CN101456765B - Special compound fertilizer for saline-alkali soil improvement - Google Patents

Special compound fertilizer for saline-alkali soil improvement Download PDF

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CN101456765B
CN101456765B CN2007101792690A CN200710179269A CN101456765B CN 101456765 B CN101456765 B CN 101456765B CN 2007101792690 A CN2007101792690 A CN 2007101792690A CN 200710179269 A CN200710179269 A CN 200710179269A CN 101456765 B CN101456765 B CN 101456765B
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soil
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saline
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宋文亮
周涛
梁锦绣
郭少阳
刘春虎
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Petrochina Co Ltd
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Abstract

The invention relates to a special compound fertilizer for improving saline-alkali soil, which is used for improving saline-alkali soil and growing crops in the saline-alkali soil, and is characterized in that: based on 100kg of ingredients: 15kg of desulfurization residues, 8kg of bentonite, 25kg of monoammonium phosphate, 27kg of urea, 21kg of potassium chloride or potassium sulfate and 4kg of zinc sulfate; can improve organic nutrient components such as medium elements, trace elements, humic acid and the like, improve the quality of crops, increase the storage amount of soil nutrients, improve the effectiveness of nitrogen, phosphorus, potassium and trace elements, play an important role in balancing the soil nutrient resources of saline-alkali soil, update and activate old organic matters, and improve the quality of humic substances, thereby comprehensively improving the soil fertility, reducing the nitrification of ammonia, improving the utilization rate of nitrogen, promoting the absorption of the crops to phosphorus, improving the activity of multiple enzymes such as invertase, protease, amylase and the like in the soil, reducing the environmental pollution, being beneficial to environmental protection, reducing the dosage of chemical fertilizers, and saving the fertilization cost.

