Substances 0.000 description 3
- 229940016114 calcium malate Drugs 0.000 description 3
- FNAQSUUGMSOBHW-UHFFFAOYSA-H calcium citrate Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O FNAQSUUGMSOBHW-UHFFFAOYSA-H 0.000 description 2
- 239000001354 calcium citrate Substances 0.000 description 2
- 229960004256 calcium citrate Drugs 0.000 description 2
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 2
- 239000004227 calcium gluconate Substances 0.000 description 2
- 235000013927 calcium gluconate Nutrition 0.000 description 2
- 229960004494 calcium gluconate Drugs 0.000 description 2
- 239000000920 calcium hydroxide Substances 0.000 description 2
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 2
- OLOZVPHKXALCRI-UHFFFAOYSA-L calcium malate Chemical compound [Ca+2].[O-]C(=O)C(O)CC([O-])=O OLOZVPHKXALCRI-UHFFFAOYSA-L 0.000 description 2
- 235000011038 calcium malates Nutrition 0.000 description 2
- NEEHYRZPVYRGPP-UHFFFAOYSA-L calcium;2,3,4,5,6-pentahydroxyhexanoate Chemical compound [Ca+2].OCC(O)C(O)C(O)C(O)C([O-])=O.OCC(O)C(O)C(O)C(O)C([O-])=O NEEHYRZPVYRGPP-UHFFFAOYSA-L 0.000 description 2
- 235000019987 cider Nutrition 0.000 description 2
- 235000008935 nutritious Nutrition 0.000 description 2
- 235000015205 orange juice Nutrition 0.000 description 2
- 235000013337 tricalcium citrate Nutrition 0.000 description 2
- RWYRUDPAALLKPX-UHFFFAOYSA-N 2,2-difluoro-n-methylethanamine;hydrochloride Chemical compound Cl.CNCC(F)F RWYRUDPAALLKPX-UHFFFAOYSA-N 0.000 description 1
- 239000001749 Calcium fumarate Substances 0.000 description 1
- 241000541656 Carex marina Species 0.000 description 1
- KVSINRZVPDJZGE-UHFFFAOYSA-N [Ca].[Ca].[Ca].C(CC(O)(C(=O)O)CC(=O)O)(=O)O Chemical compound [Ca].[Ca].[Ca].C(CC(O)(C(=O)O)CC(=O)O)(=O)O KVSINRZVPDJZGE-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229940024606 amino acid Drugs 0.000 description 1
- 235000001014 amino acid Nutrition 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- YFPHTCQIAVMAJR-UHFFFAOYSA-L azanium;calcium;2-hydroxypropane-1,2,3-tricarboxylate Chemical compound [NH4+].[Ca+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O YFPHTCQIAVMAJR-UHFFFAOYSA-L 0.000 description 1
- 235000008429 bread Nutrition 0.000 description 1
- 229940043430 calcium compound Drugs 0.000 description 1
- 150000001674 calcium compounds Chemical class 0.000 description 1
- 235000019296 calcium fumarate Nutrition 0.000 description 1
- QXDHJHQRJCJRAU-UHFFFAOYSA-N calcium;2-hydroxypropane-1,2,3-tricarboxylic acid Chemical compound [Ca].OC(=O)CC(O)(C(O)=O)CC(O)=O QXDHJHQRJCJRAU-UHFFFAOYSA-N 0.000 description 1
