CN1487991A - 地板清洁剂和光泽增强剂 - Google Patents
地板清洁剂和光泽增强剂 Download PDFInfo
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
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Abstract
一种用来清洁和提高地板光泽的组合物，其中增塑剂能够清洁和提高地板涂层的光泽。在优选实施方案中，增塑剂是磷酸三(丁氧基乙酯)。
Description
本发明的技术领域
本发明涉及用来清洁和提高地板光泽的组合物。更具体地说，它涉及提供改善的清洁和提高光泽特性的上述类型的组合物。
本发明的现有技术
在现有技术中已知的是使用诸如聚丙烯酸酯聚合物、蜡、表面活性剂、溶剂和增塑剂之类的各种不同的组分来提高光泽和在某些情况下清洁地板。
美国专利第4,747,880号揭示一种用来清洁和擦亮地板的地板养护产品。它包括诸如碳酸钠之类与诸如苯乙烯-丙烯酸共聚物之类作为成膜剂的碱溶性聚合物或树脂混合的碱性增效剂。在美国专利第4,230,605号中，揭示了一种清洁地板的组合物，该组合物包括由甲基丙烯酸甲酯、丙烯酸丁酯和丙烯酸组成的三聚物和包括二乙醇胺的表面活性剂。美国专利第4,861,518号揭示一种不成膜的地板清洁剂，它包括含单乙醇胺或乙二醇一丁基醚和聚乙二醇的非离子型表面活性剂。美国专利第5,342,551号揭示一种利用乙二醇醚作为溶剂和柠檬酸单乙醇胺的地板涂复层清除剂(floor finish remover)。
现有技术不提供用来清洁和提高地板光泽的组合物，其中增塑剂与其它成分一起发挥作用，以便提高光泽并且在先前已经涂上或尚未涂上一层传统的地板涂复层的地面砖上产生意想不到的清洁效果。
所以，本发明的目的是：
(a)提供一种改进的用来清洁和提高地板光泽的组合物；
(b)提供一种用来清洁和提高地板光泽的组合物，该组合物导致更好地清洁事先已经涂上或尚未涂上一层传统的地板涂复层的地面砖，和额外地增强光泽。
(c)提供一种能对地板提供改善的维护的上述类型的组合物。
(d)提供一种能保持光泽的上述类型的组合物。
(e)提供一种容易配制成不同的浓度并且容易稀释从而导致成本降低的上述类型的组合物。
(f)提供一种能消除对地板涂复层或基体的有害影响的上述类型的组合物。
本发明的这些和另外一些目的和优势从下面的描述将变得明显。在下面的详细描述中，本发明的优选实施方案将根据本发明的整个范围予以描述。然而，本发明可以被用在其它的实施方案中。
本发明的概述
借助这项发明的能够清洁地板和提高地板光泽的组合物，现有技术的缺点被克服，上述的目的得以实现。在一个实施方案中，组合物包括按重量计0.1-30％的乙二醇溶剂、0.1-30％的能清洁和提高地板涂层光泽的增塑剂、0.1-30％的非离子型表面活性剂、胺和非必选的水。
在另一个实施方案中，增塑剂是磷酸三(丁氧基乙酯)，而乙二醇溶剂是二甘醇一乙基醚。
在优选实施方案中，乙二醇溶剂是二甘醇一丁基醚。
在第三个实施方案中，非离子型表面活性剂是有1到10摩尔乙氧基的C8-C15烃，而胺是二乙醇胺。
在第四个实施方案中，包括有C8-C20烃链的氨基化合物，而且氨基化合物是也被称为古柯酰胺二乙醇胺的油酸二乙醇胺酰胺。
在第五个实施方案中，包括高熔点氧化的聚乙烯蜡。
在第六个实施方案中，组合物包括三乙酸化乙二胺以及着色剂和芳香剂。
优选实施方案的描述
下面的表1在实施例1中举例说明这项发明的优选配方之一以及在实施例2-7中已被用来相对清洁方案验证实施例1的配方的其它相关的配方。本质上大量的清洁剂将涂到干净的白色乙烯基复合砖(“VCT”)——一种有6个涂层、每个涂层0.0003-0.0005英寸厚、并且允许每个涂层干燥1小时的复合砖上。这些砖被干涂的或悬浮在水混合物中的细石墨弄脏。然后，这些配方被稀释，而这些砖瓦通过用稀释溶液覆盖得到清洗。红色垫子与Gardner洗刷器试验装置一起使用，以模拟清洁过程。其它的垫子也可以被使用，包括刷子和海绵。在清洁之前和之后，都用MinoltaCR200色度计读取反射率读数。这台仪器能够发现颜色的细微变化，而且在这种情况下从白色到黑色/灰色。
表1中的配方从实施例3中的碱性清洁剂变化到诸如在实施例5、6、7中举例说明的那些在市场上买得到的一些维护剂。在北美和欧洲使用的实施例2和4也被包括在内。实施例2的产品有许多能在实施例1的产品中找到的相同组分，其主要差别是不包含磷酸三(丁氧基乙酯)(商品名KP-140)。实施例3的清洁剂是用于清洁磨光的和未磨光的地板的标准清洁剂的例子。它由溶剂、表面活性剂和胺/氨组成。实施例4的产品是不仅包含表面活性剂而且包含丙烯酸酯聚合物和高熔点的聚乙烯蜡的传统的地板维护剂。实施例5的产品是不包含磷酸三(丁氧基乙酯)(“KP-140”)但确实作为增塑剂的维护剂的例子。实施例6和7的其它产品展示维护剂的一般类别和它们的清洁性能。当这些产品有多种稀释用途的时候，各种不同的稀释从1∶8延伸到1∶128。只有实施例1和2的产品是具有能够超出传统的稀释范围被稀释并且仍然展现清洁作用的能力的超级浓缩物。