Description

Composite fertilizer special for alkaline land improved type
Technical field
The present invention relates to a kind of improvement in salinization arable land and composite fertilizer special for alkaline land improved type of salinization arable land plant growth of being used for.
Background technology
(1) Shandong Province has developed improved fertilizer for hortriculture saline-alkali soil, and this product is organic--and the extraordinary fertilizer of inorganic type compound, 16 kinds of preparation of raw material such as formulating of recipe utilization " sodium ion sorbent material ", " chemical improvement agent ", " improvement of full unit is smart " form.Interior nitrogenous phosphorus potassium 8~10%, pH5.5 utilizes acid-base neutralisation, ionic adsorption, conversion salt chemical principle, reduces soil salt content, potential of hydrogen, improves various salt affected soils, and complete first nutrition is obvious for the fertilizer efficiency fruit, and prevents the flowers and trees yellows.Be applicable to the saline-alkali soil of saltiness below 0.4%, ornamental trees and shrubs, flowers, lawn, potted flower and the fresh cutting flower cultivation of protection ground etc.The Yinchuan City association for science and technology is used for the nursery, Xinjiang, every mu of consumption 100kg, and high growth of nursery stock and leading thread girth growth, comparison is according to increasing 49cm, 0.49cm respectively.Be used for Xinjiang poplar afforestation, the fertile 1kg of improvement is executed in strain, and the surviving rate comparison is according to improving 8.7%, and the shoot growth amount increases 3.7cm.Be used for dragon spruce, arbor-vitae young growth, 1.5kg is executed in strain, and increase 2.9cm and 4.9cm are shone in the high growth of annual comparison respectively.More than the soil pH value 8.0 at three places, use improvement after fertile four months, measure the pH value and be respectively 7.0,6.75,6.25.Emerald green booth village school district, development area, Tianjin uses in the greenery patches surviving rates such as improved fertilizer for hortriculture saline-alkali soil plantation cdear, Chinese rose, lawn and reaches 95%.
(2) China has carried out a large amount of work at the staple crop fertilizer application formula, has formed the general formulation scheme of some staple crops, mainly is record to some extent in " Chinese fertilizer " etc.But because variation has taken place crop varieties, the various places soil nutrient also changes bigger, and some characteristic crops occur after the agricultural restructuring in addition.Nutrient prescription at staple crop still rests on the former understanding in recent years, and does not appear in the newspapers at composite fertilizer's prescription of Wine Grape, matrimony vine, Chinese medicinal materials.Therefore, this project is produced and is managed for composite fertilizer at the staple crop composite fertilizer prescription of the north agriculture main producing region exploitation and all has innovation.
(3) utilize peat and weathered coal improvement saline-alkali soil to have effects such as the soil porosity of raising, reduction pH value, active ions, increase nutrient and enhancing enzyme biologic activity, the root system vigor of rice plant of tillering stage, jointing stage, productive phase obviously improves; Heading stage and go out fringe 2 during week the stem flow stream velocity enlarge markedly; Tiller number during results, full rate, thousand seed weight, plant height, spike length, straw weight, grain weight and the heavy raising that all has in various degree of root.For peat and weathered coal provide scientific basis as the widespread use of alkaline land modifying agent, the agriculture production and the ecological environment treatment of saline-alkali soil there is directive significance.
(4) Daqing Area applies topsoil with a certain amount of humic acid substance (0~20cm) finds for the physico-chemical property of saline-alkali soil positive effect to be arranged, the pH value reduces, total salt quantity reduces, alkalization of soils degree (ESP) descends, soil total alkalinity (HCO3-and CO32-content sum) reduces, soil density descends, and the soil organism increases to some extent.The obvious effect of increasing production of the herbage in this saline-alkali soil district (flower of Stinkgrass) can promote plant nutrient to absorb in addition, and the stimulating plant growth improves resistance.
(5) fertile by the saltings gypsum improvement of Shandong Xin Wen Mining Group cream industry company and Shandong Agricultural University's joint research and development exploitation, this improvement fertilizer is to be main raw material with the gypsum, add multiple high-tech biotechnological formulation, the efficient organic fertilizer that the process special process processes.Follow the tracks of chemical examination through Shandong Agricultural University, the alkalization of soils degree pH value after the improvement obviously reduces, and the soil alkaline matter is neutralized, and soil aggregate is reasonable.And its effective nutrient total amount reaches 10% and 15%, merged all specialities of farm manure, can increase soil fertility, and plant nutrition is provided, and improves crop quality, reduces disease and pest, increases crop yield 30% and 50%.Behind the application test that it's a year are past 6000 mu of saltings back warps, effect obtains the expert fully to be approved, and wins national patent, successfully puts on market at present.
(6) preparation and the application process of the two component alkaline land modifying agents in Quanzhou City, Fujian Province.The present invention utilizes material preparations such as brown sugar, black Other-of, light-coloured vinegar, ammonium nitrate, wheat bran, soya-bean cake, gelatine, brown coal to contain two component alkaline land modifying agents of solution and residue, makes modifying agent directly act on depth of soils, root system of plant position.Using this modifying agent can increase organism in the soil greatly, improve water retention capacity, improve the physicochemical property of soil and activate organophosphorus in the soil, the growth of plant is had promoter action, is a kind of Perfected process of administering the saltings.
Summary of the invention
The objective of the invention is to utilize flue gas desulfurization waste as carrier, add conventional additives and inorganic fertilizer, increase the content of flue gas desulfurization waste humic acid, adopt rational nutrient prescription at different soils and Different Crop, guarantee the composite fertilizer special for alkaline land improved type of the fair supply of N, P, K three elements proportioning and an amount of trace element.
The solution of the present invention is: composite fertilizer special for alkaline land improved type nitrogen phosphoris and potassium fertilizer ratio: N: P: k=15: 10: 10
With 100kg proportion meter: desulfurization slag 15kg, wilkinite 8kg, monoammonium phosphate 25kg, urea 27kg, Repone K or vitriolate of tartar 21kg, zinc sulfate 4kg.
Take tower granulation and quick-drying method, the stable and effect of enhanced granule intensity, assurance humic acid.It is big that its compound fertilizer granules has density, is convenient to long-distance transport and mechanized; Good water absorption easily decomposes in soil; Safety, long, quick-acting one, characteristics such as fertilizer efficiency height.
