CN101993312A - Resource utilization of coal-fired flue gas desulfurization waste - Google Patents
Resource utilization of coal-fired flue gas desulfurization waste Download PDFInfo
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- CN101993312A CN101993312A CN2009100917344A CN200910091734A CN101993312A CN 101993312 A CN101993312 A CN 101993312A CN 2009100917344 A CN2009100917344 A CN 2009100917344A CN 200910091734 A CN200910091734 A CN 200910091734A CN 101993312 A CN101993312 A CN 101993312A
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- Prior art keywords
- saline
- soil
- coal
- desulfurization waste
- alkali
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- 239000002699 waste material Substances 0.000 title claims abstract description 31
- 238000006477 desulfuration reaction Methods 0.000 title claims abstract description 28
- 230000023556 desulfurization Effects 0.000 title claims abstract description 28
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 title claims abstract description 15
- 239000003546 flue gas Substances 0.000 title claims abstract description 15
- 239000003245 coal Substances 0.000 claims abstract description 30
- 230000006872 improvement Effects 0.000 claims abstract description 10
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 7
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 claims abstract description 7
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000004202 carbamide Substances 0.000 claims abstract description 7
- 235000019837 monoammonium phosphate Nutrition 0.000 claims abstract description 7
- 239000006012 monoammonium phosphate Substances 0.000 claims abstract description 7
- 239000000203 mixture Substances 0.000 claims abstract description 3
- 208000006558 Dental Calculus Diseases 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 4
- 210000003608 fece Anatomy 0.000 claims description 2
- 239000010871 livestock manure Substances 0.000 claims description 2
- 239000002689 soil Substances 0.000 abstract description 41
- 239000003337 fertilizer Substances 0.000 abstract description 25
- 150000003839 salts Chemical class 0.000 abstract description 13
- 239000003513 alkali Substances 0.000 abstract description 12
- 230000001976 improved effect Effects 0.000 abstract description 9
- 230000000694 effects Effects 0.000 abstract description 8
- 230000035558 fertility Effects 0.000 abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 3
- 239000005416 organic matter Substances 0.000 abstract description 2
- 239000000440 bentonite Substances 0.000 abstract 1
- 229910000278 bentonite Inorganic materials 0.000 abstract 1
- 230000035699 permeability Effects 0.000 abstract 1
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 abstract 1
- 229910052939 potassium sulfate Inorganic materials 0.000 abstract 1
- 235000011151 potassium sulphates Nutrition 0.000 abstract 1
- 238000009423 ventilation Methods 0.000 abstract 1
- 238000009938 salting Methods 0.000 description 13
- 235000015097 nutrients Nutrition 0.000 description 7
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 description 6
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 6
- 239000004021 humic acid Substances 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 229910052698 phosphorus Inorganic materials 0.000 description 6
- 239000002994 raw material Substances 0.000 description 6
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 5
- 239000011575 calcium Substances 0.000 description 5
- 229910052791 calcium Inorganic materials 0.000 description 5
- 239000002131 composite material Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 4
- 239000005864 Sulphur Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000010440 gypsum Substances 0.000 description 4
- 229910052602 gypsum Inorganic materials 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- 239000013543 active substance Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000011785 micronutrient Substances 0.000 description 3
- 235000013369 micronutrients Nutrition 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 230000004069 differentiation Effects 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 230000001863 plant nutrition Effects 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 239000002688 soil aggregate Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 235000021232 nutrient availability Nutrition 0.000 description 1
- 235000021049 nutrient content Nutrition 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 239000003895 organic fertilizer Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000002681 soil colloid Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
Landscapes
- Fertilizers (AREA)
Abstract
The invention relates to resource application of coal-fired flue gas desulfurization waste in saline-alkali farmland improvement and crop growth fertilizer of the saline-alkali farmland; a fertilizer for improving the saline-alkali soil and growing crops in the saline-alkali soil; the composition is prepared and used according to the following components in percentage by weight: monoammonium phosphate, measured at 1000 Kg: 208Kg, differentiated coal: 50Kg, urea: 435Kg, potassium sulfate: 100Kg, bentonite: 157Kg and coal fired flue gas desulfurization waste: 50 Kg; the special fertilizer for applying the saline-alkali soil into the plough layer (0-20 cm) has an obvious effect on the physicochemical properties of the saline-alkali soil, the pH value is reduced, the total salt content is reduced, the soil alkalization degree (ESP) is reduced, the organic matter of the soil is increased, the ventilation and water permeability of the saline-alkali soil are improved, the hardened structure of the saline-alkali soil is improved, the soil fertility is improved, and the yield and the quality of crops planted in the saline-alkali soil can be improved.