- XWCQMJTVAVMJGM-UHFFFAOYSA-N calcium;2-hydroxypropane-1,2,3-tricarboxylic acid Chemical compound [Ca].[Ca].OC(=O)CC(O)(C(O)=O)CC(O)=O XWCQMJTVAVMJGM-UHFFFAOYSA-N 0.000 description 1
- SPGDAODMONVAAC-UHFFFAOYSA-K calcium;potassium;2-hydroxypropane-1,2,3-tricarboxylate Chemical compound [K+].[Ca+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O SPGDAODMONVAAC-UHFFFAOYSA-K 0.000 description 1
- IISIZTZBVOYMAH-UHFFFAOYSA-K calcium;sodium;2-hydroxypropane-1,2,3-tricarboxylate Chemical compound [Na+].[Ca+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O IISIZTZBVOYMAH-UHFFFAOYSA-K 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- CPEPWXXWVALFCE-UHFFFAOYSA-J dicalcium 2-hydroxypropanoate Chemical compound [Ca+2].[Ca+2].CC(O)C([O-])=O.CC(O)C([O-])=O.CC(O)C([O-])=O.CC(O)C([O-])=O CPEPWXXWVALFCE-UHFFFAOYSA-J 0.000 description 1
- 230000035622 drinking Effects 0.000 description 1
- 235000013569 fruit product Nutrition 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000002372 labelling Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 239000001814 pectin Substances 0.000 description 1
- 235000010987 pectin Nutrition 0.000 description 1
- 229920001277 pectin Polymers 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 235000021262 sour milk Nutrition 0.000 description 1
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23D—EDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
- A23D7/00—Edible oil or fat compositions containing an aqueous phase, e.g. margarines
- A23D7/005—Edible oil or fat compositions containing an aqueous phase, e.g. margarines characterised by ingredients other than fatty acid triglycerides
- A23D7/0056—Spread compositions
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L19/00—Products from fruits or vegetables; Preparation or treatment thereof
- A23L19/09—Mashed or comminuted products, e.g. pulp, purée, sauce, or products made therefrom, e.g. snacks
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
- A23L2/02—Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation containing fruit or vegetable juices
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
- A23L2/52—Adding ingredients
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L21/00—Marmalades, jams, jellies or the like; Products from apiculture; Preparation or treatment thereof
- A23L21/10—Marmalades; Jams; Jellies; Other similar fruit or vegetable compositions; Simulated fruit products
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L33/00—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
- A23L33/10—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof using additives
- A23L33/16—Inorganic salts, minerals or trace elements