Table 1 multi-element biologic organic fertilizer quality index
Figure DEST_PATH_GSB00000264795100011
The saltings compound fertilizer special is made the high-quality compound manure with desulfurization slag as main carrier, can produce the material that humic acid etc. stimulates plant growth, has improved the utilization ratio of phosphorus potassium resource.With the eubiosis and microecology is theoretical basis, and this three is organically combined, and interacts, connects each other, becomes an organic unity body with multi-function action.And, by the reasonable raw material prescription with take advanced technology and technology, and assurance product quality management and gordian technique equipment, formed the leading technology of a whole set of advanced production biologic organic, inorganic composite fertilizer, make this product have following characteristics: the nutritive ingredient of (1) humic acid: saltings composite fertilizer also can provide organotrophy compositions such as a considerable amount of middle amounts, trace element and humic acid except that containing N, P, K and organic nutrient.(2) can improve the product quality of crop: fertilizer can produce desirable influence to its product quality by improving plant nutrition and growth conditions.(3) to the influence of soil nutrient resource and nutrient balance: use fertilizer can increase soil system nutrient reserves, improve the validity of nitrogen, phosphorus, potassium and trace element, especially the balance for alkaline land soil nutrient resource has vital role.(4) to the influence of the soil organism and structure: use the saltings by forming organic mineral complex and micelle
Aggressiveness had both improved the quantity of the soil organism, upgraded again and had activated old organic matter, improved the soil ulmin quality, thereby increase soil fertility comprehensively.(5) organic-inorganic is in conjunction with improving chemical fertilizer utilization ratio: humic acid and chemical fertilizer compounding application can reduce the redox potential of soil, and minimizing nitrated can be improved the utilization ratio of nitrogen.Chemical phosphatic ferfilizer and fertilizer are joined and are executed, and can increase the solubleness of phosphorus, improve the activity of calcium phosphate in the soil, promote the absorption of crop to phosphorus.(6) to the influence of soil enzyme activities: use the activity that fertilizer dedicated to alkaline land can improve plurality of enzymes such as saccharase in the soil, proteolytic enzyme, amylase, therefore with soil in the conversion, the raising and the energy metabolism of validity of nutrient confidential relation is all arranged.(7) reduced environmental pollution: there is not problem of environmental pollution basically in the production process of fertilizer dedicated to alkaline land, and to a certain extent still to the utilization again of organic waste, helps environment protection.(8) lowered cost: compare with producing chemical fertilizer, fertilizer dedicated to alkaline land makes full use of certain specific character of desulfurization slag, and available nutrient is purpose in the soil to increase, and can reduce the consumption of chemical fertilizer, thereby save the fertilising cost.
Embodiment
Embodiment 1
With 100kg proportion meter: desulfurization slag 15kg, wilkinite 8kg, monoammonium phosphate 25kg, urea 27kg, Repone K or vitriolate of tartar 21kg, zinc sulfate 4kg.
The Wine Grape test
In the field, gardens, two test bases of Yuquan battalion arrange test.The contrast design is adopted in test, establishes 6 processing altogether, i.e. (1) space management (not applying fertilizer), (2) urea (40kg/ mu), (4) saltings fertilizer (80kg/ mu), (4) saltings fertilizer (95kg/ mu), (5) saltings fertilizer (65kg/ mu), (6) special-purpose fertile (80kg/ mu); Three repetitions are established in each processing, and the experimental plot area is 20 * 3m 2, total area 1080m experimental field 2Rate of fertilizer application (calculating by mu) adopts design equidistantly, and fertilising applies at twice, and trench digging 30cm row replacement is in time poured water after executing.Each sub-district is except that test fertilizer difference, and other agronomic measures is all consistent with field management.Arrange 5 mu of model fields at adjacent field piece experimental field, execute 45% (15-15-15) " Ninghua " composite fertilizer 80kg for every mu, altogether need be with 45% (15-15-15) " Ninghua " composite fertilizer 870kg.The result shows: handling that 6. sugar is the highest, reach 19.81, secondly is to handle 3., reaches 19.75, handle 1. minimum, 19.2.Sugar degree be in proper order S 6.>S 3.>S 4.>S 5.>S 2.>S 1., the use of saltings fertilizer is described, sugar degree to Wine Grape is significantly improved, and according to the test gained, in 20kg on probation~80kg scope, along with the increase of the usage quantity of saltings fertilizer, the sugar degree of Wine Grape also increases gradually.It is the heaviest to handle 6. single fringe, reaches the 99.06g/ fringe, handles 4. secondly, reaches the 99g/ fringe, handle 1. minimum, 86.58g/ fringe only.It is followed successively by in proper order S 6.>S 4.>S 3.>S 5.>S 2.>S 1..Handle that 4. 100-grain weight is the heaviest, reach 125.5g, handle 3. secondly, reach 120.1g, handle 1. minimum, 107.2g only.It is followed successively by in proper order S 4.>S 3.>S 5.>S 6.>S 2.>S 1..Handle that 6. output is the highest, reach 1193.65kg/ mu, handle 3. secondly, reach 1182.15kg/ mu, handle 1. minimum, 970.91kg/ mu.Each output of handling all between 1000~1200kg, its be followed successively by in proper order S 6.>S 3.>S 5.>S 4.>S 2.>S 1..
Field, gardens Wine Grape questionnaire
Figure 2007101792690A00800051
Carry out because the test of the composite fertilizer of Florian and Hui Bin mainly is arranged in the Wine Grape seedling garden of life in 2 years, therefore, indexs such as fringe weight, output can't normally be measured.From the pol situation that records, 4. sugar is the highest to represent the refined processing of favour of aeolian sandy soil type, reaches 23.55, secondly is to handle 6., reaches 23.53, handle 1. minimum, 22.31.Sugar degree be in proper order S 4.>S 6.>S 3.>S 5.>S 2.>S 1., the use of saltings fertilizer is described, the Wine Grape sugar degree is significantly improved.And represent in the Florian of grey desert soil type, handle 6. that sugar is the highest, reach 20.07, secondly be to handle 4., reach 19.96, handle 1. minimum, 18.33.Sugar degree be in proper order S 6.>S 4.>S 3.>S 5.>S 2.>S 1., the use of saltings fertilizer is described too, the Wine Grape sugar degree is significantly improved, but simultaneously, illustrates that also the nitrogen phosphorus potassium proportioning that regional Wine Grape is used composite fertilizer at the foot of a hill or mountain, Shandong, Helan should suitably strengthen the nitrogen amount.
The Wine Grape questionnaire
Figure 2007101792690A00800061
