CN1541985A - Series multielement chelate special-purpose composite fertilizer and method for preparing the same - Google Patents
Series multielement chelate special-purpose composite fertilizer and method for preparing the same Download PDFInfo
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- CN1541985A CN1541985A CNA2003101035546A CN200310103554A CN1541985A CN 1541985 A CN1541985 A CN 1541985A CN A2003101035546 A CNA2003101035546 A CN A2003101035546A CN 200310103554 A CN200310103554 A CN 200310103554A CN 1541985 A CN1541985 A CN 1541985A
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- 239000003337 fertilizer Substances 0.000 title claims abstract description 89
- 239000002131 composite material Substances 0.000 title claims abstract description 48
- 239000013522 chelant Substances 0.000 title claims abstract description 27
- 238000000034 method Methods 0.000 title claims description 15
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 21
- 239000002689 soil Substances 0.000 claims abstract description 17
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 16
- 229910052742 iron Inorganic materials 0.000 claims abstract description 15
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 10
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 10
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 9
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 5
- 235000015097 nutrients Nutrition 0.000 claims description 21
- 241000196324 Embryophyta Species 0.000 claims description 20
- 239000000126 substance Substances 0.000 claims description 18
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 14
- 239000002253 acid Substances 0.000 claims description 12
- 229910052750 molybdenum Inorganic materials 0.000 claims description 11
- 150000001875 compounds Chemical class 0.000 claims description 10
- 229910052802 copper Inorganic materials 0.000 claims description 10
- 229910052757 nitrogen Inorganic materials 0.000 claims description 10
- 229910052698 phosphorus Inorganic materials 0.000 claims description 10
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 8
- 229910052700 potassium Inorganic materials 0.000 claims description 8
- 239000011591 potassium Substances 0.000 claims description 8
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 7
- 229910017053 inorganic salt Inorganic materials 0.000 claims description 7
- 239000011574 phosphorus Substances 0.000 claims description 7
- 150000001413 amino acids Chemical class 0.000 claims description 6
- 229910052796 boron Inorganic materials 0.000 claims description 6
- WOAHJDHKFWSLKE-UHFFFAOYSA-N 1,2-benzoquinone Chemical compound O=C1C=CC=CC1=O WOAHJDHKFWSLKE-UHFFFAOYSA-N 0.000 claims description 5
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 5
- 230000035558 fertility Effects 0.000 claims description 5
- 230000012010 growth Effects 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 239000003352 sequestering agent Substances 0.000 claims description 5
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims description 4
- 235000017491 Bambusa tulda Nutrition 0.000 claims description 4
- 240000007594 Oryza sativa Species 0.000 claims description 4
- 235000007164 Oryza sativa Nutrition 0.000 claims description 4
- 244000082204 Phyllostachys viridis Species 0.000 claims description 4
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims description 4
- 239000011425 bamboo Substances 0.000 claims description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 235000009566 rice Nutrition 0.000 claims description 4
- 235000010149 Brassica rapa subsp chinensis Nutrition 0.000 claims description 3
- 235000000536 Brassica rapa subsp pekinensis Nutrition 0.000 claims description 3
- 241000499436 Brassica rapa subsp. pekinensis Species 0.000 claims description 3
- 244000241257 Cucumis melo Species 0.000 claims description 3
- 235000009847 Cucumis melo var cantalupensis Nutrition 0.000 claims description 3
- 230000008901 benefit Effects 0.000 claims description 3
- 235000006667 Aleurites moluccana Nutrition 0.000 claims description 2
- 244000144730 Amygdalus persica Species 0.000 claims description 2
- 235000017060 Arachis glabrata Nutrition 0.000 claims description 2
- 244000105624 Arachis hypogaea Species 0.000 claims description 2
- 235000010777 Arachis hypogaea Nutrition 0.000 claims description 2
