CN1439045A - 可生物降解的植物油组合物 - Google Patents
可生物降解的植物油组合物 Download PDFInfo
- Publication number
- CN1439045A CN1439045A CN01811866A CN01811866A CN1439045A CN 1439045 A CN1439045 A CN 1439045A CN 01811866 A CN01811866 A CN 01811866A CN 01811866 A CN01811866 A CN 01811866A CN 1439045 A CN1439045 A CN 1439045A
- Authority
- CN
- China
- Prior art keywords
- oil
- composition
- acid
- carbon atoms
- modification
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 62
- 235000015112 vegetable and seed oil Nutrition 0.000 title claims description 8
- 239000008158 vegetable oil Substances 0.000 title claims description 8
- 239000003921 oil Substances 0.000 claims abstract description 123
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 36
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 claims abstract description 35
- 239000001257 hydrogen Substances 0.000 claims abstract description 21
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 21
- 230000000994 depressogenic effect Effects 0.000 claims abstract description 18
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 16
- 239000004793 Polystyrene Substances 0.000 claims abstract description 11
- 125000002877 alkyl aryl group Chemical group 0.000 claims abstract description 11
- 229920002223 polystyrene Polymers 0.000 claims abstract description 11
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 10
- 150000001412 amines Chemical class 0.000 claims abstract description 9
- 125000003118 aryl group Chemical group 0.000 claims abstract description 9
- 125000003710 aryl alkyl group Chemical group 0.000 claims abstract description 8
- 125000001931 aliphatic group Chemical group 0.000 claims abstract description 4
- 235000019198 oils Nutrition 0.000 claims description 121
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 50
- 235000013311 vegetables Nutrition 0.000 claims description 45
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 33
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 33
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 33
- 239000005642 Oleic acid Substances 0.000 claims description 33
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 33
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 33
- 150000002148 esters Chemical class 0.000 claims description 26
- -1 Alpha-Naphthyl Chemical group 0.000 claims description 23
- 238000007385 chemical modification Methods 0.000 claims description 23
- 238000012239 gene modification Methods 0.000 claims description 20
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 17
- 239000002253 acid Substances 0.000 claims description 17
- 210000000582 semen Anatomy 0.000 claims description 13
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 11
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 10
- ZOJBYZNEUISWFT-UHFFFAOYSA-N allyl isothiocyanate Chemical compound C=CCN=C=S ZOJBYZNEUISWFT-UHFFFAOYSA-N 0.000 claims description 9
- 229910052799 carbon Inorganic materials 0.000 claims description 9
- 238000006243 chemical reaction Methods 0.000 claims description 9
- 150000002431 hydrogen Chemical group 0.000 claims description 9
- 239000008164 mustard oil Substances 0.000 claims description 9
- 235000019483 Peanut oil Nutrition 0.000 claims description 8
- 239000000312 peanut oil Substances 0.000 claims description 8
- 239000003549 soybean oil Substances 0.000 claims description 8
- 235000012424 soybean oil Nutrition 0.000 claims description 8
- 235000019484 Rapeseed oil Nutrition 0.000 claims description 7
- 125000000217 alkyl group Chemical group 0.000 claims description 7
- 239000002199 base oil Substances 0.000 claims description 7
- 229920013639 polyalphaolefin Polymers 0.000 claims description 7
- ZEMPKEQAKRGZGQ-AAKVHIHISA-N 2,3-bis[[(z)-12-hydroxyoctadec-9-enoyl]oxy]propyl (z)-12-hydroxyoctadec-9-enoate Chemical compound CCCCCCC(O)C\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CC(O)CCCCCC)COC(=O)CCCCCCC\C=C/CC(O)CCCCCC ZEMPKEQAKRGZGQ-AAKVHIHISA-N 0.000 claims description 6
- 230000004048 modification Effects 0.000 claims description 6
- 238000012986 modification Methods 0.000 claims description 6
- 239000010496 thistle oil Substances 0.000 claims description 6
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 5
- 108090000623 proteins and genes Proteins 0.000 claims description 5
- 241001072282 Limnanthes Species 0.000 claims description 4
- 230000029936 alkylation Effects 0.000 claims description 3
- 238000005804 alkylation reaction Methods 0.000 claims description 3
- 230000008859 change Effects 0.000 claims description 3
- 241000390166 Physaria Species 0.000 claims description 2
- 230000002152 alkylating effect Effects 0.000 claims description 2
- 241000219198 Brassica Species 0.000 claims 1
- 235000003351 Brassica cretica Nutrition 0.000 claims 1
- 235000003343 Brassica rupestris Nutrition 0.000 claims 1
- QKSKPIVNLNLAAV-UHFFFAOYSA-N bis(2-chloroethyl) sulfide Chemical compound ClCCSCCCl QKSKPIVNLNLAAV-UHFFFAOYSA-N 0.000 claims 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims 1
- 150000002763 monocarboxylic acids Chemical class 0.000 claims 1
- 235000010460 mustard Nutrition 0.000 claims 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 abstract description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 2
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 1
- OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 description 15
- 229960004232 linoleic acid Drugs 0.000 description 14
- 239000000314 lubricant Substances 0.000 description 14
- 239000002585 base Substances 0.000 description 10
- 239000012752 auxiliary agent Substances 0.000 description 8
- 238000005984 hydrogenation reaction Methods 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 7
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- 150000001298 alcohols Chemical class 0.000 description 6
- 239000012530 fluid Substances 0.000 description 6
- 125000002947 alkylene group Chemical group 0.000 description 5
- 230000006872 improvement Effects 0.000 description 5
- 239000010699 lard oil Substances 0.000 description 5
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 5
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 235000019486 Sunflower oil Nutrition 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 230000032050 esterification Effects 0.000 description 4
- 238000005886 esterification reaction Methods 0.000 description 4
- 239000012208 gear oil Substances 0.000 description 4
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 239000002480 mineral oil Substances 0.000 description 4
- 235000010446 mineral oil Nutrition 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 239000002600 sunflower oil Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 description 3
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 3
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 3
- 235000021355 Stearic acid Nutrition 0.000 description 3