The soil organism and available nutrient of soil content be the more important thing is with fertilising and crop to be absorbed with much relations except the physico-chemical property that is subjected to soil self and natural cause etc. influence.Using the content that saltings fertilizer can improve the soil available potassium fast, find that also saltings fertilizer cooperates urea to use back soil quick-acting potassium content and increases a little less than using separately, mainly is because the increase of cooperation urea ensuing crop output has strengthened the consumption to the potassium element.Illustrate that the foot of a hill or mountain, Shandong, Helan area Wine Grape uses in the nitrogen phosphorus potassium proportioning of composite fertilizer, the effect of nitrogen amount is bigger.
Embodiment 2
Use composite fertilizer's matrimony vine test of the proportioning preparation of embodiment 1
Test arrangement the field, gardens, in peaceful two test bases.The contrast design is adopted in test, establishes 6 processing altogether, i.e. (1) space management (not applying fertilizer), (2) saltings fertilizer (170kg/ mu), (3) saltings fertilizer (200kg/ mu), (4) saltings fertilizer (230kg/ mu), (5) urea (40kg/ mu), (6) special-purpose fertile (80kg/ mu); Three repetitions are established in each processing, and the experimental plot area is 10 * 3m 2, total area 540m experimental field 2, rate of fertilizer application (by mu calculating) adopts design equidistantly, fertilising to divide and applies for three times, in time pours water after executing.Each sub-district is except that test fertilizer difference, and other agronomic measures is all consistent with field management.Arrange 5 mu of model fields at adjacent field piece experimental field, execute 45% (15-15-15) " Ninghua " composite fertilizer 100kg for every mu, altogether need be with 45% (15-15-15) " Ninghua " composite fertilizer 1030kg.
Fertile test back, saltings output situation is carried out as can be seen in therefrom peaceful matrimony vine field, and testing between each processing all has significant difference, and the significance level assay is as table.Find that simultaneously the output of handling 6. is best, its value reaches 1009.49kg; Next is to handle 3., also reaches 1005.14kg, and it is little that all the other handle differences, its be followed successively by in proper order S 6.>S 3.>S 5.>S 4.>S 2.>S 1., the output of each processing has improved 16.4%~31.2% compared with the control.Though it is little but effect is pretty good relatively to handle 6. the amount of executing, explanation in the nitrogen phosphorus potassium proportioning of " Ninghua " composite fertilizer of peaceful area 45% (15-15-15) should suitably strengthen the nitrogen amount, have only nitrogen phosphorus potassium and trace element to join and execute rationally, could constantly increase the nutrient in the soil, for good envrionment conditions is created in the matrimony vine growth, make the matrimony vine well-grown, spend many, fruit is big, output is high, product are of fine quality, obtains high economic benefit.
Fertile testing program of medlar in alkaline land and output (kg)
Figure 2007101792690A00800071
In in the peaceful matrimony vine test, the matrimony vine biological character of fertile each different treatment in saltings has notable difference.The matrimony vine of each different treatment as a result indexs such as branch number, fruit-setting rate, dry fruit 100-grain weight each is variant.It is all better to handle fruit-setting rate 4., hundred dry weights etc.Matrimony vine growth is that high investment, high production, year vegetative period are long, from mid-March to early November, the experience bud differentiation, shoot and leaf growth, yield positive results, important growth and development process such as root growth, the nutrient of its needs is many, the confession long fertilizers period, if the supply of nutrient proportioning is uneven, will make the branch of New Development short, a little less than, bud differentiation is affected, and spends number few, and fruit drop is serious, fruit is little, also influence the photosynthesis of root growth and blade, not only annual production is worked as in influence, but also directly recuperate branch accumulation and 1 year growth result are set in influence.The rational application of fertilizer, nitrogen phosphorus potassium and micro-reasonable disposition constantly increase the nutrient in the soil, are that the matrimony vine growth creates good envrionment conditions, make its well-grown, spend many, fruit greatly, output is high, product are of fine quality, obtains high economic benefit.In peaceful regional many thatches farmings blindly strengthen the nitrogen phosphorus fertilizer amount of application, not only cost increases, and does not also obtain high yield, fruit is little, pulp is thin, quality also descends.
Matrimony vine biological character questionnaire
Figure 2007101792690A00800072
The soil organism and available nutrient of soil content be the more important thing is with fertilising and crop to be absorbed with much relations except the physico-chemical property that is subjected to soil self and natural cause etc. influence.Use the content that saltings fertilizer can improve the soil available potassium fast, the soil available potassium increases by 11.9%, 19.1% and 29.2% than primitive soil respectively after using saltings fertile 170kg, 200kg and 230kg/ mu, the soil quick-acting potassium content increases lower slightly also to find to handle 5., increasing by 8.5% than primitive soil soil available potassium, mainly is because nitrogen promotes plant growth to strengthen the consumption to the potassium element.Soil available potassium increasing degree is less after rather using saltings fertilizer in relatively finding with field, gardens soil, mainly be since in peaceful matrimony vine production peasant household recognized progressively that potash fertilizer is to matrimony vine output, especially the effect on quality improving has progressively increased the consumption of potash fertilizer, and soil potassium content more several years ago is significantly improved.The full potassium content of soil changes little when also finding not use saltings fertilizer, mainly be since in rather belong to anthropogenic-alluvial soil soil, the full potassium of soil can be converted into available potassium rapidly and the balance of additional potassium element, full potassium content is significantly improved after using saltings fertilizer, mainly be because soil preservation nutrient ability is strong, and can transform to the slow nutrient rapidly.But the soil quick-acting potassium content obviously descends after using the fertilizer of nitrogenous, phosphorus, but full potassium content fall is little.And application of potash fertilizer can reduce the content of quick-acting nitrogen in the soil separately, mainly is the output that can improve crop after potash fertilizer is used, and has strengthened the absorption to the quick-acting nitrogen of soil.And separately organic matter descends to some extent behind the application of potash fertilizer, mainly is owing to increase the mineralising utilization to organic matter behind the application of potash fertilizer, but potash fertilizer and nitrogen, phosphate fertilizer compounding application can obviously improve the nutrient resource situation of soil.
In peaceful available nutrient of soil analytical results (mg/kg) table
Figure 2007101792690A00800082