- 235000018262 Arachis monticola Nutrition 0.000 claims description 2
- 244000003416 Asparagus officinalis Species 0.000 claims description 2
- 235000005340 Asparagus officinalis Nutrition 0.000 claims description 2
- 235000006008 Brassica napus var napus Nutrition 0.000 claims description 2
- 235000011299 Brassica oleracea var botrytis Nutrition 0.000 claims description 2
- 235000001169 Brassica oleracea var oleracea Nutrition 0.000 claims description 2
- 240000003259 Brassica oleracea var. botrytis Species 0.000 claims description 2
- 235000004936 Bromus mango Nutrition 0.000 claims description 2
- 240000004957 Castanea mollissima Species 0.000 claims description 2
- 235000018244 Castanea mollissima Nutrition 0.000 claims description 2
- 235000007763 Castanea pumila Nutrition 0.000 claims description 2
- 244000025797 Castanea pumila Species 0.000 claims description 2
- 241001674939 Caulanthus Species 0.000 claims description 2
- 244000241235 Citrullus lanatus Species 0.000 claims description 2
- 235000012828 Citrullus lanatus var citroides Nutrition 0.000 claims description 2
- 240000008067 Cucumis sativus Species 0.000 claims description 2
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 claims description 2
- 240000001008 Dimocarpus longan Species 0.000 claims description 2
- 235000009008 Eriobotrya japonica Nutrition 0.000 claims description 2
- 244000061508 Eriobotrya japonica Species 0.000 claims description 2
- 244000004281 Eucalyptus maculata Species 0.000 claims description 2
- 235000000235 Euphoria longan Nutrition 0.000 claims description 2
- 235000003228 Lactuca sativa Nutrition 0.000 claims description 2
- 240000008415 Lactuca sativa Species 0.000 claims description 2
- 235000014826 Mangifera indica Nutrition 0.000 claims description 2
- 240000007228 Mangifera indica Species 0.000 claims description 2
- 240000005561 Musa balbisiana Species 0.000 claims description 2
- 235000018290 Musa x paradisiaca Nutrition 0.000 claims description 2
- 235000002637 Nicotiana tabacum Nutrition 0.000 claims description 2
- 244000061176 Nicotiana tabacum Species 0.000 claims description 2
- 241001560086 Pachyrhizus Species 0.000 claims description 2
- 235000006040 Prunus persica var persica Nutrition 0.000 claims description 2
- 235000009184 Spondias indica Nutrition 0.000 claims description 2
- 235000021307 Triticum Nutrition 0.000 claims description 2
- 244000098338 Triticum aestivum Species 0.000 claims description 2
- 235000009754 Vitis X bourquina Nutrition 0.000 claims description 2
- 235000012333 Vitis X labruscana Nutrition 0.000 claims description 2
- 240000006365 Vitis vinifera Species 0.000 claims description 2
- 235000014787 Vitis vinifera Nutrition 0.000 claims description 2
- 235000012907 honey Nutrition 0.000 claims description 2
- 235000019198 oils Nutrition 0.000 claims description 2
- 235000020232 peanut Nutrition 0.000 claims description 2
- 239000002994 raw material Substances 0.000 claims description 2
- 150000001735 carboxylic acids Chemical class 0.000 claims 2
- 235000000832 Ayote Nutrition 0.000 claims 1
- 235000002566 Capsicum Nutrition 0.000 claims 1
- 235000008534 Capsicum annuum var annuum Nutrition 0.000 claims 1
- 240000008384 Capsicum annuum var. annuum Species 0.000 claims 1
- 240000008574 Capsicum frutescens Species 0.000 claims 1
- 240000004244 Cucurbita moschata Species 0.000 claims 1
- 235000009854 Cucurbita moschata Nutrition 0.000 claims 1
- 235000009804 Cucurbita pepo subsp pepo Nutrition 0.000 claims 1
- 244000050510 Cunninghamia lanceolata Species 0.000 claims 1
- 235000019687 Lamb Nutrition 0.000 claims 1
- 240000002834 Paulownia tomentosa Species 0.000 claims 1
- 241000142776 Pinus elliottii Species 0.000 claims 1
- 235000011334 Pinus elliottii Nutrition 0.000 claims 1
- 241000018650 Pinus massoniana Species 0.000 claims 1
- 235000011609 Pinus massoniana Nutrition 0.000 claims 1
- 235000002597 Solanum melongena Nutrition 0.000 claims 1
- 244000061458 Solanum melongena Species 0.000 claims 1
- 239000001390 capsicum minimum Substances 0.000 claims 1
- 235000015136 pumpkin Nutrition 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 5
- 239000011573 trace mineral Substances 0.000 abstract description 4
- 235000013619 trace mineral Nutrition 0.000 abstract description 4
- 230000007774 longterm Effects 0.000 abstract description 3