- 150000004703 alkoxides Chemical class 0.000 description 3
- 125000003545 alkoxy group Chemical group 0.000 description 3
- DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 description 3
- 235000020661 alpha-linolenic acid Nutrition 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 3
- 150000002191 fatty alcohols Chemical class 0.000 description 3
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 3
- 229940051250 hexylene glycol Drugs 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- 229960004488 linolenic acid Drugs 0.000 description 3
- KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 description 3
- 239000010687 lubricating oil Substances 0.000 description 3
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 3
- 229940055577 oleyl alcohol Drugs 0.000 description 3
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 3
- 125000006353 oxyethylene group Chemical group 0.000 description 3
- 238000000746 purification Methods 0.000 description 3
- 239000008117 stearic acid Substances 0.000 description 3
- 125000001424 substituent group Chemical group 0.000 description 3
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 3
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N 1-nonene Chemical compound CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- DCTOHCCUXLBQMS-UHFFFAOYSA-N 1-undecene Chemical compound CCCCCCCCCC=C DCTOHCCUXLBQMS-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- UNXHWFMMPAWVPI-UHFFFAOYSA-N Erythritol Natural products OCC(O)C(O)CO UNXHWFMMPAWVPI-UHFFFAOYSA-N 0.000 description 2
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- NEAPKZHDYMQZCB-UHFFFAOYSA-N N-[2-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperazin-1-yl]ethyl]-2-oxo-3H-1,3-benzoxazole-6-carboxamide Chemical compound C1CN(CCN1CCNC(=O)C2=CC3=C(C=C2)NC(=O)O3)C4=CN=C(N=C4)NC5CC6=CC=CC=C6C5 NEAPKZHDYMQZCB-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000005864 Sulphur Substances 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- UJMDYLWCYJJYMO-UHFFFAOYSA-N benzene-1,2,3-tricarboxylic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1C(O)=O UJMDYLWCYJJYMO-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 229960000541 cetyl alcohol Drugs 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- 230000002950 deficient Effects 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 2
- UNXHWFMMPAWVPI-ZXZARUISSA-N erythritol Chemical compound OC[C@H](O)[C@H](O)CO UNXHWFMMPAWVPI-ZXZARUISSA-N 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- JFCQEDHGNNZCLN-UHFFFAOYSA-N glutaric acid Chemical compound OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 2
- 235000003642 hunger Nutrition 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 150000002632 lipids Chemical class 0.000 description 2
- 230000001050 lubricating effect Effects 0.000 description 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 2
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 2
- BKIMMITUMNQMOS-UHFFFAOYSA-N nonane Chemical compound CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 2
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 229940059574 pentaerithrityl Drugs 0.000 description 2
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- WLJVNTCWHIRURA-UHFFFAOYSA-N pimelic acid Chemical compound OC(=O)CCCCCC(O)=O WLJVNTCWHIRURA-UHFFFAOYSA-N 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- CYIDZMCFTVVTJO-UHFFFAOYSA-N pyromellitic acid Chemical compound OC(=O)C1=CC(C(O)=O)=C(C(O)=O)C=C1C(O)=O CYIDZMCFTVVTJO-UHFFFAOYSA-N 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 150000003333 secondary alcohols Chemical class 0.000 description 2
- FVEFRICMTUKAML-UHFFFAOYSA-M sodium tetradecyl sulfate Chemical compound [Na+].CCCCC(CC)CCC(CC(C)C)OS([O-])(=O)=O FVEFRICMTUKAML-UHFFFAOYSA-M 0.000 description 2
- TYFQFVWCELRYAO-UHFFFAOYSA-N suberic acid Chemical compound OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 description 2
- 125000002769 thiazolinyl group Chemical group 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 2
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 2
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 2
- 239000010913 used oil Substances 0.000 description 2
- MEIRRNXMZYDVDW-MQQKCMAXSA-N (2E,4E)-2,4-hexadien-1-ol Chemical compound C\C=C\C=C\CO MEIRRNXMZYDVDW-MQQKCMAXSA-N 0.000 description 1
- CFQZKFWQLAHGSL-FNTYJUCDSA-N (3e,5e,7e,9e,11e,13e,15e,17e)-18-[(3e,5e,7e,9e,11e,13e,15e,17e)-18-[(3e,5e,7e,9e,11e,13e,15e)-octadeca-3,5,7,9,11,13,15,17-octaenoyl]oxyoctadeca-3,5,7,9,11,13,15,17-octaenoyl]oxyoctadeca-3,5,7,9,11,13,15,17-octaenoic acid Chemical compound OC(=O)C\C=C\C=C\C=C\C=C\C=C\C=C\C=C\C=C\OC(=O)C\C=C\C=C\C=C\C=C\C=C\C=C\C=C\C=C\OC(=O)C\C=C\C=C\C=C\C=C\C=C\C=C\C=C\C=C CFQZKFWQLAHGSL-FNTYJUCDSA-N 0.000 description 1
- AAWZDTNXLSGCEK-LNVDRNJUSA-N (3r,5r)-1,3,4,5-tetrahydroxycyclohexane-1-carboxylic acid Chemical compound O[C@@H]1CC(O)(C(O)=O)C[C@@H](O)C1O AAWZDTNXLSGCEK-LNVDRNJUSA-N 0.000 description 1
- IKYKEVDKGZYRMQ-PDBXOOCHSA-N (9Z,12Z,15Z)-octadecatrien-1-ol Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCCO IKYKEVDKGZYRMQ-PDBXOOCHSA-N 0.000 description 1
- 239000001707 (E,7R,11R)-3,7,11,15-tetramethylhexadec-2-en-1-ol Substances 0.000 description 1
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- 239000005968 1-Decanol Substances 0.000 description 1
- VQOXUMQBYILCKR-UHFFFAOYSA-N 1-Tridecene Chemical group CCCCCCCCCCCC=C VQOXUMQBYILCKR-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 description 1
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 1
- UXFQFBNBSPQBJW-UHFFFAOYSA-N 2-amino-2-methylpropane-1,3-diol Chemical compound OCC(N)(C)CO UXFQFBNBSPQBJW-UHFFFAOYSA-N 0.000 description 1
- WJQOZHYUIDYNHM-UHFFFAOYSA-N 2-tert-Butylphenol Chemical compound CC(C)(C)C1=CC=CC=C1O WJQOZHYUIDYNHM-UHFFFAOYSA-N 0.000 description 1
- AFPHTEQTJZKQAQ-UHFFFAOYSA-N 3-nitrobenzoic acid Chemical compound OC(=O)C1=CC=CC([N+]([O-])=O)=C1 AFPHTEQTJZKQAQ-UHFFFAOYSA-N 0.000 description 1
- LHRYNURXGHTOSZ-UHFFFAOYSA-N 5,6-dihydrobenzo[b][1]benzoxepine Chemical compound C1CC2=CC=CC=C2OC2=CC=CC=C12 LHRYNURXGHTOSZ-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- 235000005637 Brassica campestris Nutrition 0.000 description 1
- 240000002791 Brassica napus Species 0.000 description 1
- 235000011293 Brassica napus Nutrition 0.000 description 1
- 241001301148 Brassica rapa subsp. oleifera Species 0.000 description 1
- DPUOLQHDNGRHBS-UHFFFAOYSA-N Brassidinsaeure Natural products CCCCCCCCC=CCCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-UHFFFAOYSA-N 0.000 description 1
- SFXUXMZHNAWMEX-UHFFFAOYSA-N C(O)C1(C(C(=O)O)C=CC=C1C(=O)O)C Chemical compound C(O)C1(C(C(=O)O)C=CC=C1C(=O)O)C SFXUXMZHNAWMEX-UHFFFAOYSA-N 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- AAWZDTNXLSGCEK-UHFFFAOYSA-N Cordycepinsaeure Natural products OC1CC(O)(C(O)=O)CC(O)C1O AAWZDTNXLSGCEK-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 1