Claims (1)

1. a composite fertilizer special for alkaline land improved type is characterized in that: with 100kg proportion meter: desulfurization slag 15kg, wilkinite 8kg, monoammonium phosphate 25kg, urea 27kg, Repone K or vitriolate of tartar 21kg, zinc sulfate 4kg.
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Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101993312A (en) * 2009-08-24 2011-03-30 中国石油天然气股份有限公司 Resource utilization of coal-fired flue gas desulfurization waste
CN102219614B (en) * 2011-04-12 2013-04-03 天津海林园艺环保科技工程有限公司 Biological improving fertilizer special for saline-alkali soil and preparation method thereof
CN102701855B (en) * 2012-06-13 2014-04-16 方宁 humic acid Fertilizer produced by using coal special for improving saline-alkali soil
CN104250176B (en) * 2013-06-28 2016-08-10 中国石油天然气股份有限公司 Method for improving sand blown soil by using multi-element compound fertilizer
CN115417710A (en) * 2016-07-01 2022-12-02 青岛合子肥生物科技有限公司 Organic-inorganic polymerization water-retention fertilizer and preparation method and application thereof
CN114916299A (en) * 2022-05-19 2022-08-19 攀枝花学院 Soil biochemical fertilization method

Citations (3)

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Publication number Priority date Publication date Assignee Title
CN1233606A (en) * 1998-04-25 1999-11-03 中国科学院新疆生态与地理研究所 Soil fertility amendment
CN1440956A (en) * 2003-02-26 2003-09-10 徐德芳 Nitrogen fertilizer specially for green rice in sline-alkaline land
CN1948429A (en) * 2006-11-01 2007-04-18 宁夏大学 Nutritive soil improver special for salt alkali land and its processing method

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1233606A (en) * 1998-04-25 1999-11-03 中国科学院新疆生态与地理研究所 Soil fertility amendment
CN1440956A (en) * 2003-02-26 2003-09-10 徐德芳 Nitrogen fertilizer specially for green rice in sline-alkaline land
CN1948429A (en) * 2006-11-01 2007-04-18 宁夏大学 Nutritive soil improver special for salt alkali land and its processing method

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