实施例1的产品表现出超过在提高光泽方面有其它的主要利益而且仍然不侵蚀涂层的传统的碱性清洁剂和中性清洁剂的清洁性能。
实施例1的产品是通过边搅拌边将乙二醇醚引入适当的容器制备的。在添加KP-140、Tergitol 15-S-9之后添加古柯酰胺二乙醇胺(the cocamide diethanolamine)。随后，依次添加水、EDTA、芳香剂和染料。相似的程序可以在制备实施例2-14的产品中使用。
在表1中，在例子5和6中所用的X′表示某种组分被包含在它们的配方里面。因为它们是分别购自Spartan Chemical Co.和Level Industries的市售产品，所以这些组分没有数量。所用的每种组分特定的数量没有在标签上指出。
表1
| 组分及供应商 | 化学组成和/或功能 | 实施例1％Wt | 实施例2％Wt | 实施例3％Wt | 实施例4％Wt | 实施例5％Wt | 实施例6％Wt | 实施例7％Wt |
| 二甘醇一乙基醚 | 溶剂 | 17.4 | 20 | |||||
| 乙二醇一丁基醚 | 溶剂 | 20 | 2 | |||||
| 二甘醇 | 溶剂 | |||||||
| 磷酸三(丁氧基乙酯) | 增塑剂 | 5.2 | X | 1 | ||||
| 古柯酰胺二乙醇胺 | 油酸二乙醇胺/乳化剂的C8-C20烃链 | 7.8 | ||||||
| 一乙醇胺 | 碱性中和剂 | 35.2 | ||||||
| 氨 | 碱性中和剂 | 3.4 | ＞0.1 | |||||
| C11烷醇的乙氧基化物(6EO) | 表面活性剂 | 6 | 5 | |||||
| C11烷醇的乙氧基化物(8EO) | 表面活性剂 | 1.5 | ||||||
| Tergitol 15-S-9/Union Carbide | 有9摩尔被乙氧基化的C12-C14仲醇乙氧基化物/表面活性剂 | 6 | 15.6 | X | ||||
| 脂肪醇的乙氧基化物 | 表面活性剂 | 1 | ||||||
| 辛基葡糖甙(65％) | 表面活性剂 | 0.6 | ||||||
| 醇式酯 | 表面活性剂 | X | ||||||
| 椰子脂肪酸 | 乳化剂 | 0.6 | ||||||
| 乙二胺四乙酸四钠 | 螯合剂/硬水调节 | 0.32 | 0.64 |
| 丙烯酸酯聚合物 | 分散剂 | 1 | ||||||
| 氢氧化钠(47％) | 碱性中和剂 | 0.51 | ||||||
| 丙烯酸聚合物 | 成膜剂 | 11.2 | X | |||||
| 苯乙烯丙烯酸共聚物(20％活性的) | 成膜剂 | X | 20 | |||||
| 聚乙烯蜡乳液(30％活性的) | 2.1 | 20 | ||||||
| 聚丙烯蜡乳液(30％活性的) | 21 | 6.3 | X | X | ||||
| 芳香剂 | 0.12 | 0.12 | 0.3 | ＞0.1 | ||||
| 染料 | ＞0.1 | ＞0.1 | ＞0.1 | ＞0.1 | ||||
| 去离子水 | 到100％ | 到100％ | 到100％ | 到100％ | 到100％ | 到100％ | 到100％ | |
| Percent Cleaning-Premia FloorFinish /JohnsonWax Professional | Acrylic-WaxFinish | |||||||
| 1∶8 | 27.91 | |||||||
| 1∶32 | 43.71 | 20.69 | 5.6 | |||||
| 1∶64 | ||||||||
| 1∶100 | 9.04 | |||||||
| 1∶128 | 30.59 | 18.59 | ||||||
| 1∶256 | 19.91 | 15.52 | 17.61 | 0.68 | ||||
| 1∶512 | 12.99 | 12.6 | 9.08 |
表1A
| 组分及供应商 | 化学组成和/或功能 | 实施例8％Wt | 实施例9％Wt | 实施例10％Wt | 实施例11％Wt | 实施例12％Wt | 实施例13％Wt | 实施例14％Wt | 实施例15％Wt |
| Carbitol | 二甘醇一乙基醚/溶剂 | 17.4 | 17.4 | 17.4 | 17.4 | 17.4 | 17.4 | 17.4 | |
| Ninol 1281/Stephan | 酰胺/乳化剂 | 7.8 | 12.5 | 7.8 | 7.8 | 7.8 | 7.8 | 7.8 | |
| Neodol 91-6/TohmanChemical | 有6摩尔被乙氧基化的C9-C11烷醇乙氧基化物/表面活性剂 | 7.0 | 9.0 | 6.0 | 6.0 | 6.0 | 6.0 | 6.0 | |