Description
Technical field
The present invention relates to the resource utilization of a kind of flue gas desulfurization waste of fire coal in improvement and salinization arable land crop growth fertilizer are ploughed in salinization uses.
Background technology
The domestic different methods research manufacturing fertilizer dedicated to alkaline land material of taking, the saltings gypsum improvement that Shandong Agricultural University and cartel are developed is fertile to be main raw material with the gypsum, add multiple high-tech biotechnological formulation, alkalization of soils degree after the improvement, pH value obviously reduce, soil aggregate is reasonable, and plant nutrition can be provided, improve crop quality.Some area is main raw material with the gypsum, add the high-quality organic matter,, make the scientific and reasonable ratio proportioning of gypsum and organic raw material by adopting the biological organic fertilizer technology of present comparative maturity, again through high-quality, preferably, bacteria agent fermentation efficiently, it is special-purpose fertile to form soil improvement.Some areas as carrier, produce compound fertilizer special with humic acid material, for the physico-chemical property of saline-alkali soil effect are significantly arranged.The Heilongjiang Province develops a kind of Soline alkali resisting rice fertilizer, and this special use fertilizer mainly contains the effective ingredient of following weight proportion: nitrogen 10%-28%, phosphorus 5%-10%, potassium 5%-10%, sulphur 10%-25%, amino acid/11 %-5%, humic acid 1%-10%, middle micro-0%-5%.To add clay in the above-mentioned raw materials as carrier, granulation makes behind the mechanical mixing.Some area neutralizes with the alkalescence in saltings mutually with the acidity of fertilizer itself, or changes the inflexible structure in saltings with active substance, to reach the unusual effect of administering the saltings.But as the alkaline land improving active substance, development is applicable to that the compound manure prescription in saltings and production technique thereof do not see that as yet report is arranged with flue gas desulfurization waste of fire coal.
Summary of the invention
The purpose of this invention is to provide a kind of saltings composite fertilizer special that contains the desulfurization waste, a kind of improvement in salinization arable land and fertilizer of salinization arable land crop growth of being used for.By this approach, make that flue gas desulfurization waste of fire coal obtains reasonable use in the production of synthetic ammonia, solve the recycling problem of desulfurization waste.
This saltings composite fertilizer special is formulated by weight proportion by following ingredients: A: urea soln B: monoammonium phosphate C: vitriolate of tartar D: flue gas desulfurization waste of fire coal E: differentiation coal F: wilkinite.The specific complex fertilizer formula: by 1000Kg, monoammonium phosphate: 208Kg breaks up coal: 50Kg urea: the 435Kg vitriolate of tartar: the 100Kg wilkinite: 157Kg flue gas desulfurization waste of fire coal: 50Kg.
In the above-mentioned raw materials with monoammonium phosphate as chemically acid fertilizer, with vitriolate of tartar as physiological acidic fertilizer, with flue gas desulfurization waste of fire coal and humatite weathered coal as the alkaline land improving active substance,, make as the nutrient carrier with inorganic mineral wilkinite and humatite weathered coal with urea soln whitewashing rotary drum prilling process technology.