- 230000000050 nutritive effect Effects 0.000 abstract description 3
- WZLMXYBCAZZIRQ-UHFFFAOYSA-N [N].[P].[K] Chemical compound [N].[P].[K] WZLMXYBCAZZIRQ-UHFFFAOYSA-N 0.000 description 22
- 239000011572 manganese Substances 0.000 description 17
- 239000011701 zinc Substances 0.000 description 17
- 239000011707 mineral Substances 0.000 description 10
- 235000010755 mineral Nutrition 0.000 description 10
- 239000011575 calcium Substances 0.000 description 9
- 229910052500 inorganic mineral Inorganic materials 0.000 description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 9
- 239000011777 magnesium Substances 0.000 description 9
- 239000010949 copper Substances 0.000 description 8
- 210000003608 fece Anatomy 0.000 description 6
- 239000010871 livestock manure Substances 0.000 description 6
- 208000006558 Dental Calculus Diseases 0.000 description 5
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 5
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 5
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 5
- 239000004202 carbamide Substances 0.000 description 5
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 4
- 229940024606 amino acid Drugs 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000005995 Aluminium silicate Substances 0.000 description 3
- 235000012211 aluminium silicate Nutrition 0.000 description 3
- 230000003042 antagnostic effect Effects 0.000 description 3
- QLULGSLAHXLKSR-UHFFFAOYSA-N azane;phosphane Chemical compound N.P QLULGSLAHXLKSR-UHFFFAOYSA-N 0.000 description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 3
- 239000004575 stone Substances 0.000 description 3
- 241001269238 Data Species 0.000 description 2
- 239000005696 Diammonium phosphate Substances 0.000 description 2
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 description 2
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 description 2
- YYRMJZQKEFZXMX-UHFFFAOYSA-L calcium bis(dihydrogenphosphate) Chemical compound [Ca+2].OP(O)([O-])=O.OP(O)([O-])=O YYRMJZQKEFZXMX-UHFFFAOYSA-L 0.000 description 2
- FUFJGUQYACFECW-UHFFFAOYSA-L calcium hydrogenphosphate Chemical compound [Ca+2].OP([O-])([O-])=O FUFJGUQYACFECW-UHFFFAOYSA-L 0.000 description 2
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 2
- 229910000389 calcium phosphate Inorganic materials 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 2
- 229910000388 diammonium phosphate Inorganic materials 0.000 description 2
- 235000019838 diammonium phosphate Nutrition 0.000 description 2
- 235000013312 flour Nutrition 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000006012 monoammonium phosphate Substances 0.000 description 2
- 235000019837 monoammonium phosphate Nutrition 0.000 description 2
- 235000019691 monocalcium phosphate Nutrition 0.000 description 2
- 235000021049 nutrient content Nutrition 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- DWNBOPVKNPVNQG-LURJTMIESA-N (2s)-4-hydroxy-2-(propylamino)butanoic acid Chemical compound CCCN[C@H](C(O)=O)CCO DWNBOPVKNPVNQG-LURJTMIESA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- QNAYBMKLOCPYGJ-REOHCLBHSA-N L-alanine Chemical compound C[C@H](N)C(O)=O QNAYBMKLOCPYGJ-REOHCLBHSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- XUYPXLNMDZIRQH-LURJTMIESA-N N-acetyl-L-methionine Chemical compound CSCC[C@@H](C(O)=O)NC(C)=O XUYPXLNMDZIRQH-LURJTMIESA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- YMKIRWHSXOBLCF-UHFFFAOYSA-N [Mg].[P].[Ca] Chemical compound [Mg].[P].[Ca] YMKIRWHSXOBLCF-UHFFFAOYSA-N 0.000 description 1
- RDXARWSSOJYNLI-UHFFFAOYSA-N [P].[K] Chemical compound [P].[K] RDXARWSSOJYNLI-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 229940037003 alum Drugs 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- HIVLDXAAFGCOFU-UHFFFAOYSA-N ammonium hydrosulfide Chemical compound [NH4+].[SH-] HIVLDXAAFGCOFU-UHFFFAOYSA-N 0.000 description 1
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 description 1
- 239000011609 ammonium molybdate Substances 0.000 description 1
- 229940010552 ammonium molybdate Drugs 0.000 description 1
- 235000018660 ammonium molybdate Nutrition 0.000 description 1
- INQZXVMNJLSCGI-UHFFFAOYSA-M azanium;potassium;hydrogen phosphate Chemical compound [NH4+].[K+].OP([O-])([O-])=O INQZXVMNJLSCGI-UHFFFAOYSA-M 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 235000010338 boric acid Nutrition 0.000 description 1