| Neodol 91-2.5/TohmanChemical | 有2.5摩尔被乙氧基化的C9-C11烷醇乙氧基化物/表面活性剂 | ||||||||
| 去离子水 | 52.4 | 53.5 | 60.0 | 62.8 | 62.8 | 62.8 | 62.8 | ||
| 油酸 | 增塑剂 | 6.0 | |||||||
| 萘磺酸盐，50％ | 水溶助长剂-偶联剂 | 7.8 | |||||||
| 己二酸二丁酯 | 增塑剂 | 6.0 | |||||||
| RhodafacRS-610/RhonePoulenc | 增塑剂 | 5.2 | |||||||
| RhodafacRS-710/RhonePoulenc | 增塑剂 | 5.2 | |||||||
| RhodagfacRS-690/RhonePoulenc | 增塑剂 | 5.2 | |||||||
| Benozoflex2088/Velsicol | 增塑剂 | 5.2 | |||||||
| 苯甲酸异癸酯/Velsicol | 增塑剂 | 6.0 |
| 乙二胺四乙酸四钠 | 螯合剂/硬水调节 | 1.6 | 1.6 | 2.8 | 0.8 | 0.8 | 0.8 | 0.8 | |
| 乙二醇一丁基醚/Dow | 20.0 | ||||||||
| 一乙醇胺/Dow | 35.2 | ||||||||
| 氨 | 3.4 | ||||||||
| C11烷醇乙氧基化物(6EO)/Tomah | 6.0 | ||||||||
| 丙烯酸酯分散剂/Rohm&Haas | 1.0 | ||||||||
| 芳香剂 | 0.3 | ||||||||
| 染料 | ＜0.1 | ||||||||
| 去离子水 | 到100％ | ||||||||
| PercentCleaning-PremiaFloor Finish/JohnsonWaxProfessional | Acrylic-WaxFinish | ||||||||
| 1∶512 | 21.89 | 21.83 | 12.61 | 14.48 | 23.87 | 13.33 | 9.09 | 18.61 |
在表1A中，七种不同的增塑剂就其清洁和增强光泽的能力进行比较。请注意，尽管在这些实施例中使用不同的增塑剂表现出不同的清洁能力水平，然而就这些增塑剂而论没有光泽的提高。表1A的实施例15被用于比较，它仅仅清洁剂，没有提高光泽的要素。它展示单纯的清洁剂的清洁效率及其缺乏提高光泽的作用。
在表2中，四种产品就其提高光泽的能力进行比较。这些是实施例1、2、4、7的产品。请注意，实施例1的产品与其它产品相比即使被稀释到较高的稀释程度时也仍然表现出较高的光泽增强。
表2
| 产品 | 稀释 | 在试验时的涂复层 | 光泽(平均) | ％增加 | ||||
| 20° | 60° | 85° | 20° | 60° | 85° | |||
| 实施例1 | 1∶256 | 无涂复层 | 0.25 | 3.55 | 32.3 | |||
| 起始 | 2.11 | 4.55 | 53.4 | 740 | 309 | 65.3 | ||
| 抛光轮 | 2.65 | 17.3 | 57.7 | 960 | 387 | 78.6 | ||
| 实施例2 | 1∶128 | 无涂复层 | 0.25 | 3.55 | 32.3 | |||
| 起始 | 1.5 | 10.05 | 48.05 | 500 | 183 | 48.7 | ||
| 抛光轮 | 2.7 | 16.85 | 55.45 | 980 | 374 | 71.67 | ||
| 实施例4 | 1∶32 | 无涂复层 | 0.25 | 3.55 | 32.3 | |||
| 起始 | 1.7 | 11.9 | 50.55 | 580 | 235 | 56.5 | ||
| 抛光轮 | 5.8 | 13.8 | 54.5 | 2220 | 288 | 68.73 | ||
| 实施例7 | 1∶128 | 无涂复层 | 0.25 | 3.55 | 32.3 | |||
| 起始 | 1.8 | 12.5 | 52.6 | 620 | 252 | 62.8 | ||
| 抛光轮 | 1.75 | 13.85 | 54.9 | 600 | 290 | 70 | ||
下面的程序是在试验表2的产品时使用的。黑色的VCT地板被剥离和清洁，而且采用下面的步骤。首先，用上述的稀释产品实例填充Clark自动擦洗器。其次，地板分割成25英尺的区段。第三，擦洗器配备下压力为100磅的红色清洁垫，而且每种清洁剂都被用于擦洗，然后立刻借助抽真空从地板拿掉。然后，在初始的应用之后，进行第二次和第三次重复擦洗。第四，在第三次应用之后，抛光机(1500转/分钟)在经过处理的表面上通过三次。在整个试验过程中，都在地板上读取最初、第三次应用之后和和在抛光之后的光泽读数。