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 description 1
- HECLRDQVFMWTQS-UHFFFAOYSA-N Dicyclopentadiene Chemical compound C1C2C3CC=CC3C1C=C2 HECLRDQVFMWTQS-UHFFFAOYSA-N 0.000 description 1
- URXZXNYJPAJJOQ-UHFFFAOYSA-N Erucic acid Natural products CCCCCCC=CCCCCCCCCCCCC(O)=O URXZXNYJPAJJOQ-UHFFFAOYSA-N 0.000 description 1
- 239000004386 Erythritol Substances 0.000 description 1
- 239000004258 Ethoxyquin Substances 0.000 description 1
- 230000010558 Gene Alterations Effects 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 241000490472 Helianthus sp. Species 0.000 description 1
- OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 1
- 229930195725 Mannitol Natural products 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- BLUHKGOSFDHHGX-UHFFFAOYSA-N Phytol Natural products CC(C)CCCC(C)CCCC(C)CCCC(C)C=CO BLUHKGOSFDHHGX-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 229920002367 Polyisobutene Polymers 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- AAWZDTNXLSGCEK-ZHQZDSKASA-N Quinic acid Natural products O[C@H]1CC(O)(C(O)=O)C[C@H](O)C1O AAWZDTNXLSGCEK-ZHQZDSKASA-N 0.000 description 1
- 235000019485 Safflower oil Nutrition 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- HNZBNQYXWOLKBA-UHFFFAOYSA-N Tetrahydrofarnesol Natural products CC(C)CCCC(C)CCCC(C)=CCO HNZBNQYXWOLKBA-UHFFFAOYSA-N 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000001348 alkyl chlorides Chemical class 0.000 description 1
- BOTWFXYSPFMFNR-OALUTQOASA-N all-rac-phytol Natural products CC(C)CCC[C@H](C)CCC[C@H](C)CCCC(C)=CCO BOTWFXYSPFMFNR-OALUTQOASA-N 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- PYMYPHUHKUWMLA-WDCZJNDASA-N arabinose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)C=O PYMYPHUHKUWMLA-WDCZJNDASA-N 0.000 description 1
- PYMYPHUHKUWMLA-UHFFFAOYSA-N arabinose Natural products OCC(O)C(O)C(O)C=O PYMYPHUHKUWMLA-UHFFFAOYSA-N 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- SRBFZHDQGSBBOR-UHFFFAOYSA-N beta-D-Pyranose-Lyxose Natural products OC1COC(O)C(O)C1O SRBFZHDQGSBBOR-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical class OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 1
- OWBTYPJTUOEWEK-UHFFFAOYSA-N butane-2,3-diol Chemical compound CC(O)C(C)O OWBTYPJTUOEWEK-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 230000006208 butylation Effects 0.000 description 1
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- JYYOBHFYCIDXHH-UHFFFAOYSA-N carbonic acid;hydrate Chemical compound O.OC(O)=O JYYOBHFYCIDXHH-UHFFFAOYSA-N 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 239000010725 compressor oil Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000002285 corn oil Substances 0.000 description 1
- 235000005687 corn oil Nutrition 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical class C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 239000012990 dithiocarbamate Substances 0.000 description 1
- 229960000735 docosanol Drugs 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229910001651 emery Inorganic materials 0.000 description 1
- 150000002085 enols Chemical class 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- DPUOLQHDNGRHBS-KTKRTIGZSA-N erucic acid Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-KTKRTIGZSA-N 0.000 description 1
- 235000019414 erythritol Nutrition 0.000 description 1
- 229940009714 erythritol Drugs 0.000 description 1
- 239000010696 ester oil Substances 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- DECIPOUIJURFOJ-UHFFFAOYSA-N ethoxyquin Chemical compound N1C(C)(C)C=C(C)C2=CC(OCC)=CC=C21 DECIPOUIJURFOJ-UHFFFAOYSA-N 0.000 description 1
- 229940093500 ethoxyquin Drugs 0.000 description 1
- 235000019285 ethoxyquin Nutrition 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 238000010362 genome editing Methods 0.000 description 1
- 239000000174 gluconic acid Substances 0.000 description 1
- 235000012208 gluconic acid Nutrition 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- MNQZXJOMYWMBOU-UHFFFAOYSA-N glyceraldehyde Chemical compound OCC(O)C=O MNQZXJOMYWMBOU-UHFFFAOYSA-N 0.000 description 1
- 229960005150 glycerol Drugs 0.000 description 1
- 125000005908 glyceryl ester group Chemical group 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 230000002650 habitual effect Effects 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- SXCBDZAEHILGLM-UHFFFAOYSA-N heptane-1,7-diol Chemical compound OCCCCCCCO SXCBDZAEHILGLM-UHFFFAOYSA-N 0.000 description 1
- XVEOUOTUJBYHNL-UHFFFAOYSA-N heptane-2,4-diol Chemical compound CCCC(O)CC(C)O XVEOUOTUJBYHNL-UHFFFAOYSA-N 0.000 description 1
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- OHMBHFSEKCCCBW-UHFFFAOYSA-N hexane-2,5-diol Chemical compound CC(O)CCC(C)O OHMBHFSEKCCCBW-UHFFFAOYSA-N 0.000 description 1
- 235000012907 honey Nutrition 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 1
- 229940033355 lauric acid Drugs 0.000 description 1
- 235000020778 linoleic acid Nutrition 0.000 description 1
- OYHQOLUKZRVURQ-IXWMQOLASA-N linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 description 1
- HBOQXIRUPVQLKX-UHFFFAOYSA-N linoleic acid triglyceride Natural products CCCCCC=CCC=CCCCCCCCC(=O)OCC(OC(=O)CCCCCCCC=CCC=CCCCCC)COC(=O)CCCCCCCC=CCC=CCCCCC HBOQXIRUPVQLKX-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 230000005389 magnetism Effects 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 125000002960 margaryl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000010688 mineral lubricating oil Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 235000013379 molasses Nutrition 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000010705 motor oil Substances 0.000 description 1
- GVKQRLXYDPFTKR-UHFFFAOYSA-N n-phenylaniline;styrene Chemical compound C=CC1=CC=CC=C1.C=1C=CC=CC=1NC1=CC=CC=C1 GVKQRLXYDPFTKR-UHFFFAOYSA-N 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- ZWLPBLYKEWSWPD-UHFFFAOYSA-N o-toluic acid Chemical compound CC1=CC=CC=C1C(O)=O ZWLPBLYKEWSWPD-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- IWDCLRJOBJJRNH-UHFFFAOYSA-N p-cresol Chemical compound CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- BOTWFXYSPFMFNR-PYDDKJGSSA-N phytol Chemical compound CC(C)CCC[C@@H](C)CCC[C@@H](C)CCC\C(C)=C\CO BOTWFXYSPFMFNR-PYDDKJGSSA-N 0.000 description 1
- 229920001083 polybutene Polymers 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- WEHMXWJFCCNXHJ-UHFFFAOYSA-N propa-1,2-dienylbenzene Chemical compound C=C=CC1=CC=CC=C1 WEHMXWJFCCNXHJ-UHFFFAOYSA-N 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000003813 safflower oil Substances 0.000 description 1
- 235000005713 safflower oil Nutrition 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000003079 shale oil Substances 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 238000010583 slow cooling Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 229940012831 stearyl alcohol Drugs 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 235000020238 sunflower seed Nutrition 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M101/00—Lubricating compositions characterised by the base-material being a mineral or fatty oil