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2002/00—Food compositions, function of food ingredients or processes for food or foodstuffs
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Nutrition Science (AREA)
- Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Mycology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Coloring Foods And Improving Nutritive Qualities (AREA)
- Preparation Of Fruits And Vegetables (AREA)
- Non-Alcoholic Beverages (AREA)
Abstract
本发明涉及用钙对含有水果的食品进行强化的方法，所述食品例如果汁、水果提浓物、水果浆或水果涂抹食品。所述方法包括将无机钙盐和有机酸钙盐加入含有水果的食品中。本发明方法特别适合含有含花色素苷的水果(例如蔓越桔)的食品。优选的钙盐组合为乳酸钙和氯化钙。
Description
本发明涉及含水果的食品的钙强化方法，所述食品例如是果汁、水果提浓物、水果浆或涂抹食品。
这类方法在现有技术中已有报道。WO 00/28838中描述了一种含有脱果胶果汁和一种选自天然奶、矿物质、乳酸钙、葡糖酸钙或它们的混合物的钙源的钙强化果汁基营养饮料。所述饮料还可以含有例如维他命的营养成分。在EP397232中也描述了一种含有果汁的营养饮料，其中使用氯化钙、碳酸钙或柠檬酸-苹果酸钙作为钙源。
US 6086927描述了一种通过将氢氧化钙、含磷的酸、乳酸钙和磷酸钙混入水中或果汁中来制备钙强化食品的方法。该混合物中总钙含量的约40重量％来自氢氧化钙，总钙含量的约15重量％来自乳酸钙，总钙含量的约45重量％来自磷酸钙。
在将钙化合物加入含水果的食品中时，会出现颜色变化的问题。特别是对于得自含有对pH敏感的色素(如花色素苷)的水果的果汁或提浓物。花色素苷在低pH值下是稳定的，在较高的pH下其会从红色或蓝色变成棕色。这是不希望发生的。除了颜色稳定性还要求强化食品具有稳定的和可接受的口味。
本发明的目的是提供一种用钙对含有水果的食品进行强化的方法，以使得食品的颜色可接受，优选食品的口味也可接受，并且在较长的时间内保持稳定。
本发明的目的是提供一种用钙对含有水果的食品进行强化的方法，其包括向所述食品中加入无机钙盐和有机酸钙盐。优选，所加的总钙量中至少20重量％由有机钙盐来提供，更优选所加的总钙量中至少50重量％由有机钙盐来提供。已发现当所加的总钙量中至少20重量％由有机钙盐来提供时，食品的良好口味可以得到保障。
所述有机酸钙盐优选选自合适的食品级羧酸的钙盐，特别是乳酸、葡糖酸、柠檬酸、苹果酸、富马酸、酒石酸、己二酸或它们的混合物，最优选乳酸。这些钙盐的实例是乳酸钙、葡糖酸钙、柠檬酸钙(柠檬酸单钙、柠檬酸二钙、柠檬酸三钙、柠檬酸钙钠、柠檬酸钙钾、柠檬酸钙铵)、柠檬酸/苹果酸钙、苹果酸钙、氨基酸钙络合物和富马酸钙。
有机酸的钙盐还可以通过向食品中加入有机酸或其钾盐、钠盐和/或铵盐以及氢氧化钙、钙水合物和/或碳酸钙从而原位形成来获得。
无机钙盐优选选自氯化钙、磷酸钙(磷酸单钙、磷酸二钙、磷酸三钙、磷酸钙钠、磷酸钙钾、磷酸钙铵)、硫酸钙、氢氧化钙、钙水合物、碳酸钙和它们的混合物，优选氯化钙、磷酸钙或硫酸钙，最优选氯化钙。值得一提的是，如果在原位形成无机钙盐，那么无机钙盐应选自氯化钙、磷酸钙或硫酸钙。
当所述无机钙盐是氯化钙或磷酸钙时，其还可通过将氢氧化钙、钙水合物和/或碳酸钙与磷酸或其钾盐、钠盐和/或铵盐和/或盐酸一起加入食品中来原位形成。
优选，所加的总钙量中至少20重量％由无机钙盐提供。已发现当所加的总钙量中至少20重量％由无机钙盐来提供时，可以确保食品的良好色彩稳定性。
于是，最优选总钙量的20-80重量％由无机钙盐提供，并且总钙量的20-80重量％由有机钙盐(优选乳酸钙)提供。
天然钙源也可以作为无机钙盐的一个来源，例如奶钙、海苔钙或得自岩矿的钙。这些产品含有例如碳酸钙或磷酸钙。
本发明的另一方面涉及一种如上所述的方法，其中所述无机钙盐是选自磷酸单钙、磷酸二钙、磷酸三钙、磷酸钙钠、磷酸钙钾、磷酸钙铵的磷酸钙，并且由磷酸钙提供的钙占总钙量的15-100％。如上所述，这些盐也可以原位形成。
本发明还涉及通过以上方法得到的钙强化食品，所述食品中添加有无机钙盐和有机酸的钙盐，其中优选所加的总钙量中至少20重量％由有机钙盐来提供。优选所述食品中总钙量的50-80重量％为乳酸钙且总钙量的20-50重量％为氯化钙。添加的钙的意思是指所述钙并非天然地存在于食品原料中。比如说，如果食品中含有奶，奶中所含有的奶钙并不包括在所加的总钙量之中。
本发明的含有水果的食品不仅包括果汁，还包括水果提浓物、含水果的饮料、蜜汁饮料、水果浆等，还可以是涂抹食品，其包括可涂抹的水果产品例如果酱、桔子果酱和水果馅。
本发明方法特别适合基于含有花色素苷的水果的食品，这样的水果例如越桔、欧洲越桔、蔓越桔、接骨木果、草莓、树莓、黑莓、黑醋栗、红葡萄、黑葡萄和蓝葡萄、李子和樱桃。
钙强化后得到的食品的pH低于4.5，优选低于3.5，尤其优选在2.5-3.5之间。
根据建议的日常食品摄入数值确定最终产品中的钙浓度，但是优选小于3000ppm，更优选小于600ppm。果汁或涂抹食品中合适的钙浓度为400-900ppm。
实施例
实施例1
使用1200ppm的钙对橙汁和苹果汁进行强化。以不同比例加入磷酸钙和乳酸钙。40℃下5天之后对颜色、pH和口味进行分析。结果列于表2和3中。
表2用乳酸钙/磷酸钙强化的橙汁
| 来自乳酸钙/磷酸钙的钙的百分比 | pH | 颜色稳定性 | 口味 |
| 空白 | 3.73 | 良好 | 良好 |
| 100∶0 | 3.84 | 良好 | 良好 |
| 75∶25 | 3.78 | 良好 | 良好 |