- 235000013877 carbamide Nutrition 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910021540 colemanite Inorganic materials 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229940116318 copper carbonate Drugs 0.000 description 1
- 229910001779 copper mineral Inorganic materials 0.000 description 1
- 229910000365 copper sulfate Inorganic materials 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- GEZOTWYUIKXWOA-UHFFFAOYSA-L copper;carbonate Chemical compound [Cu+2].[O-]C([O-])=O GEZOTWYUIKXWOA-UHFFFAOYSA-L 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 239000010881 fly ash Substances 0.000 description 1
- 229960002989 glutamic acid Drugs 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 229930182817 methionine Natural products 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- VLAPMBHFAWRUQP-UHFFFAOYSA-L molybdic acid Chemical compound O[Mo](O)(=O)=O VLAPMBHFAWRUQP-UHFFFAOYSA-L 0.000 description 1
- 235000021048 nutrient requirements Nutrition 0.000 description 1
- 239000003895 organic fertilizer Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- VGTPKLINSHNZRD-UHFFFAOYSA-N oxoborinic acid Chemical compound OB=O VGTPKLINSHNZRD-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 230000008635 plant growth Effects 0.000 description 1
- 239000011505 plaster Substances 0.000 description 1
- GNSKLFRGEWLPPA-UHFFFAOYSA-M potassium dihydrogen phosphate Chemical compound [K+].OP(O)([O-])=O GNSKLFRGEWLPPA-UHFFFAOYSA-M 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 230000009919 sequestration Effects 0.000 description 1
- TVXXNOYZHKPKGW-UHFFFAOYSA-N sodium molybdate (anhydrous) Chemical compound [Na+].[Na+].[O-][Mo]([O-])(=O)=O TVXXNOYZHKPKGW-UHFFFAOYSA-N 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
Landscapes
- Fertilizers (AREA)
Abstract
The multi-element chelate special composite fertilizer contains: macro components N, P2O5 and K2O IN 30-48 wt%; medium amount elements Ca, Mg and S in 3-20 wt%; trace elements Mo,Cu, b, Zn, Fe and Mn in 0.06-3.00 wt% with Zn, Fe and Mn being chelated; and special elements Ti, Si and Al in amount depending on crop. The serial multi-element chelate special composite fertilizer can produce the near term effects of full utilization of fertilizer, reduced consumption, low cost and high nutritive components; as well as the long term effects of maintaining positive cycle of soil and improving natural environment.
Description
Technical field
The serial composite fertilizer that the present invention relates to use on the agroforestry especially can be applied to the multi-element chelate composite fertilizer special of multiple kinds of crops or plant.
Background technology
In agriculture production, the fertilizer material used for agriculture that is absolutely necessary.Present existing fertilizer, be divided into mineral manure and organic fertilizer, the fertilizer that mineral manure is mineral substance or processes through the inorganic chemistry reaction, its production technology is very ripe, and existing mineral manure has single fertilizers such as urea, calcium superphosphate, monoammonium phosphate or diammonium phosphate, vitriolate of tartar or Repone K.Existing at present trace element or the functional elements of adding in mineral manure, perhaps multiple element mineral manure is mixed into composite fertilizer.These composite fertilizers are because nutritive ingredient is comprehensive, compare with single fertilizer, its fertilizer efficiency increases, yet existing composite the simple superposition of considering various fertilizer, do not consider the required nutrient of soil fertility and plant-growth as yet and make composite fertilizer special, and, the composite fertilizer of these simple superposition, can produce antagonistic action between the trace element, influence the performance of fertilizer efficiency.
The innovation and creation content
The purpose of this invention is to provide a series of with strong points, that can effectively reduce antagonistic action between some elements to farm crop or plant, promote multi-element chelate composite fertilizer special that plant absorbs nitrogen phosphorus potassium, that fertilizer efficiency improves.
Another object of the present invention is to provide a kind of compound method of above-mentioned composite fertilizer.