- C10M101/04—Fatty oil fractions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
- C10M105/08—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen
- C10M105/32—Esters
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M107/00—Lubricating compositions characterised by the base-material being a macromolecular compound
- C10M107/02—Hydrocarbon polymers; Hydrocarbon polymers modified by oxidation
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M107/00—Lubricating compositions characterised by the base-material being a macromolecular compound
- C10M107/20—Lubricating compositions characterised by the base-material being a macromolecular compound containing oxygen
- C10M107/30—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M107/32—Condensation polymers of aldehydes or ketones; Polyesters; Polyethers
- C10M107/34—Polyoxyalkylenes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
- C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
- C10M129/68—Esters
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
- C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
- C10M133/04—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M133/12—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to a carbon atom of a six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
- C10M133/52—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of 30 or more atoms
- C10M133/54—Amines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M143/00—Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M143/00—Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation
- C10M143/10—Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation containing aromatic monomer, e.g. styrene
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
- C10M145/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M145/10—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate
- C10M145/12—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate monocarboxylic
- C10M145/14—Acrylate; Methacrylate
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
- C10M145/18—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M145/24—Polyethers
- C10M145/26—Polyoxyalkylenes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M149/00—Lubricating compositions characterised by the additive being a macromolecular compound containing nitrogen
- C10M149/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/0206—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/028—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/04—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing aromatic monomers, e.g. styrene
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/024—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings having at least two phenol groups but no condensed ring
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/2805—Esters used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/281—Esters of (cyclo)aliphatic monocarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/281—Esters of (cyclo)aliphatic monocarboxylic acids
- C10M2207/2815—Esters of (cyclo)aliphatic monocarboxylic acids used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/282—Esters of (cyclo)aliphatic oolycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/282—Esters of (cyclo)aliphatic oolycarboxylic acids
- C10M2207/2825—Esters of (cyclo)aliphatic oolycarboxylic acids used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/283—Esters of polyhydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/283—Esters of polyhydroxy compounds
- C10M2207/2835—Esters of polyhydroxy compounds used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/284—Esters of aromatic monocarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/285—Esters of aromatic polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/285—Esters of aromatic polycarboxylic acids
- C10M2207/2855—Esters of aromatic polycarboxylic acids used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/286—Esters of polymerised unsaturated acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/287—Partial esters
- C10M2207/289—Partial esters containing free hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/287—Partial esters
- C10M2207/289—Partial esters containing free hydroxy groups
- C10M2207/2895—Partial esters containing free hydroxy groups used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/34—Esters having a hydrocarbon substituent of thirty or more carbon atoms, e.g. substituted succinic acid derivatives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/34—Esters having a hydrocarbon substituent of thirty or more carbon atoms, e.g. substituted succinic acid derivatives
- C10M2207/345—Esters having a hydrocarbon substituent of thirty or more carbon atoms, e.g. substituted succinic acid derivatives used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
- C10M2207/401—Fatty vegetable or animal oils used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
- C10M2207/402—Castor oils
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
- C10M2207/404—Fatty vegetable or animal oils obtained from genetically modified species
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
- C10M2207/404—Fatty vegetable or animal oils obtained from genetically modified species
- C10M2207/4045—Fatty vegetable or animal oils obtained from genetically modified species used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
- C10M2209/084—Acrylate; Methacrylate
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
- C10M2209/086—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type polycarboxylic, e.g. maleic acid
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/1033—Polyethers, i.e. containing di- or higher polyoxyalkylene groups used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
- C10M2209/1045—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/105—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing three carbon atoms only
- C10M2209/1055—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing three carbon atoms only used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/106—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing four carbon atoms only
- C10M2209/1065—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing four carbon atoms only used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/107—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of two or more specified different alkylene oxides covered by groups C10M2209/104 - C10M2209/106
- C10M2209/1075—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of two or more specified different alkylene oxides covered by groups C10M2209/104 - C10M2209/106 used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/108—Polyethers, i.e. containing di- or higher polyoxyalkylene groups etherified