表3展示研究各种不同的主要组分的作用和清洁性能的其它方案和配方。人们可以看到最有效的清洁是在使用KP-140作为主要组分的情况下获得的。所用的表面活性剂的数量和类型影响清洁性能，而优选的非离子型表面活性剂表现出最好的结果。胺也呈现积极的影响，但是不如使用磷酸三(丁氧基乙酯)和表面活性剂那样显著。蜡就清洁而言不是关键成份，因为在所有包含这种组分的配方中在清洁方面不显著的增加。
表3
| 组分 | 实施例16％WT | 实施例17％WT | 实施例18％WT | 实施例19％WT | 实施例20％WT | 实施例21％WT | 实施例22％WT |
| 二甘醇一乙基醚 | 5 | 5 | 5 | 8.7 | 8.94 | 8.67 | |
| 乙二醇一丁基醚 | 2 | ||||||
| 乙二醇一己基醚 | 1 | ||||||
| 磷酸三(丁氧基乙酯) | 6 | 6 | 6 | 6 | 2.6 | ||
| 古柯酰胺二乙醇胺 | 3.9 | 3.9 | 3.9 | 3.9 | 3.9 | ||
| 二乙醇胺 | 1.65 | 1.65 | 1.65 | ||||
| 氨(28％活性的) | 0.45 | 0.45 | 0.45 | 0.45 | |||
| Tergitol 15-S-9 | 3.9 | 8 | 8 | 8 | 8 | ||
| 乙二胺四乙酸四钠 | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 |
| 聚丙烯蜡乳液(30％活性的) | 5.25 | 5.25 | 5.25 | 5.25 | 5.25 | 2.6 | |
| 去离子水 | 到100％ | 到100％ | 到100％ | 到100％ | 到100％ | 到100％ | 到100％ |
| Percent Cleaning-PremiaFloor Finish | |||||||
| 1∶32 | 29.97 | 28.45 | 97.66 | 96.95 | 81.67 | 78.84 | 24.12 |
在表4中，就光泽的增强对几种变化进行评估，无论是与低蜡的还是无蜡的配方进行比较，蜡都表现出提高光泽。
表4
| 结果 | |||||
| 产品 | 平均的20°光泽 | ％增加 | 平均的60°光泽 | ％增加 | |
| 实施例2 | 起始光泽 | 19 | 59.6 | ||
| 擦伤之前 | 38.3 | 101.6 | 73.8 | 23.8 | |
| 最终的光泽 | 42.3 | 122.6 | 75.5 | 26.7 | |
| 实施例12 | 起始光泽 | 18 | 57.5 | ||
| 擦伤之前 | 36.5 | 102.8 | 72.5 | 26.1 | |
| 最终的光泽 | 38 | 111.1 | 73.5 | 27.8 | |
| 实施例13 | 起始光泽 | 20.5 | 59.5 | ||
| 擦伤之前 | 32 | 56.1 | 70.5 | 18.5 | |
| 最终的光泽 | 38.5 | 87.8 | 72.5 | 21.8 | |
| 实施例14 | 起始光泽 | 22 | 63 | ||
| 擦伤之前 | 37.5 | 70.5 | 75.5 | 19.8 | |
| 最终的光泽 | 44.5 | 102.3 | 76 | 20.6 | |
下面的程序是在试验表4的产品时使用的。砖被涂上两层Premia地板涂复层、干燥和磨光。清洁剂/光泽增强剂被涂上去，然后被干燥和磨光，重复4个周期，接下来用蓝色的剥离垫抛光表面。最后，反复涂溶液跟在抛光后面，重复附加的4个周期，总共8个周期。所有的稀释都按1∶32进行。
表5描绘在清洁剂中与溶剂和表面活性剂组合时碱性度的不利影响及其从地板上剥离地板涂复层的能力。虽然碱性度在历史上已被用来增加清洁能力，但是它确实有有害的作用。请注意，即使实施例1的产品有溶剂、表面活性剂和低碱性度，它对涂上一层Premia地板涂复层的砖瓦也没有不利的影响。这是理想的，因为现有技术教导我们，为了增强硬表面的清洁，有效的清洁剂通常是由碱性组分或与溶剂的组合组成的。这种技术表明：虽然碱性度能改善清洁性能，但是它在获得好的清洁方面不是关键组分，这是有益的，因为所用的地板涂复层和设备没有表现出有害的作用。
下面的程序是在试验表5的产品中使用的。首先，VCT砖瓦被清洁和剥离。其次，涂布5层Premia地板涂复层，在涂布每个涂层之后，用对应于该涂层的数字在砖瓦上作记号。然后，将这些砖瓦干燥48小时，此后砖瓦被切成2英寸*12英寸、剥离和放进Gardner擦洗器，清洁剂/维护剂的稀释液被允许在砖瓦上停留5分钟。最后砖瓦用轻的清洁垫(红色)擦洗25个周期，并且记录除去的涂层编号。
表5
| 结果 | ||
| 产品 | 稀释 | 被除去的涂层编号 |
| 实施例1 | 1∶512 | 0 |
| 实施例3 | 1∶512 | 1 |