The desulfurization waste has the function and the effect in improvement saltings, has the function of regulating soil pH value, the structure of improving the soil, improving plant recovery of nutrient, can provide micronutrient element in sulphur, calcium, the silicon etc. for farm crop simultaneously.Utilize the desulfurization waste to produce fertilizer dedicated to alkaline land, can turn waste into wealth, resource is fully used, environment improves and purify.By in composite fertilizer, adding the desulfurization waste, improve the ventilating permeable of salt affected soil, improve the salt affected soil fertility level.The saltings compound fertilizer special is by the reasonable raw material prescription and take advanced Technology, has following advantage and characteristics:
1, the recycling of waste: Ningxia autonomous region and neighbouring province Inner Mongolia Autonomous Region thereof have abundant weathered coal resource, utilize flue gas desulfurization waste of fire coal and depleted weathered coal resource to produce the fertilizer dedicated to alkaline land material, can turn waste into wealth, resource rationally be utilized, environment improves and purify.
2, organic-inorganic combines: the desulfurization waste has the function and the effect of improvement alkaline soil, its principle is that calcium sulfate contained in the desulfurization waste is with the sodium particle in the calcium particle displacement soil colloid, the sodium particle of replacing is with pouring water or rainwater is got rid of, thereby reduced salt affected soil pH value and basicity; The humatite weathered coal is rich in humic acid, can eliminate the toxic action of salt, fertilizing soil.Humic acid is a weak organic acid, can form a buffering system with salt, has the function of adjusting and stable soil pH value.Desulfurization waste and weathered coal compounding application can be got rid of saline and alkaline, can improve the soil effectively again physicochemical property, fertilizing soil all have improved effect for alkaline earth and solonchak, and the two compounding application is better than using the salt affected soil improved effect separately.
3, to the influence of Soil structure: the salt affected soil structure deteriorate, ventilating permeable is poor, physical property deterioration.The contained calcareous nutriment of desulfurization waste has vital role in soil structure improved addictive, breaking up humic acid contained in the coal simultaneously can increase the content of the soil organism, improve the soil water-reataining fertilizer-keeping ability, help the formation of soil aggregate, the two combination of weathered coal and desulfurization waste is used, for the structure of improving salt affected soil and ventilating permeable better effects if.
4, improve nutrient availability: the humatite weathered coal can promote the activity of soil microorganisms, improve the activity of soil plurality of enzymes and the validity of phosphorus element, can also increase the solvability of calcium sulfate in the soil solution in the desulfurization waste, promote the exchange of sodium particle in calcium particle and the alkaline soil, help crop nutrient absorbing utilizations such as phosphorus, sulphur, calcium.
5, improve crop yield, improve the quality of agricultural-food: this saltings composite fertilizer is except that containing N, P, K plant nutrition three elements, simultaneously contained desulfurization waste can provide micronutrient element in sulphur, calcium, the silicon etc. for crop, contained weathered coal can provide a considerable amount of middle amounts, micronutrient element, can improve the salt affected soil fertility level comprehensively, thereby the quality of crop yield and agricultural-food is produced desirable influence.
6, improved the slow-releasing and the utilization ratio of fertilizer product nutrient: the main component calcium sulfate in the desulfurization waste is slightly soluble in water, can increase the granule strength of product, slow down the disintegration rate of product particle, the contained adsorbable guarantor of humic acid of weathered coal holds multiple nutrient simultaneously, prevent nutrient loss such as nitrogen, the plant recovery of nutrient of fertilizer product is improved.
Using fertilizer dedicated to alkaline land applies topsoil (0～20cm) physico-chemical property for saline-alkali soil has positive effect, the pH value reduces, total salt quantity reduces, alkalization of soils degree (ESP) descends, the soil organism increases to some extent, improves the ventilating permeable of salt affected soil, the improvement salt affected soil structure that hardens, increase soil fertility, can improve the yield and quality of saltings kind plant.
Embodiment
A: urea soln (containing N 46%) B: monoammonium phosphate (contains N 10%, P
2O
548%) C: vitriolate of tartar (contains K
2O 50%) D: flue gas desulfurization waste of fire coal E: weathered coal F: wilkinite.
Saltings composite fertilizer special total nutrient content 35% (contains N 20%, P
2O
510%, K
2O 5%);
Saltings specific complex fertilizer formula: by 1000Kg, monoammonium phosphate: 208Kg, differentiation coal: 50Kg, urea: 435Kg, vitriolate of tartar: 100Kg, wilkinite: 157Kg and flue gas desulfurization waste of fire coal: 50Kg.