- C10M2209/1085—Polyethers, i.e. containing di- or higher polyoxyalkylene groups etherified used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/109—Polyethers, i.e. containing di- or higher polyoxyalkylene groups esterified
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/109—Polyethers, i.e. containing di- or higher polyoxyalkylene groups esterified
- C10M2209/1095—Polyethers, i.e. containing di- or higher polyoxyalkylene groups esterified used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
- C10M2215/064—Di- and triaryl amines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
- C10M2215/064—Di- and triaryl amines
- C10M2215/065—Phenyl-Naphthyl amines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
- C10M2215/066—Arylene diamines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
- C10M2215/067—Polyaryl amine alkanes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
- C10M2215/068—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings having amino groups bound to polycyclic aromatic ring systems, i.e. systems with three or more condensed rings
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/221—Six-membered rings containing nitrogen and carbon only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/225—Heterocyclic nitrogen compounds the rings containing both nitrogen and oxygen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/225—Heterocyclic nitrogen compounds the rings containing both nitrogen and oxygen
- C10M2215/226—Morpholines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/26—Amines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/30—Heterocyclic compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/06—Thio-acids; Thiocyanates; Derivatives thereof
- C10M2219/062—Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
- C10M2219/066—Thiocarbamic type compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/06—Thio-acids; Thiocyanates; Derivatives thereof
- C10M2219/062—Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
- C10M2219/066—Thiocarbamic type compounds
- C10M2219/068—Thiocarbamate metal salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2290/00—Mixtures of base materials or thickeners or additives
- C10M2290/02—Mineral base oils; Mixtures of fractions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
- C10N2020/01—Physico-chemical properties
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/64—Environmental friendly compositions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/02—Bearings
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
- C10N2040/042—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for automatic transmissions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
- C10N2040/044—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for manual transmissions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
- C10N2040/046—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for traction drives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/08—Hydraulic fluids, e.g. brake-fluids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
- C10N2040/251—Alcohol-fuelled engines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
- C10N2040/255—Gasoline engines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
- C10N2040/255—Gasoline engines
- C10N2040/28—Rotary engines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/10—Semi-solids; greasy
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2070/00—Specific manufacturing methods for lubricant compositions
- C10N2070/02—Concentrating of additives
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Lubricants (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Anti-Oxidant Or Stabilizer Compositions (AREA)
- Fats And Perfumes (AREA)
- Biological Depolymerization Polymers (AREA)
Abstract
一种组合物,包括:A)至少一种(I)式的甘油三酯油,其中R1、R2和R3是含有约7~约23个碳原子的脂肪烃基;B)降凝剂包括(1)烷基化聚苯乙烯或(2)聚烷基甲基丙烯酸酯;和C)一种抗氧化剂,其包括(II)式的胺,其中R4为(III),R5为氢、烷芳基或芳烷基,R6为一种芳基、烷芳基或芳烷基,条件是当R5为氢时,R4为一种芳基。可选择地,A)、B)和C)组合物可以进一步包括D)其它油。
Description
技术领域
本发明涉及可生物降解润滑剂组合物,其由植物油甘油三酯以及降凝剂和胺类抗氧化剂制成。这些润滑剂组合物可以用于润滑发动机、变速器、齿轮箱以及用于液压。这种组合物提供了抗氧稳定性以及低温性能。这些组合物也可用作要求具有氧化稳定性和耐低温性的生物可降解油脂或其它可降解润滑剂组合物的基本原料,如用于渗透组合物和金属加工组合物。
背景技术
植物油是一种可由可再生资源大量获得的并且普遍具有容易生物降解或“环保”的特征的一类物质。所以,这类油在广泛应用方面具有潜在的吸引力。
植物油用于润滑并不是十分理想。许多植物油不具有关于倾点、氧化稳定性以及与其它辅助剂的兼容性这一系列的理想特征。然而,植物油也有许多用作润滑剂的优良特征。特别是,植物油普遍具有良好的边界润滑性、良好的粘度、高粘度指数以及高闪点。除此之外,植物油一般是无毒的和易于生物降解的。例如,在标准测试条件(如OCED 301D测试方法)下,普通的植物油在28天内将有可达80%的部分降解成二氧化碳和水,而其它普通石油基润滑液体的降解率为25%或更少。
美国专利4,783,274(Jokinen等,1998年11月8日)涉及一种无水油性润滑剂,这种润滑剂以植物油为基础代替矿物润滑油,并且其主要成份甘油三酯是饱和和/或不饱和的C10~C20直链脂肪酸和甘油醇的酯类。这种润滑剂的特征在于其含有至少70%重量的甘油三酯,其中甘油酯的碘价至少为50,并且不超过125,其粘度指数至少为190。润滑油也可以含有由所述甘油三酯或相应的甘油三酯通过热聚合而制得的聚合物,该聚合物可以替代上述的甘油三酯或与其一同作为润滑油的基本组份。润滑油可以含有辅助剂如溶剂、脂肪酸衍生物,特别是它们的金属盐、有机的或无机的,天然的或合成的聚合物,以及惯用的润滑辅助剂。
美国专利5,298,177(Stoffa,1994年3月29日)公开了一种官能液,其包括:
(A)至少一种甘油三酯;
(B)至少一种清洁剂-抑制剂辅助剂;和
(C)至少一种粘度改性辅助剂,并进一步含有
(D)至少一种合成油。
美国专利5,388,471(Lal,1994年8月16日)涉及具有至少60%的单一不饱和成分的植物油,以及进行过酯交换并且含有至少一种降凝剂的植物油。除了降凝剂,植物油和酯交换产品也含有一种性能助剂,其目的在于提高植物油和酯交换产品在用作液压流体,两循环(两冲程)内燃机,齿轮油和客车发动机用油时性能。
美国专利5,399,275(Lange等,1995年3月21日)涉及具有粘度系数改进特征的甘油三酯,其中,甘油三酯油具有有至少60%的单一不饱和成分。含有该粘度改进剂的甘油三酯油可用作客车发动机用油(PCMO)、齿轮油、汽车变速器流体(ATF)、液压流体、链条润滑剂、用于机械操作的导轨润滑剂、柴油机用润滑剂以及拖拉机用流体。
美国专利5,413,725(Lal等,1995年5月9日)涉及具有至少60%的单一不饱和成分以及含有至少一种降凝剂的植物油。除降凝剂外,植物油也可含有一种性能助剂,其目的在于提高植物油和酯交换产品在用作液压流体,两循环(两冲程)内燃机,齿轮油和客车发动机用油时性能。
美国专利5,538,654(Lawate等,1996年7月23日)描述了一种食品等级的润滑剂组合物,该组合物可以用作液压油、齿轮油以及用于食品服务工业设备的压缩机用油。这种组合物包括(A)主要为基因改性的植物油和(B)少量性能助剂。在其它实施例中,该组合物含有(C)一种磷化合物或(D)一种非基因改性的植物油。
美国专利5,641,734(Naegely,1997年7月24日)描述了一种用于链条锯的链条润滑剂的润滑剂组合物,其包括:
(A)至少一种甘油三酯,其中油酸部分:亚油酸部分为约2到约90;
(B)至少一种粘度改进助剂;和
(C)至少一种增粘剂。
可选择地,组合物也可包含
(D)至少一种降凝剂和;
(E)至少一种耐磨剂。
发明内容
一种组合物,包括:
(A)至少一种下式的甘油三酯其中R1、R2和R3是含有约7~约23个碳原子的脂肪烃基;
(B)降凝剂,包括
(1)烷基化聚苯乙烯或
(2)聚烷基甲基丙烯酸酯;和
(D)其它油,其包括:
(1)一种合成酯基油或
(2)一种聚α-烯烃。
具体实施方式(A)甘油三酯油
在本发明的实践中,基油是一种合成的甘油三酯或下式的天然油
其中,R1、R2和R3是含有约7~约23个碳原子的脂肪族烃基。此处使用的“烃基”表示有一个碳原子直连接在分子剩余部分的自由基。脂肪烃基包括如下:
(1)脂肪族烃基;即,烷基如庚基、壬基、十一烷基、十三烷基、十七烷基;含有一个双键的烯烃基如庚烯基、壬烯基、十一烯基、十三烯基、十七烯基、二十一烯基;含有2或3个双键的烯烃基如8,11-十七二烯基和8,11,14-十七三烯基。也包括所有上述物质的异构体,但是优选为直链基。
(2)取代脂肪烃基;即非烃取代基。在本发明中,非烃取代物基没有改变主要的烃基的特性。业内技术人员可以领会到适当的取代物;取代物的例子如羟基、烷氧羰基(carbalkoxy)(特别是低链烷氧羰基carbalkoxy)和烷氧基(特别是低链烷氧基),“低链”表示含有不大于7个碳原子的基团。
(3)杂基,即,在本发明范围内的主要具有脂肪烃特性时,可以在本由脂肪族碳原子组成的链或环上含有非碳的原子。对于业内人士杂原子的选择是比较容易的,如氧、氮和硫。
适合于本发明使用的甘油三酯油是植物油和改性的植物油。植物油甘油三酯是天然产生的油类。“天然产生”意味着是从其中获得油的种子没有经过任何的基因改变。进一步,“天然产生”意味着所获得的油没有进行过改变其双-或三-不饱和特性的氢化处理和任何化学处理。本发明所利用的天然产生的植物油包括至少一种大豆油、油菜籽油、葵花油、椰子油、lesquerella油、芥末油、花生油、玉米油、棉籽油、棕榈油、红花油、meadowfoam或蓖麻油。
甘油三酯油也可以是改性的植物油。甘油三酯油可以通过化学或基因进行改性。对天然产生的甘油三酯的氢化是化学改性的主要方法。天然产生的甘油三酯具有不同的脂肪酸组成。天然产生的葵花油的脂肪酸组成为
棕榈酸 70%
硬脂酸 4.5%
油酸 18.7%
亚油酸 67.5%
亚麻酸 0.8%
其它酸 1.5%
通过氢化方法对葵花油进行化学改性,意味着氢和不饱和脂肪酸如油酸、亚麻酸和亚油酸进行反应。目的不是去掉所有的不饱和键。进一步,其目的并不是氢化油酸组成来而使其还原为硬脂酸组成。通过氢化的化学改性的目的是使亚油酸组成的大部分还原或转化为油酸组成。天然产生的葵花油的亚油酸的含量占67.5%。化学改性的目的是对亚油酸进行氢化而使其含量降低到约25%。这意味着油酸的组成从约18.7%增加到约61%(原来18.7%的油酸组+从亚油酸氢化的42.5%的油酸)。
氢化是植物油和氢气在催化剂存在条件下的反应。最普遍使用的催化剂是镍催化剂。这种处理结果是将氢加成到油上,从而降低了亚油酸和亚麻酸的含量。仅仅不饱和脂肪酸组分参与了氢化反应。在氢化反应中,其他的反应也可能发生,如双键转移到新的位置并且由顺式纽转成具有更高熔点的反式。