| 50∶50 | 3.71 | 良好 | 良好 |
| 25∶75 | 3.63 | 良好 | 良好 |
| 0∶100 | 3.53 | 良好 | 苦涩 |
表3 用乳酸钙/磷酸钙强化的苹果汁
| 来自乳酸钙/磷酸钙的钙的百分比 | pH | 颜色稳定性 | 口味 |
| 空白 | 3.50 | 良好 | 良好 |
| 100∶ 0 | 3.86 | 良好 | 良好 |
| 75∶25 | 3.78 | 良好 | 良好 |
| 50∶50* | 3.69 | 良好 | 良好 |
| 25∶75* | 3.58 | 良好 | 良好 |
| 0∶100* | 3.44 | 良好 | 苦涩 |
*)出现沉淀
表2和3表明当来自磷酸钙的钙超过75重量％时，对食品口味带来不利的影响。而使至少20重量％的所加钙来自乳酸钙就可以确保良好的口味。使用乳酸钙/柠檬酸钙混合物进行相同的实验，得出了同样的结果。
实施例2
使用500ppm的钙对蔓越桔汁进行强化。首先向果汁中加入乳酸钙，然后搅拌至溶解。此后加入氯化钙。测量pH并评估口味。将所得果汁在35℃下保存40小时以检查颜色稳定性。
实验结果示于表1中：
表1
| 来自乳酸钙的钙(ppm) | 来自氯化钙的钙(ppm) | pH | 颜色稳定性 | 口味 |
| 0 | 0 | 2.67 | ||
| 0 | 500 | 2.53 | 非常浅淡 | 氯气味/苦涩 |
| 100 | 400 | 2.62 | 良好 | 氯气味/苦涩 |
| 200 | 300 | 2.71 | 良好 | 氯气味/苦涩 |
| 300 | 200 | 2.80 | 良好 | 良好 |
| 400 | 100 | 2.91 | 良好 | 良好 |
| 500 | 0 | 3.00 | 浅/棕色 | 酸/涩 |
这些结果表明当所提供的钙中有至少20重量％来自无机钙盐时，可以确保良好的色彩稳定性，而至少20重量％的所加钙来自乳酸钙则可以确保良好的口味。
实施例3
使用乳酸钙/氯化钙的混合物强化柠檬汁(Orange form ex KarvanCevltam)(剂量水平20％RDI，250ml保存)。PH和口味结果示于表4中。
表3用乳酸钙/氯化钙强化的柠檬汁
| 来自乳酸钙/氯化钙的钙的百分比 | pH | 口味 |
| 空白 | 3.21 | 良好 |
| 100∶0 | 2.96 | 良好 |
| 75∶25 | 3.39 | 良好 |
| 50∶50 | 3.62 | 良好 |
| 25∶75 | 3.79 | 轻微氯气味 |
| 0∶100 | 3.91 | 氯气味→不能接受 |
这些结果表明在柠檬汁中乳酸钙和无机钙盐的结合使用对于获得可接受的口味也是必须的。至少20重量％的所加钙来自有机钙盐可以确保良好的口味。
实施例4
使用乳酸钙和柠檬酸单钙的混合物对饮用酸奶进行强化(675ppm)。当至少20重量％的所加钙来自乳酸钙时，可以确保良好的口味。
Claims (24)
1、用钙对含有水果的食品进行强化的方法，其包括向所述食品中加入无机钙盐和有机酸钙盐。
2、根据权利要求1的方法，其中所加的钙的总量的至少20重量％是由有机酸钙盐提供的。
3、根据权利要求2的方法，其中所述有机酸钙盐为乳酸钙。
4、根据权利要求1的方法，其中所加的钙的总量的至少20重量％是由无机钙盐提供的。
5、根据权利要求1的方法，其中所加的钙的总量的20-80重量％由有机酸钙盐提供，并且所加的钙的总量的20-80重量％由无机钙盐提供。
6、根据权利要求1的方法，其中所述食品中的水果含有对pH敏感的色素。
7、根据权利要求6的方法，其中所述食品中的水果含有花色素苷。
8、根据权利要求7的方法，其中所述水果选自越桔、欧洲越桔、蔓越桔、接骨木果、草莓、树莓、黑莓、黑醋栗、红葡萄、黑葡萄和蓝葡萄、李子和樱桃。
9、根据权利要求8的方法，其中所述水果是蔓越桔。
10、根据权利要求1的方法，其中所述有机酸钙盐选自乳酸、葡糖酸、柠檬酸、苹果酸、富马酸、酒石酸、己二酸的钙盐及其混合物。
11、根据权利要求1的方法，其中通过向所述食品中加入有机酸或其钾盐、钠盐或铵盐以及氢氧化钙、钙水合物或碳酸钙，在所述食品中原位形成所述有机酸的钙盐。
12、根据权利要求10的方法，其中所述有机酸的钙盐为乳酸钙盐。
13、根据权利要求1的方法，其中所述无机钙盐选自氯化钙、磷酸钙、硫酸钙、钙水合物、碳酸钙及它们的混合物。
14、根据权利要求1的方法，其中通过向所述食品中加入氢氧化钙、钙水合物和/或碳酸钙以及磷酸和/或盐酸或它们的钾盐、钠盐或铵盐，在所述食品中原位形成所述无机钙盐。
15、根据权利要求11的方法，其中所述无机钙盐是氯化钙。
16、根据权利要求1的方法，其中所述经过钙强化的食品的pH值小于4.5。
17、根据权利要求14的方法，其中所述经过钙强化的食品的pH值小于3.5。
18、根据权利要求1的方法，其中强化后食品中的钙浓度低于3000ppm。
19、根据权利要求16的方法，其中强化后食品中的钙浓度低于600ppm。
20、根据权利要求1的方法，其中所述无机钙盐选自如下的磷酸钙盐：磷酸单钙、磷酸二钙、磷酸三钙、磷酸钙钠、磷酸钙钾、磷酸钙铵。
21、含有水果的钙强化食品，其含有一种添加的无机钙盐和一种添加的有机酸钙盐，其中所加的钙的总量的至少20重量％是由有机酸钙盐提供的。
22、根据权利要求20的钙强化食品，其中所述有机酸的钙盐为乳酸钙盐。
23、根据权利要求21的钙强化食品，其中所加的钙的总量的50-80重量％为乳酸钙，并且所加的钙的总量的10-50重量％为氯化钙。
24、根据权利要求18的钙强化食品，其是一种汁、提浓物、饮料、浆、蜜汁饮料或涂抹食品。
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP01203615.8 | 2001-09-21 | ||
| EP01203615A EP1295536A1 (en) | 2001-09-21 | 2001-09-21 | Process for the fortification of a fruit based food product with calcium |