尽管磷酸三(丁氧基乙酯)对于清洁地板涂复层和提高地板涂复层的光泽两者都是优选的，但是如同在表1、1A和3的实施例中展示的那样其它的增塑剂也可以使用。
工业应用
这项发明的组合物在清洁地板涂复层和提高地板涂复层的光泽两方面是有用的。它们能够用水稀释并且仍然提供清洁和提高光泽。
Claims (14)
1.一种用来清洁和提高地板光泽的组合物，该组合物包括：
按重量计0.1-30％的乙二醇溶剂；
0.1-30％的能够清洁和提高地板涂层的光泽的增塑剂；
0.1-30％的非离子型表面活性剂；
胺；以及
非必选的水。
2.根据权利要求1的组合物，其中增塑剂是磷酸三(丁氧基乙酯)。
3.根据权利要求1的组合物，其中乙二醇溶剂是二甘醇一乙基醚。
4.根据权利要求1的组合物，其中乙二醇溶剂是乙二醇一丁基醚和乙二醇一己基醚。
5.根据权利要求1的组合物，其中非离子型表面活性剂是有1到10摩尔乙氧基的C8-C15烃。
6.根据权利要求1的组合物，其中胺是二乙醇胺。
7.根据权利要求1的组合物，其中胺是古柯酰胺二乙醇胺(cocamidediethanolamine)。
8.根据权利要求1的组合物，进一步包括有C8-C20烃链的氨基化合物。
9.根据权利要求8的组合物，其中氨基化合物是油酸二乙醇胺酰胺。
10.根据权利要求1的组合物，进一步包括蜡。
11.根据权利要求10的组合物，其中蜡包括高熔点的聚乙烯或聚丙烯。
12.根据权利要求1的组合物，进一步包括三乙酸化乙二胺。
13.根据权利要求1的组合物，进一步包括着色剂和芳香剂。
14.一种清洁和提高地板光泽的方法，包括使地板接触根据权利要求1的组合物。
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/774,973 US6403546B1 (en) | 2001-01-31 | 2001-01-31 | Floor cleaner and gloss enhancer |
| US09/774,973 | 2001-01-31 |
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| CN1487991A true CN1487991A (zh) | 2004-04-07 |
| CN100523160C CN100523160C (zh) | 2009-08-05 |
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| KR (1) | KR20030074755A (zh) |
| CN (1) | CN100523160C (zh) |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102482624A (zh) * | 2010-05-14 | 2012-05-30 | 化学工厂克鲁特有限公司 | 含有非离子表面活性剂的voc减少和温和碱性的水洗液及其浓缩物 |
| CN115572644A (zh) * | 2022-11-03 | 2023-01-06 | 赞宇科技集团股份有限公司 | 一种提升硬质表面光泽度的液体组合物与硬表面洗涤剂 |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050215678A1 (en) * | 2004-03-24 | 2005-09-29 | Johnsondiversey, Inc. | Fluorochemical free aqueous coating compositions and methods of use thereof |
| US7071153B2 (en) | 2004-04-29 | 2006-07-04 | Johnsondiversey, Inc. | Method of enhancing a soiled porous surface and maintenance thereof |
| US20060252878A1 (en) * | 2005-05-09 | 2006-11-09 | Razdik Jason M | Plasticized aqueous alkali-soluble resin coating compositions with reduced odor and pH |
| US7547670B2 (en) * | 2005-10-25 | 2009-06-16 | Cognis Ip Management Gmbh | Low odor ester-based microemulsions for cleaning hard surfaces |
| US7730761B2 (en) * | 2006-06-16 | 2010-06-08 | Rohm And Haas Company | Producing stress on surfaces |