表1显示了从天然选择的植物油的油酸(18∶1)、亚油酸(18∶2)和亚麻酸(18∶3)组成。可以通过氢化对甘油三酯的亚油酸组成大部分进行化学改性而使油酸组成提高到60%以上。
表1
油 | 18∶1 | 18∶2 | 18∶3 |
玉米油 | 25.4 | 59.6 | 1.2 |
棉籽油 | 18.6 | 54.4 | 0.7 |
花生油 | 46.7 | 32.0 | -- |
红花油 | 12.0 | 77.7 | 0.4 |
大豆油 | 23.2 | 53.7 | 7.6 |
葵花油 | 18.7 | 67.5 | 0.8 |
基因的改进是对种子储备进行的。丰收的农作物含有一种甘油三酯,其榨取物中具有较高的油酸组成和较低的亚油酸组成时,。参照上面的表1,自然产生的葵花油具有18.7%的油酸。基因改性的葵花油具有81.3%的油酸组成和9.0%的亚油酸。也可以对表1所列的各种植物油进行基因改性来获得大于90%的油酸组成。化学改性的植物油包括至少一种化学改性的玉米油、化学改性的棉籽油、化学改性的花生油、化学改性棕榈油、化学改性蓖麻油、化学改性芥末油、化学改进油菜籽油、化学改进红花油、化学改进大豆油和化学改进葵花油的至少一种。
在优选的实施例中,脂肪族烃基R1、R2和R3是含有至少60%,优选为70%,更优选为80%的单一不饱和性的甘油三脂。在本发明中利用的甘油三酯通过基因改性而含有比一般油酸含量高的植物油来说明。一般的葵花油具有25-30%的油酸含量。通过对葵花种子的基因改性,获得的葵花油中油酸的含量从约60%提高到约90%。也就是说,R1、R2和R3基团是十七烯基,并且R1COO-、R2COO-和R3COO-是连接在1,2,3-丙三基CH2CHCH2上的油酸分子的残余部分。美国专利4,627,192和美国专利4,743,402公开的高油酸葵花油的制备在此一并引入作为参考。
例如,只包括油酸部分的甘油三酯具有100%的油酸含量和因而含有100%的单一性不饱成分。当甘油三酯是由70%的油酸、10%的硬脂酸、13%的棕榈酸和7%的亚油酸组成时,单一性的不饱和成分为70%。优选的甘油三酯油为高油酸,即基因改性的植物油(至少60%)的甘油三酯油。在本发明中,普通利用的高油酸植物油是高油酸红花油、高油酸芥末油、高油酸花生油、高油酸玉米油、高油酸油菜籽油、高油酸葵花油、高油酸棉籽油、高油酸lesquerlla油、高油酸棕榈油、高油酸蓖麻油、高油酸meadowfoam和高油酸大豆油。芥末油是含有1%芥酸的油菜籽油的一类油。优选的高油酸植物油是从Helianthus sp获得的高油酸葵花油。这种产品由AC Humko,Cordova,TN,38018生产如TriSunTM高油酸葵花油得到。另一种高油酸植物油是由Brassica campestris或Brassica napus生产,也由AC Humko生产如RS高油酸芥末油。RS80油表示一种芥末油,其中,其酸的部分含有80%的油酸。
进一步注意,基因改性的植物油具有以双-和三-不饱和酸为代价的高油酸含量。正常的葵花油具有20-40%的油酸部分和50-70%亚油酸部分。这表明正常葵花油单-和双-不饱和部分(20+70)或(40+50)的含量为90%。本发明的基因改性的植物油产生一种低链的双或三-不饱和部分的植物油。本发明的基因改性油的油酸部分:亚油酸的比例为2-90左右。甘油三酯的60%的油酸部分和30%的亚油酸部分的比为2。由80%的油酸部分和10%的亚油酸部分组成的甘油三酯油的比为8。由90%的油酸部分和1%的亚油酸甘油三酯油部分组成的甘油三酯油的比为90。正常花生油的比为0.5(30%的油酸部分和60%的亚油酸部分)。(B)降凝剂
在低温时,植物油存在一种自然变稠现象,特别是具有高度单一不饱性成分的植物油。这类似于在降低温度时蜂蜜或糖蜜的变稠现象。为了维持植物油在降低温度下“倾倒”或“流动”,就需要加入降凝剂。在本发明中的所用的降凝剂是烷化聚苯乙烯和聚甲基丙烯酸烷基酯。
在制备烷化聚苯乙烯时,可有两种不同的反应途径。第一途径是将烷基氯或烯烃与苯乙烯反应形成烷化苯乙烯。然后将烷化苯乙烯聚合形成烷化聚苯乙烯。第二条途径是将苯丙烯聚合形成聚苯乙烯,将丙烯或丁烯或其混和物聚合形成聚丙烯或聚丁烯或其混和物,也叫作聚烯烃。然后将聚苯乙烯与聚烯烃进行烷基化形成烷基化的聚苯乙烯。
在烷化聚苯乙烯类中,优选的降凝剂是Keil-FloTM150,由FerroCorporation-Petroleum Additives,3000 Sheffield Avenue,Hammond,Indiana46327生产。
有本发明中适用的聚烷甲基丙烯酸酯是通过C1-C30的甲基丙烯酸酯的聚合来制得。这些聚合物的制备可以进一步包括使用具有含氮官能团、羟基团和/或烷氧基团的丙烯酸单体,这些基团提供了聚烷甲基丙烯酸酯的其它特性如提高其分散性。聚烷基甲基丙烯酸酯优选为具有从10000-250000,更优选为从20000-200000数均分子量。聚烷基甲基丙烯酸酯也可以通过传统的自由基或阴离子聚合方法来制备。在聚烷基甲基丙烯酸酯类中,优选的降凝剂是RohMax,USA,Delran,NJ 08075生产的EF171。(C)胺类抗氧化剂
如由Goodyear,Akron,OH44316生产的Wingstay@29。
在其它优选胺类抗氧化剂中,R5为氢时,R4一定为芳基。优选烷基具有结构以及该优选的胺类抗氧化剂具有结构
这种结构为苯基-α-萘胺(PANA)。(D)其它油类
本发明的(A)、(B)和(C)组合物可以进一步包括其它油,其包括(D)(1)合成酯基油,(D)(2)聚α-烯烃或(D)(3)未提炼的、提炼的、再提炼的油以及(D)(1)、(D)(2)、(D)(3)两种以上的混和物。合成酯基油(D)(1)包括下列酸与醇的反应,其中,酸包括:下式表示的单羧酸
R8COOH
下式表示的二羧酸
或下式表示的芳基羧酸
R10-Ar(COOH)p
其中,R8为一含有约4-约24个碳原子的羟基,R9为氢或含有约4-约50个碳原子的羟基,R10为氢或含有1-约24个碳原子的羟基,m为从0-约6的整数,p为从1-约4的整数;醇如下式所示,其中,R11为含有1-约24个碳原子的脂肪基或含有6-约18个碳原子的芳基,R12为氢或含有1-约2个碳原子的烷基,t为0-约40,n为1-约6。
在单羧酸中,R8优选为含有约6-约18个碳原子。一个说明但并没有穷举的单羧酸可例举为丁酸、已酸、辛酸、壬酸、癸酸、十一酸、十二酸、棕榈酸或硬脂酸的异构体。
在二羧酸中,R9优选为含有约4-约24个碳原子,m为1-约3的整数。一个说明但并没有穷举的二羧酸可例举为丁二酸、戊二酸、己二酸、庚二酸、辛二酸、壬二酸、癸二酸、顺丁烯二酸或反丁烯二酸。
作为芳基羧酸,R10优选为含有约6-约18个碳原子,p为2。用到的芳基羧酸有安息香酸、甲苯甲酸、乙苯酸、邻苯二甲酸、对苯二甲酸、间苯二甲酸、苯连三酸、三聚酸和均苯四酸。
醇中,R11优选为含有约3-约18个碳原子,t为0-约20。醇可以是单羟基的、多羟基的或者烷氧化的单羟基和多羟基的醇。单羟基的醇可以包括如伯醇或仲醇。然而优选的单羟基醇是一级脂肪醇,特别是脂肪烃醇如烯醇和烷醇。优选的衍生成R11的单羟基醇是1-辛醇、1-癸醇、1-十二醇、1-十四醇、1-十六醇、1-十八醇、油醇、亚油醇、亚麻醇、叶绿醇、十四烷醇、十二烷醇、十四烷醇月桂醇、十六烷醇、十八烷醇、二十二醇。
多羟基醇的例子包括含有2-约6个羟基的醇。例如,烷撑二醇类说明如乙二醇、二乙二醇、三乙二醇、四乙二醇、二丙二醇、三丙二醇、二丁二醇、三丁二醇、和其它烷撑二醇。适合于本发明使用的优选的醇类是含有达到12个碳原子的多羟基醇。这类醇包括丙三醇、赤藓醇、季戊四醇、二季戊四醇、葡萄糖酸、甘油醛、葡萄糖、树胶醛醣、1,7-庚二醇、2,4-庚二醇、1,2,3-已二醇、1,2,4-已二醇、1,2,5-已二醇、2,3,4-已二醇、1,2,3-丁二醇、1,2,4-丁二醇、奎尼酸、2,2,6,6-四(羟甲基)环已醇、1-10-癸二醇、毛地黄烷醇等。
另一些适用于本发明的多羟基醇类为含有3-10碳原子的多羟基醇,特别是含有3-6个碳原子的至少具有三个羟基团的多羟基醇。这种醇的例子如丙三醇、赤藻糖醇、季戊四醇、甘露醇、山梨醇、2-羟甲基-2-甲基-1,3-丙二醇(三甲基丙醇)、双-三羟甲基丙烷、1,2,4-已三醇等。
烷氧化醇可以是烷氧化单羟基醇或烷氧化多羟基醇。烷氧醇一般是由过量的烯化氧处理醇而得到,烯化氧如环氧乙烷或环氧丙烷。例如,可用约6-约40摩尔的环氧乙烷或环氧丙烷可以和脂肪醇进行缩合。
在一个实施例中,脂肪醇含有约14-约24个碳原子,其可以从长链脂肪醇如十八醇或油醇衍生。
与羧酸反应来制备合成酯所用的烷氧醇在商业上可以获得,如UnionCarbide的“TRITON”和“TERGITOL”,Vista Chemical的“ALFONIC”,Shell Chemical Company的“NEODOL”。TRITON一般为聚乙氧化烷基苯酚,这些酚可以从直链或支链烷基苯酚衍生。TERGITOL为伯醇或仲醇的聚乙二醇醚类;ALFONIC为乙氧化的线性醇相同,其可以用一般的结构
CH3(CH2)xCH2(OCH2CH2)nOH表示,其中x取4-16的值,n取3-11之间的值。具有上式特性的ALFONIC乙氧化物的具体例子包括ALFONIC1012-60,其中,x为约8-10,n为约为5.7的平均值;ALFONIC1012-70,其中,x为10-12,n为约为10.6的平均值;ALFONIC1412-60,其中,x为10-12,n为约为7的平均值;以及ALFONIC1218-70,其中,x为10-16,n为约为10.7的平均值;
NEODOL乙氧化物为乙氧化醇,其中醇类为含有9-约15个碳原子的线性和支链醇类的混和物。乙氧化物可以通过醇类和过量的环氧乙烯反应来制备,如每摩尔的醇与3-12摩尔或更多的环氧乙烯反应。例如,NEODOL乙氧化物23-6.5是一种含有12-13个碳原子以及含有平均约6.5个单元的乙氧单元的线性或支链醇化物的混和物。
如上所述,合成酯基油包括将上述任意酸或其混和物与上述任意醇或其混和物以1个COOH比1个OH的比例进行酯化反应,该反应利用了现有技术的酯化工序、条件和催化剂。
生产合成酯的公司和其商品名的非穷举例子为BASF的Glissofluild,Ciba-Geigy的Reolube,JCI的Emkarote,Oleofina的Radialube以及EmeryGroup of Henkel Coporation的Emery。
聚α-烯烃类(D)(2)如烯化氧聚合物和内聚合物及其衍生物,其中端羟烃基已经通过酯化或醚化等改性变成了另一类可以使用的油。这些可以通过环氧乙烯或环氧丙烯所制得的油类说明,这些聚氧化烯聚合物(如具有约1000的平均分子量的甲基聚异丙烯乙二醚,具有500-1000分子量聚乙二醇二苯醚,具有1000-1500分子量的聚丙二醇二乙基醚等)或者其的单-及聚羧酸酯如乙酸乙酯,C3到C8脂肪酸酯混合物,或四乙二醇的C13含氧酸二酯。
未提炼的、提炼的、再提炼的油(D)(3)以及它们中的两种或者多种的混合物可以作为本发明的润滑剂组合物。未提炼的油是直接从天然或合成来源获得的,没有进行进一步的提纯处理。例如,直接从干馏操作中获得的页岩油、直接通过蒸馏获得的石油、成品油,直接经过酯化处理获得的酯油以及没有经过处理所使用的物质是未提炼油。提炼的油与未提炼的油除了在经过一次或多次提纯步骤提高一项或多项特性之外,其它的特性相同。对于业内人士来说,已知的许多提纯技术,如蒸馏、溶剂萃取、酸或碱萃取、过滤以及渗透的方法。再提炼的油是通过使用类似于得到提炼油的提炼方法而获得的,该方法是应用于已经被使用的提炼油。这种再提炼油也被称作回收或再加工油,并且通常通过其它技术处理来去掉失效的助剂和油分解产物。
本发明的组合物包括组份(A)、(B)和(C)或者(A)、(B)、(C)和(D),其用作可生物降解的润滑剂。
当组合物包括组份(A)、(B)和(C)时,下面表明了这些组份的重量范围。
组份 | 一般 | 优选 | 更优选 |
(A) | 50-99 | 65-99 | 90-99 |
(B) | 0.1-5 | 0.5-4 | 0.75-3 |
(C) | 0.1-5 | 0.1-3 | 0.1-2 |
当组份包括组份(A)、(B)、(C)和(D)时,下面表明了这些组份的重量范围。
组份 | 一般 | 优选 | 更优选 |
(A) | 40-90 | 40-80 | 45-75 |
(B) | 0.1-5 | 0.5-4 | 0.75-3 |
(C) | 0.1-5 | 0.1-3 | 0.1-2 |
(D) | 1-80 | 10-60 | 25-50 |
可以理解,除了(A)、(B)、(C)和(D),还可以有其它组份包含在本发明的组合物里。
本发明的组份根据上述范围混合得到溶液。虽然加入的顺序没有要求,但一般是将(B)和(C)或(B)、(C)和(D)加到(A)中。
表2是一个旋转弹内氧化试验(RBOT)(ASTM D2272)的比较。在表2中,例1和例2是100%植物油组合物的基准。其它的例子含有不同量的其它助剂。例5-7介绍了本发明和剩余的例子,它们虽不属于本发明,但可以与例5-7进行比较。在三个例子中,非本发明的例子(11-13)最好与例子5-7比较。这是由于例11和13利用了本发明的组份,还有例12是一种矿物油配方而不是植物油配方。对在全新配制的例子中,可以注意到RBOT的改进。所有的均以重量份来计算的。
a:2,6-二叔丁酚b:无烟酚类抗氧化剂c:含有Lubrizol Corp生产的如LZ5186B耐磨剂和抗氧化剂的完整液压组件d:含有Lubrizol Corp生产的如LZ7653耐磨剂和抗氧化剂和降凝剂的完整商业液压组件e:Rhein Chemie生产如AdditinRC 9308的防锈和抗氧化剂f:烷基化二苯胺g:丁基化羟基甲苯h:一种含有硫或磷的有机化学助剂的耐磨剂/抗氧化剂i:二硫代氨基甲酸酯j:甲苯基三唑烷k:Ciba Geigy生产的如Irganox L 135的液态酚类抗氧化剂l:对甲酚和二环戊二烯的丁基化反应产物
表2 | |||||
实施例 | 组份 | ||||
(A) | (B) | (C) | (D) | RBOT | |
1 | 100份TriSun90 | 无 | 无 | 无 | 16 |
2 | 100份RS 80 | 无 | 无 | 无 | 14 |
3 | 98.0份TriSun 90+2.0份a | 无 | 无 | 无 | 131 |
4 | 98.0份TriSun 90+2.0份b | 无 | 无 | 无 | 138 |
5 | 28.66份TriSun 90+28.66份RS 80 | 1.28份Keil Flo 150 | 0.3份Wingstay 290.3份PANA | 20.04份PAO20.04份合成酯 | 261 |
6 | 33.73份TriSun 90+33.73份RS 80 | 1.52份Keil Flo 150 | 0.35份Wingstay 290.35份PANA | 15.16份PAO15.16份合成酯 | 273 |
7 | 67.08份TriSun 90 | 2.03份Keil Flo 150 | 0.26份Wingstay 290.26份PANA | 15.25份PAO15.25份合成酯 | 402 |
8 | 98.75份TriSun 90+1.25份c | 无 | 无 | 无 | 147 |
9 | 67.2份TriSun 90+4.0份d | 无 | 无 | 28.8份合成酯 | 197 |
10 | 96.0份RS 80+4.0份d | 无 | 无 | 无 | 139 |
11 | 98.27份TriSun 90+1.0份d | 无 | 0.365份Wingstay290.365份PANA | 无 | 276 |
12 | 98.75.2份矿物油+1.25份c | 无 | 无 | 无 | 262 |
13 | 48.17份RS80+1.25份c | 2.0份Keil Flo 150 | 0.205份Wingstay290.205份PANA | 48.17份再提炼油 | 237 |