| US09/956,856 | 2001-09-21 | ||
| US09/956,856 US20030059499A1 (en) | 2001-09-21 | 2001-09-21 | Process for the fortification of a fruit based food product with calcium |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1556678A true CN1556678A (zh) | 2004-12-22 |
| CN100536694C CN100536694C (zh) | 2009-09-09 |
Family
ID=26077000
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB028185692A Expired - Lifetime CN100536694C (zh) | 2001-09-21 | 2002-09-19 | 含水果的食品的钙强化方法 |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP1429630B1 (zh) |
| JP (1) | JP4486814B2 (zh) |
| CN (1) | CN100536694C (zh) |
| BR (1) | BR0212687A (zh) |
| ES (1) | ES2576404T3 (zh) |
| WO (1) | WO2003024250A1 (zh) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103250858A (zh) * | 2013-06-08 | 2013-08-21 | 普宁市梅乡食品有限公司 | 一种梅饼及其制备方法 |
| CN103859421A (zh) * | 2014-03-03 | 2014-06-18 | 四川华通柠檬有限公司 | 液态柠檬果酸钙制备方法、柠檬果酸钙口服液及制备方法 |
| CN104522824A (zh) * | 2014-12-11 | 2015-04-22 | 李跃 | 灯笼果速溶补钙冲剂 |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7422761B2 (en) * | 2003-12-03 | 2008-09-09 | Tropicana Products, Inc. | In-line process for preparing calcium-supplemented juice beverages |
| US20070003672A1 (en) * | 2005-07-01 | 2007-01-04 | Anglea Timothy A | Tri-part calcium fortified compositions and methods of making the same |
| US20090162490A1 (en) * | 2007-12-20 | 2009-06-25 | Tropicana Products, Inc. | Calcium-fortified beverages and method of making thereof |
| JP4537471B2 (ja) * | 2008-05-29 | 2010-09-01 | 株式会社 伊藤園 | 乳タンパク質含有容器詰野菜飲料 |
| JP2011036130A (ja) * | 2009-08-06 | 2011-02-24 | Meiji Seika Kaisha Ltd | カシスアントシアニン含有飲料 |
| JP6280522B2 (ja) * | 2015-06-05 | 2018-02-14 | マルハニチロ株式会社 | 収穫後にイチゴの果実品質を向上させる方法 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4740380A (en) | 1986-02-18 | 1988-04-26 | Stauffer Chemical Company | Calcium fortified acid beverages |
| US4919963A (en) | 1986-05-07 | 1990-04-24 | The Procter & Gamble Company | Method of preparing fruit juice beverages and juice concentrates nutritionally supplemented with calcium |
| US4871554A (en) | 1987-08-12 | 1989-10-03 | Coca-Cola Company | Calcium fortified food product |
| JP2673262B2 (ja) * | 1989-06-30 | 1997-11-05 | 雪印乳業株式会社 | クエン酸及びカルシウムが共存する果汁含有カプセル化ゼリーの製法 |
| US5500232A (en) * | 1994-10-06 | 1996-03-19 | Bristol-Myers Squibb Company | Calcium fortified beverages |
| GB9603518D0 (en) | 1996-02-20 | 1996-04-17 | Smithkline Beecham Plc | Novel process |
| US6086927A (en) * | 1998-08-06 | 2000-07-11 | Pasco Beverage Co. | Process for preparing calcium enriched food products and the products therefrom |