Serial multi-element chelate composite fertilizer special of the present invention is the chemical fertilizer that is applicable to farm crop and plant, comprises following component:
(1) contains the compound or the mixture of inorganic nitrogen, phosphorus and potassium;
(2) contain vitriol and other inorganicss of Ca, Mg, S element;
(3) contain Mo, Cu, the inorganic salt of B element or mineral and contain Zn, Fe, the inner complex of Mn element;
(4) can contain part special elements Ti, Si, Al.
Further, above-mentioned serial multi-element chelate composite fertilizer special is to select for use said components to process by following constituent content scope:
(1) in composite fertilizer, macroelement N, P
2O
5, K
2O content summation is 30-48% (weight);
(2) in composite fertilizer, moderate-element Ca, Mg, S content summation is 3-20% (weight);
(3) in composite fertilizer, contain Mo, Cu, the inorganic salt of B element or mineral and contain Zn, Fe, the inner complex of Mn element; Trace element Mo, Cu, B, Zn, Fe, Mn content summation is 0.06-3.00% (weight);
(4) in composite fertilizer, can contain among special elements Ti, Si, the Al one or more, the content summation is in 0-5% (weight).
In the above-mentioned serial multi-element chelate composite fertilizer special, the inner complex of described Zn, Fe, Mn is to be processed by one or two or more sequestrant in amino acid, xanthohumic acid, polyamino poly carboxylic acid, hydroxycarboxylic acid, multi-hydroxy carboxy acid, multi-hydroxy multi-carboxy acid, the o-quinone phenol.
The present invention provides the collocation method of above-mentioned serial multi-element chelate composite fertilizer special simultaneously, comprises the steps:
1) collects the required nutrient of the process of growth of required farm crop of using or plant and to each nutrient absorbing rate;
2) collect the soil fertility of farm crop or plant growing region and the survey soil data of chemical state;
3) according to 1) and 2) data computation go out farm crop or plant nutrient in planted agent's benefit in predetermined vegetative period;
4) result foundation 3) organizes chemical fertilizer raw material, and each component is mixed.
Above-mentioned serial multi-element chelate composite fertilizer special, can on following farm crop and plant, use respectively: Chinese cabbage, Cauliflower, lettuce, wild cabbage, cucumber, muskmelon, watermelon, asparagus, bamboo shoot bamboo, lichee, longan, loquat, banana, honey peach, Chinese chestnut, chinquapin, mango, grape, oil how, tobacco, tealeaves, eucalyptus, peanut, pachyrhizus, paddy rice, wheat etc.
Above-mentioned serial multi-element chelate composite fertilizer special can be used on the farm crop of establishing in large scale or plant.
Adopt technique scheme, serial multi-element chelate composite fertilizer special of the present invention be collect the required nutrient of farm crop or growing process and to the soil fertility of nutrient absorbing rate, region, place and chemical state (pH value, redox potential), estimate data such as needing the nutrient that replenishes in the vegetative period that farm crop or plant be scheduled to and combine field experiment and the prescription formulated.Use the special-purpose fertile 3 years arable land of the present invention continuously, also need survey soil, collect each available nutrient of soil and chemical state data, for the adjustment of chemical fertilizer prescription of the present invention.
Serial multi-element chelate composite fertilizer special of the present invention is mainly used in the farm crop or the plant of establishing in large scale, generally is the cultivated area more than thousand mu.
Serial multi-element chelate composite fertilizer special of the present invention, from recent effect, it is pointed by force, the performance fertilizer efficiency is abundant, amount of application reduces, production cost reduces, the nutritive ingredient advantages of higher; From long-range meaning, this fertilizer of long-term application can be kept the benign cycle of soil nutrient, and the protection Soil structure improves physical environment, is a kind of agrochemical that can long-term application.
Embodiment
The present invention's series multi-element chelate composite fertilizer special grows up on the fertile basis of existing simple composite, is on the basis of four kinds of master datas, the prescription of formulating in conjunction with field experiment.Specified farm crop and plant above the object that " series " refers to fertilising has been contained collected their required nutrients of process of growth and to each nutrient absorbing rate separately; " special use " is on the described in the above data, cooperates the soil fertility of farm crop or region, plant place and the survey soil data of chemical state (pH value, redox potential), calculates farm crop or plant at the predetermined nutrient that vegetative period, the planted agent mended; The implication of " multielement " is made a general reference those according to the selected element sum of special use; " chelating " is for reducing the antagonistic action between some element, stimulate farm crop or plant to absorption big, moderate-element, improving the technical measures of fertilizer efficiency.The function and significance of these four kinds of data, partly content covers mutually, and it is organically in conjunction with having formed the present invention.Various special-purpose fertilizer does not in the past all relate to so many master datas.