表2 | |||||
实施例 | 组份 | ||||
(A) | (B) | (C) | (D) | RBOT | |
14 | 99份TriSun 90+1.0份e | 无 | 无 | 无 | 97 |
15 | 98份TriSun90+0.65份f,0.35份g,0.85份h | 无 | 无 | 无 | 104 |
16 | 97.8份TriSun90+1.4份f,0.8份g | 无 | 无 | 无 | 61 |
17 | 98.15TriSun90+0.2份i,0.4份j,1.25份c | 无 | 无 | 无 | 94 |
18 | 98.0份TriSun90+1.0份b,1.0份g | 无 | 无 | 无 | 110 |
19 | 98.15TriSun90+0.65份f,0.35份g,0.85份h | 无 | 无 | 无 | 104 |
20 | 98.6份TriSun90+0.5份j,0.9份k | 无 | 无 | 无 | 108 |
21 | 98.65份TriSun90+0.9份j,0.32份k | 无 | 无 | 无 | 115 |
22 | 98.15份TriSun90+0.3份j,0.3份k,1.25份c | 无 | 无 | 无 | 149 |
23 | 98.15份TriSun90+0.3份j,0.3份l,1.25份c | 无 | 无 | 无 | 128 |
表3介绍了一种微型旋转粘度计(MRV)(ASTM D4684)。MRV是一种低剪切速率测量仪器。该仪器的关键特征为测试慢的样品冷却速率。对样品预热以使其包含一个具体的加热、缓慢冷却、均温的循环的热记录,其包括。MRV测量表观屈服应力,这个应力是使油流动的最小应力。MRV也测量在1到50s-1剪切速率下的表观粘度。该过程可被发展为用于预测野外使用马达的低温泵流性。
为了测量低温特性,在多个不同温度下对本发明的组合物进行评价。例如,当评价的温度为-25℃时,表示了15个冬用级规格。下面温度表示其对应的粘度级。
-40℃ 0W
-35 5
-30 10
-25 15
-20 20
-15 25
无论组合物在什么温度下测量时,如果要要符合要求,则粘度测量值必须低于6000,厘泊(cP),并且该cP越低越好。MRV是一种比标准倾点程序(ASTMD97)更严格的评价。
在表3中,例1和2是100%植物油组合物的基准。在-25℃时,例1和2太粘稠而不能测量(TVTM),结果不合格。其它的例子含有不同量的其他助剂。例3-6是含有降凝剂的植物油,这些降凝剂并不是本发明的部分。例3-6所有的都太粘稠而不能测量,结果不合格。例7-13是包括本发明的降凝剂的植物油组合物。例7-13不仅显示了MRV测量的合格结果,而且粘度也均很好的低于6000cP这一合格/不合格的分界点。
*太粘稠而不能测量m由Lubrizol Corp生产的LZ6662矿物油中顺丁烯二酐-苯乙烯共聚合物的酯n由Lubrizol Corp生产的LZ7671矿物油中顺丁烯二酐-苯乙烯共聚合物的酯。
表3 | ||||||
实施例 | 组份 | |||||
(A) | (B) | (C) | (D) | cP | ℃ | |
1 | 100份TriSun90 | 无 | 无 | 无 | TVTM* | -15 |
2 | 100份RS80 | 无 | 无 | 无 | TVTM | -20 |
3 | 98.0份RS80+2.0份m | 无 | 无 | 无 | TVTM | -25 |
4 | 34份TriSun9034份RS80+2份n | 无 | 无 | 30份合成酯 | TVTM | -30 |
5 | 34份TriSun90+34份RS80+2份m | 无 | 无 | 30份合成酯 | TVTM | -25 |
6 | 68份TriSun90+2份n | 无 | 无 | 30份合成酯 | TVTM | -25 |
7 | 98份RS 80 | 2份Keil Flo 150 | 无 | 无 | 1864 | -25 |
8 | 68份高油酸大豆油 | 2份Keil Flo 150 | 无 | 30份合成酯 | 9089 | -30 |
9 | 68份TriSun90 | 2份Keil Flo 150 | 无 | 30份合成酯 | 1861 | -25 |
10 | 68份TriSun90 | 2份RohMax10-310 | 无 | 30份合成酯 | 19482730 | -25-30 |
11 | 34份TriSun90+34份RS80 | 2份Keil Flo 150 | 无 | 30份合成酯 | 15312687 | -25-30 |
12 | 34份Trisun90+34份RS80 | 2份RohMas10-310 | 无 | 30份合成酯 | 15762581 | -25-30 |
13 | 98份RS80+ | 2份RohMax10-310 | 无 | 无 | 17913438 | -25-30 |
尽管以上优选的实施例对本发明作了解释,但可以理解在业内人士通过阅读说明书后是容易对其进行各种改进的。因此,这里公开的本发明就是要覆盖这样的改进以使其落入本发明的权利要求范围内。
Claims (20)
2.根据权利要求1的组合物,其中在(A)中,甘油三酯油是一种天然产生的植物油。
3.根据权利要求1的组合物,其中在(A)中,甘油三酯油是一种改性的植物油。
4.根据权利要求2的组合物,其中天然产生的植物油包括至少一种大豆油、油菜籽油、葵花油、椰子油、lesquerella油、芥末油、花生油、玉米油、棉籽油、棕榈油、红花油、meadowfoam或蓖麻油。
5.根据权利要求3的组合物,其中,改性植物油是一种化学改性植物油或一种基因改性植物油。
6.根据权利要求5的组合物,其中,R1、R2和R3具有由油酸残余部分衍生的含有至少60%的单一性不饱和成分。
7.根据权利要求6的组合物,其中,化学改性的植物油包括化学改性的玉米油、化学改性的棉籽油、化学改性的花生油、化学改性的棕榈油、化学改性的蓖麻油、化学改性的芥末油、化学改性的油菜籽油、化学改性的红花油、化学改性的大豆油和化学改进葵花油的至少一种。
8.根据权利要求6的组物,其中,基因改性的植物油包括基因改性的红花油、基因改性的芥末油、基因改性的花生油、基因改性的玉米油、基因改性的油菜籽油、基因改性的葵花油、基因改性的棉籽油、基因改性的lesquerlla油、基因改性的棕榈油、基因改性的蓖麻油、基因改性的meadowfoam油和基因改芥末大豆油中的至少一种。
9.根据权利要求1的组合物,其中在(B)中,降凝剂是一种烷基化的聚苯乙烯。
10.根据权利要求1的组合物,其中在(C)中,R5和R6是烷芳基,其中的烷芳基是R7是含有1-4个碳原子的脂肪族基。
11.根据权利要求10的组合物,其中,R7含2个碳原子。
13.根据权利要求1的组合物,其中在(C)中,R5为氢,R4是α-萘基。
14.根据权利要求1的组合物进一步包括:
(D)其它油,其包括:
(1)一种合成酯基油或
(2)一种聚α-烯烃。
16.根据权利要求15的组合物,其中R8含有约6-约18个碳原子。
17.根据权利要求15的组合物,其中R9含有约4-约24个碳原子,m为0。
18.根据权利要求15的组合物,其中R9为氢,m为4。
19.根据权利要求15的组合物,其中R10含有约6-18个碳原子,p为2。
20.根据权利要求15的组合物,其中R11含有约3-约18个碳原子。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/605,324 | 2000-06-28 | ||
US09/605,324 US6383992B1 (en) | 2000-06-28 | 2000-06-28 | Biodegradable vegetable oil compositions |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1439045A true CN1439045A (zh) | 2003-08-27 |
CN1188502C CN1188502C (zh) | 2005-02-09 |
Family
ID=24423187
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB018118666A Expired - Lifetime CN1188502C (zh) | 2000-06-28 | 2001-06-28 | 可生物降解的植物油组合物 |
Country Status (8)
Country | Link |
---|---|
US (1) | US6383992B1 (zh) |
EP (1) | EP1294833A2 (zh) |
JP (1) | JP4004403B2 (zh) |
CN (1) | CN1188502C (zh) |
AU (2) | AU7156501A (zh) |
BR (1) | BR0112081A (zh) |
MX (1) | MXPA03000091A (zh) |
WO (1) | WO2002000815A2 (zh) |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101892111A (zh) * | 2010-07-19 | 2010-11-24 | 黑龙江省大豆技术开发研究中心 | 一种润滑油基础油 |
CN101984806A (zh) * | 2010-07-22 | 2011-03-16 | 福建诺德生物科技有限责任公司 | 含有萜类的植物油组合物及其应用 |
CN102812114A (zh) * | 2010-03-31 | 2012-12-05 | 出光兴产株式会社 | 具有难燃性能的生物降解性润滑油组合物 |
US8778034B2 (en) | 2006-09-14 | 2014-07-15 | Afton Chemical Corporation | Biodegradable fuel performance additives |
CN104031726A (zh) * | 2014-06-29 | 2014-09-10 | 柳州美纳机械有限公司 | 薄板冲压拉深润滑油的制备方法 |
TWI465561B (zh) * | 2007-04-25 | 2014-12-21 | Dow Global Technologies Llc | 潤滑劑摻合物組成物 |
CN102766483B (zh) * | 2005-06-10 | 2016-01-06 | 马来西亚棕榈油总署 | 基于棕榈的生物柴油制剂 |
CN107541307A (zh) * | 2017-08-31 | 2018-01-05 | 青岛中科润美润滑材料技术有限公司 | 一种植物油基胺类抗氧化添加剂及其制备方法 |
CN108026467A (zh) * | 2015-08-14 | 2018-05-11 | 范德比尔特化学品有限责任公司 | 改善的抗氧化剂组合物和含有所述抗氧化剂组合物的润滑组合物 |
CN111635799A (zh) * | 2020-05-15 | 2020-09-08 | 清华大学 | 润滑油组合物及其用途 |
CN113444562A (zh) * | 2021-06-22 | 2021-09-28 | 道骐科技有限公司 | 一种功能润滑油及其制备方法 |
Families Citing this family (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6531430B1 (en) * | 1995-06-06 | 2003-03-11 | James W. Lambert | Engines lubricated with vegetable oil lubricants |
FR2809116B1 (fr) * | 2000-05-19 | 2002-08-30 | Usinor | Utilisation d'une composition huileuse pour le traitement temporaire des surfaces metalliques |
US6534454B1 (en) * | 2000-06-28 | 2003-03-18 | Renewable Lubricants, Inc. | Biodegradable vegetable oil compositions |
US6803351B2 (en) * | 2001-06-20 | 2004-10-12 | Frank J. Popelar | Biodegradable machine tool coolant |
US20040241309A1 (en) * | 2003-05-30 | 2004-12-02 | Renewable Lubricants. | Food-grade-lubricant |
CN1823154B (zh) * | 2003-05-30 | 2014-03-26 | 可再生润滑油有限公司 | 改良的食品级润滑剂 |
US7585990B2 (en) * | 2003-07-31 | 2009-09-08 | Cargill, Incorporated | Low trans-fatty acid fat compositions; low-temperature hydrogenation, e.g., of edible oils |
WO2005012471A2 (en) * | 2003-07-31 | 2005-02-10 | Cargill, Incorporated | Low trans-fatty acid fat compositions; low-temperature hydrogenation, e.g., of edible oils |
US20060211585A1 (en) * | 2003-09-12 | 2006-09-21 | Renewable Lubricants, Inc. | Vegetable oil lubricant comprising Fischer Tropsch synthetic oils |
MXPA06002862A (es) * | 2003-09-12 | 2006-06-14 | Renewable Lubricants Inc | Lubricante de aceite vegetal que comprende aceites sinteticos completamente hidroprocesados. |
US8058217B2 (en) * | 2003-12-25 | 2011-11-15 | Nippon Oil Corporation | Metal working fluid |
DE102004009895B3 (de) * | 2004-02-26 | 2005-07-21 | Cognis Deutschland Gmbh & Co. Kg | Gleitmittelkombinationen |
US20060105920A1 (en) * | 2004-11-16 | 2006-05-18 | Dalman David A | Performance-enhancing additives for lubricating oils |
CN101218331B (zh) * | 2005-04-26 | 2013-04-24 | 可再生润滑油有限公司 | 含氮化硼的高温生物润滑剂组合物 |
US20070010607A1 (en) * | 2005-06-24 | 2007-01-11 | Smith Kim R | Surface treatment composition and method for treating a surface |
US20080163542A1 (en) * | 2007-01-08 | 2008-07-10 | Innospec, Inc. | Synergistic fuel composition for enhancing fuel cold flow properties |