| JP4583364B2 (ja) * | 2006-12-28 | 2010-11-17 | 株式会社ソフト９９コーポレーション | 塗膜洗浄剤及び塗膜洗浄用ウェットクロス |
| JP5260210B2 (ja) * | 2008-09-24 | 2013-08-14 | 花王株式会社 | 床用つや出し洗浄剤組成物 |
| KR101098373B1 (ko) | 2009-07-23 | 2011-12-23 | 남방씨.엔.에이 주식회사 | 슬래그 제거제용 조성물 |
| US8206511B2 (en) * | 2009-10-06 | 2012-06-26 | Ecolab Usa Inc. | Daily cleaner with slip-resistant and gloss-enhancing properties |
| US9920281B2 (en) | 2009-11-12 | 2018-03-20 | Ecolab Usa Inc. | Soil resistant surface treatment |
| US20110186083A1 (en) * | 2010-02-04 | 2011-08-04 | Illinois Tool Works Inc. | Pharmaceutical cell cleaning process |
| US8440751B2 (en) | 2010-05-18 | 2013-05-14 | Ecolab Usa Inc. | Reduced phosphorus (TBEP) floor coatings |
| WO2012040561A1 (en) | 2010-09-24 | 2012-03-29 | Invista Technologies S.A R.L. | Composition for surface treatment and process |
| US8585829B2 (en) | 2010-12-13 | 2013-11-19 | Ecolab Usa Inc. | Soil resistant floor cleaner |
| WO2013004302A1 (en) * | 2011-07-05 | 2013-01-10 | Ecolab Inc. | Acid marble cleaner |
| DE102013204824A1 (de) * | 2013-03-15 | 2014-09-18 | Henkel Ag & Co. Kgaa | Reinigungsmittel für harte Oberflächen enthaltend Phosphorsäureester eines Polyether-modifizierten Alkylalkohols |
| CN103436189B (zh) * | 2013-09-02 | 2014-12-24 | 浙江红高梁木业有限公司 | 一种木地板光亮剂 |
| EP3118298B1 (en) * | 2015-07-13 | 2018-10-31 | The Procter and Gamble Company | Hard surface cleaners comprising a solvent |
| AU2017228378B2 (en) | 2016-03-04 | 2021-08-05 | S.C. Johnson & Son, Inc. | Multi-purpose floor finish composition |
| DE102016225903A1 (de) | 2016-12-21 | 2018-06-21 | Henkel Ag & Co. Kgaa | Reinigungsmittel für harte Oberflächen mit langanhaltender Duft- und Glanzwirkung |
| JP6975969B2 (ja) * | 2017-11-13 | 2021-12-01 | シーバイエス株式会社 | 架橋された塗膜用の洗浄剤組成物および床面の管理方法 |
| US20190230929A1 (en) * | 2018-01-30 | 2019-08-01 | W.M. Barr & Company, Inc. | Composition for residual sanitization |
| EP3572489A1 (en) | 2018-05-24 | 2019-11-27 | The Procter & Gamble Company | Spray container comprising a detergent composition |
| EP3572490A1 (en) | 2018-05-24 | 2019-11-27 | The Procter & Gamble Company | Spray container comprising a detergent composition |