| EP1198182A1 (en) | 1999-07-06 | 2002-04-24 | Société des Produits Nestlé S.A. | Isotonic juice drink for children |
-
2002
- 2002-09-19 ES ES02760890.0T patent/ES2576404T3/es not_active Expired - Lifetime
- 2002-09-19 WO PCT/NL2002/000597 patent/WO2003024250A1/en active Application Filing
- 2002-09-19 JP JP2003528153A patent/JP4486814B2/ja not_active Expired - Fee Related
- 2002-09-19 BR BR0212687-7A patent/BR0212687A/pt not_active Application Discontinuation
- 2002-09-19 CN CNB028185692A patent/CN100536694C/zh not_active Expired - Lifetime
- 2002-09-19 EP EP02760890.0A patent/EP1429630B1/en not_active Expired - Lifetime
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103250858A (zh) * | 2013-06-08 | 2013-08-21 | 普宁市梅乡食品有限公司 | 一种梅饼及其制备方法 |
| CN103250858B (zh) * | 2013-06-08 | 2014-06-04 | 普宁市梅乡食品有限公司 | 一种梅饼的制备方法 |
| CN103859421A (zh) * | 2014-03-03 | 2014-06-18 | 四川华通柠檬有限公司 | 液态柠檬果酸钙制备方法、柠檬果酸钙口服液及制备方法 |
| CN103859421B (zh) * | 2014-03-03 | 2016-01-06 | 四川华通柠檬有限公司 | 液态柠檬果酸钙制备方法、柠檬果酸钙口服液及制备方法 |
| CN104522824A (zh) * | 2014-12-11 | 2015-04-22 | 李跃 | 灯笼果速溶补钙冲剂 |
| CN104522824B (zh) * | 2014-12-11 | 2016-05-11 | 李跃 | 灯笼果速溶补钙冲剂 |
Also Published As
| Publication number | Publication date |
|---|---|
| BR0212687A (pt) | 2004-10-19 |
| JP2005502373A (ja) | 2005-01-27 |
| EP1429630A1 (en) | 2004-06-23 |
| WO2003024250A1 (en) | 2003-03-27 |
| JP4486814B2 (ja) | 2010-06-23 |
| CN100536694C (zh) | 2009-09-09 |
| ES2576404T3 (es) | 2016-07-07 |
| EP1429630B1 (en) | 2016-04-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1476300B (zh) | 加钙饮料及其生产方法 | |
| CN100539855C (zh) | 钙强化饮料 | |
| CN1556678A (zh) | 含水果的食品的钙强化方法 | |
| AU2003218893B2 (en) | Manufactured mineral water composition | |
| TWI248344B (en) | Calcium-fortified, grape-based products and methods for making them | |
| CN101052318A (zh) | 饮料 | |
| US20040161496A1 (en) | Process for the fortification of a fruit-based food product with calcium | |
| EP1295536A1 (en) | Process for the fortification of a fruit based food product with calcium | |
| US6803064B1 (en) | Calcium fortified beverage compositions and process for preparing the same | |
| US20030059499A1 (en) | Process for the fortification of a fruit based food product with calcium | |
| CN112770641A (zh) | 含有苹果酸的无酒精饮料 | |
| CN101065025A (zh) | 饮料生产方法 | |
| CN1092940C (zh) | 一种食用含矿物元素浓缩液及其制备方法 | |
| JP2002017315A (ja) | 海洋深層水を利用した飲料 | |
| US10736341B1 (en) | Electrolyte-fortified carbonated beverage compositions | |
| CN1901817A (zh) | 含有乳酸葡糖酸柠檬酸钙的淡口感钙强化饮料 | |
| JP2021101692A (ja) | 鉄含有飲料 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CX01 | Expiry of patent term |
Granted publication date: 20090909 |
|
| CX01 | Expiry of patent term |