Claims (1)
1. a flue gas desulfurization waste of fire coal resource utilization is used, and it is characterized in that: be used for the improvement in salinization arable land and the compound manure of salinization arable land crop growth; Use by following composition and part by weight preparation: by 1000Kg, monoammonium phosphate: 208Kg, weathered coal: 50Kg, urea: 435Kg, vitriolate of tartar: 100Kg, wilkinite: 157Kg and flue gas desulfurization waste of fire coal: 50Kg.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100917344A CN101993312A (en) | 2009-08-24 | 2009-08-24 | Resource utilization of coal-fired flue gas desulfurization waste |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100917344A CN101993312A (en) | 2009-08-24 | 2009-08-24 | Resource utilization of coal-fired flue gas desulfurization waste |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101993312A true CN101993312A (en) | 2011-03-30 |
Family
ID=43784137
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2009100917344A Pending CN101993312A (en) | 2009-08-24 | 2009-08-24 | Resource utilization of coal-fired flue gas desulfurization waste |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101993312A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102674950A (en) * | 2012-04-16 | 2012-09-19 | 江苏稼宝肥业有限公司 | Formula and preparation method of slow release fertilizer special for coastal wetlands |
| CN103283338A (en) * | 2013-07-03 | 2013-09-11 | 张维 | Method for planting paddy rice on saline-alkali soil |
| CN104250176A (en) * | 2013-06-28 | 2014-12-31 | 中国石油天然气股份有限公司 | Method for improving sand blown soil by using multi-element compound fertilizer |
| CN106187594A (en) * | 2016-07-12 | 2016-12-07 | 山东胜伟园林科技有限公司 | A kind of based on gardens desulfurated plaster changing alkali and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5874781A (en) * | 1982-10-04 | 1983-05-06 | Mitsubishi Chem Ind Ltd | Soil conditioner |
| CN101456765A (en) * | 2007-12-12 | 2009-06-17 | 中国石油天然气股份有限公司 | Special compound fertilizer for saline-alkali soil improvement |
| CN101503327A (en) * | 2009-03-03 | 2009-08-12 | 宁夏大学 | Special improver for alkaline soil alkalinity reducing salt-restricting sunflower and method of processing the same |
-
2009
- 2009-08-24 CN CN2009100917344A patent/CN101993312A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5874781A (en) * | 1982-10-04 | 1983-05-06 | Mitsubishi Chem Ind Ltd | Soil conditioner |
| CN101456765A (en) * | 2007-12-12 | 2009-06-17 | 中国石油天然气股份有限公司 | Special compound fertilizer for saline-alkali soil improvement |
| CN101503327A (en) * | 2009-03-03 | 2009-08-12 | 宁夏大学 | Special improver for alkaline soil alkalinity reducing salt-restricting sunflower and method of processing the same |
Non-Patent Citations (1)
| Title |
|---|
| 陈欢等: ""烟气脱硫废弃物在碱化土壤改良中的应用及效果"", 《干旱地区农业研究》 * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102674950A (en) * | 2012-04-16 | 2012-09-19 | 江苏稼宝肥业有限公司 | Formula and preparation method of slow release fertilizer special for coastal wetlands |
| CN104250176A (en) * | 2013-06-28 | 2014-12-31 | 中国石油天然气股份有限公司 | Method for improving sand blown soil by using multi-element compound fertilizer |
| CN104250176B (en) * | 2013-06-28 | 2016-08-10 | 中国石油天然气股份有限公司 | Method for improving sand blown soil by using multi-element compound fertilizer |
| CN103283338A (en) * | 2013-07-03 | 2013-09-11 | 张维 | Method for planting paddy rice on saline-alkali soil |
| CN103283338B (en) * | 2013-07-03 | 2016-08-24 | 张维 | A kind of method of salt-soda soil rice cultivation |
| CN106187594A (en) * | 2016-07-12 | 2016-12-07 | 山东胜伟园林科技有限公司 | A kind of based on gardens desulfurated plaster changing alkali and preparation method thereof |
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Application publication date: 20110330 |