| EP3572493A1 (en) | 2018-05-24 | 2019-11-27 | The Procter & Gamble Company | Spray container comprising a detergent composition |
| EP3572492A1 (en) | 2018-05-24 | 2019-11-27 | The Procter & Gamble Company | Fine mist hard surface cleaning spray |
| EP3572491A1 (en) | 2018-05-24 | 2019-11-27 | The Procter & Gamble Company | Spray container comprising a detergent composition |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2383114A (en) | 1942-07-24 | 1945-08-21 | Cities Service Oil Co | Detergent composition |
| US3711436A (en) * | 1971-03-02 | 1973-01-16 | Sinclair Koppers Co | Floor polish composition having improved initial water and detergent resistance |
| US3926893A (en) * | 1974-08-26 | 1975-12-16 | Westvaco Corp | Polish containing a C{HD 21 {B -cycloaliphatic dicarboxylic acid |
| US4070510A (en) * | 1976-03-12 | 1978-01-24 | Acme Chemical Company | Aqueous polish composition |
| US4230605A (en) | 1978-12-13 | 1980-10-28 | Armstrong Cork Company | Cleaning composition for no-wax vinyl composition floor covering |
| US4747880A (en) | 1984-12-12 | 1988-05-31 | S. C. Johnson & Son, Inc. | Dry, granular maintenance product reconstitutable to an aqueous clean and shine product |
| DE3530623A1 (de) | 1985-08-28 | 1987-03-12 | Henkel Kgaa | Demulgierendes reinigungsmittel mit flaechenfeuchthalteeffekt |
| EP0239084A3 (en) | 1986-03-26 | 1989-03-29 | S.C. Johnson & Son, Inc. | Non-homogenized multi-surface polish compositions |
| DE3643934A1 (de) | 1986-12-22 | 1988-06-23 | Henkel Kgaa | Verwendung ausgewaehlter alkyl- und/oder alkenyl-diethanolaminverbindungen als loesungsvermittler fuer schaumarme tenside |
| US4857114A (en) | 1987-04-13 | 1989-08-15 | Amway Corporation | Floor polish remover |
| US4861518A (en) | 1988-08-01 | 1989-08-29 | Ecolab Inc. | Non-filming high performance solid floor cleaner |
| US4869934A (en) * | 1988-09-16 | 1989-09-26 | Sterling Drug Inc. | Floor polishing and coating composition |
| US5191002A (en) * | 1991-10-18 | 1993-03-02 | Puritan/Churchill Chemical Company | Method and compositions for a floor care maintenance system |