Each prescription of series multi-element chelate composite fertilizer special, in following ratio range, select:
(1) contains the mixture or the compound of inorganic nitrogen, phosphorus and potassium; N in composite fertilizer, P
2O
5, K
2O content summation is 30-48% (weight);
(2) contain vitriol and other inorganic salt of Ca, Mg, S element; Ca in composite fertilizer, Mg, S content summation is 3-20% (weight);
(3) contain Mo, Cu, the inorganic salt of B element and contain Zn, Fe, the inner complex of Mn element; In composite fertilizer, micro-Mo, Cu, B, Zn, Fe, Mn content summation is 0.06-3.00% (weight);
(4) contain the inorganic salt of Ti, Si, Al; In composite fertilizer, the content summation of special elements Ti, Si, Al is 0-5% (weight).
Here, above-mentioned N, P
2O
5, K
2O comes from mineral manure such as urea, sulphur ammonium, monoammonium phosphate, diammonium phosphate, potassium-ammonium phosphate, potassium phosphate,monobasic, potassium primary phosphate, secondary calcium phosphate, calcium superphosphate or double superhosphate and vitriolate of tartar, Repone K respectively;
Zn, Mn, Fe are respectively the inner complex that processes with one or two or more sequestrant in amino acid, xanthohumic acid, polyamino poly carboxylic acid, hydroxycarboxylic acid, multi-hydroxy carboxy acid, multi-hydroxy multi-carboxy acid, the o-quinone phenol, as take from L-glutamic acid in the raffinate that amino acid produces, Methionin, winter propylhomoserin etc. as sequestrant, adopt Zn, Mn, the Fe metallo-chelate of the process for sequestration preparation on the textbook.
B, Mo, Cu can be from borax or boric acid, ammonium molybdate and copper sulfate and mineral etc.; Ca, Mg, S can come bin cure ammonium, sal epsom, secondary calcium phosphate, nitrocalcite etc.; Al is from Tai-Ace S 150, aluminum chloride, alum; SiO
2From Starso, Calucium Silicate powder, flyash etc.; Ti is from titanate.
The preparation of multi-element chelate composite fertilizer special: with nitrogen, phosphorus, potassium, Mo, Cu, B compound, Zn, Fe, Mn inner complex and the compound that contains Ca, Mg, S and special elements form in selected ratio.
Embodiment 1: Fertilizer Prescription Special for Rice (is used the place: Minhou County somewhere, Fujian Province)
Present embodiment is according to the required nutrient of paddy growth and to the nutrient absorbing rate, in conjunction with the survey soil data of using the place, calculate this area paddy rice predetermined vegetative period nutrient that the planted agent mends as follows:
N+P
2O
5+ K
2O=38% (weight)
Ca+Mg+S=6.7% (weight)
Zn+Mn+B+Mo=0.082% (weight)
SiO
2=1.6% (weight)
Particularly, with reference to this ground soil nutrient take off data, available following material mixed preparing and reach above-mentioned nutrient requirement.Contain various components listed in the table in the fertilizer per ton.