CN102027056B (zh) | 2008-05-15 | 2013-09-18 | 巴斯夫欧洲公司 | 用于乳液聚合的橡胶的基本稳定体系 |
US20100216678A1 (en) * | 2009-02-24 | 2010-08-26 | Abhimanyu Onkar Patil | Lubricant compositions containing glycerol tri-esters |
WO2011037778A1 (en) | 2009-09-24 | 2011-03-31 | Dow Global Technologies Inc. | Estolide compositions having excellent low temperature properties |
EP2828351A4 (en) | 2012-03-19 | 2015-12-02 | David W Sugg | Plant oils, vegetable oil mixtures and methods of use thereof |
US9879197B2 (en) | 2012-03-19 | 2018-01-30 | Edward A. Sugg | Vegetable oils, vegetable oil blends, and methods of use thereof |
WO2014040919A1 (en) | 2012-09-13 | 2014-03-20 | Evonik Oil Additives Gmbh | A composition to improve low temperature properties and oxidation stability of vegetable oils and animal fats |
US10190067B2 (en) * | 2016-02-24 | 2019-01-29 | Washington State University | High performance environmentally acceptable hydraulic fluid |
CN110157519B (zh) * | 2019-05-22 | 2022-02-01 | 西安石油大学 | 用大豆油和丙烯酸酯类共聚的润滑油降凝剂及其制备方法 |
CN111378518A (zh) * | 2020-03-02 | 2020-07-07 | 上海宝山大陆汽车配件股份有限公司 | 一种汽车底盘冲压件用润滑油 |
CN112175697A (zh) * | 2020-09-14 | 2021-01-05 | 克拉玛依市贝德化工有限责任公司 | 一种严寒区抽油机用润滑油 |
TWI836410B (zh) * | 2022-04-25 | 2024-03-21 | 國立成功大學 | 以植物油為基底而在使用時可自形成摩擦膜的潤滑油 |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1354749A (en) * | 1971-07-14 | 1974-06-05 | Exxon Research Engineering Co | Palm oil compositions |
FI66899C (fi) | 1983-02-11 | 1984-12-10 | Kasvisoeljy Vaextolje Ab Oy | Smoerjmedel med triglycerider som huvudkomponent |
WO1993003123A1 (en) | 1991-08-09 | 1993-02-18 | The Lubrizol Corporation | Functional fluid with triglycerides, detergent-inhibitor additives and viscosity modifying additives |
US5641734A (en) | 1991-10-31 | 1997-06-24 | The Lubrizol Corporation | Biodegradable chain bar lubricant composition for chain saws |
US5399275A (en) | 1992-12-18 | 1995-03-21 | The Lubrizol Corporation | Environmentally friendly viscosity index improving compositions |
US5413725A (en) | 1992-12-18 | 1995-05-09 | The Lubrizol Corporation | Pour point depressants for high monounsaturated vegetable oils and for high monounsaturated vegetable oils/biodegradable base and fluid mixtures |
US5338471A (en) | 1993-10-15 | 1994-08-16 | The Lubrizol Corporation | Pour point depressants for industrial lubricants containing mixtures of fatty acid esters and vegetable oils |
DE69524038T2 (de) * | 1994-10-12 | 2003-04-24 | Rohmax Additives Gmbh | Zusatz für Schmieröl |
BR9504838A (pt) * | 1994-11-15 | 1997-10-07 | Lubrizol Corp | Ester de poliol composição de óleo lubrificante |
US5538654A (en) | 1994-12-02 | 1996-07-23 | The Lubrizol Corporation | Environmental friendly food grade lubricants from edible triglycerides containing FDA approved additives |
WO1996025474A1 (en) * | 1995-02-14 | 1996-08-22 | Kao Corporation | Biodegradable lubricating base oil, lubricating oil composition containing the same and use thereof |
US5990055A (en) * | 1996-05-15 | 1999-11-23 | Renewable Lubricants, Inc. | Biodegradable lubricant composition from triglycerides and oil soluble antimony |
-
2000
- 2000-06-28 US US09/605,324 patent/US6383992B1/en not_active Expired - Lifetime
-
2001
- 2001-06-28 JP JP2002505931A patent/JP4004403B2/ja not_active Expired - Lifetime
- 2001-06-28 BR BR0112081-6A patent/BR0112081A/pt not_active Application Discontinuation
- 2001-06-28 CN CNB018118666A patent/CN1188502C/zh not_active Expired - Lifetime
- 2001-06-28 AU AU7156501A patent/AU7156501A/xx active Pending
- 2001-06-28 WO PCT/US2001/020576 patent/WO2002000815A2/en active IP Right Grant
- 2001-06-28 AU AU2001271565A patent/AU2001271565B2/en not_active Expired
- 2001-06-28 EP EP01950591A patent/EP1294833A2/en not_active Ceased
- 2001-06-28 MX MXPA03000091A patent/MXPA03000091A/es active IP Right Grant
Cited By (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102766483B (zh) * | 2005-06-10 | 2016-01-06 | 马来西亚棕榈油总署 | 基于棕榈的生物柴油制剂 |
CN101144039B (zh) * | 2006-09-14 | 2016-02-10 | 雅富顿公司 | 可生物降解汽油性能添加剂 |
US8778034B2 (en) | 2006-09-14 | 2014-07-15 | Afton Chemical Corporation | Biodegradable fuel performance additives |
US9562498B2 (en) | 2006-09-14 | 2017-02-07 | Afton Chemical Corporation | Biodegradable fuel performance additives |
TWI465561B (zh) * | 2007-04-25 | 2014-12-21 | Dow Global Technologies Llc | 潤滑劑摻合物組成物 |
CN102812114A (zh) * | 2010-03-31 | 2012-12-05 | 出光兴产株式会社 | 具有难燃性能的生物降解性润滑油组合物 |
CN101892111A (zh) * | 2010-07-19 | 2010-11-24 | 黑龙江省大豆技术开发研究中心 | 一种润滑油基础油 |
CN101984806A (zh) * | 2010-07-22 | 2011-03-16 | 福建诺德生物科技有限责任公司 | 含有萜类的植物油组合物及其应用 |
CN101984806B (zh) * | 2010-07-22 | 2012-11-21 | 福建诺德生物科技有限责任公司 | 含有萜类的植物油组合物及其应用 |
CN104031726A (zh) * | 2014-06-29 | 2014-09-10 | 柳州美纳机械有限公司 | 薄板冲压拉深润滑油的制备方法 |
CN108026467A (zh) * | 2015-08-14 | 2018-05-11 | 范德比尔特化学品有限责任公司 | 改善的抗氧化剂组合物和含有所述抗氧化剂组合物的润滑组合物 |
CN107541307A (zh) * | 2017-08-31 | 2018-01-05 | 青岛中科润美润滑材料技术有限公司 | 一种植物油基胺类抗氧化添加剂及其制备方法 |
CN107541307B (zh) * | 2017-08-31 | 2020-02-14 | 青岛中科润美润滑材料技术有限公司 | 一种植物油基胺类抗氧化添加剂及其制备方法 |
CN111635799A (zh) * | 2020-05-15 | 2020-09-08 | 清华大学 | 润滑油组合物及其用途 |
CN113444562A (zh) * | 2021-06-22 | 2021-09-28 | 道骐科技有限公司 | 一种功能润滑油及其制备方法 |
CN113444562B (zh) * | 2021-06-22 | 2022-03-11 | 道骐科技有限公司 | 一种功能润滑油及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
CN1188502C (zh) | 2005-02-09 |
US6383992B1 (en) | 2002-05-07 |
JP2004502023A (ja) | 2004-01-22 |
WO2002000815A3 (en) | 2002-05-30 |
WO2002000815A2 (en) | 2002-01-03 |
BR0112081A (pt) | 2003-09-02 |
MXPA03000091A (es) | 2003-09-25 |
EP1294833A2 (en) | 2003-03-26 |
AU2001271565B2 (en) | 2004-11-18 |
AU7156501A (en) | 2002-01-08 |
JP4004403B2 (ja) | 2007-11-07 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN1188502C (zh) | 可生物降解的植物油组合物 | |
AU2001271565A1 (en) | Biodegradable vegetable oil compositions | |
US6534454B1 (en) | Biodegradable vegetable oil compositions | |
CN103620008B (zh) | 具有高氧化稳定性的交内酯组合物 | |
US8168572B2 (en) | Lubricant blend composition | |
CN1057113C (zh) | 可生物降解的双循环发动机油组合物的酯基料 | |
CN101589132B (zh) | 包含环氧化酯和天冬氨酸衍生物的润滑油组合物 | |
CN1173195A (zh) | 可生物降解的支化合成酯基本原料和由其形成的润滑剂 | |
US20100105583A1 (en) | High temperature biobased lubricant compositions from boron nitride | |
CN102171320A (zh) | 用于传动装置的润滑组合物 | |
EP0747466A1 (en) | Vegetable oils containing styrene/butadiene copolymers in combination with additional commercial polymers that have good low temperature and high temperature viscometrics | |
CN1261551C (zh) | 减少烟雾生成的二冲程发动机润滑油 | |
JP3807743B2 (ja) | 2サイクル潤滑油 | |
JP3283206B2 (ja) | ギヤー油組成物 | |
US10577557B2 (en) | Fluid with polyalkylene glycol and unsaturated ester | |
JP3944999B2 (ja) | 生分解性潤滑油 | |
JP2022531533A (ja) | ポリアルキレングリコール潤滑剤組成物 | |
MX2007013347A (es) | Composiciones lubricantes de biobase de alta temperatura que comprenden nitruro de boro |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CX01 | Expiry of patent term |
Granted publication date: 20050209 |
|
CX01 | Expiry of patent term |