| US5382376A (en) | 1992-10-02 | 1995-01-17 | The Procter & Gamble Company | Hard surface detergent compositions |
| US5342551A (en) | 1992-11-04 | 1994-08-30 | Cello Corporation | Noncaustic floor finish remover |
| DE4335046A1 (de) * | 1993-10-14 | 1995-04-20 | Henkel Kgaa | Wäßriges Fußbodenreinigungsmittel |
| ES2202412T3 (es) | 1996-02-13 | 2004-04-01 | Johnsondiversey, Inc. | Dispositivo y procedimiento de tratamiento de superficies. |
-
2001
- 2001-01-31 US US09/774,973 patent/US6403546B1/en not_active Expired - Lifetime
-
2002
- 2002-01-15 AU AU2002251786A patent/AU2002251786B2/en not_active Expired
- 2002-01-15 JP JP2002561585A patent/JP2004526821A/ja active Pending
- 2002-01-15 KR KR10-2003-7010037A patent/KR20030074755A/ko not_active Application Discontinuation
- 2002-01-15 CN CNB028039386A patent/CN100523160C/zh not_active Expired - Lifetime
- 2002-01-15 BR BR0206795-1A patent/BR0206795A/pt not_active Application Discontinuation
- 2002-01-15 WO PCT/US2002/001433 patent/WO2002061028A1/en not_active Application Discontinuation
- 2002-01-15 CA CA2434298A patent/CA2434298C/en not_active Expired - Lifetime
- 2002-01-15 NZ NZ526899A patent/NZ526899A/en not_active IP Right Cessation
- 2002-01-15 EP EP02720812A patent/EP1366143A1/en not_active Withdrawn
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102482624A (zh) * | 2010-05-14 | 2012-05-30 | 化学工厂克鲁特有限公司 | 含有非离子表面活性剂的voc减少和温和碱性的水洗液及其浓缩物 |
| CN102482624B (zh) * | 2010-05-14 | 2014-09-24 | 化学工厂克鲁特有限公司 | 含有非离子表面活性剂的voc减少和温和碱性的水洗液及其浓缩物 |
| CN115572644A (zh) * | 2022-11-03 | 2023-01-06 | 赞宇科技集团股份有限公司 | 一种提升硬质表面光泽度的液体组合物与硬表面洗涤剂 |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2004526821A (ja) | 2004-09-02 |
| KR20030074755A (ko) | 2003-09-19 |
| US6403546B1 (en) | 2002-06-11 |
| AU2002251786B2 (en) | 2006-02-02 |
| NZ526899A (en) | 2004-11-26 |
| EP1366143A1 (en) | 2003-12-03 |
| WO2002061028A1 (en) | 2002-08-08 |
| CN100523160C (zh) | 2009-08-05 |
| CA2434298C (en) | 2012-03-06 |
| BR0206795A (pt) | 2004-02-03 |
| CA2434298A1 (en) | 2002-08-08 |
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