Unit: kilogram
| The phosphorus ammonium | ????158 |
| Urea | ????270 |
| Repone K | ????135 |
| Vitriolate of tartar | ????162 |
| Sal epsom | ????56 |
| Calcium magnesium phosphorus | ????80 |
| The boron rock stone flour | ????9.5 |
| Chelating zinc * | ????6 |
| Chelated Manganese * | ????2 |
| Oxidizing aqueous molybdenum | ????0.01 |
| Kaolin | Surplus |
* prepare chelating attitude zinc and chelating attitude manganese with Gourmet Powder Factory's amino acid concentrating spent liquor
Effect behind this routine chemical fertilizer application (comparing) with the common nitrogen phosphorus potassium summation 48% of no chelated microelements, the fertilizer of common nitrogen phosphorus potassium summation 38%:
1. output: (jin/mu)
| This fertilizer | Nitrogen phosphorus potassium total content 48% | Nitrogen phosphorus potassium total content 38% |
| 1180.28 | 1139.69 | 901.30 |
2. quality: setting percentage (%)
| This fertilizer | Nitrogen phosphorus potassium total content 48% | Nitrogen phosphorus potassium total content 38% |
| 93.76 | 88.99 | 82.11 |
Example 2: Chinese cabbage (early assorted No.) special-purpose fertile (use the place: the suburb, Fuzhou City, Fujian Province):
Equally, calculate this example chemical fertilizer nutrient content with reference to this ground soil nutrient take off data:
N+P
2O
5+ K
2O=38% (weight)
Ca+Mg+S=3.8% (weight)
Zn+Mn+B+Mo=0.103% (weight)
Chemical fertilizer per ton is formed by following component mixed preparing:
Unit: kilogram
| The phosphorus ammonium | ????111 |
| Urea | ????257 |
| Repone K | ????166 |
| Vitriolate of tartar | ????200 |
| Boric acid | ????2.6 |
| Chelating zinc * | ????7.2 |
| Chelated Manganese * | ????5 |
| Molybdic acid anhydride | ????0.008 |
| Kaolin | Surplus |
Use back effect (comparing) with the common nitrogen phosphorus potassium summation 48% of no chelated microelements, the fertilizer of common nitrogen phosphorus potassium summation 38%:
1. output: (kilogram/mu)
| This fertilizer | Nitrogen phosphorus potassium total content 48% | Nitrogen phosphorus potassium total content 38% |
| 2150 | 1918 | 1671 |
2. quality:
| This fertilizer | Nitrogen phosphorus potassium total content 48% | Nitrogen phosphorus potassium total content 38% |
| Tall and straight glossy, mouthfeel is good | Glossy, mouthfeel is medium | Outward appearance, color and luster, mouthfeel are relatively poor |
Example 3: muskmelon is special-purpose fertile (uses the place: the Lang Qidao of Fujian Province)
Equally, with reference to this ground soil nutrient take off data as calculated, this example chemical fertilizer nutrient content:
N+P
2O
5+ K
2O=38% (weight)
Ca+Mg+S=12.7% (weight)
Zn+Mn+B+Mo+Cu=0.2% (weight)
Chemical fertilizer per ton is formed by following component mixed preparing:
Unit: kilogram
| The phosphorus ammonium | ????118 |
| Urea | ????302 |
| Vitriolate of tartar | ????350 |
| Sal epsom | ????60 |
| Plaster stone | ????60 |
| The colemanite stone flour | ????5 |
| Chelating zinc * | ????6 |
| Chelated Manganese * | ????2 |
| Sodium orthomolybdate | ????0.07 |
| Copper carbonate | ????0.05 |
| Kaolin | Surplus |
* be that recombiner prepares chelating zinc and Chelated Manganese with L-Ala and o-quinone phenol
Use back effect (comparing) with the common nitrogen phosphorus potassium summation 48% of no chelated microelements, the fertilizer of common nitrogen phosphorus potassium summation 38%:
1. output: (kilogram/mu)
| This fertilizer | Nitrogen phosphorus potassium total content 48% | Nitrogen phosphorus potassium total content 38% |
| ????2090 | ????2130 | ????1810 |
This routine chemical fertilizer (N+P
2O
5+ K
2O=38%) chemical fertilizer with common nitrogen phosphorus potassium summation 48% is suitable on the output, but obviously surpasses the fertilizer production of common nitrogen phosphorus potassium summation 38%.
2. quality:
| This fertilizer | Nitrogen phosphorus potassium total content 48% | Nitrogen phosphorus potassium total content 38% |
| Outward appearance is bright-coloured, mouthfeel good | Outward appearance is general, mouthfeel is general | Outward appearance is general, mouthfeel is general |
Above embodiment is only for proving absolutely embodiments of the present invention, for other and the similar farm crop of embodiment, can be according to characteristics separately, and adopting uses the same method obtains its proiprietary formula.
By above embodiment as can be seen, (prescription is N+P to the special-purpose fertilizer of the present invention
2O
5+ K
2O=38%) (prescription is N+P with pure Nitrogen, Phosphorus and Potassium
2O
5+ K
2O=48%) compare, be applied to same farm crop, fertilizer efficiency is suitable; But it is better to use the crop growth state that chemical fertilizer of the present invention obtains, and the quality of agricultural-food obviously improves.
(prescription is N+P to the special-purpose fertilizer of the present invention
2O
5+ K
2O=38%) (prescription is N+P with pure Nitrogen, Phosphorus and Potassium
2O
5+ K
2O=38%) compare, to same farm crop, use the special-purpose fertile increasing crop yield 10-30% of the present invention, and farm crop are stronger in the disease-resistant anti-disaster ability of growing period, the quality of agricultural-food obviously improves.Denitrogenate phosphorus potassium summation and be outside 38% the special-purpose fertilizer of the present invention, all the other nitrogen phosphorus potassium summations of the present invention are that special-purpose fertile its fertilizer efficiency of 36～48% is also apparently higher than the common composite fertilizer of same N-P-K content.Do not exemplify one by one at this.
Claims (8)
1, serial multi-element chelate composite fertilizer special comprises following component:
(1) contains the mixture or the compound of inorganic nitrogen, phosphorus and potassium;
(2) contain vitriol and other inorganicss of Ca, Mg, S element;
(3) contain Mo, Cu, the inorganic salt of B element and contain Zn, Fe, the inner complex of Mn element.
2, serial multi-element chelate composite fertilizer special according to claim 1 is characterized in that, also comprises:
(4) contain compound or the mixture of part special elements Ti, Si, Al.
3, serial multi-element chelate composite fertilizer special according to claim 1 and 2 is characterized in that being mixed into the following composite fertilizer of content by following component:
(1) contains the mixture or the compound of inorganic nitrogen, phosphorus and potassium; In composite fertilizer, macroelement N, P
2O
5, K
2O content summation is 30-48 weight %.
(2) contain vitriol and other inorganicss of Ca, Mg, S element; In composite fertilizer, moderate-element Ca, Mg, S content summation is 3-20 weight %.
(3) contain Mo, Cu, the inorganic salt of B element and contain Zn, Fe, the inner complex of Mn element; In composite fertilizer, micro-Mo, Cu, B, Zn, Fe, Mn content summation is 0.06-3.00 weight %.
(4) contain one or more inorganics among Ti, Si, the Al; In composite fertilizer, one or more among special elements Ti, Si, the Al, the content summation is at 0-5 weight %.
4, serial multi-element chelate composite fertilizer special according to claim 1 and 2, it is characterized in that the inner complex of described Zn, Fe, Mn is to be processed by one or two or more sequestrant in amino acid, xanthohumic acid, polyamino poly carboxylic acid, hydroxycarboxylic acid, multi-hydroxy carboxy acid, multi-hydroxy multi-carboxy acid, the o-quinone phenol.
5, serial multi-element chelate composite fertilizer special according to claim 3, it is characterized in that the inner complex of described Zn, Fe, Mn is to be processed by one or two kind of sequestrant in amino acid, xanthohumic acid, polyamino poly carboxylic acid, hydroxycarboxylic acid, multi-hydroxy carboxy acid, multi-hydroxy multi-carboxy acid, the o-quinone phenol.
6, the compound method of the arbitrary described serial multi-element chelate composite fertilizer special of claim 1 to 4 comprises the steps:
1) collects the required nutrient of the process of growth of required farm crop of using or plant and to each nutrient absorbing rate;
2) collect the soil fertility of farm crop or plant growing region and the survey soil data of chemical state; According to 1) and 2) data computation go out farm crop or plant nutrient in planted agent's benefit in predetermined vegetative period;
3) result foundation 3) organizes chemical fertilizer raw material, and each component is mixed.
7, the arbitrary described serial multi-element chelate composite fertilizer special of claim 1 to 4 is applied on following farm crop and the plant:
Chinese cabbage, Cauliflower, green pepper, capsicum, lettuce, wild cabbage, eggplant, cucumber, muskmelon, pumpkin, watermelon, asparagus, bamboo shoot bamboo, lichee, longan, loquat, banana, honey peach, Chinese chestnut, chinquapin, mango, grape, oil how, tobacco, tealeaves, eucalyptus, Pinus massoniana Lamb, Chinese fir, slash pine, paulownia, peanut, pachyrhizus, paddy rice, wheat, flowers, lawn etc.
8, the application of the arbitrary serial multi-element chelate composite fertilizer special of claim 1 to 4 on farm crop that are applied to establishing in large scale or plant.
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